Gorjanović, Stanislava

Link to this page

Authority KeyName Variants
orcid::0000-0003-3676-5892
  • Gorjanović, Stanislava (24)
Projects
Content of bioactive components in small and stone fruits as affected by cultivar specificities and growing conditions, and obtaining biologically valuable products by improved and newly developed technologies Modulation of antioxidative metabolism in plants for improvement of plant abiotic stress tolerance and identification of new biomarkers for application in remediation and monitoring of degraded biotopes
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200051 (Institute of General and Physical Chemistry, Belgrade) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200168 (University of Belgrade, Faculty of Chemistry)
Natural products of wild, cultivated and edible plants: structure and bioactivity determination Bioactive natural products as potential sources of new pharmaceuticals and food supplements
Regulacija antioksidativnog metabolizma biljaka u toku rastenja, infekcije patogenima i delovanja abiotičkog stresa: mehanizmi transporta, signalizacije i otpornosti Osmotic dehydration of food - energy and ecological aspects of sustainable production
Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200023 (Institute of Technology of Nuclear and Other Mineral Row Materials - ITNMS, Belgrade) Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM)
Novel encapsulation and enzyme technologies for designing of new biocatalysts and biologically active compounds targeting enhancement of food quality, safety and competitiveness Molekularne karakteristike kancera
Ministry of Science, Education and Sports, Republic of Croatia [058-0000000-3470]

Author's Bibliography

2 in 1 versus 1 plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination

Pastor, Ferenc T.; Dojčinović, Biljana P.; Kodranov, Igor D.; Gorjanović, Stanislava; Ivanović, Tijana; Popović, Daniela Ž.; Miladinović, Jelena

TY  - JOUR
AU  - Pastor, Ferenc T.
AU  - Dojčinović, Biljana P.
AU  - Kodranov, Igor D.
AU  - Gorjanović, Stanislava
AU  - Ivanović, Tijana
AU  - Popović, Daniela Ž.
AU  - Miladinović, Jelena
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6390
AB  - Due to the similar chemical properties of Ni2+ and Co2+, several dozens of adsorptive stripping voltammetric (AdSV) methods have been developed for their simultaneous determination. The question was would there be some benefits if a stripping method made for simultaneous determination of Ni2+ and Co2+ will be optimized for the determination of only one of them (Ni2+). It was found that the optimized method has for an order of magnitude lower LOQ (1.89×10−10 M), an order of magnitude lower influence of Co2+, and the applicability of one calibration line for four orders of magnitude of Ni2+ concentration. The influence of some common anions and cations has been examined. The developed method was successfully applied for nickel content determination in real samples. The suitability of the developed method for the determination of Co2+ from the same solution in the second run, upon optimizations of deposition potential and time, was also explored. The LOQ obtained for Co2+ (3.61×10−11 M) is almost two orders of magnitude lower than LOQ of the method for simultaneous determination of both cations and, its LOD and LOQ are among few lowest obtained by AdSV methods for Co2+ determination. The developed method for Ni2+ and Co2+ determination from the same solution in two successive runs has significantly better analytical performances than the starting method for their simultaneous determination in one run.
PB  - Wiley
T2  - Electroanalysis
T1  - 2 in 1 versus 1 plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination
VL  - n/a
IS  - n/a
SP  - e202300259
DO  - 10.1002/elan.202300259
ER  - 
@article{
author = "Pastor, Ferenc T. and Dojčinović, Biljana P. and Kodranov, Igor D. and Gorjanović, Stanislava and Ivanović, Tijana and Popović, Daniela Ž. and Miladinović, Jelena",
abstract = "Due to the similar chemical properties of Ni2+ and Co2+, several dozens of adsorptive stripping voltammetric (AdSV) methods have been developed for their simultaneous determination. The question was would there be some benefits if a stripping method made for simultaneous determination of Ni2+ and Co2+ will be optimized for the determination of only one of them (Ni2+). It was found that the optimized method has for an order of magnitude lower LOQ (1.89×10−10 M), an order of magnitude lower influence of Co2+, and the applicability of one calibration line for four orders of magnitude of Ni2+ concentration. The influence of some common anions and cations has been examined. The developed method was successfully applied for nickel content determination in real samples. The suitability of the developed method for the determination of Co2+ from the same solution in the second run, upon optimizations of deposition potential and time, was also explored. The LOQ obtained for Co2+ (3.61×10−11 M) is almost two orders of magnitude lower than LOQ of the method for simultaneous determination of both cations and, its LOD and LOQ are among few lowest obtained by AdSV methods for Co2+ determination. The developed method for Ni2+ and Co2+ determination from the same solution in two successive runs has significantly better analytical performances than the starting method for their simultaneous determination in one run.",
publisher = "Wiley",
journal = "Electroanalysis",
title = "2 in 1 versus 1 plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination",
volume = "n/a",
number = "n/a",
pages = "e202300259",
doi = "10.1002/elan.202300259"
}
Pastor, F. T., Dojčinović, B. P., Kodranov, I. D., Gorjanović, S., Ivanović, T., Popović, D. Ž.,& Miladinović, J..2 in 1 versus 1 plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination. in Electroanalysis
Wiley., n/a(n/a), e202300259.
https://doi.org/10.1002/elan.202300259
Pastor FT, Dojčinović BP, Kodranov ID, Gorjanović S, Ivanović T, Popović DŽ, Miladinović J. 2 in 1 versus 1 plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination. in Electroanalysis.n/a(n/a):e202300259.
doi:10.1002/elan.202300259 .
Pastor, Ferenc T., Dojčinović, Biljana P., Kodranov, Igor D., Gorjanović, Stanislava, Ivanović, Tijana, Popović, Daniela Ž., Miladinović, Jelena, "2 in 1 versus 1 plus 1 – Outcomes of the transformation of adsorptive stripping method for the Ni2+ and Co2+ determination" in Electroanalysis, n/a, no. n/a:e202300259,
https://doi.org/10.1002/elan.202300259 . .
1

Recovery of Biologically Active Compounds from Stinging Nettle Leaves Part II: Processing of Exhausted Plant Material after Supercritical Fluid Extraction

Zeković, Zoran P.; Smyatskaya, Yulia A.; Bazarnova, Julia G.; Pastor, Ferenc; Gorjanović, Stanislava; Gašić, Uroš M.; Pezo, Lato; Đurović, Saša

(MDPI, 2023)

TY  - JOUR
AU  - Zeković, Zoran P.
AU  - Smyatskaya, Yulia A.
AU  - Bazarnova, Julia G.
AU  - Pastor, Ferenc
AU  - Gorjanović, Stanislava
AU  - Gašić, Uroš M.
AU  - Pezo, Lato
AU  - Đurović, Saša
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5886
AB  - Stinging nettle (Urtica dioica L.) is one fantastic plant widely used in folk medicine, pharmacy, cosmetics, and food. This plant’s popularity may be explained by its chemical composition, containing a wide range of compounds significant for human health and diet. This study aimed to investigate extracts of exhausted stinging nettle leaves after supercritical fluid extraction obtained using ultrasound and microwave techniques. Extracts were analyzed to obtain insight into the chemical composition and biological activity. These extracts were shown to be more potent than those of previously untreated leaves. The principal component analysis was applied as a pattern recognition tool to visualize the antioxidant capacity and cytotoxic activity of extract obtained from exhausted stinging nettle leaves. An artificial neural network model is presented for the prediction of the antioxidant activity of samples according to polyphenolic profile data, showing a suitable anticipation property (the r2 value during the training cycle for output variables was 0.999).
PB  - MDPI
T2  - Foods
T1  - Recovery of Biologically Active Compounds from Stinging Nettle Leaves Part II: Processing of Exhausted Plant Material after Supercritical Fluid Extraction
VL  - 12
IS  - 4
SP  - 809
DO  - 10.3390/foods12040809
ER  - 
@article{
author = "Zeković, Zoran P. and Smyatskaya, Yulia A. and Bazarnova, Julia G. and Pastor, Ferenc and Gorjanović, Stanislava and Gašić, Uroš M. and Pezo, Lato and Đurović, Saša",
year = "2023",
abstract = "Stinging nettle (Urtica dioica L.) is one fantastic plant widely used in folk medicine, pharmacy, cosmetics, and food. This plant’s popularity may be explained by its chemical composition, containing a wide range of compounds significant for human health and diet. This study aimed to investigate extracts of exhausted stinging nettle leaves after supercritical fluid extraction obtained using ultrasound and microwave techniques. Extracts were analyzed to obtain insight into the chemical composition and biological activity. These extracts were shown to be more potent than those of previously untreated leaves. The principal component analysis was applied as a pattern recognition tool to visualize the antioxidant capacity and cytotoxic activity of extract obtained from exhausted stinging nettle leaves. An artificial neural network model is presented for the prediction of the antioxidant activity of samples according to polyphenolic profile data, showing a suitable anticipation property (the r2 value during the training cycle for output variables was 0.999).",
publisher = "MDPI",
journal = "Foods",
title = "Recovery of Biologically Active Compounds from Stinging Nettle Leaves Part II: Processing of Exhausted Plant Material after Supercritical Fluid Extraction",
volume = "12",
number = "4",
pages = "809",
doi = "10.3390/foods12040809"
}
Zeković, Z. P., Smyatskaya, Y. A., Bazarnova, J. G., Pastor, F., Gorjanović, S., Gašić, U. M., Pezo, L.,& Đurović, S.. (2023). Recovery of Biologically Active Compounds from Stinging Nettle Leaves Part II: Processing of Exhausted Plant Material after Supercritical Fluid Extraction. in Foods
MDPI., 12(4), 809.
https://doi.org/10.3390/foods12040809
Zeković ZP, Smyatskaya YA, Bazarnova JG, Pastor F, Gorjanović S, Gašić UM, Pezo L, Đurović S. Recovery of Biologically Active Compounds from Stinging Nettle Leaves Part II: Processing of Exhausted Plant Material after Supercritical Fluid Extraction. in Foods. 2023;12(4):809.
doi:10.3390/foods12040809 .
Zeković, Zoran P., Smyatskaya, Yulia A., Bazarnova, Julia G., Pastor, Ferenc, Gorjanović, Stanislava, Gašić, Uroš M., Pezo, Lato, Đurović, Saša, "Recovery of Biologically Active Compounds from Stinging Nettle Leaves Part II: Processing of Exhausted Plant Material after Supercritical Fluid Extraction" in Foods, 12, no. 4 (2023):809,
https://doi.org/10.3390/foods12040809 . .
2
1

Food Waste (Beetroot and Apple Pomace) as Sorbent for Lead from Aqueous Solutions—Alternative to Landfill Disposal

Šoštarić, Tatjana D.; Simić, Marija; Lopičić, Zorica; Zlatanović, Snežana; Pastor, Ferenc; Antanasković, Anja; Gorjanović, Stanislava

(MDPI, 2023)

TY  - JOUR
AU  - Šoštarić, Tatjana D.
AU  - Simić, Marija
AU  - Lopičić, Zorica
AU  - Zlatanović, Snežana
AU  - Pastor, Ferenc
AU  - Antanasković, Anja
AU  - Gorjanović, Stanislava
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6265
AB  - This article presents studies, whose main goal was to minimize food waste. To achieve this goal, it is necessary to expand the scope of their application, for example, for the purification of polluted water from heavy metals. Millions of tons of waste from the fruit and vegetable industry, including pomace of apples and beetroots, are thrown into landfills, posing a danger to the environment. In order to solve the problems with the disposal of these wastes, the authors investigated their sorption potential for the removal of lead from wastewater. The sorbents, dried apple (AP), and beetroots (BR) pomaces were characterized by various methods (study of composition, zeta potential, FTIR-ATR, and SEM-EDX). Various models of sorption kinetics and sorption isotherms were analyzed. Kinetical studies under optimal conditions showed that the sorption process occurs through complexation and ion exchange and the determining stage limiting the rate of sorption is the diffusion of lead ions in the sorbent. The maximum sorption capacity was 31.7 and 79.8 mg/g for AP and BR, respectively. The thermodynamic data revealed the spontaneous sorption of lead ions by sorbents. The temperature rise contributes to the sorption increase by the AP sorbent, while for the BR sorbent, the opposite effect is observed. The obtained results showed that apple and beetroots pomaces can serve as effective renewable materials for the preparation of sorbents, contributing to the solution of complex environmental problems.
PB  - MDPI
T2  - Processes
T1  - Food Waste (Beetroot and Apple Pomace) as Sorbent for Lead from Aqueous Solutions—Alternative to Landfill Disposal
VL  - 11
IS  - 5
SP  - 1343
DO  - 10.3390/pr11051343
ER  - 
@article{
author = "Šoštarić, Tatjana D. and Simić, Marija and Lopičić, Zorica and Zlatanović, Snežana and Pastor, Ferenc and Antanasković, Anja and Gorjanović, Stanislava",
year = "2023",
abstract = "This article presents studies, whose main goal was to minimize food waste. To achieve this goal, it is necessary to expand the scope of their application, for example, for the purification of polluted water from heavy metals. Millions of tons of waste from the fruit and vegetable industry, including pomace of apples and beetroots, are thrown into landfills, posing a danger to the environment. In order to solve the problems with the disposal of these wastes, the authors investigated their sorption potential for the removal of lead from wastewater. The sorbents, dried apple (AP), and beetroots (BR) pomaces were characterized by various methods (study of composition, zeta potential, FTIR-ATR, and SEM-EDX). Various models of sorption kinetics and sorption isotherms were analyzed. Kinetical studies under optimal conditions showed that the sorption process occurs through complexation and ion exchange and the determining stage limiting the rate of sorption is the diffusion of lead ions in the sorbent. The maximum sorption capacity was 31.7 and 79.8 mg/g for AP and BR, respectively. The thermodynamic data revealed the spontaneous sorption of lead ions by sorbents. The temperature rise contributes to the sorption increase by the AP sorbent, while for the BR sorbent, the opposite effect is observed. The obtained results showed that apple and beetroots pomaces can serve as effective renewable materials for the preparation of sorbents, contributing to the solution of complex environmental problems.",
publisher = "MDPI",
journal = "Processes",
title = "Food Waste (Beetroot and Apple Pomace) as Sorbent for Lead from Aqueous Solutions—Alternative to Landfill Disposal",
volume = "11",
number = "5",
pages = "1343",
doi = "10.3390/pr11051343"
}
Šoštarić, T. D., Simić, M., Lopičić, Z., Zlatanović, S., Pastor, F., Antanasković, A.,& Gorjanović, S.. (2023). Food Waste (Beetroot and Apple Pomace) as Sorbent for Lead from Aqueous Solutions—Alternative to Landfill Disposal. in Processes
MDPI., 11(5), 1343.
https://doi.org/10.3390/pr11051343
Šoštarić TD, Simić M, Lopičić Z, Zlatanović S, Pastor F, Antanasković A, Gorjanović S. Food Waste (Beetroot and Apple Pomace) as Sorbent for Lead from Aqueous Solutions—Alternative to Landfill Disposal. in Processes. 2023;11(5):1343.
doi:10.3390/pr11051343 .
Šoštarić, Tatjana D., Simić, Marija, Lopičić, Zorica, Zlatanović, Snežana, Pastor, Ferenc, Antanasković, Anja, Gorjanović, Stanislava, "Food Waste (Beetroot and Apple Pomace) as Sorbent for Lead from Aqueous Solutions—Alternative to Landfill Disposal" in Processes, 11, no. 5 (2023):1343,
https://doi.org/10.3390/pr11051343 . .

Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography

Lugonja, Nikoleta; Gorjanović, Stanislava; Pastor, Ferenc; Marinković, Vesna S.; Miličić, Biljana; Vrvić, Miroslav M.; Spasić, Snežana

(Springer Link, 2021)

TY  - JOUR
AU  - Lugonja, Nikoleta
AU  - Gorjanović, Stanislava
AU  - Pastor, Ferenc
AU  - Marinković, Vesna S.
AU  - Miličić, Biljana
AU  - Vrvić, Miroslav M.
AU  - Spasić, Snežana
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4517
AB  - Antioxidants present in infant food contribute to its nutritive value and provide protection from oxidative damage. Here, a direct current polarographic method, based on a decrease of anodic current from the hydroxoperhydroxo-mercury(II) complex (HPMC) formed at a mercury dropping electrode at its potential of dissolution, was used to determine the total antioxidant capacity (TAC) of infant formulas, human milk collected from mothers of full-term and preterm infants, human milk supplemented with fortifier, and cow milk. TAC of milk samples and infant formula correlated with protein content measured by the Bradford method (Pearson correlation coefficient 0.605, p<0.001), while TAC of human milk correlated with content of free thiol groups measured by the Ellman method (0.779, p<0.001). The results obtained showed that, in contrast to the 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay, HPMC enables specific insight into the quality of infant milk food which reflects the amounts of free thiol groups and protein content. The significant contribution of milk proteins and the most prevalent amino acids, particularly cysteine, arginine, and phenylalanine, to TAC was shown. Thus, the HPMC method might be useful in monitoring the quality of infant formulas and human milk for preterm infants before and after supplementation with fortifier.
PB  - Springer Link
T2  - Food Analytical Methods
T2  - Food Analytical Methods
T1  - Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography
VL  - 14
SP  - 1987
EP  - 1994
DO  - 10.1007/s12161-021-02030-3
ER  - 
@article{
author = "Lugonja, Nikoleta and Gorjanović, Stanislava and Pastor, Ferenc and Marinković, Vesna S. and Miličić, Biljana and Vrvić, Miroslav M. and Spasić, Snežana",
year = "2021",
abstract = "Antioxidants present in infant food contribute to its nutritive value and provide protection from oxidative damage. Here, a direct current polarographic method, based on a decrease of anodic current from the hydroxoperhydroxo-mercury(II) complex (HPMC) formed at a mercury dropping electrode at its potential of dissolution, was used to determine the total antioxidant capacity (TAC) of infant formulas, human milk collected from mothers of full-term and preterm infants, human milk supplemented with fortifier, and cow milk. TAC of milk samples and infant formula correlated with protein content measured by the Bradford method (Pearson correlation coefficient 0.605, p<0.001), while TAC of human milk correlated with content of free thiol groups measured by the Ellman method (0.779, p<0.001). The results obtained showed that, in contrast to the 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay, HPMC enables specific insight into the quality of infant milk food which reflects the amounts of free thiol groups and protein content. The significant contribution of milk proteins and the most prevalent amino acids, particularly cysteine, arginine, and phenylalanine, to TAC was shown. Thus, the HPMC method might be useful in monitoring the quality of infant formulas and human milk for preterm infants before and after supplementation with fortifier.",
publisher = "Springer Link",
journal = "Food Analytical Methods, Food Analytical Methods",
title = "Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography",
volume = "14",
pages = "1987-1994",
doi = "10.1007/s12161-021-02030-3"
}
Lugonja, N., Gorjanović, S., Pastor, F., Marinković, V. S., Miličić, B., Vrvić, M. M.,& Spasić, S.. (2021). Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography. in Food Analytical Methods
Springer Link., 14, 1987-1994.
https://doi.org/10.1007/s12161-021-02030-3
Lugonja N, Gorjanović S, Pastor F, Marinković VS, Miličić B, Vrvić MM, Spasić S. Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography. in Food Analytical Methods. 2021;14:1987-1994.
doi:10.1007/s12161-021-02030-3 .
Lugonja, Nikoleta, Gorjanović, Stanislava, Pastor, Ferenc, Marinković, Vesna S., Miličić, Biljana, Vrvić, Miroslav M., Spasić, Snežana, "Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography" in Food Analytical Methods, 14 (2021):1987-1994,
https://doi.org/10.1007/s12161-021-02030-3 . .
2
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Formulation of novel liqueurs from juice industry waste: Consumer acceptance, phenolic profile and preliminary monitoring of antioxidant activity and colour changes during storage

Petrović, Marija S.; Veljović, Sonja; Tomić, Nikola; Zlatanović, Snežana; Tosti, Tomislav; Vukosavljević, Predrag V.; Gorjanović, Stanislava

(University of Zagreb, Faculty of Food Technology and Biotechnology, 2021)

TY  - JOUR
AU  - Petrović, Marija S.
AU  - Veljović, Sonja
AU  - Tomić, Nikola
AU  - Zlatanović, Snežana
AU  - Tosti, Tomislav
AU  - Vukosavljević, Predrag V.
AU  - Gorjanović, Stanislava
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4756
AB  - Research background. Apple juice is one of the most popular and liked beverages worldwide. Due to the increased health consciousness among consumers, beetroot and chokeberry juices have also rising consumption trends. Despite representing a consider-able percentage of the processed fruit and rich source of bioactive compounds, fruit pom-ace, remaining after juice production, has still been underutilised. Here, the possibility of using apple, beetroot and chokeberry pomace in liqueur formulations is investigated. Experimental approach. Apple and chokeberry liqueurs were produced from apple and chokeberry pomace extracts, respectively. Apple/chokeberry and apple/beetroot liqueurs were obtained by combining apple pomace with chokeberry and beetroot pomace extracts in ratios 50:50 and 70:30, respectively. The sensory quality and acceptability of freshly prepared liqueurs were evaluated by experts and consumers. Sugars and phenolics were identified and quantified by high-performance anion-exchange chromatography with pulsed-amperometric detection (HPAEC-PAD) and high-performance liquid chromatog-raphy–diode array detection–tandem mass spectrometry (HPLC–DAD–MS/MS), respec-tively. Storability was preliminarily evaluated based on monitoring of total phenolic con-centration, antioxidant activity and colour each month during 6 months of storage at 4 and 22 °C. Results and conclusions. The expert and the consumer testing indicated that apple and chokeberry pomace could be used as raw materials without any flavour corrections while apple/beetroot pomace liqueur would require modification. High total phenolic content and antioxidant activity were found in all freshly prepared liqueurs, with chokeberry liqueur being by far superior. Among identified phenolics, ellagic acid and phlorizin were quantified as the most prominent, except in chokeberry liqueur, where phlorizin was not quantified. Despite the decrease in total phenolic concentration and antioxidant activity after 6 months, liqueurs still represented a rich source of phytochemicals. The highest phenolic compound retention and antioxidant activity maintenance were observed in chokeberry liqueur. Also, the appealing colour was retained despite the changes detected in chromatic characteristics. Novelty and scientific contribution. The possibility of apple, beetroot and chokeberry pomace restoration into the food chain by the production of liqueurs has been demon-strated for the first time. Functional and sensorial properties of newly developed liqueurs indicated that the selected pomace represents the promising raw material for liqueur pro-duction. The applied approach represents a contribution to the circular economy in juice production. © 2021, University of Zagreb. All rights reserved.
PB  - University of Zagreb, Faculty of Food Technology and Biotechnology
T2  - Food Technology and Biotechnology
T1  - Formulation of novel liqueurs from juice industry waste: Consumer acceptance, phenolic profile and preliminary monitoring of antioxidant activity and colour changes during storage
VL  - 59
IS  - 3
SP  - 282
EP  - 294
DO  - 10.17113/ftb.59.03.21.6759
ER  - 
@article{
author = "Petrović, Marija S. and Veljović, Sonja and Tomić, Nikola and Zlatanović, Snežana and Tosti, Tomislav and Vukosavljević, Predrag V. and Gorjanović, Stanislava",
year = "2021",
abstract = "Research background. Apple juice is one of the most popular and liked beverages worldwide. Due to the increased health consciousness among consumers, beetroot and chokeberry juices have also rising consumption trends. Despite representing a consider-able percentage of the processed fruit and rich source of bioactive compounds, fruit pom-ace, remaining after juice production, has still been underutilised. Here, the possibility of using apple, beetroot and chokeberry pomace in liqueur formulations is investigated. Experimental approach. Apple and chokeberry liqueurs were produced from apple and chokeberry pomace extracts, respectively. Apple/chokeberry and apple/beetroot liqueurs were obtained by combining apple pomace with chokeberry and beetroot pomace extracts in ratios 50:50 and 70:30, respectively. The sensory quality and acceptability of freshly prepared liqueurs were evaluated by experts and consumers. Sugars and phenolics were identified and quantified by high-performance anion-exchange chromatography with pulsed-amperometric detection (HPAEC-PAD) and high-performance liquid chromatog-raphy–diode array detection–tandem mass spectrometry (HPLC–DAD–MS/MS), respec-tively. Storability was preliminarily evaluated based on monitoring of total phenolic con-centration, antioxidant activity and colour each month during 6 months of storage at 4 and 22 °C. Results and conclusions. The expert and the consumer testing indicated that apple and chokeberry pomace could be used as raw materials without any flavour corrections while apple/beetroot pomace liqueur would require modification. High total phenolic content and antioxidant activity were found in all freshly prepared liqueurs, with chokeberry liqueur being by far superior. Among identified phenolics, ellagic acid and phlorizin were quantified as the most prominent, except in chokeberry liqueur, where phlorizin was not quantified. Despite the decrease in total phenolic concentration and antioxidant activity after 6 months, liqueurs still represented a rich source of phytochemicals. The highest phenolic compound retention and antioxidant activity maintenance were observed in chokeberry liqueur. Also, the appealing colour was retained despite the changes detected in chromatic characteristics. Novelty and scientific contribution. The possibility of apple, beetroot and chokeberry pomace restoration into the food chain by the production of liqueurs has been demon-strated for the first time. Functional and sensorial properties of newly developed liqueurs indicated that the selected pomace represents the promising raw material for liqueur pro-duction. The applied approach represents a contribution to the circular economy in juice production. © 2021, University of Zagreb. All rights reserved.",
publisher = "University of Zagreb, Faculty of Food Technology and Biotechnology",
journal = "Food Technology and Biotechnology",
title = "Formulation of novel liqueurs from juice industry waste: Consumer acceptance, phenolic profile and preliminary monitoring of antioxidant activity and colour changes during storage",
volume = "59",
number = "3",
pages = "282-294",
doi = "10.17113/ftb.59.03.21.6759"
}
Petrović, M. S., Veljović, S., Tomić, N., Zlatanović, S., Tosti, T., Vukosavljević, P. V.,& Gorjanović, S.. (2021). Formulation of novel liqueurs from juice industry waste: Consumer acceptance, phenolic profile and preliminary monitoring of antioxidant activity and colour changes during storage. in Food Technology and Biotechnology
University of Zagreb, Faculty of Food Technology and Biotechnology., 59(3), 282-294.
https://doi.org/10.17113/ftb.59.03.21.6759
Petrović MS, Veljović S, Tomić N, Zlatanović S, Tosti T, Vukosavljević PV, Gorjanović S. Formulation of novel liqueurs from juice industry waste: Consumer acceptance, phenolic profile and preliminary monitoring of antioxidant activity and colour changes during storage. in Food Technology and Biotechnology. 2021;59(3):282-294.
doi:10.17113/ftb.59.03.21.6759 .
Petrović, Marija S., Veljović, Sonja, Tomić, Nikola, Zlatanović, Snežana, Tosti, Tomislav, Vukosavljević, Predrag V., Gorjanović, Stanislava, "Formulation of novel liqueurs from juice industry waste: Consumer acceptance, phenolic profile and preliminary monitoring of antioxidant activity and colour changes during storage" in Food Technology and Biotechnology, 59, no. 3 (2021):282-294,
https://doi.org/10.17113/ftb.59.03.21.6759 . .
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4
3

Evaluation of novel green walnut liqueur as a source of antioxidants: Multi-method approach

Petrović, Marija S.; Pastor, Ferenc; Đurović, Saša; Veljović, Sonja; Gorjanović, Stanislava; Sredojević, Milica; Vukosavljević, Predrag V.

