TY  - JOUR
AU  - Nikolić, Vladimir
AU  - Veličković, Sava
AU  - Antonović, Dušan G.
AU  - Popović, Aleksandar R.
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1425
AB  - In this paper, a biodegradation study of grafted copolymers of cornstarch and polystyrene (PS) and cornstarch and poly(methacrylic acid) in model river water is described. These copolymers were obtained in the presence of different amine activators. The synthesized copolymers and products of degradation were characterized by Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). Biodegradation was monitored by mass decrease and the number of microorganisms by the Koch method. Biodegradation of both copolymers advanced with time, the starch-graft-poly(methacrylic acid) copolymers had completely degraded after 21 day, and the starch graft polystyrene had partially degraded (45.8-93.1 % mass loss) after 27 days. The differences in the degree of biodegradation are the consequences of the different structures of the samples, and there was a significant negative correlation between the share of polystyrene in the copolymer and the degree of biodegradation. The grafting degree of PS necessary to prevent biodegradation was 54 %. Based on experimental evidence, the mechanisms of both biodegradation processes are proposed, and influence of degree of starch and synthetic component of copolymers on the degradation of the samples were established.
AB  - U ovom radu proučavana je biodegradacija kalemljenih kopolimera kukuruznog skroba i polistirena i kukuruznog skroba i poli(metakrilne kiseline) u rečnoj vodi. Ovi kopolimeri su sintetisani u prisustvu različitih aminoaktivatora. Sintetisani kopolimeri i produkta biodegradacije su karakterisani FTIR spektroskopijom i SEM mikroskopijom. Biodegradacija je praćena gubitkom mase uzoraka, a broj mikroorganizama Kohovom metodom. Stepen biodegradacije obe vrste kopolimera raste sa vremenom. Kalemljeni polimeri skroba i poli(metakrilne kiseline) potpuno se razgrađuju za 21 dan, dok se polimeri na bazi skroba i polistirena delimično razgrađuju nakon 27 dana (45,8-93,1 % od ukupne mase). Razlike u stepenu biodegradacije su posledica različite strukture uzoraka, a postoji i značajna negativna korelacija između udela polistirena u kopolimeru i stepena biodegradacije. Stepen kalemljenja polistirena (udeo polistirena u kopolimeru) koji sprečava biodegradaciju iznosio je 54 %. Na osnovu eksperimentalnih dokaza, predloženi su mehanizmi oba biodegradaciona procesa i ustanovljeni su uticaji količine skroba i sintetske komponente kopolimera na biodegradaciju.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Biodegradation of starch-graft-polystyrene and starch-graft-poly(methacrylic acid) copolymers in model river water
T1  - Biodegradacija kalemljenih kopolimera skroba i polistirena i skroba i poli(metakrilne kiseline) u rečnoj vodi
VL  - 78
IS  - 9
SP  - 1425
EP  - 1441
DO  - 10.2298/JSC121216051N
ER  - 

@article{
author = "Nikolić, Vladimir and Veličković, Sava and Antonović, Dušan G. and Popović, Aleksandar R.",
year = "2013",
abstract = "In this paper, a biodegradation study of grafted copolymers of cornstarch and polystyrene (PS) and cornstarch and poly(methacrylic acid) in model river water is described. These copolymers were obtained in the presence of different amine activators. The synthesized copolymers and products of degradation were characterized by Fourier transform infrared (FTIR) spectroscopy and scanning electron microscopy (SEM). Biodegradation was monitored by mass decrease and the number of microorganisms by the Koch method. Biodegradation of both copolymers advanced with time, the starch-graft-poly(methacrylic acid) copolymers had completely degraded after 21 day, and the starch graft polystyrene had partially degraded (45.8-93.1 % mass loss) after 27 days. The differences in the degree of biodegradation are the consequences of the different structures of the samples, and there was a significant negative correlation between the share of polystyrene in the copolymer and the degree of biodegradation. The grafting degree of PS necessary to prevent biodegradation was 54 %. Based on experimental evidence, the mechanisms of both biodegradation processes are proposed, and influence of degree of starch and synthetic component of copolymers on the degradation of the samples were established., U ovom radu proučavana je biodegradacija kalemljenih kopolimera kukuruznog skroba i polistirena i kukuruznog skroba i poli(metakrilne kiseline) u rečnoj vodi. Ovi kopolimeri su sintetisani u prisustvu različitih aminoaktivatora. Sintetisani kopolimeri i produkta biodegradacije su karakterisani FTIR spektroskopijom i SEM mikroskopijom. Biodegradacija je praćena gubitkom mase uzoraka, a broj mikroorganizama Kohovom metodom. Stepen biodegradacije obe vrste kopolimera raste sa vremenom. Kalemljeni polimeri skroba i poli(metakrilne kiseline) potpuno se razgrađuju za 21 dan, dok se polimeri na bazi skroba i polistirena delimično razgrađuju nakon 27 dana (45,8-93,1 % od ukupne mase). Razlike u stepenu biodegradacije su posledica različite strukture uzoraka, a postoji i značajna negativna korelacija između udela polistirena u kopolimeru i stepena biodegradacije. Stepen kalemljenja polistirena (udeo polistirena u kopolimeru) koji sprečava biodegradaciju iznosio je 54 %. Na osnovu eksperimentalnih dokaza, predloženi su mehanizmi oba biodegradaciona procesa i ustanovljeni su uticaji količine skroba i sintetske komponente kopolimera na biodegradaciju.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Biodegradation of starch-graft-polystyrene and starch-graft-poly(methacrylic acid) copolymers in model river water, Biodegradacija kalemljenih kopolimera skroba i polistirena i skroba i poli(metakrilne kiseline) u rečnoj vodi",
volume = "78",
number = "9",
pages = "1425-1441",
doi = "10.2298/JSC121216051N"
}

