TY  - JOUR
AU  - Adejumo, Temiloluwa T.
AU  - Danopoulou, Marianna
AU  - Zorba, Leandros P.
AU  - Pevec, Andrej
AU  - Zlatar, Matija
AU  - Radanović, Dušanka D.
AU  - Savić, Milica
AU  - Gruden, Maja
AU  - Anđelković, Katarina K.
AU  - Turel, Iztok
AU  - Čobeljić, Božidar
AU  - Vougioukalakis, Georgios C.
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6366
AB  - Two new Zn(II) complexes bearing tridentate hydrazone-based ligands with NNO or NNS donor atoms were synthesised and characterised by elemental analysis, infrared (IR) and nuclear magnetic resonance (NMR) spectroscopies, and single crystal X-ray diffraction methods. These complexes, together with four previously synthesised analogues, having hydrazone ligands with a NNO donor set of atoms, were successfully employed as catalysts in the ketone-amine-alkyne (KA2) coupling reaction, furnishing tetrasubstituted propargylamines, compounds with unique applications in organic chemistry. DFT calculations at the CAM-B3LYP/TZP level of theory were performed to elucidate the electronic structure of the investigated Zn(II) complexes, excellently correlating the structure of the complexes to their catalytic reactivity.
PB  - Wiley
T2  - European Journal of Inorganic Chemistry
T1  - Correlating Structure and KA2 Catalytic Activity of ZnII Hydrazone Complexes
VL  - 26
IS  - 33
SP  - e202300193
DO  - 10.1002/ejic.202300193
ER  - 

@article{
author = "Adejumo, Temiloluwa T. and Danopoulou, Marianna and Zorba, Leandros P. and Pevec, Andrej and Zlatar, Matija and Radanović, Dušanka D. and Savić, Milica and Gruden, Maja and Anđelković, Katarina K. and Turel, Iztok and Čobeljić, Božidar and Vougioukalakis, Georgios C.",
year = "2023",
abstract = "Two new Zn(II) complexes bearing tridentate hydrazone-based ligands with NNO or NNS donor atoms were synthesised and characterised by elemental analysis, infrared (IR) and nuclear magnetic resonance (NMR) spectroscopies, and single crystal X-ray diffraction methods. These complexes, together with four previously synthesised analogues, having hydrazone ligands with a NNO donor set of atoms, were successfully employed as catalysts in the ketone-amine-alkyne (KA2) coupling reaction, furnishing tetrasubstituted propargylamines, compounds with unique applications in organic chemistry. DFT calculations at the CAM-B3LYP/TZP level of theory were performed to elucidate the electronic structure of the investigated Zn(II) complexes, excellently correlating the structure of the complexes to their catalytic reactivity.",
publisher = "Wiley",
journal = "European Journal of Inorganic Chemistry",
title = "Correlating Structure and KA2 Catalytic Activity of ZnII Hydrazone Complexes",
volume = "26",
number = "33",
pages = "e202300193",
doi = "10.1002/ejic.202300193"
}

Adejumo, T. T., Danopoulou, M., Zorba, L. P., Pevec, A., Zlatar, M., Radanović, D. D., Savić, M., Gruden, M., Anđelković, K. K., Turel, I., Čobeljić, B.,& Vougioukalakis, G. C.. (2023). Correlating Structure and KA2 Catalytic Activity of ZnII Hydrazone Complexes. in European Journal of Inorganic Chemistry
Wiley., 26(33), e202300193.
https://doi.org/10.1002/ejic.202300193

Adejumo TT, Danopoulou M, Zorba LP, Pevec A, Zlatar M, Radanović DD, Savić M, Gruden M, Anđelković KK, Turel I, Čobeljić B, Vougioukalakis GC. Correlating Structure and KA2 Catalytic Activity of ZnII Hydrazone Complexes. in European Journal of Inorganic Chemistry. 2023;26(33):e202300193.
doi:10.1002/ejic.202300193 .

Adejumo, Temiloluwa T., Danopoulou, Marianna, Zorba, Leandros P., Pevec, Andrej, Zlatar, Matija, Radanović, Dušanka D., Savić, Milica, Gruden, Maja, Anđelković, Katarina K., Turel, Iztok, Čobeljić, Božidar, Vougioukalakis, Georgios C., "Correlating Structure and KA2 Catalytic Activity of ZnII Hydrazone Complexes" in European Journal of Inorganic Chemistry, 26, no. 33 (2023):e202300193,
https://doi.org/10.1002/ejic.202300193 . .