(Springer India, New Delhi, 2021)

TY  - JOUR
AU  - Petrović, Marija S.
AU  - Pastor, Ferenc
AU  - Đurović, Saša
AU  - Veljović, Sonja
AU  - Gorjanović, Stanislava
AU  - Sredojević, Milica
AU  - Vukosavljević, Predrag V.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4769
AB  - In this study, a novel green walnut liqueur (GWL) based on green walnuts, as the main ingredient, with the addition of fruits, aromatic plants, chocolate and honey, was produced at the pilot-scale. Antioxidant activity (AO) of the obtained GWL was determined using multiple AO assays in parallel, standard spectrophotometric (FC, DPPH and FRAP) and recently developed electrochemical ones, HydroxoPerhydroxoMercury(II) Complex and Mercury Reduction Antioxidant Power, and compared to similar commercial alcoholic beverages. Characterization of the GWL in terms of volatile and polyphenolic components was performed using SPE-GC-MS and HPLC-DAD-MS/MS, respectively. Sensory quality assessment was performed by experts in the field of sensory analysis of alcoholic beverages, using a scoring method. According to all AO assays applied, AO activity and total phenolics content of GWL were superior in comparison to commercial spirits considered. The volatile fraction of GWL was mainly composed of eugenol,alpha-terpineol and vanillin, while the most prevalent phenolic compounds were gallic (5.054 mg/L) and chlorogenic acid (1.307 mg/L) and flavonoids such as catechine (0.882 mg/L), quercetin (0.499 mg/L) and its sugar-conjugated derivatives, quercetin 3-O-glucoside (0.774 mg/L) and quercetin-3-O-rhamnoside (0.614 mg/L). Gallic acid is the major contributor to total AO activity, especially determined by DPPH and FRAP, followed by catechine, quercetin and chlorogenic acid. Among the terpenoids, contribution of eugenol to total AO activity is estimated as the highest. Excellent sensory quality (18.52 of maximum 20 scores) was ascribed to GWL. Consequently, the presence of bioactive compounds and high AO activity of GWL, in addition to high sensory quality score, indicates a high market potential for this high-value product.
PB  - Springer India, New Delhi
T2  - Journal of Food Science and Technology-Mysore
T1  - Evaluation of novel green walnut liqueur as a source of antioxidants: Multi-method approach
VL  - 58
IS  - 6
SP  - 2160
EP  - 2169
DO  - 10.1007/s13197-020-04726-6
ER  - 
@article{
author = "Petrović, Marija S. and Pastor, Ferenc and Đurović, Saša and Veljović, Sonja and Gorjanović, Stanislava and Sredojević, Milica and Vukosavljević, Predrag V.",
year = "2021",
abstract = "In this study, a novel green walnut liqueur (GWL) based on green walnuts, as the main ingredient, with the addition of fruits, aromatic plants, chocolate and honey, was produced at the pilot-scale. Antioxidant activity (AO) of the obtained GWL was determined using multiple AO assays in parallel, standard spectrophotometric (FC, DPPH and FRAP) and recently developed electrochemical ones, HydroxoPerhydroxoMercury(II) Complex and Mercury Reduction Antioxidant Power, and compared to similar commercial alcoholic beverages. Characterization of the GWL in terms of volatile and polyphenolic components was performed using SPE-GC-MS and HPLC-DAD-MS/MS, respectively. Sensory quality assessment was performed by experts in the field of sensory analysis of alcoholic beverages, using a scoring method. According to all AO assays applied, AO activity and total phenolics content of GWL were superior in comparison to commercial spirits considered. The volatile fraction of GWL was mainly composed of eugenol,alpha-terpineol and vanillin, while the most prevalent phenolic compounds were gallic (5.054 mg/L) and chlorogenic acid (1.307 mg/L) and flavonoids such as catechine (0.882 mg/L), quercetin (0.499 mg/L) and its sugar-conjugated derivatives, quercetin 3-O-glucoside (0.774 mg/L) and quercetin-3-O-rhamnoside (0.614 mg/L). Gallic acid is the major contributor to total AO activity, especially determined by DPPH and FRAP, followed by catechine, quercetin and chlorogenic acid. Among the terpenoids, contribution of eugenol to total AO activity is estimated as the highest. Excellent sensory quality (18.52 of maximum 20 scores) was ascribed to GWL. Consequently, the presence of bioactive compounds and high AO activity of GWL, in addition to high sensory quality score, indicates a high market potential for this high-value product.",
publisher = "Springer India, New Delhi",
journal = "Journal of Food Science and Technology-Mysore",
title = "Evaluation of novel green walnut liqueur as a source of antioxidants: Multi-method approach",
volume = "58",
number = "6",
pages = "2160-2169",
doi = "10.1007/s13197-020-04726-6"
}
Petrović, M. S., Pastor, F., Đurović, S., Veljović, S., Gorjanović, S., Sredojević, M.,& Vukosavljević, P. V.. (2021). Evaluation of novel green walnut liqueur as a source of antioxidants: Multi-method approach. in Journal of Food Science and Technology-Mysore
Springer India, New Delhi., 58(6), 2160-2169.
https://doi.org/10.1007/s13197-020-04726-6
Petrović MS, Pastor F, Đurović S, Veljović S, Gorjanović S, Sredojević M, Vukosavljević PV. Evaluation of novel green walnut liqueur as a source of antioxidants: Multi-method approach. in Journal of Food Science and Technology-Mysore. 2021;58(6):2160-2169.
doi:10.1007/s13197-020-04726-6 .
Petrović, Marija S., Pastor, Ferenc, Đurović, Saša, Veljović, Sonja, Gorjanović, Stanislava, Sredojević, Milica, Vukosavljević, Predrag V., "Evaluation of novel green walnut liqueur as a source of antioxidants: Multi-method approach" in Journal of Food Science and Technology-Mysore, 58, no. 6 (2021):2160-2169,
https://doi.org/10.1007/s13197-020-04726-6 . .
10
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5

Serbian aromatized wine “Bermet”: Electrochemical, chemiluminescent and spectrophotometric determination of antioxidant activity

Gorjanović, Stanislava; Pastor, Ferenc; Loupassaki, Sofia; Veljović, Mile S.; Vukosavljević, Predrag V.; Zlatanović, Snežana; Pezo, Lato

(Journal of the Serbian Chemical Society, 2020)

TY  - JOUR
AU  - Gorjanović, Stanislava
AU  - Pastor, Ferenc
AU  - Loupassaki, Sofia
AU  - Veljović, Mile S.
AU  - Vukosavljević, Predrag V.
AU  - Zlatanović, Snežana
AU  - Pezo, Lato
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4058
AB  - Serbian aromatized wine “Bermet” from grapes grown on Fruška Gora Mountain has been in production since the 15th century. Ten commercial Bermets produced according to the traditional procedure by different manufacturers, and six prepared within the scope of this study were assessed for antioxidant (AO) activity using electrochemical, chemiluminescent and spectrophotometric AO assays. Direct current polarographic assay based on the decrease of anodic current of [hydrogen(peroxido)(1-)]hydroxidomercury(II) complex formation in alkaline H2O2 solution at potential of mercury oxidation, chemiluminescent H2O2 scavenging assay, as well as commonly used spectrophotometric assays (2,2’-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid (ABTS) based Trolox equivalent antioxidant capacity (TEAC), 2,2-diphenyl-1-picrylhydrazyl (DPPH) and ferric reducing antioxidant power (FRAP)) were used. Total phenolic content (TPC) was determined by Folin–Ciocalteu assay. The results obtained were correlated using regression analysis, ANOVA and F-test. An integrated approach to AO capacity determination allowed a more comprehensive comparison between samples. The approach is based on the introduction of the relative antioxidant capacity index, calculated by assigning each AO assay equal weight, and by PCA analysis. In addition, the introduction of phenolic antioxidant coefficients, calculated as the ratio between individual AO capacity and TPC, enabled a better understanding of their relation.
PB  - Journal of the Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Serbian aromatized wine “Bermet”: Electrochemical, chemiluminescent and spectrophotometric determination of antioxidant activity
VL  - 85
IS  - 4
SP  - 517
EP  - 529
DO  - 10.2298/JSC190404139G
ER  - 
@article{
author = "Gorjanović, Stanislava and Pastor, Ferenc and Loupassaki, Sofia and Veljović, Mile S. and Vukosavljević, Predrag V. and Zlatanović, Snežana and Pezo, Lato",
year = "2020",
abstract = "Serbian aromatized wine “Bermet” from grapes grown on Fruška Gora Mountain has been in production since the 15th century. Ten commercial Bermets produced according to the traditional procedure by different manufacturers, and six prepared within the scope of this study were assessed for antioxidant (AO) activity using electrochemical, chemiluminescent and spectrophotometric AO assays. Direct current polarographic assay based on the decrease of anodic current of [hydrogen(peroxido)(1-)]hydroxidomercury(II) complex formation in alkaline H2O2 solution at potential of mercury oxidation, chemiluminescent H2O2 scavenging assay, as well as commonly used spectrophotometric assays (2,2’-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid (ABTS) based Trolox equivalent antioxidant capacity (TEAC), 2,2-diphenyl-1-picrylhydrazyl (DPPH) and ferric reducing antioxidant power (FRAP)) were used. Total phenolic content (TPC) was determined by Folin–Ciocalteu assay. The results obtained were correlated using regression analysis, ANOVA and F-test. An integrated approach to AO capacity determination allowed a more comprehensive comparison between samples. The approach is based on the introduction of the relative antioxidant capacity index, calculated by assigning each AO assay equal weight, and by PCA analysis. In addition, the introduction of phenolic antioxidant coefficients, calculated as the ratio between individual AO capacity and TPC, enabled a better understanding of their relation.",
publisher = "Journal of the Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Serbian aromatized wine “Bermet”: Electrochemical, chemiluminescent and spectrophotometric determination of antioxidant activity",
volume = "85",
number = "4",
pages = "517-529",
doi = "10.2298/JSC190404139G"
}
Gorjanović, S., Pastor, F., Loupassaki, S., Veljović, M. S., Vukosavljević, P. V., Zlatanović, S.,& Pezo, L.. (2020). Serbian aromatized wine “Bermet”: Electrochemical, chemiluminescent and spectrophotometric determination of antioxidant activity. in Journal of the Serbian Chemical Society
Journal of the Serbian Chemical Society., 85(4), 517-529.
https://doi.org/10.2298/JSC190404139G
Gorjanović S, Pastor F, Loupassaki S, Veljović MS, Vukosavljević PV, Zlatanović S, Pezo L. Serbian aromatized wine “Bermet”: Electrochemical, chemiluminescent and spectrophotometric determination of antioxidant activity. in Journal of the Serbian Chemical Society. 2020;85(4):517-529.
doi:10.2298/JSC190404139G .
Gorjanović, Stanislava, Pastor, Ferenc, Loupassaki, Sofia, Veljović, Mile S., Vukosavljević, Predrag V., Zlatanović, Snežana, Pezo, Lato, "Serbian aromatized wine “Bermet”: Electrochemical, chemiluminescent and spectrophotometric determination of antioxidant activity" in Journal of the Serbian Chemical Society, 85, no. 4 (2020):517-529,
https://doi.org/10.2298/JSC190404139G . .
2
1
1
2

Trametes versicolor ethanol extract, a promising candidate for health-promoting food supplement

Janjušević, Ljiljana; Pejin, Boris; Kaišarević, Sonja; Gorjanović, Stanislava; Pastor, Ferenc; Tešanović, Kristina; Karaman, Maja

(Taylor & Francis Ltd, Abingdon, 2018)

TY  - JOUR
AU  - Janjušević, Ljiljana
AU  - Pejin, Boris
AU  - Kaišarević, Sonja
AU  - Gorjanović, Stanislava
AU  - Pastor, Ferenc
AU  - Tešanović, Kristina
AU  - Karaman, Maja
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2076
AB  - This study aimed to estimate antiradical, antioxidant (AO) and cytotoxic activities of the fungus Trametes versicolor ethanol fruiting body extract. The extract was found to effectively scavenge both O-2(center dot-) and NO center dot (29.62 and 52.48g/mL, respectively). It also showed a good AO activity in the polarographic HPMC assay (950%/mL). p-Hydroxybenzoic acid may be one of the responsible compounds for the afore-mentioned activities. The same extract also exhibited a concentration-dependent cytotoxicity against MCF-7 and HepG2 tumour cell lines reaching IC50 values of 123.51 and 134.29g/mL, respectively with no cytotoxic activity against normal MRC-5 cells. Gentisic, syringic and protocatechuic acids may be among the bioactive principles for the observed cytotoxicity. Taken all together, T. versicolor ethanol extract can be considered as a promising candidate for development of health promoting food supplement. [GRAPHICS] .
PB  - Taylor & Francis Ltd, Abingdon
T2  - Natural Product Research
T1  - Trametes versicolor ethanol extract, a promising candidate for health-promoting food supplement
VL  - 32
IS  - 8
SP  - 963
EP  - 967
DO  - 10.1080/14786419.2017.1366484
ER  - 
@article{
author = "Janjušević, Ljiljana and Pejin, Boris and Kaišarević, Sonja and Gorjanović, Stanislava and Pastor, Ferenc and Tešanović, Kristina and Karaman, Maja",
year = "2018",
abstract = "This study aimed to estimate antiradical, antioxidant (AO) and cytotoxic activities of the fungus Trametes versicolor ethanol fruiting body extract. The extract was found to effectively scavenge both O-2(center dot-) and NO center dot (29.62 and 52.48g/mL, respectively). It also showed a good AO activity in the polarographic HPMC assay (950%/mL). p-Hydroxybenzoic acid may be one of the responsible compounds for the afore-mentioned activities. The same extract also exhibited a concentration-dependent cytotoxicity against MCF-7 and HepG2 tumour cell lines reaching IC50 values of 123.51 and 134.29g/mL, respectively with no cytotoxic activity against normal MRC-5 cells. Gentisic, syringic and protocatechuic acids may be among the bioactive principles for the observed cytotoxicity. Taken all together, T. versicolor ethanol extract can be considered as a promising candidate for development of health promoting food supplement. [GRAPHICS] .",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Natural Product Research",
title = "Trametes versicolor ethanol extract, a promising candidate for health-promoting food supplement",
volume = "32",
number = "8",
pages = "963-967",
doi = "10.1080/14786419.2017.1366484"
}
Janjušević, L., Pejin, B., Kaišarević, S., Gorjanović, S., Pastor, F., Tešanović, K.,& Karaman, M.. (2018). Trametes versicolor ethanol extract, a promising candidate for health-promoting food supplement. in Natural Product Research
Taylor & Francis Ltd, Abingdon., 32(8), 963-967.
https://doi.org/10.1080/14786419.2017.1366484
Janjušević L, Pejin B, Kaišarević S, Gorjanović S, Pastor F, Tešanović K, Karaman M. Trametes versicolor ethanol extract, a promising candidate for health-promoting food supplement. in Natural Product Research. 2018;32(8):963-967.
doi:10.1080/14786419.2017.1366484 .
Janjušević, Ljiljana, Pejin, Boris, Kaišarević, Sonja, Gorjanović, Stanislava, Pastor, Ferenc, Tešanović, Kristina, Karaman, Maja, "Trametes versicolor ethanol extract, a promising candidate for health-promoting food supplement" in Natural Product Research, 32, no. 8 (2018):963-967,
https://doi.org/10.1080/14786419.2017.1366484 . .
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Supplementary data for the article: Janjušević, L.; Pejin, B.; Kaišarević, S.; Gorjanović, S.; Pastor, F.; Tešanović, K.; Karaman, M. Trametes Versicolor Ethanol Extract, a Promising Candidate for Health–Promoting Food Supplement. Natural Product Research 2018, 32 (8), 963–967. https://doi.org/10.1080/14786419.2017.1366484

Janjušević, Ljiljana; Pejin, Boris; Kaišarević, Sonja; Gorjanović, Stanislava; Pastor, Ferenc; Tešanović, Kristina; Karaman, Maja

(Taylor & Francis Ltd, Abingdon, 2018)

TY  - DATA
AU  - Janjušević, Ljiljana
AU  - Pejin, Boris
AU  - Kaišarević, Sonja
AU  - Gorjanović, Stanislava
AU  - Pastor, Ferenc
AU  - Tešanović, Kristina
AU  - Karaman, Maja
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2896
PB  - Taylor & Francis Ltd, Abingdon
T2  - Natural Product Research
T1  - Supplementary data for the article: Janjušević, L.; Pejin, B.; Kaišarević, S.; Gorjanović, S.; Pastor, F.; Tešanović, K.; Karaman, M. Trametes Versicolor Ethanol Extract, a Promising Candidate for Health–Promoting Food Supplement. Natural Product Research 2018, 32 (8), 963–967. https://doi.org/10.1080/14786419.2017.1366484
DO  - 10.1080/14786419.2017.1366484
ER  - 
@misc{
author = "Janjušević, Ljiljana and Pejin, Boris and Kaišarević, Sonja and Gorjanović, Stanislava and Pastor, Ferenc and Tešanović, Kristina and Karaman, Maja",
year = "2018",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Natural Product Research",
title = "Supplementary data for the article: Janjušević, L.; Pejin, B.; Kaišarević, S.; Gorjanović, S.; Pastor, F.; Tešanović, K.; Karaman, M. Trametes Versicolor Ethanol Extract, a Promising Candidate for Health–Promoting Food Supplement. Natural Product Research 2018, 32 (8), 963–967. https://doi.org/10.1080/14786419.2017.1366484",
doi = "10.1080/14786419.2017.1366484"
}
Janjušević, L., Pejin, B., Kaišarević, S., Gorjanović, S., Pastor, F., Tešanović, K.,& Karaman, M.. (2018). Supplementary data for the article: Janjušević, L.; Pejin, B.; Kaišarević, S.; Gorjanović, S.; Pastor, F.; Tešanović, K.; Karaman, M. Trametes Versicolor Ethanol Extract, a Promising Candidate for Health–Promoting Food Supplement. Natural Product Research 2018, 32 (8), 963–967. https://doi.org/10.1080/14786419.2017.1366484. in Natural Product Research
Taylor & Francis Ltd, Abingdon..
https://doi.org/10.1080/14786419.2017.1366484
Janjušević L, Pejin B, Kaišarević S, Gorjanović S, Pastor F, Tešanović K, Karaman M. Supplementary data for the article: Janjušević, L.; Pejin, B.; Kaišarević, S.; Gorjanović, S.; Pastor, F.; Tešanović, K.; Karaman, M. Trametes Versicolor Ethanol Extract, a Promising Candidate for Health–Promoting Food Supplement. Natural Product Research 2018, 32 (8), 963–967. https://doi.org/10.1080/14786419.2017.1366484. in Natural Product Research. 2018;.
doi:10.1080/14786419.2017.1366484 .
Janjušević, Ljiljana, Pejin, Boris, Kaišarević, Sonja, Gorjanović, Stanislava, Pastor, Ferenc, Tešanović, Kristina, Karaman, Maja, "Supplementary data for the article: Janjušević, L.; Pejin, B.; Kaišarević, S.; Gorjanović, S.; Pastor, F.; Tešanović, K.; Karaman, M. Trametes Versicolor Ethanol Extract, a Promising Candidate for Health–Promoting Food Supplement. Natural Product Research 2018, 32 (8), 963–967. https://doi.org/10.1080/14786419.2017.1366484" in Natural Product Research (2018),
https://doi.org/10.1080/14786419.2017.1366484 . .
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Antioxidant efficiency of polyphenols from coffee and coffee substitutes-electrochemical versus spectrophotometric approach

Gorjanović, Stanislava; Komes, Drazenka; Lalicic-Petronijevic, Jovanka; Pastor, Ferenc; Belscak-Cvitanovic, Ana; Veljović, Mile S.; Pezo, Lato; Suznjevic, Desanka Z.

(Springer India, New Delhi, 2017)

TY  - JOUR
AU  - Gorjanović, Stanislava
AU  - Komes, Drazenka
AU  - Lalicic-Petronijevic, Jovanka
AU  - Pastor, Ferenc
AU  - Belscak-Cvitanovic, Ana
AU  - Veljović, Mile S.
AU  - Pezo, Lato
AU  - Suznjevic, Desanka Z.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2484
AB  - Antioxidant (AO) capacity of instant, espresso, filter and Turkish/Greek coffee brews, coffee substitutes (roasted chicory root, barley, pea, chickpea, carob and dried fig) and individual compounds (phenolic acids, flavonoids, methylxanthines, N-methyl pyridinium and HMW melanoidins) was assessed using DC polarographic assay based on decrease of anodic current originating from hydroxo-perhydroxo mercury complex formed in alkaline solutions of H2O2 at potential of mercury dissolution, as well as three spectrophotometric assays (DPPH, ABTS and FRAP). A large difference between applied assays ability to recognize various types of individual AOs was noticed. Only according to DC polarographic assay significant AO activity was ascribed to methylxanthines and N-methyl pyridinum. The total content of phenolics (TPC) present in complex samples was determined by FC assay. The highest TPC was ascribed to instant coffees and coffee substitutes while the lowest to decaffeinated filter coffee. Complex samples were grouped based on principal components analysis, phenolics AO coefficient, calculated as the ratio between AO capacity and TPC, and relative AO capacity index (RACI), calculated by assigning equal weight to all applied assays including FC. The highest values of RACI were ascribed to instant coffee brews, followed by substitutes while the lowest to the decaffeinated espresso coffee.
PB  - Springer India, New Delhi
T2  - Journal of Food Science and Technology, Mysore
T1  - Antioxidant efficiency of polyphenols from coffee and coffee substitutes-electrochemical versus spectrophotometric approach
VL  - 54
IS  - 8
SP  - 2324
EP  - 2331
DO  - 10.1007/s13197-017-2672-y
ER  - 
@article{
author = "Gorjanović, Stanislava and Komes, Drazenka and Lalicic-Petronijevic, Jovanka and Pastor, Ferenc and Belscak-Cvitanovic, Ana and Veljović, Mile S. and Pezo, Lato and Suznjevic, Desanka Z.",
year = "2017",
abstract = "Antioxidant (AO) capacity of instant, espresso, filter and Turkish/Greek coffee brews, coffee substitutes (roasted chicory root, barley, pea, chickpea, carob and dried fig) and individual compounds (phenolic acids, flavonoids, methylxanthines, N-methyl pyridinium and HMW melanoidins) was assessed using DC polarographic assay based on decrease of anodic current originating from hydroxo-perhydroxo mercury complex formed in alkaline solutions of H2O2 at potential of mercury dissolution, as well as three spectrophotometric assays (DPPH, ABTS and FRAP). A large difference between applied assays ability to recognize various types of individual AOs was noticed. Only according to DC polarographic assay significant AO activity was ascribed to methylxanthines and N-methyl pyridinum. The total content of phenolics (TPC) present in complex samples was determined by FC assay. The highest TPC was ascribed to instant coffees and coffee substitutes while the lowest to decaffeinated filter coffee. Complex samples were grouped based on principal components analysis, phenolics AO coefficient, calculated as the ratio between AO capacity and TPC, and relative AO capacity index (RACI), calculated by assigning equal weight to all applied assays including FC. The highest values of RACI were ascribed to instant coffee brews, followed by substitutes while the lowest to the decaffeinated espresso coffee.",
publisher = "Springer India, New Delhi",
journal = "Journal of Food Science and Technology, Mysore",
title = "Antioxidant efficiency of polyphenols from coffee and coffee substitutes-electrochemical versus spectrophotometric approach",
volume = "54",
number = "8",
pages = "2324-2331",
doi = "10.1007/s13197-017-2672-y"
}
Gorjanović, S., Komes, D., Lalicic-Petronijevic, J., Pastor, F., Belscak-Cvitanovic, A., Veljović, M. S., Pezo, L.,& Suznjevic, D. Z.. (2017). Antioxidant efficiency of polyphenols from coffee and coffee substitutes-electrochemical versus spectrophotometric approach. in Journal of Food Science and Technology, Mysore
Springer India, New Delhi., 54(8), 2324-2331.
https://doi.org/10.1007/s13197-017-2672-y
Gorjanović S, Komes D, Lalicic-Petronijevic J, Pastor F, Belscak-Cvitanovic A, Veljović MS, Pezo L, Suznjevic DZ. Antioxidant efficiency of polyphenols from coffee and coffee substitutes-electrochemical versus spectrophotometric approach. in Journal of Food Science and Technology, Mysore. 2017;54(8):2324-2331.
doi:10.1007/s13197-017-2672-y .
Gorjanović, Stanislava, Komes, Drazenka, Lalicic-Petronijevic, Jovanka, Pastor, Ferenc, Belscak-Cvitanovic, Ana, Veljović, Mile S., Pezo, Lato, Suznjevic, Desanka Z., "Antioxidant efficiency of polyphenols from coffee and coffee substitutes-electrochemical versus spectrophotometric approach" in Journal of Food Science and Technology, Mysore, 54, no. 8 (2017):2324-2331,
https://doi.org/10.1007/s13197-017-2672-y . .
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Determination of Copper in Wine by Anodic Stripping Voltammetry with Rotating Glassy Carbon and Microfiber Carbon Electrode

Suznjevic, Desanka Z.; Pastor, Ferenc; Gorjanović, Stanislava

(Croatian Chemical Soc, Zagreb, 2017)

TY  - JOUR
AU  - Suznjevic, Desanka Z.
AU  - Pastor, Ferenc
AU  - Gorjanović, Stanislava
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2554
AB  - Anodic stripping voltammetry (ASV) with rotating glassy carbon electrode (RGCE) and microfiber carbon electrode (mu FCE), both filmed with mercury, were used to determine copper content in wine. Influence of phenolics on in situ mercury film formation was studied. Wine and quercetin were added gradually into solution of Hg(II) in acetic acid-sodium acetate buffer (pH = 4.60). Reduction of Hg(II) was observed in both cases. In situ filmed electrode was found unsuitable. Results obtained using ex situ filmed RGCE and mu FCE were found in good agreement with ASV using hanging mercury drop electrode. Thus, ASV with ex situ mercury filmed electrodes can be recommended for accurate quantification of copper in complex samples containing phenolics, without any special pretreatments.
PB  - Croatian Chemical Soc, Zagreb
T2  - Croatica Chemica Acta
T1  - Determination of Copper in Wine by Anodic Stripping Voltammetry with Rotating Glassy Carbon and Microfiber Carbon Electrode
VL  - 90
IS  - 2
SP  - 353
EP  - 357
DO  - 10.5562/cca3178
ER  - 
@article{
author = "Suznjevic, Desanka Z. and Pastor, Ferenc and Gorjanović, Stanislava",
year = "2017",
abstract = "Anodic stripping voltammetry (ASV) with rotating glassy carbon electrode (RGCE) and microfiber carbon electrode (mu FCE), both filmed with mercury, were used to determine copper content in wine. Influence of phenolics on in situ mercury film formation was studied. Wine and quercetin were added gradually into solution of Hg(II) in acetic acid-sodium acetate buffer (pH = 4.60). Reduction of Hg(II) was observed in both cases. In situ filmed electrode was found unsuitable. Results obtained using ex situ filmed RGCE and mu FCE were found in good agreement with ASV using hanging mercury drop electrode. Thus, ASV with ex situ mercury filmed electrodes can be recommended for accurate quantification of copper in complex samples containing phenolics, without any special pretreatments.",
publisher = "Croatian Chemical Soc, Zagreb",
journal = "Croatica Chemica Acta",
title = "Determination of Copper in Wine by Anodic Stripping Voltammetry with Rotating Glassy Carbon and Microfiber Carbon Electrode",
volume = "90",
number = "2",
pages = "353-357",
doi = "10.5562/cca3178"
}
Suznjevic, D. Z., Pastor, F.,& Gorjanović, S.. (2017). Determination of Copper in Wine by Anodic Stripping Voltammetry with Rotating Glassy Carbon and Microfiber Carbon Electrode. in Croatica Chemica Acta
Croatian Chemical Soc, Zagreb., 90(2), 353-357.
https://doi.org/10.5562/cca3178
Suznjevic DZ, Pastor F, Gorjanović S. Determination of Copper in Wine by Anodic Stripping Voltammetry with Rotating Glassy Carbon and Microfiber Carbon Electrode. in Croatica Chemica Acta. 2017;90(2):353-357.
doi:10.5562/cca3178 .
Suznjevic, Desanka Z., Pastor, Ferenc, Gorjanović, Stanislava, "Determination of Copper in Wine by Anodic Stripping Voltammetry with Rotating Glassy Carbon and Microfiber Carbon Electrode" in Croatica Chemica Acta, 90, no. 2 (2017):353-357,
https://doi.org/10.5562/cca3178 . .
1
1

Investigation of antioxidant capacity of several luting cements processes by HPMC method

Ilić, Dragan V.; Obradović-Đuričić, Kosovka; Medić, Vesna; Poštić, Srđan; Gorjanović, Stanislava; Pastor, Ferenc; Radović, Katarina

(2016)

TY  - JOUR
AU  - Ilić, Dragan V.
AU  - Obradović-Đuričić, Kosovka
AU  - Medić, Vesna
AU  - Poštić, Srđan
AU  - Gorjanović, Stanislava
AU  - Pastor, Ferenc
AU  - Radović, Katarina
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/218
AB  - Background: Free radicals (FR) occur in oral cavity where lot of food was transferred to through entire life under specific saliva conditions. Many enzymes, microorganism, alcohol beverages, nicotine and other harmful or indifferent substances when in contact to oral tissues might provoke oxidation process under specific condition creating FR's. The similar role might have various dental materials. Aim of the study was to record the level of antioxidant (AO) activity of several permanent (P) luting cements alone or combined with quercetin AO substance. Materials/Methods: P cements were Zn-phosphate, Zn-polycarboxilate, GIC and composite resin cement. They were prepared as original prescription and their variant by 1% weight addition of quercetin. AO activity of cements was measured by HPMC test evaluated by Student t test. Results: There were statistically significant differences among Zn-phosphate, Zn-polycarboxilate and resin dental cements (p  gt  0,05). GIC displayed significantly higher AO values (p  lt  0,01) versus other three cements. There were no difference in AO capacity between sample of original P cements and their corresponding quercetin variants (p  gt  0,05). Conclusions: Conventional GIC displayed the most powerful AO activity among P luting cements. Addition of 1% antioxidant quercetin did not improve AO capacity of investigated cements.
T2  - Balkan Journal of Dental Medicine
T1  - Investigation of antioxidant capacity of several luting cements processes by HPMC method
VL  - 20
IS  - 3
SP  - 155
EP  - 159
DO  - 10.1515/bjdm-2016-0025
ER  - 
@article{
author = "Ilić, Dragan V. and Obradović-Đuričić, Kosovka and Medić, Vesna and Poštić, Srđan and Gorjanović, Stanislava and Pastor, Ferenc and Radović, Katarina",
year = "2016",
abstract = "Background: Free radicals (FR) occur in oral cavity where lot of food was transferred to through entire life under specific saliva conditions. Many enzymes, microorganism, alcohol beverages, nicotine and other harmful or indifferent substances when in contact to oral tissues might provoke oxidation process under specific condition creating FR's. The similar role might have various dental materials. Aim of the study was to record the level of antioxidant (AO) activity of several permanent (P) luting cements alone or combined with quercetin AO substance. Materials/Methods: P cements were Zn-phosphate, Zn-polycarboxilate, GIC and composite resin cement. They were prepared as original prescription and their variant by 1% weight addition of quercetin. AO activity of cements was measured by HPMC test evaluated by Student t test. Results: There were statistically significant differences among Zn-phosphate, Zn-polycarboxilate and resin dental cements (p  gt  0,05). GIC displayed significantly higher AO values (p  lt  0,01) versus other three cements. There were no difference in AO capacity between sample of original P cements and their corresponding quercetin variants (p  gt  0,05). Conclusions: Conventional GIC displayed the most powerful AO activity among P luting cements. Addition of 1% antioxidant quercetin did not improve AO capacity of investigated cements.",
journal = "Balkan Journal of Dental Medicine",
title = "Investigation of antioxidant capacity of several luting cements processes by HPMC method",
volume = "20",
number = "3",
pages = "155-159",
doi = "10.1515/bjdm-2016-0025"
}
Ilić, D. V., Obradović-Đuričić, K., Medić, V., Poštić, S., Gorjanović, S., Pastor, F.,& Radović, K.. (2016). Investigation of antioxidant capacity of several luting cements processes by HPMC method. in Balkan Journal of Dental Medicine, 20(3), 155-159.
https://doi.org/10.1515/bjdm-2016-0025
Ilić DV, Obradović-Đuričić K, Medić V, Poštić S, Gorjanović S, Pastor F, Radović K. Investigation of antioxidant capacity of several luting cements processes by HPMC method. in Balkan Journal of Dental Medicine. 2016;20(3):155-159.
doi:10.1515/bjdm-2016-0025 .
Ilić, Dragan V., Obradović-Đuričić, Kosovka, Medić, Vesna, Poštić, Srđan, Gorjanović, Stanislava, Pastor, Ferenc, Radović, Katarina, "Investigation of antioxidant capacity of several luting cements processes by HPMC method" in Balkan Journal of Dental Medicine, 20, no. 3 (2016):155-159,
https://doi.org/10.1515/bjdm-2016-0025 . .