TY  - JOUR
AU  - Vitomirov, Teodora
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Radanović, Dušanka
AU  - Novaković, Irena T.
AU  - Savić, Milica
AU  - Anđelković, Katarina K.
AU  - Ristović, Maja Šumar
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6387
AB  - The condensation product of 7-acetyl-6-azaindole and Girard’s T reagent ((E)-2-(2-(1-(1H-pyrrolo[2,3-c]pyridin-7-yl)ethylidene)hydrazineyl)-N,N,N-trimethyl-2-oxoethan-1-aminium, HL ligand) was used as a ligand in the reaction with Cu(BF4)2·6H2O and NaN3. The reaction led to the formation of a binuclear Cu(II) complex containing two end-to-end (di-m-1,3-N3) azide bridges, as well as two NNO-donor hydrazone ligands, forming an axially elongated square pyramidal geometry around each Cu(II) center. This end-to-end (di-m-1,3-N3) azide bridge binding mode has not yet been reported, in Cu(II) complexes containing the NNO-donor hydrazone ligands, which makes the structure of the complex even more interesting for further studies. The com­plex was characterized by elemental analysis, IR spectroscopy and X-ray crys­tal­lography, and it was found that it crystallizes in the triclinic space group P–1 with the asymmetric unit comprising one Cu(II) centre, zwitterionic ligand L, one azide (N3-) ligand and BF4- counter anion. Examination of antimicrobial activity of the complex shows higher antifungal and antibacterial activity towards tested Gram-positive bacteria in comparison to the hydrazone ligand, with the antifungal activity of the complex even being comparable to the act­ivity of amphotericin B.
PB  - Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Binuclear azide-bridged hydrazone Cu(II) complex: Synthesis, characterization and evaluation of biological activity: Scientific paper
VL  - 88
IS  - 9
SP  - 877
EP  - 888
DO  - 10.2298/JSC230623044V
ER  - 

@article{
author = "Vitomirov, Teodora and Čobeljić, Božidar and Pevec, Andrej and Radanović, Dušanka and Novaković, Irena T. and Savić, Milica and Anđelković, Katarina K. and Ristović, Maja Šumar",
year = "2023",
abstract = "The condensation product of 7-acetyl-6-azaindole and Girard’s T reagent ((E)-2-(2-(1-(1H-pyrrolo[2,3-c]pyridin-7-yl)ethylidene)hydrazineyl)-N,N,N-trimethyl-2-oxoethan-1-aminium, HL ligand) was used as a ligand in the reaction with Cu(BF4)2·6H2O and NaN3. The reaction led to the formation of a binuclear Cu(II) complex containing two end-to-end (di-m-1,3-N3) azide bridges, as well as two NNO-donor hydrazone ligands, forming an axially elongated square pyramidal geometry around each Cu(II) center. This end-to-end (di-m-1,3-N3) azide bridge binding mode has not yet been reported, in Cu(II) complexes containing the NNO-donor hydrazone ligands, which makes the structure of the complex even more interesting for further studies. The com­plex was characterized by elemental analysis, IR spectroscopy and X-ray crys­tal­lography, and it was found that it crystallizes in the triclinic space group P–1 with the asymmetric unit comprising one Cu(II) centre, zwitterionic ligand L, one azide (N3-) ligand and BF4- counter anion. Examination of antimicrobial activity of the complex shows higher antifungal and antibacterial activity towards tested Gram-positive bacteria in comparison to the hydrazone ligand, with the antifungal activity of the complex even being comparable to the act­ivity of amphotericin B.",
publisher = "Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Binuclear azide-bridged hydrazone Cu(II) complex: Synthesis, characterization and evaluation of biological activity: Scientific paper",
volume = "88",
number = "9",
pages = "877-888",
doi = "10.2298/JSC230623044V"
}

Vitomirov, T., Čobeljić, B., Pevec, A., Radanović, D., Novaković, I. T., Savić, M., Anđelković, K. K.,& Ristović, M. Š.. (2023). Binuclear azide-bridged hydrazone Cu(II) complex: Synthesis, characterization and evaluation of biological activity: Scientific paper. in Journal of the Serbian Chemical Society
Serbian Chemical Society., 88(9), 877-888.
https://doi.org/10.2298/JSC230623044V

Vitomirov T, Čobeljić B, Pevec A, Radanović D, Novaković IT, Savić M, Anđelković KK, Ristović MŠ. Binuclear azide-bridged hydrazone Cu(II) complex: Synthesis, characterization and evaluation of biological activity: Scientific paper. in Journal of the Serbian Chemical Society. 2023;88(9):877-888.
doi:10.2298/JSC230623044V .

Vitomirov, Teodora, Čobeljić, Božidar, Pevec, Andrej, Radanović, Dušanka, Novaković, Irena T., Savić, Milica, Anđelković, Katarina K., Ristović, Maja Šumar, "Binuclear azide-bridged hydrazone Cu(II) complex: Synthesis, characterization and evaluation of biological activity: Scientific paper" in Journal of the Serbian Chemical Society, 88, no. 9 (2023):877-888,
https://doi.org/10.2298/JSC230623044V . .