Content of Total Phenolics, Flavan-3-Ols and Proanthocyanidins, Oxidative Stability and Antioxidant Capacity of Chocolate During Storage

Lalicic-Petronijevic, Jovanka; Komes, Drazenka; Gorjanović, Stanislava; Belscak-Cvitanovic, Ana; Pezo, Lato; Pastor, Ferenc; Ostojić, Sanja B.; Popov-Raljic, Jovanka; Sužnjević, Desanka

(Faculty Food Technology Biotechnology, Zagreb, 2016)

TY  - JOUR
AU  - Lalicic-Petronijevic, Jovanka
AU  - Komes, Drazenka
AU  - Gorjanović, Stanislava
AU  - Belscak-Cvitanovic, Ana
AU  - Pezo, Lato
AU  - Pastor, Ferenc
AU  - Ostojić, Sanja B.
AU  - Popov-Raljic, Jovanka
AU  - Sužnjević, Desanka
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1919
AB  - Antioxidant (AO) capacity of chocolates with 27, 44 and 75 % cocoa was assessed after production and during twelve months of storage by direct current (DC) polarographic assay, based on the decrease of anodic current caused by the formation of hydroxo-perhydroxyl mercury(II) complex (HPMC) in alkaline solutions of hydrogen peroxide at potentials of mercury oxidation, and two spectrophotometric assays. Relative antioxidant capacity index (RACI) was calculated by taking the average value of the AO assay (the sample mass in all assays was identical). Oxidative stability of chocolate fat was determined by differential scanning calorimetry. Measured parameters and RACI were correlated mutually and with the content of total phenols (Folin-Ciocalteu assay), flavan-3-ols (vanillin and p-dimethylaminocinnamaldehyde assay) and proanthocyanidins (modified Bate-Smith assay). During storage, the studied functional and health-related characteristics remained unchanged. Amongst applied AO assays, the DC polarographic one, whose validity was confirmed by two-way ANOVA and F-test, correlated most significantly with oxidative stability (oxidation onset temperature and induction time). In addition, principal component analysis was applied to characterise chocolate types.
PB  - Faculty Food Technology Biotechnology, Zagreb
T2  - Food Technology and Biotechnology
T1  - Content of Total Phenolics, Flavan-3-Ols and Proanthocyanidins, Oxidative Stability and Antioxidant Capacity of Chocolate During Storage
VL  - 54
IS  - 1
SP  - 13
EP  - 20
UR  - https://hdl.handle.net/21.15107/rcub_cherry_1919
ER  - 
@article{
author = "Lalicic-Petronijevic, Jovanka and Komes, Drazenka and Gorjanović, Stanislava and Belscak-Cvitanovic, Ana and Pezo, Lato and Pastor, Ferenc and Ostojić, Sanja B. and Popov-Raljic, Jovanka and Sužnjević, Desanka",
year = "2016",
abstract = "Antioxidant (AO) capacity of chocolates with 27, 44 and 75 % cocoa was assessed after production and during twelve months of storage by direct current (DC) polarographic assay, based on the decrease of anodic current caused by the formation of hydroxo-perhydroxyl mercury(II) complex (HPMC) in alkaline solutions of hydrogen peroxide at potentials of mercury oxidation, and two spectrophotometric assays. Relative antioxidant capacity index (RACI) was calculated by taking the average value of the AO assay (the sample mass in all assays was identical). Oxidative stability of chocolate fat was determined by differential scanning calorimetry. Measured parameters and RACI were correlated mutually and with the content of total phenols (Folin-Ciocalteu assay), flavan-3-ols (vanillin and p-dimethylaminocinnamaldehyde assay) and proanthocyanidins (modified Bate-Smith assay). During storage, the studied functional and health-related characteristics remained unchanged. Amongst applied AO assays, the DC polarographic one, whose validity was confirmed by two-way ANOVA and F-test, correlated most significantly with oxidative stability (oxidation onset temperature and induction time). In addition, principal component analysis was applied to characterise chocolate types.",
publisher = "Faculty Food Technology Biotechnology, Zagreb",
journal = "Food Technology and Biotechnology",
title = "Content of Total Phenolics, Flavan-3-Ols and Proanthocyanidins, Oxidative Stability and Antioxidant Capacity of Chocolate During Storage",
volume = "54",
number = "1",
pages = "13-20",
url = "https://hdl.handle.net/21.15107/rcub_cherry_1919"
}
Lalicic-Petronijevic, J., Komes, D., Gorjanović, S., Belscak-Cvitanovic, A., Pezo, L., Pastor, F., Ostojić, S. B., Popov-Raljic, J.,& Sužnjević, D.. (2016). Content of Total Phenolics, Flavan-3-Ols and Proanthocyanidins, Oxidative Stability and Antioxidant Capacity of Chocolate During Storage. in Food Technology and Biotechnology
Faculty Food Technology Biotechnology, Zagreb., 54(1), 13-20.
https://hdl.handle.net/21.15107/rcub_cherry_1919
Lalicic-Petronijevic J, Komes D, Gorjanović S, Belscak-Cvitanovic A, Pezo L, Pastor F, Ostojić SB, Popov-Raljic J, Sužnjević D. Content of Total Phenolics, Flavan-3-Ols and Proanthocyanidins, Oxidative Stability and Antioxidant Capacity of Chocolate During Storage. in Food Technology and Biotechnology. 2016;54(1):13-20.
https://hdl.handle.net/21.15107/rcub_cherry_1919 .
Lalicic-Petronijevic, Jovanka, Komes, Drazenka, Gorjanović, Stanislava, Belscak-Cvitanovic, Ana, Pezo, Lato, Pastor, Ferenc, Ostojić, Sanja B., Popov-Raljic, Jovanka, Sužnjević, Desanka, "Content of Total Phenolics, Flavan-3-Ols and Proanthocyanidins, Oxidative Stability and Antioxidant Capacity of Chocolate During Storage" in Food Technology and Biotechnology, 54, no. 1 (2016):13-20,
https://hdl.handle.net/21.15107/rcub_cherry_1919 .
11
23

Antioxidant Capacity Determination of Complex Samples and Individual Phenolics - Multilateral Approach

Petrović, Marija S.; Sužnjević, Desanka; Pastor, Ferenc; Veljović, Mile S.; Pezo, Lato; Antić, Mališa; Gorjanović, Stanislava

(Bentham Science Publ Ltd, Sharjah, 2016)

TY  - JOUR
AU  - Petrović, Marija S.
AU  - Sužnjević, Desanka
AU  - Pastor, Ferenc
AU  - Veljović, Mile S.
AU  - Pezo, Lato
AU  - Antić, Mališa
AU  - Gorjanović, Stanislava
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1963
AB  - Antioxidant (AO) capacity of various medicinal plants extracts and phenolic compounds was assessed by the most widely used spectrophotometric assays such as ferric reducing antioxidant power (FRAP) and scavenging of 2,2-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS) and 2,2-diphenyl-1-picrylhydrazyl (DPPH). In addition, two direct current (DC) polarographic assays, one based on a decrease of anodic current of [Hg(O2H)(OH)]-HydroxoPerhydroxoMercury(II) Complex (HPMC) formation in alkaline solution of H2O2, at the potential of mercury dissolution and another recently developed Mercury Reduction Antioxidant Power (MRAP), based on a a decrease of cathodic current of Hg(II) reduction were employed. Percentage of both currents decrease was plotted versus the volume of gradually added complex samples or the amount of individual ones and the slopes of these plots were used to express AO capacity. Total phenolic content (TPC) of extracts was determined by Folin-Ciocalteu (FC) assay. Correlations between applied assays were calculated by regression analysis. Relative Antioxidant Capacity Index (RACI), calculated by assigning equal weight to all applied assays and Phenolic Antioxidant Coefficients (PAC), calculated as a ratio between particular AO capacity and TPC, were used to achieve more comprehensive comparison between analyzed samples, as well as applied assays.
PB  - Bentham Science Publ Ltd, Sharjah
T2  - Combinatorial Chemistry and High Throughput Screening
T1  - Antioxidant Capacity Determination of Complex Samples and Individual Phenolics - Multilateral Approach
VL  - 19
IS  - 1
SP  - 58
EP  - 65
DO  - 10.2174/1386207318666151102094227
ER  - 
@article{
author = "Petrović, Marija S. and Sužnjević, Desanka and Pastor, Ferenc and Veljović, Mile S. and Pezo, Lato and Antić, Mališa and Gorjanović, Stanislava",
year = "2016",
abstract = "Antioxidant (AO) capacity of various medicinal plants extracts and phenolic compounds was assessed by the most widely used spectrophotometric assays such as ferric reducing antioxidant power (FRAP) and scavenging of 2,2-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS) and 2,2-diphenyl-1-picrylhydrazyl (DPPH). In addition, two direct current (DC) polarographic assays, one based on a decrease of anodic current of [Hg(O2H)(OH)]-HydroxoPerhydroxoMercury(II) Complex (HPMC) formation in alkaline solution of H2O2, at the potential of mercury dissolution and another recently developed Mercury Reduction Antioxidant Power (MRAP), based on a a decrease of cathodic current of Hg(II) reduction were employed. Percentage of both currents decrease was plotted versus the volume of gradually added complex samples or the amount of individual ones and the slopes of these plots were used to express AO capacity. Total phenolic content (TPC) of extracts was determined by Folin-Ciocalteu (FC) assay. Correlations between applied assays were calculated by regression analysis. Relative Antioxidant Capacity Index (RACI), calculated by assigning equal weight to all applied assays and Phenolic Antioxidant Coefficients (PAC), calculated as a ratio between particular AO capacity and TPC, were used to achieve more comprehensive comparison between analyzed samples, as well as applied assays.",
publisher = "Bentham Science Publ Ltd, Sharjah",
journal = "Combinatorial Chemistry and High Throughput Screening",
title = "Antioxidant Capacity Determination of Complex Samples and Individual Phenolics - Multilateral Approach",
volume = "19",
number = "1",
pages = "58-65",
doi = "10.2174/1386207318666151102094227"
}
Petrović, M. S., Sužnjević, D., Pastor, F., Veljović, M. S., Pezo, L., Antić, M.,& Gorjanović, S.. (2016). Antioxidant Capacity Determination of Complex Samples and Individual Phenolics - Multilateral Approach. in Combinatorial Chemistry and High Throughput Screening
Bentham Science Publ Ltd, Sharjah., 19(1), 58-65.
https://doi.org/10.2174/1386207318666151102094227
Petrović MS, Sužnjević D, Pastor F, Veljović MS, Pezo L, Antić M, Gorjanović S. Antioxidant Capacity Determination of Complex Samples and Individual Phenolics - Multilateral Approach. in Combinatorial Chemistry and High Throughput Screening. 2016;19(1):58-65.
doi:10.2174/1386207318666151102094227 .
Petrović, Marija S., Sužnjević, Desanka, Pastor, Ferenc, Veljović, Mile S., Pezo, Lato, Antić, Mališa, Gorjanović, Stanislava, "Antioxidant Capacity Determination of Complex Samples and Individual Phenolics - Multilateral Approach" in Combinatorial Chemistry and High Throughput Screening, 19, no. 1 (2016):58-65,
https://doi.org/10.2174/1386207318666151102094227 . .
25
16
26
18

DC polarographic examination of Hg2+ reduction applicability to antioxidant activity determination

Suznjevic, Desanka Z.; Pastor, Ferenc; Gorjanović, Stanislava

(Pergamon-Elsevier Science Ltd, Oxford, 2015)

TY  - JOUR
AU  - Suznjevic, Desanka Z.
AU  - Pastor, Ferenc
AU  - Gorjanović, Stanislava
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1708
AB  - Direct current polarographic (DCP) antioxidant assay based on the decrease of anodic limiting current of HydroxoPerhydroxoMercury(II) Complex [Hg(O2H)(OH)] (HPMC) upon addition of antioxidants (AOs) was verified. Here, influence of several common AOs on DCP cathodic currents of both HPMC and Hg2+ was followed. Amperometric titrations of HPMC and Hg2+ with AOs and potentiometric titrations of Hg2+ were performed. The changes of DCP i-E curves and limiting currents decrease during amperometric titrations, as well as end points of amperometric and potentiometric titrations for each AO used as titrant proved the occurrence of Hg2+ reduction, either from complex (HPMC) or salt (HgCl2) solution. Constant H2O2 reduction current during amperometric titration of HPMC further confirmed the participation of Hg2+ as the oxidant species in reaction with AOs. The possibility of determining AO activity of flavonoids, phenolic acids, ascorbic acid and Trolox based on the decrease of Hg2+ reduction current was demonstrated. Strict correlation (R-2 = 0.96) between a new AO assay named MRAP (Mercury Reduction Antioxidant Power) and HPMC assay was found. Total AO capacity of real samples was measured by the proposed fast, simple and inexpensive MRAP assay as well. (C) 2015 Elsevier Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Electrochimica Acta
T1  - DC polarographic examination of Hg2+ reduction applicability to antioxidant activity determination
VL  - 168
SP  - 240
EP  - 245
DO  - 10.1016/j.electacta.2015.04.008
ER  - 
@article{
author = "Suznjevic, Desanka Z. and Pastor, Ferenc and Gorjanović, Stanislava",
year = "2015",
abstract = "Direct current polarographic (DCP) antioxidant assay based on the decrease of anodic limiting current of HydroxoPerhydroxoMercury(II) Complex [Hg(O2H)(OH)] (HPMC) upon addition of antioxidants (AOs) was verified. Here, influence of several common AOs on DCP cathodic currents of both HPMC and Hg2+ was followed. Amperometric titrations of HPMC and Hg2+ with AOs and potentiometric titrations of Hg2+ were performed. The changes of DCP i-E curves and limiting currents decrease during amperometric titrations, as well as end points of amperometric and potentiometric titrations for each AO used as titrant proved the occurrence of Hg2+ reduction, either from complex (HPMC) or salt (HgCl2) solution. Constant H2O2 reduction current during amperometric titration of HPMC further confirmed the participation of Hg2+ as the oxidant species in reaction with AOs. The possibility of determining AO activity of flavonoids, phenolic acids, ascorbic acid and Trolox based on the decrease of Hg2+ reduction current was demonstrated. Strict correlation (R-2 = 0.96) between a new AO assay named MRAP (Mercury Reduction Antioxidant Power) and HPMC assay was found. Total AO capacity of real samples was measured by the proposed fast, simple and inexpensive MRAP assay as well. (C) 2015 Elsevier Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "DC polarographic examination of Hg2+ reduction applicability to antioxidant activity determination",
volume = "168",
pages = "240-245",
doi = "10.1016/j.electacta.2015.04.008"
}
Suznjevic, D. Z., Pastor, F.,& Gorjanović, S.. (2015). DC polarographic examination of Hg2+ reduction applicability to antioxidant activity determination. in Electrochimica Acta
Pergamon-Elsevier Science Ltd, Oxford., 168, 240-245.
https://doi.org/10.1016/j.electacta.2015.04.008
Suznjevic DZ, Pastor F, Gorjanović S. DC polarographic examination of Hg2+ reduction applicability to antioxidant activity determination. in Electrochimica Acta. 2015;168:240-245.
doi:10.1016/j.electacta.2015.04.008 .
Suznjevic, Desanka Z., Pastor, Ferenc, Gorjanović, Stanislava, "DC polarographic examination of Hg2+ reduction applicability to antioxidant activity determination" in Electrochimica Acta, 168 (2015):240-245,
https://doi.org/10.1016/j.electacta.2015.04.008 . .
6
5
8
6

Reduction of Hg2+ by Individual Phenolics and Complex Samples and Its Application in Polarographic Antioxidant Assay

Sužnjević, Desanka; Petrović, Marija S.; Pastor, Ferenc; Veljović, Mile S.; Zlatanović, Snežana; Antić, Mališa; Gorjanović, Stanislava

(Electrochemical Soc Inc, Pennington, 2015)

TY  - JOUR
AU  - Sužnjević, Desanka
AU  - Petrović, Marija S.
AU  - Pastor, Ferenc
AU  - Veljović, Mile S.
AU  - Zlatanović, Snežana
AU  - Antić, Mališa
AU  - Gorjanović, Stanislava
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1721
AB  - Direct current (DC) polarographic antioxidant (AO) HPMC assay based on the decrease of anodic limiting current of [Hg(O2H)(OH)] (HydroxoPerhydroxoMercury(II) Complex-HPMC), formed in alkaline solution of H2O2, at potential of mercury oxidation, occurring upon AO addition, was validated and widely used recently. Here, a novel DC polarographic assay, MRAP (Mercury Reduction Antioxidant Power), based on the decrease of Hg2+ cathodic current with addition of AOs was applied. Percentage of this decrease was plotted versus the amount of various individual phenolics or the volume of medicinal plant extracts, and the slope obtained was used to express AO activity. A high correlation between MRAP and HPMC assays was found for individual compounds (r = 0.974) and real samples (r = 0.968). MRAP was shown to be effective in the determination of AO activity of both synthetic mixtures of individual AOs and real samples containing various AOs. Agreement between the decrease of Hg2+ cathodic current and HPMC anodic current lead to the assumption that Hg2+ reduction causes a decrease in concentration of Hg2+ available for HMPC complex formation, i.e. its anodic current decrease. The validity Of MRAP assay was also confirmed through good correlation with FRAP assay.
PB  - Electrochemical Soc Inc, Pennington
T2  - Journal of the Electrochemical Society
T1  - Reduction of Hg2+ by Individual Phenolics and Complex Samples and Its Application in Polarographic Antioxidant Assay
VL  - 162
IS  - 7
DO  - 10.1149/2.0141507jes
ER  - 
@article{
author = "Sužnjević, Desanka and Petrović, Marija S. and Pastor, Ferenc and Veljović, Mile S. and Zlatanović, Snežana and Antić, Mališa and Gorjanović, Stanislava",
year = "2015",
abstract = "Direct current (DC) polarographic antioxidant (AO) HPMC assay based on the decrease of anodic limiting current of [Hg(O2H)(OH)] (HydroxoPerhydroxoMercury(II) Complex-HPMC), formed in alkaline solution of H2O2, at potential of mercury oxidation, occurring upon AO addition, was validated and widely used recently. Here, a novel DC polarographic assay, MRAP (Mercury Reduction Antioxidant Power), based on the decrease of Hg2+ cathodic current with addition of AOs was applied. Percentage of this decrease was plotted versus the amount of various individual phenolics or the volume of medicinal plant extracts, and the slope obtained was used to express AO activity. A high correlation between MRAP and HPMC assays was found for individual compounds (r = 0.974) and real samples (r = 0.968). MRAP was shown to be effective in the determination of AO activity of both synthetic mixtures of individual AOs and real samples containing various AOs. Agreement between the decrease of Hg2+ cathodic current and HPMC anodic current lead to the assumption that Hg2+ reduction causes a decrease in concentration of Hg2+ available for HMPC complex formation, i.e. its anodic current decrease. The validity Of MRAP assay was also confirmed through good correlation with FRAP assay.",
publisher = "Electrochemical Soc Inc, Pennington",
journal = "Journal of the Electrochemical Society",
title = "Reduction of Hg2+ by Individual Phenolics and Complex Samples and Its Application in Polarographic Antioxidant Assay",
volume = "162",
number = "7",
doi = "10.1149/2.0141507jes"
}
Sužnjević, D., Petrović, M. S., Pastor, F., Veljović, M. S., Zlatanović, S., Antić, M.,& Gorjanović, S.. (2015). Reduction of Hg2+ by Individual Phenolics and Complex Samples and Its Application in Polarographic Antioxidant Assay. in Journal of the Electrochemical Society
Electrochemical Soc Inc, Pennington., 162(7).
https://doi.org/10.1149/2.0141507jes
Sužnjević D, Petrović MS, Pastor F, Veljović MS, Zlatanović S, Antić M, Gorjanović S. Reduction of Hg2+ by Individual Phenolics and Complex Samples and Its Application in Polarographic Antioxidant Assay. in Journal of the Electrochemical Society. 2015;162(7).
doi:10.1149/2.0141507jes .
Sužnjević, Desanka, Petrović, Marija S., Pastor, Ferenc, Veljović, Mile S., Zlatanović, Snežana, Antić, Mališa, Gorjanović, Stanislava, "Reduction of Hg2+ by Individual Phenolics and Complex Samples and Its Application in Polarographic Antioxidant Assay" in Journal of the Electrochemical Society, 162, no. 7 (2015),
https://doi.org/10.1149/2.0141507jes . .
6
4
7
6

Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds

Gorjanović, Stanislava; Pastor, Ferenc; Vasic, Radica; Novaković, Miroslav M.; Simonovic, Mladen; Milic, Sonja; Sužnjević, Desanka

(Amer Chemical Soc, Washington, 2013)

TY  - JOUR
AU  - Gorjanović, Stanislava
AU  - Pastor, Ferenc
AU  - Vasic, Radica
AU  - Novaković, Miroslav M.
AU  - Simonovic, Mladen
AU  - Milic, Sonja
AU  - Sužnjević, Desanka
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1491
AB  - Antioxidant (AO) activity of extracts of hop cones (Serbian domestic varieties) and commercial hop products (Saaz, Spalter, Spalter select, and Magnum pellets) was determined by parallel application of recently developed direct current (DC) polarographic and widely used DPPH assay. Correlations between 2,2-diphenyl-1-picrylhydrazyl radical (DPPH) scavenging and total phenolics (TPC) determined by the Folin-Ciocalteu assay (FC) (0.99), and between H2O2 scavenging,: (HPS) and humulone content (H) determined by conductometric method (0.94), total resins (TR) (0.85), and hop storage index (HIS) (-0.90), were found statistically significant at p  lt  0.05 level while complete lack of HPS correlation with TPC and DPPH was observed. To obtain an insight into differences between results of AO assays applied, activity of individual compounds, prevalent hop phenolics, and bitter acids was determined. By far superior HPS activity of humulone was followed by catechin, quercetin, xanthohumol, lupulone, and rutin. In contrast, DPPH scavenging activity of phenolics (quercetin  gt  catechin  gt  rutin  gt  xantohumol) was found substantially higher than activity of bitter acids. According to ferric reducing antioxidant power (FRAP) and scavenging of 2,2-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS), higher AO activity was ascribed to phenolics, while almost neglecting humulone. Besides reliability, low cost, and an easy-to-handle procedure, an ability to recognize humulone as the major contributor of hop AO activity could allow DC polarographic assay to be applied in analysis of various hop-derived products.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Agricultural and Food Chemistry
T1  - Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds
VL  - 61
IS  - 38
SP  - 9089
EP  - 9096
DO  - 10.1021/jf401718z
ER  - 
@article{
author = "Gorjanović, Stanislava and Pastor, Ferenc and Vasic, Radica and Novaković, Miroslav M. and Simonovic, Mladen and Milic, Sonja and Sužnjević, Desanka",
year = "2013",
abstract = "Antioxidant (AO) activity of extracts of hop cones (Serbian domestic varieties) and commercial hop products (Saaz, Spalter, Spalter select, and Magnum pellets) was determined by parallel application of recently developed direct current (DC) polarographic and widely used DPPH assay. Correlations between 2,2-diphenyl-1-picrylhydrazyl radical (DPPH) scavenging and total phenolics (TPC) determined by the Folin-Ciocalteu assay (FC) (0.99), and between H2O2 scavenging,: (HPS) and humulone content (H) determined by conductometric method (0.94), total resins (TR) (0.85), and hop storage index (HIS) (-0.90), were found statistically significant at p  lt  0.05 level while complete lack of HPS correlation with TPC and DPPH was observed. To obtain an insight into differences between results of AO assays applied, activity of individual compounds, prevalent hop phenolics, and bitter acids was determined. By far superior HPS activity of humulone was followed by catechin, quercetin, xanthohumol, lupulone, and rutin. In contrast, DPPH scavenging activity of phenolics (quercetin  gt  catechin  gt  rutin  gt  xantohumol) was found substantially higher than activity of bitter acids. According to ferric reducing antioxidant power (FRAP) and scavenging of 2,2-azino-bis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS), higher AO activity was ascribed to phenolics, while almost neglecting humulone. Besides reliability, low cost, and an easy-to-handle procedure, an ability to recognize humulone as the major contributor of hop AO activity could allow DC polarographic assay to be applied in analysis of various hop-derived products.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Agricultural and Food Chemistry",
title = "Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds",
volume = "61",
number = "38",
pages = "9089-9096",
doi = "10.1021/jf401718z"
}
Gorjanović, S., Pastor, F., Vasic, R., Novaković, M. M., Simonovic, M., Milic, S.,& Sužnjević, D.. (2013). Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds. in Journal of Agricultural and Food Chemistry
Amer Chemical Soc, Washington., 61(38), 9089-9096.
https://doi.org/10.1021/jf401718z
Gorjanović S, Pastor F, Vasic R, Novaković MM, Simonovic M, Milic S, Sužnjević D. Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds. in Journal of Agricultural and Food Chemistry. 2013;61(38):9089-9096.
doi:10.1021/jf401718z .
Gorjanović, Stanislava, Pastor, Ferenc, Vasic, Radica, Novaković, Miroslav M., Simonovic, Mladen, Milic, Sonja, Sužnjević, Desanka, "Electrochemical versus Spectrophotometric Assessment of Antioxidant Activity of Hop (Humulus lupulus L.) Products and Individual Compounds" in Journal of Agricultural and Food Chemistry, 61, no. 38 (2013):9089-9096,
https://doi.org/10.1021/jf401718z . .
25
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23

Comparative analysis of antioxidant activity of honey of different floral sources using recently developed polarographic and various spectrophotometric assays

Gorjanović, Stanislava; Alvarez-Suarez, Jose Miguel; Novaković, Miroslav M.; Pastor, Ferenc; Pezo, Lato; Battino, Maurizio; Suznjevic, Desanka Z.

(Academic Press Inc Elsevier Science, San Diego, 2013)