TY  - THES
AU  - Savić, Milica
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4466
AB  - U ovom radu je sintetisan i rendgenskom strukturnom analizom i infracrvenom spektroskopijom okarakterisan Bi(III) kompleks sa (E)-N,N,N-trimetil-2-okso-2-(2-(1-(tiazol-2-il)etiliden)hidrazinil)etan-1-aminijum-hloridom (HL1Cl). Ligand je tridentatno koordinovan preko NNO donorksih atoma. Geometrijsko okruženje oko Bi(III) jona je izdužena pentagonalna bipiramida.
T1  - Sinteza i strukturna karakterizacija kompleksa Bi(III) sa kondenzacionim proizvodom 2-acetiltiazola i Žirarovog T reagensa
SP  - 1
EP  - 20
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4466
ER  - 

@mastersthesis{
author = "Savić, Milica",
year = "2021",
abstract = "U ovom radu je sintetisan i rendgenskom strukturnom analizom i infracrvenom spektroskopijom okarakterisan Bi(III) kompleks sa (E)-N,N,N-trimetil-2-okso-2-(2-(1-(tiazol-2-il)etiliden)hidrazinil)etan-1-aminijum-hloridom (HL1Cl). Ligand je tridentatno koordinovan preko NNO donorksih atoma. Geometrijsko okruženje oko Bi(III) jona je izdužena pentagonalna bipiramida.",
title = "Sinteza i strukturna karakterizacija kompleksa Bi(III) sa kondenzacionim proizvodom 2-acetiltiazola i Žirarovog T reagensa",
pages = "1-20",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4466"
}

Savić, M.. (2021). Sinteza i strukturna karakterizacija kompleksa Bi(III) sa kondenzacionim proizvodom 2-acetiltiazola i Žirarovog T reagensa. , 1-20.
https://hdl.handle.net/21.15107/rcub_cherry_4466

Savić M. Sinteza i strukturna karakterizacija kompleksa Bi(III) sa kondenzacionim proizvodom 2-acetiltiazola i Žirarovog T reagensa. 2021;:1-20.
https://hdl.handle.net/21.15107/rcub_cherry_4466 .

Savić, Milica, "Sinteza i strukturna karakterizacija kompleksa Bi(III) sa kondenzacionim proizvodom 2-acetiltiazola i Žirarovog T reagensa" (2021):1-20,
https://hdl.handle.net/21.15107/rcub_cherry_4466 .

TY  - THES
AU  - Savić, Milica
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4064
AB  - Sintetisan je i okarakterisan rendgenskom strukturnom analizom binuklearni “end-on“ (EO, μ-1,1) azidom premošćen Ni(II) kompleks sastava [Ni2L2(μ-1,1-N3)2(N3)2]6H2O, (L = (E)-N,N,N-trimetil-2-okso-2-(2-(1-(piridin-2-il)etiliden)hidrazinil)etan-1-amin). Joni Ni(II) su heksakoordinisani preko tridentatnog heteroaromatičnog hidrazonskog liganda i tri azido liganda (N3–) (jedan terminalan i dva “end-on“ mosna).
T1  - Sinteza i strukturna karakterizacija binuklearnog kompleksa Ni(II) sa tridentatnim hidrazonskim ligandom
SP  - 1
EP  - 15
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4064
ER  - 

@misc{
author = "Savić, Milica",
year = "2020",
abstract = "Sintetisan je i okarakterisan rendgenskom strukturnom analizom binuklearni “end-on“ (EO, μ-1,1) azidom premošćen Ni(II) kompleks sastava [Ni2L2(μ-1,1-N3)2(N3)2]6H2O, (L = (E)-N,N,N-trimetil-2-okso-2-(2-(1-(piridin-2-il)etiliden)hidrazinil)etan-1-amin). Joni Ni(II) su heksakoordinisani preko tridentatnog heteroaromatičnog hidrazonskog liganda i tri azido liganda (N3–) (jedan terminalan i dva “end-on“ mosna).",
title = "Sinteza i strukturna karakterizacija binuklearnog kompleksa Ni(II) sa tridentatnim hidrazonskim ligandom",
pages = "1-15",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4064"
}

Savić, M.. (2020). Sinteza i strukturna karakterizacija binuklearnog kompleksa Ni(II) sa tridentatnim hidrazonskim ligandom. , 1-15.
https://hdl.handle.net/21.15107/rcub_cherry_4064

Savić M. Sinteza i strukturna karakterizacija binuklearnog kompleksa Ni(II) sa tridentatnim hidrazonskim ligandom. 2020;:1-15.
https://hdl.handle.net/21.15107/rcub_cherry_4064 .

Savić, Milica, "Sinteza i strukturna karakterizacija binuklearnog kompleksa Ni(II) sa tridentatnim hidrazonskim ligandom" (2020):1-15,
https://hdl.handle.net/21.15107/rcub_cherry_4064 .