TY  - JOUR
AU  - Gorjanović, Stanislava
AU  - Alvarez-Suarez, Jose Miguel
AU  - Novaković, Miroslav M.
AU  - Pastor, Ferenc
AU  - Pezo, Lato
AU  - Battino, Maurizio
AU  - Suznjevic, Desanka Z.
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1629
AB  - Hydrogen peroxide scavenging (HPS) activity of honey of different floral sources and its constituents such as predominant honey flavonoids, phenolic acids, amino and organic acids, and carbohydrates have been assessed by direct current (DC) polarographic assay. The assay was based on decrease of anodic current of hydrogen peroxide complex, formed in alkaline solution, at the potential of mercury dissolution. High correlations between honey HPS activity, its total phenolic content (FC-GAE), antioxidant activity measured by four standard methods (DPPH, TEAC, FRAP and ORAC), and also the relative antioxidant capacity index, were obtained. Statistical evaluation by ANOVA and F-test further confirmed the assay validity. The results for individual compounds showed that HPS activity of honey reflects an integrated action of a wide range of constituents, both phenolics and non-phenolics. The polarographic assay applied is a fast, reliable and low cost alternative to spectrophotometric antioxidant assays commonly applied in analysis of honey and can serve as an indicator of honey quality.
PB  - Academic Press Inc Elsevier Science, San Diego
T2  - Journal of Food Composition and Analysis
T1  - Comparative analysis of antioxidant activity of honey of different floral sources using recently developed polarographic and various spectrophotometric assays
VL  - 30
IS  - 1
SP  - 13
EP  - 18
DO  - 10.1016/j.jfca.2012.12.004
ER  - 
@article{
author = "Gorjanović, Stanislava and Alvarez-Suarez, Jose Miguel and Novaković, Miroslav M. and Pastor, Ferenc and Pezo, Lato and Battino, Maurizio and Suznjevic, Desanka Z.",
year = "2013",
abstract = "Hydrogen peroxide scavenging (HPS) activity of honey of different floral sources and its constituents such as predominant honey flavonoids, phenolic acids, amino and organic acids, and carbohydrates have been assessed by direct current (DC) polarographic assay. The assay was based on decrease of anodic current of hydrogen peroxide complex, formed in alkaline solution, at the potential of mercury dissolution. High correlations between honey HPS activity, its total phenolic content (FC-GAE), antioxidant activity measured by four standard methods (DPPH, TEAC, FRAP and ORAC), and also the relative antioxidant capacity index, were obtained. Statistical evaluation by ANOVA and F-test further confirmed the assay validity. The results for individual compounds showed that HPS activity of honey reflects an integrated action of a wide range of constituents, both phenolics and non-phenolics. The polarographic assay applied is a fast, reliable and low cost alternative to spectrophotometric antioxidant assays commonly applied in analysis of honey and can serve as an indicator of honey quality.",
publisher = "Academic Press Inc Elsevier Science, San Diego",
journal = "Journal of Food Composition and Analysis",
title = "Comparative analysis of antioxidant activity of honey of different floral sources using recently developed polarographic and various spectrophotometric assays",
volume = "30",
number = "1",
pages = "13-18",
doi = "10.1016/j.jfca.2012.12.004"
}
Gorjanović, S., Alvarez-Suarez, J. M., Novaković, M. M., Pastor, F., Pezo, L., Battino, M.,& Suznjevic, D. Z.. (2013). Comparative analysis of antioxidant activity of honey of different floral sources using recently developed polarographic and various spectrophotometric assays. in Journal of Food Composition and Analysis
Academic Press Inc Elsevier Science, San Diego., 30(1), 13-18.
https://doi.org/10.1016/j.jfca.2012.12.004
Gorjanović S, Alvarez-Suarez JM, Novaković MM, Pastor F, Pezo L, Battino M, Suznjevic DZ. Comparative analysis of antioxidant activity of honey of different floral sources using recently developed polarographic and various spectrophotometric assays. in Journal of Food Composition and Analysis. 2013;30(1):13-18.
doi:10.1016/j.jfca.2012.12.004 .
Gorjanović, Stanislava, Alvarez-Suarez, Jose Miguel, Novaković, Miroslav M., Pastor, Ferenc, Pezo, Lato, Battino, Maurizio, Suznjevic, Desanka Z., "Comparative analysis of antioxidant activity of honey of different floral sources using recently developed polarographic and various spectrophotometric assays" in Journal of Food Composition and Analysis, 30, no. 1 (2013):13-18,
https://doi.org/10.1016/j.jfca.2012.12.004 . .
80
72
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76

Antioxidant Capacity of Teas and Herbal Infusions: Polarographic Assessment

Gorjanović, Stanislava; Komes, Drazenka; Pastor, Ferenc; Belscak-Cvitanovic, Ana; Pezo, Lato; Hecimovic, Ivana; Sužnjević, Desanka

(Amer Chemical Soc, Washington, 2012)

TY  - JOUR
AU  - Gorjanović, Stanislava
AU  - Komes, Drazenka
AU  - Pastor, Ferenc
AU  - Belscak-Cvitanovic, Ana
AU  - Pezo, Lato
AU  - Hecimovic, Ivana
AU  - Sužnjević, Desanka
PY  - 2012
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1533
AB  - Hydrogen peroxide scavenging (HPS) activity of unfermented (green, yellow, and white), partially fermented (oolong), and completely fermented (black) tea (Camellia sinensis), mate (Ilex paraguariensis), and various herbal infusions, as well as individual compounds (flavan-3-ols, flavonols, cinnamic and benzoic acids, and methylxanthines), was assessed by recently developed direct current (DC) polarographic assay. Correlations of tea and herbal infusion HPS activity with total phenolic content determined using the Folin-Ciocalteu assay (FC-GAE) (0.81 and 0.93), ferric reducing/antioxidant power (FRAP) (0.97 and 0.92), 1,1-diphenyl-2-picrylhydrazyl (DPPH) (0.77 and 0.80), and 2,2'-azinobis(3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) scavenging (0.86 and 0.86) were statistically significant. Correlations between relative antioxidant capacity index (RACI), calculated by assigning all applied assays equal weight, and HPS (0.98), FRAP (0.97), ABTS (0.89), and DPPH (0.89) confirmed DC polarographic assay reliability when applied individually. Correlation analysis, ANOVA, and Levene and Tukey's HSD tests unequivocally confirmed this reliable, rapid, and low-cost assay validity, clearly demonstrating its advantages over spectrophotometric assays applied.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Agricultural and Food Chemistry
T1  - Antioxidant Capacity of Teas and Herbal Infusions: Polarographic Assessment
VL  - 60
IS  - 38
SP  - 9573
EP  - 9580
DO  - 10.1021/jf302375t
ER  - 
@article{
author = "Gorjanović, Stanislava and Komes, Drazenka and Pastor, Ferenc and Belscak-Cvitanovic, Ana and Pezo, Lato and Hecimovic, Ivana and Sužnjević, Desanka",
year = "2012",
abstract = "Hydrogen peroxide scavenging (HPS) activity of unfermented (green, yellow, and white), partially fermented (oolong), and completely fermented (black) tea (Camellia sinensis), mate (Ilex paraguariensis), and various herbal infusions, as well as individual compounds (flavan-3-ols, flavonols, cinnamic and benzoic acids, and methylxanthines), was assessed by recently developed direct current (DC) polarographic assay. Correlations of tea and herbal infusion HPS activity with total phenolic content determined using the Folin-Ciocalteu assay (FC-GAE) (0.81 and 0.93), ferric reducing/antioxidant power (FRAP) (0.97 and 0.92), 1,1-diphenyl-2-picrylhydrazyl (DPPH) (0.77 and 0.80), and 2,2'-azinobis(3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) scavenging (0.86 and 0.86) were statistically significant. Correlations between relative antioxidant capacity index (RACI), calculated by assigning all applied assays equal weight, and HPS (0.98), FRAP (0.97), ABTS (0.89), and DPPH (0.89) confirmed DC polarographic assay reliability when applied individually. Correlation analysis, ANOVA, and Levene and Tukey's HSD tests unequivocally confirmed this reliable, rapid, and low-cost assay validity, clearly demonstrating its advantages over spectrophotometric assays applied.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Agricultural and Food Chemistry",
title = "Antioxidant Capacity of Teas and Herbal Infusions: Polarographic Assessment",
volume = "60",
number = "38",
pages = "9573-9580",
doi = "10.1021/jf302375t"
}
Gorjanović, S., Komes, D., Pastor, F., Belscak-Cvitanovic, A., Pezo, L., Hecimovic, I.,& Sužnjević, D.. (2012). Antioxidant Capacity of Teas and Herbal Infusions: Polarographic Assessment. in Journal of Agricultural and Food Chemistry
Amer Chemical Soc, Washington., 60(38), 9573-9580.
https://doi.org/10.1021/jf302375t
Gorjanović S, Komes D, Pastor F, Belscak-Cvitanovic A, Pezo L, Hecimovic I, Sužnjević D. Antioxidant Capacity of Teas and Herbal Infusions: Polarographic Assessment. in Journal of Agricultural and Food Chemistry. 2012;60(38):9573-9580.
doi:10.1021/jf302375t .
Gorjanović, Stanislava, Komes, Drazenka, Pastor, Ferenc, Belscak-Cvitanovic, Ana, Pezo, Lato, Hecimovic, Ivana, Sužnjević, Desanka, "Antioxidant Capacity of Teas and Herbal Infusions: Polarographic Assessment" in Journal of Agricultural and Food Chemistry, 60, no. 38 (2012):9573-9580,
https://doi.org/10.1021/jf302375t . .
1
60
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56

Polarographic study of hydrogen peroxide anodic current and its application to antioxidant activity determination

Sužnjević, Desanka; Pastor, Ferenc; Gorjanović, Stanislava

(Elsevier Science Bv, Amsterdam, 2011)

TY  - JOUR
AU  - Sužnjević, Desanka
AU  - Pastor, Ferenc
AU  - Gorjanović, Stanislava
PY  - 2011
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1192
AB  - Behavior of hydrogen peroxide in alkaline medium has been studied by direct current (DC) polarography with dropping mercury electrode (DME) aiming to apply it in antioxidant (AO) activity determination. Development of a peroxide anodic current having form of a peak, instead of common polarographic wave, has been investigated. As a base for this investigation the interaction of H(2)O(2) with anodically dissolved mercury was followed. Formation of mercury complex [Hg(O(2)H)(OH)] has been confirmed. The relevant experimental conditions, such as temperature, concentration and pH dependence, as well as time stability of hydrogen peroxide anodic current, have been assessed. Development of an AO assay based on decrease of anodic current of hydrogen peroxide in the presence of antioxidants (AOs) has been described. Under optimized working conditions, a series of benzoic acids along with corresponding cinnamate analogues have been tested for hydrogen peroxide scavenging activity. In addition, the assay versatility has been confirmed on various complex samples. (C) 2011 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Talanta
T1  - Polarographic study of hydrogen peroxide anodic current and its application to antioxidant activity determination
VL  - 85
IS  - 3
SP  - 1398
EP  - 1403
DO  - 10.1016/j.talanta.2011.06.039
ER  - 
@article{
author = "Sužnjević, Desanka and Pastor, Ferenc and Gorjanović, Stanislava",
year = "2011",
abstract = "Behavior of hydrogen peroxide in alkaline medium has been studied by direct current (DC) polarography with dropping mercury electrode (DME) aiming to apply it in antioxidant (AO) activity determination. Development of a peroxide anodic current having form of a peak, instead of common polarographic wave, has been investigated. As a base for this investigation the interaction of H(2)O(2) with anodically dissolved mercury was followed. Formation of mercury complex [Hg(O(2)H)(OH)] has been confirmed. The relevant experimental conditions, such as temperature, concentration and pH dependence, as well as time stability of hydrogen peroxide anodic current, have been assessed. Development of an AO assay based on decrease of anodic current of hydrogen peroxide in the presence of antioxidants (AOs) has been described. Under optimized working conditions, a series of benzoic acids along with corresponding cinnamate analogues have been tested for hydrogen peroxide scavenging activity. In addition, the assay versatility has been confirmed on various complex samples. (C) 2011 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Talanta",
title = "Polarographic study of hydrogen peroxide anodic current and its application to antioxidant activity determination",
volume = "85",
number = "3",
pages = "1398-1403",
doi = "10.1016/j.talanta.2011.06.039"
}
Sužnjević, D., Pastor, F.,& Gorjanović, S.. (2011). Polarographic study of hydrogen peroxide anodic current and its application to antioxidant activity determination. in Talanta
Elsevier Science Bv, Amsterdam., 85(3), 1398-1403.
https://doi.org/10.1016/j.talanta.2011.06.039
Sužnjević D, Pastor F, Gorjanović S. Polarographic study of hydrogen peroxide anodic current and its application to antioxidant activity determination. in Talanta. 2011;85(3):1398-1403.
doi:10.1016/j.talanta.2011.06.039 .
Sužnjević, Desanka, Pastor, Ferenc, Gorjanović, Stanislava, "Polarographic study of hydrogen peroxide anodic current and its application to antioxidant activity determination" in Talanta, 85, no. 3 (2011):1398-1403,
https://doi.org/10.1016/j.talanta.2011.06.039 . .
36
36
41
34

A Polarographic Study of Chlorogenic Acid and Its Interaction with Some Heavy Metal Ions

Milic, Sonja Z.; Potkonjak, Nebojsa I.; Gorjanović, Stanislava; Veljović-Jovanović, Sonja; Pastor, Ferenc; Sužnjević, Desanka

(Wiley-Blackwell, Malden, 2011)

TY  - JOUR
AU  - Milic, Sonja Z.
AU  - Potkonjak, Nebojsa I.
AU  - Gorjanović, Stanislava
AU  - Veljović-Jovanović, Sonja
AU  - Pastor, Ferenc
AU  - Sužnjević, Desanka
PY  - 2011
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1232
AB  - The behavior of chlorogenic acid (CGA) and its interaction with Hg(II), Pb(II), Cu(II), Cd(II) and Zn(II) has been studied using direct current (DC) and differential-pulse polarography (DPP). Adsorptive and kinetic/catalytic anodic waves of CGA have been detected at -0.02 and -0.18 V vs. SCE, respectively; Hg(I)-CGA surface disproportionation has been assumed. Reduction of Hg(II)-ions, added in the buffered solution of CGA (pH 7.5), occurs rather than complexation, while the complex forming ability of CGA towards Pb(II) and Cu(II) has been observed. Stoichiometry 1?:?1 for Pb(II)-CGA, and 1?:?1 and 1?:?2 for Cu(II)-CGA has been established applying Jobs method of continuous variation on DPP data. UV-vis spectrophotometric measurements additionally confirmed the existence and stoichiometry of Cu(II) complexes.
PB  - Wiley-Blackwell, Malden
T2  - Electroanalysis
T1  - A Polarographic Study of Chlorogenic Acid and Its Interaction with Some Heavy Metal Ions
VL  - 23
IS  - 12
SP  - 2935
EP  - 2940
DO  - 10.1002/elan.201100476
ER  - 
@article{
author = "Milic, Sonja Z. and Potkonjak, Nebojsa I. and Gorjanović, Stanislava and Veljović-Jovanović, Sonja and Pastor, Ferenc and Sužnjević, Desanka",
year = "2011",
abstract = "The behavior of chlorogenic acid (CGA) and its interaction with Hg(II), Pb(II), Cu(II), Cd(II) and Zn(II) has been studied using direct current (DC) and differential-pulse polarography (DPP). Adsorptive and kinetic/catalytic anodic waves of CGA have been detected at -0.02 and -0.18 V vs. SCE, respectively; Hg(I)-CGA surface disproportionation has been assumed. Reduction of Hg(II)-ions, added in the buffered solution of CGA (pH 7.5), occurs rather than complexation, while the complex forming ability of CGA towards Pb(II) and Cu(II) has been observed. Stoichiometry 1?:?1 for Pb(II)-CGA, and 1?:?1 and 1?:?2 for Cu(II)-CGA has been established applying Jobs method of continuous variation on DPP data. UV-vis spectrophotometric measurements additionally confirmed the existence and stoichiometry of Cu(II) complexes.",
publisher = "Wiley-Blackwell, Malden",
journal = "Electroanalysis",
title = "A Polarographic Study of Chlorogenic Acid and Its Interaction with Some Heavy Metal Ions",
volume = "23",
number = "12",
pages = "2935-2940",
doi = "10.1002/elan.201100476"
}
Milic, S. Z., Potkonjak, N. I., Gorjanović, S., Veljović-Jovanović, S., Pastor, F.,& Sužnjević, D.. (2011). A Polarographic Study of Chlorogenic Acid and Its Interaction with Some Heavy Metal Ions. in Electroanalysis
Wiley-Blackwell, Malden., 23(12), 2935-2940.
https://doi.org/10.1002/elan.201100476
Milic SZ, Potkonjak NI, Gorjanović S, Veljović-Jovanović S, Pastor F, Sužnjević D. A Polarographic Study of Chlorogenic Acid and Its Interaction with Some Heavy Metal Ions. in Electroanalysis. 2011;23(12):2935-2940.
doi:10.1002/elan.201100476 .
Milic, Sonja Z., Potkonjak, Nebojsa I., Gorjanović, Stanislava, Veljović-Jovanović, Sonja, Pastor, Ferenc, Sužnjević, Desanka, "A Polarographic Study of Chlorogenic Acid and Its Interaction with Some Heavy Metal Ions" in Electroanalysis, 23, no. 12 (2011):2935-2940,
https://doi.org/10.1002/elan.201100476 . .
21
16
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20

Changes of Hydrogen Peroxide and Radical-Scavenging Activity of Raspberry during Osmotic, Convective, and Freeze-Drying

Novaković, Miroslav M.; Stevanovic, Snezana M.; Gorjanović, Stanislava; Jovanović, Predrag M.; Tešević, Vele; Janković, Miodrag A.; Sužnjević, Desanka

(Wiley-Blackwell, Malden, 2011)

TY  - JOUR
AU  - Novaković, Miroslav M.
AU  - Stevanovic, Snezana M.
AU  - Gorjanović, Stanislava
AU  - Jovanović, Predrag M.
AU  - Tešević, Vele
AU  - Janković, Miodrag A.
AU  - Sužnjević, Desanka
PY  - 2011
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1333
AB  - This study was conducted to investigate the influence of different drying treatments on antioxidant (AO) activity and phenolic content of raspberry (Rubus idaeus), cultivar Willamette. Whole raspberry fruits were dried convectively (air-drying), osmotically, and freeze-dried. Acetone-water extracts of fresh and dried raspberries were assessed for total phenolic content by standard Folin-Ciocalteau method. Two AO assays were applied, a recently developed direct current (DC) polarographic assay based on decrease of anodic oxidation current of hydrogen peroxide and widely used radical scavenge against the 1,1-diphenyl-2-picrylhydrazyl (DPPH). Strong correlation has been obtained between both AO assays and total phenolic content. In addition, some individual phenolic compounds present in raspberry have been assessed using DPPH and DC polarographic assay. Comparison and evaluation of drying methods has been based on preservation of AO activity and total phenolic content. Obtained results confirmed superiority of freeze-drying; convective drying caused slight changes while osmotic dehydration showed a significant decrease of phenolic compounds and AO activity. Practical Application Optimization of drying process could be based on surveying of AO activity.
PB  - Wiley-Blackwell, Malden
T2  - Journal of Food Science
T1  - Changes of Hydrogen Peroxide and Radical-Scavenging Activity of Raspberry during Osmotic, Convective, and Freeze-Drying
VL  - 76
IS  - 4
DO  - 10.1111/j.1750-3841.2011.02144.x
ER  - 
@article{
author = "Novaković, Miroslav M. and Stevanovic, Snezana M. and Gorjanović, Stanislava and Jovanović, Predrag M. and Tešević, Vele and Janković, Miodrag A. and Sužnjević, Desanka",
year = "2011",
abstract = "This study was conducted to investigate the influence of different drying treatments on antioxidant (AO) activity and phenolic content of raspberry (Rubus idaeus), cultivar Willamette. Whole raspberry fruits were dried convectively (air-drying), osmotically, and freeze-dried. Acetone-water extracts of fresh and dried raspberries were assessed for total phenolic content by standard Folin-Ciocalteau method. Two AO assays were applied, a recently developed direct current (DC) polarographic assay based on decrease of anodic oxidation current of hydrogen peroxide and widely used radical scavenge against the 1,1-diphenyl-2-picrylhydrazyl (DPPH). Strong correlation has been obtained between both AO assays and total phenolic content. In addition, some individual phenolic compounds present in raspberry have been assessed using DPPH and DC polarographic assay. Comparison and evaluation of drying methods has been based on preservation of AO activity and total phenolic content. Obtained results confirmed superiority of freeze-drying; convective drying caused slight changes while osmotic dehydration showed a significant decrease of phenolic compounds and AO activity. Practical Application Optimization of drying process could be based on surveying of AO activity.",
publisher = "Wiley-Blackwell, Malden",
journal = "Journal of Food Science",
title = "Changes of Hydrogen Peroxide and Radical-Scavenging Activity of Raspberry during Osmotic, Convective, and Freeze-Drying",
volume = "76",
number = "4",
doi = "10.1111/j.1750-3841.2011.02144.x"
}
Novaković, M. M., Stevanovic, S. M., Gorjanović, S., Jovanović, P. M., Tešević, V., Janković, M. A.,& Sužnjević, D.. (2011). Changes of Hydrogen Peroxide and Radical-Scavenging Activity of Raspberry during Osmotic, Convective, and Freeze-Drying. in Journal of Food Science
Wiley-Blackwell, Malden., 76(4).
https://doi.org/10.1111/j.1750-3841.2011.02144.x
Novaković MM, Stevanovic SM, Gorjanović S, Jovanović PM, Tešević V, Janković MA, Sužnjević D. Changes of Hydrogen Peroxide and Radical-Scavenging Activity of Raspberry during Osmotic, Convective, and Freeze-Drying. in Journal of Food Science. 2011;76(4).
doi:10.1111/j.1750-3841.2011.02144.x .
Novaković, Miroslav M., Stevanovic, Snezana M., Gorjanović, Stanislava, Jovanović, Predrag M., Tešević, Vele, Janković, Miodrag A., Sužnjević, Desanka, "Changes of Hydrogen Peroxide and Radical-Scavenging Activity of Raspberry during Osmotic, Convective, and Freeze-Drying" in Journal of Food Science, 76, no. 4 (2011),
https://doi.org/10.1111/j.1750-3841.2011.02144.x . .
23
19
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21

Polarographic Assay Based on Hydrogen Peroxide Scavenging in Determination of Antioxidant Activity of Strong Alcohol Beverages

Gorjanović, Stanislava; Novaković, Miroslav M.; Vukosavljevic, Predrag V.; Pastor, Ferenc; Tešević, Vele; Sunjevic, Desanka Z.

(Amer Chemical Soc, Washington, 2010)

TY  - JOUR
AU  - Gorjanović, Stanislava
AU  - Novaković, Miroslav M.
AU  - Vukosavljevic, Predrag V.
AU  - Pastor, Ferenc
AU  - Tešević, Vele
AU  - Sunjevic, Desanka Z.
PY  - 2010
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1092
AB  - Total antioxidant (AO) activity of strong alcohol beverages such as wine and plum brandies, whiskeys, herbal and sweet fruit liqueurs have been assessed using a polarographic assay based on hydrogen peroxide scavenging (HPS). Rank of order of total AO activity, expressed as percentage of decrease of anodic oxidation current of hydrogen peroxide, was found analogous with total phenolic content estimated by Folin Ciocalteau (FC) assay and radical scavenging capacity against the stable free radical 1,1-dipheny1-2-picrylhydrazyl (DPPH). Application of the assay for surveying of a quarter century long maturation of plum brandy in oak barrel was demonstrated. In addition, influence of different storage conditions on preservation of AO activity of some herbal liqueurs was surveyed. Wide area of application of this simple, fast, low cost and reliable assay in analysis and quality monitoring of various strong alcohol beverages was confirmed.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Agricultural and Food Chemistry
T1  - Polarographic Assay Based on Hydrogen Peroxide Scavenging in Determination of Antioxidant Activity of Strong Alcohol Beverages
VL  - 58
IS  - 14
SP  - 8400
EP  - 8406
DO  - 10.1021/jf101158j
ER  - 
@article{
author = "Gorjanović, Stanislava and Novaković, Miroslav M. and Vukosavljevic, Predrag V. and Pastor, Ferenc and Tešević, Vele and Sunjevic, Desanka Z.",
year = "2010",
abstract = "Total antioxidant (AO) activity of strong alcohol beverages such as wine and plum brandies, whiskeys, herbal and sweet fruit liqueurs have been assessed using a polarographic assay based on hydrogen peroxide scavenging (HPS). Rank of order of total AO activity, expressed as percentage of decrease of anodic oxidation current of hydrogen peroxide, was found analogous with total phenolic content estimated by Folin Ciocalteau (FC) assay and radical scavenging capacity against the stable free radical 1,1-dipheny1-2-picrylhydrazyl (DPPH). Application of the assay for surveying of a quarter century long maturation of plum brandy in oak barrel was demonstrated. In addition, influence of different storage conditions on preservation of AO activity of some herbal liqueurs was surveyed. Wide area of application of this simple, fast, low cost and reliable assay in analysis and quality monitoring of various strong alcohol beverages was confirmed.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Agricultural and Food Chemistry",
title = "Polarographic Assay Based on Hydrogen Peroxide Scavenging in Determination of Antioxidant Activity of Strong Alcohol Beverages",
volume = "58",
number = "14",
pages = "8400-8406",
doi = "10.1021/jf101158j"
}
Gorjanović, S., Novaković, M. M., Vukosavljevic, P. V., Pastor, F., Tešević, V.,& Sunjevic, D. Z.. (2010). Polarographic Assay Based on Hydrogen Peroxide Scavenging in Determination of Antioxidant Activity of Strong Alcohol Beverages. in Journal of Agricultural and Food Chemistry
Amer Chemical Soc, Washington., 58(14), 8400-8406.
https://doi.org/10.1021/jf101158j
Gorjanović S, Novaković MM, Vukosavljevic PV, Pastor F, Tešević V, Sunjevic DZ. Polarographic Assay Based on Hydrogen Peroxide Scavenging in Determination of Antioxidant Activity of Strong Alcohol Beverages. in Journal of Agricultural and Food Chemistry. 2010;58(14):8400-8406.
doi:10.1021/jf101158j .
Gorjanović, Stanislava, Novaković, Miroslav M., Vukosavljevic, Predrag V., Pastor, Ferenc, Tešević, Vele, Sunjevic, Desanka Z., "Polarographic Assay Based on Hydrogen Peroxide Scavenging in Determination of Antioxidant Activity of Strong Alcohol Beverages" in Journal of Agricultural and Food Chemistry, 58, no. 14 (2010):8400-8406,
https://doi.org/10.1021/jf101158j . .
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Antimicrobial activity of malting barley grain thaumatin-like protein isoforms, S and R

Gorjanović, Stanislava; Beljanski, Milos V.; Gavrović-Jankulović, Marija; Gojgić-Cvijović, Gordana D.; Pavlović, Mirjana D.; Bejosano, Feliciano

(Inst Brewing, London, 2007)

TY  - JOUR
AU  - Gorjanović, Stanislava
AU  - Beljanski, Milos V.
AU  - Gavrović-Jankulović, Marija
AU  - Gojgić-Cvijović, Gordana D.
AU  - Pavlović, Mirjana D.
AU  - Bejosano, Feliciano
PY  - 2007
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/880
AB  - Two basic proteins were isolated to homogeneity from malting barley (Hordeum vulgare L.) grain. Proteins were identified as members of a Thaumatin-Like Protein (TLP) family, by Western blot. Isoforms, assigned as TLP-S and TLP-R, have slightly different mobility at about 22 and 27 kDa in nonreducing and reducing, conditions, and pI values of 9.5 and 9.4. respectively. The antifungal potency of malting barley grain TLPs isoforms was examined on Micrococcus lysodeikticus, Saccharomyces cerevisiae, Candida albicans and plant pathogen Fusarium sporotrichioides growth in vitro. It was found that that IC50 value for TLP-S was two fold hi.-her. Antibacterial and antifungal activities of both isoforms were completely abolished by divalent (Ca2+ Mn2+, Mg2+) and monovalent (K+) cations, at concentrations approximating physiological ionic strength and higher. Glucanase activity was not observed; neither TLP-S nor TLP-R digested glucan. On the basis of these results, the importance of TLP for barley grain protection against fungal diseases has been discussed together with the mechanism of antimicrobial action.
PB  - Inst Brewing, London
T2  - Journal of the Institute of Brewing
T1  - Antimicrobial activity of malting barley grain thaumatin-like protein isoforms, S and R
VL  - 113
IS  - 2
SP  - 206
EP  - 212
DO  - 10.1002/j.2050-0416.2007.tb00277.x
ER  - 
@article{
author = "Gorjanović, Stanislava and Beljanski, Milos V. and Gavrović-Jankulović, Marija and Gojgić-Cvijović, Gordana D. and Pavlović, Mirjana D. and Bejosano, Feliciano",
year = "2007",
abstract = "Two basic proteins were isolated to homogeneity from malting barley (Hordeum vulgare L.) grain. Proteins were identified as members of a Thaumatin-Like Protein (TLP) family, by Western blot. Isoforms, assigned as TLP-S and TLP-R, have slightly different mobility at about 22 and 27 kDa in nonreducing and reducing, conditions, and pI values of 9.5 and 9.4. respectively. The antifungal potency of malting barley grain TLPs isoforms was examined on Micrococcus lysodeikticus, Saccharomyces cerevisiae, Candida albicans and plant pathogen Fusarium sporotrichioides growth in vitro. It was found that that IC50 value for TLP-S was two fold hi.-her. Antibacterial and antifungal activities of both isoforms were completely abolished by divalent (Ca2+ Mn2+, Mg2+) and monovalent (K+) cations, at concentrations approximating physiological ionic strength and higher. Glucanase activity was not observed; neither TLP-S nor TLP-R digested glucan. On the basis of these results, the importance of TLP for barley grain protection against fungal diseases has been discussed together with the mechanism of antimicrobial action.",
publisher = "Inst Brewing, London",
journal = "Journal of the Institute of Brewing",
title = "Antimicrobial activity of malting barley grain thaumatin-like protein isoforms, S and R",
volume = "113",
number = "2",
pages = "206-212",
doi = "10.1002/j.2050-0416.2007.tb00277.x"
}
Gorjanović, S., Beljanski, M. V., Gavrović-Jankulović, M., Gojgić-Cvijović, G. D., Pavlović, M. D.,& Bejosano, F.. (2007). Antimicrobial activity of malting barley grain thaumatin-like protein isoforms, S and R. in Journal of the Institute of Brewing
Inst Brewing, London., 113(2), 206-212.
https://doi.org/10.1002/j.2050-0416.2007.tb00277.x
Gorjanović S, Beljanski MV, Gavrović-Jankulović M, Gojgić-Cvijović GD, Pavlović MD, Bejosano F. Antimicrobial activity of malting barley grain thaumatin-like protein isoforms, S and R. in Journal of the Institute of Brewing. 2007;113(2):206-212.
doi:10.1002/j.2050-0416.2007.tb00277.x .
Gorjanović, Stanislava, Beljanski, Milos V., Gavrović-Jankulović, Marija, Gojgić-Cvijović, Gordana D., Pavlović, Mirjana D., Bejosano, Feliciano, "Antimicrobial activity of malting barley grain thaumatin-like protein isoforms, S and R" in Journal of the Institute of Brewing, 113, no. 2 (2007):206-212,
https://doi.org/10.1002/j.2050-0416.2007.tb00277.x . .
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