Nikolić, V., Veličković, S., Antonović, D. G.,& Popović, A. R.. (2013). Biodegradation of starch-graft-polystyrene and starch-graft-poly(methacrylic acid) copolymers in model river water. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 78(9), 1425-1441.
https://doi.org/10.2298/JSC121216051N

Nikolić V, Veličković S, Antonović DG, Popović AR. Biodegradation of starch-graft-polystyrene and starch-graft-poly(methacrylic acid) copolymers in model river water. in Journal of the Serbian Chemical Society. 2013;78(9):1425-1441.
doi:10.2298/JSC121216051N .

Nikolić, Vladimir, Veličković, Sava, Antonović, Dušan G., Popović, Aleksandar R., "Biodegradation of starch-graft-polystyrene and starch-graft-poly(methacrylic acid) copolymers in model river water" in Journal of the Serbian Chemical Society, 78, no. 9 (2013):1425-1441,
https://doi.org/10.2298/JSC121216051N . .

TY  - DATA
AU  - Nešić, Aleksandra R.
AU  - Trifunović, Snežana S.
AU  - Grujić, Aleksandar S.
AU  - Veličković, Sava
AU  - Antonović, Dušan G.
PY  - 2011
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2903
PB  - Elsevier Sci Ltd, Oxford
T2  - Carbohydrate Research
T1  - Supplementary data for the article: Nesic, A. R.; Trifunovic, S. S.; Grujic, A. S.; Velickovic, S. J.; Antonovic, D. G. Complexation of Amidated Pectin with Poly(Itaconic Acid) as a Polycarboxylic Polymer Model Compound. Carbohydrate Research 2011, 346 (15), 2463–2468. https://doi.org/10.1016/j.carres.2011.08.021
UR  - https://hdl.handle.net/21.15107/rcub_cherry_2903
ER  - 

@misc{
author = "Nešić, Aleksandra R. and Trifunović, Snežana S. and Grujić, Aleksandar S. and Veličković, Sava and Antonović, Dušan G.",
year = "2011",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Carbohydrate Research",
title = "Supplementary data for the article: Nesic, A. R.; Trifunovic, S. S.; Grujic, A. S.; Velickovic, S. J.; Antonovic, D. G. Complexation of Amidated Pectin with Poly(Itaconic Acid) as a Polycarboxylic Polymer Model Compound. Carbohydrate Research 2011, 346 (15), 2463–2468. https://doi.org/10.1016/j.carres.2011.08.021",
url = "https://hdl.handle.net/21.15107/rcub_cherry_2903"
}

Nešić, A. R., Trifunović, S. S., Grujić, A. S., Veličković, S.,& Antonović, D. G.. (2011). Supplementary data for the article: Nesic, A. R.; Trifunovic, S. S.; Grujic, A. S.; Velickovic, S. J.; Antonovic, D. G. Complexation of Amidated Pectin with Poly(Itaconic Acid) as a Polycarboxylic Polymer Model Compound. Carbohydrate Research 2011, 346 (15), 2463–2468. https://doi.org/10.1016/j.carres.2011.08.021. in Carbohydrate Research
Elsevier Sci Ltd, Oxford..
https://hdl.handle.net/21.15107/rcub_cherry_2903

Nešić AR, Trifunović SS, Grujić AS, Veličković S, Antonović DG. Supplementary data for the article: Nesic, A. R.; Trifunovic, S. S.; Grujic, A. S.; Velickovic, S. J.; Antonovic, D. G. Complexation of Amidated Pectin with Poly(Itaconic Acid) as a Polycarboxylic Polymer Model Compound. Carbohydrate Research 2011, 346 (15), 2463–2468. https://doi.org/10.1016/j.carres.2011.08.021. in Carbohydrate Research. 2011;.
https://hdl.handle.net/21.15107/rcub_cherry_2903 .

Nešić, Aleksandra R., Trifunović, Snežana S., Grujić, Aleksandar S., Veličković, Sava, Antonović, Dušan G., "Supplementary data for the article: Nesic, A. R.; Trifunovic, S. S.; Grujic, A. S.; Velickovic, S. J.; Antonovic, D. G. Complexation of Amidated Pectin with Poly(Itaconic Acid) as a Polycarboxylic Polymer Model Compound. Carbohydrate Research 2011, 346 (15), 2463–2468. https://doi.org/10.1016/j.carres.2011.08.021" in Carbohydrate Research (2011),
https://hdl.handle.net/21.15107/rcub_cherry_2903 .

TY  - JOUR
AU  - Nešić, Aleksandra R.
AU  - Trifunović, Snežana S.
AU  - Grujić, Aleksandar S.
AU  - Veličković, Sava
AU  - Antonović, Dušan G.
PY  - 2011
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1219
AB  - Complexes based on amidated pectin (AP) and poly(itaconic acid) (PIA) were prepared by casting films from solutions of AP and PIA in different ratios with the pectin amount ranging from 10% to 90% by mass. The complexes were investigated by elemental analysis, Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and thermogravimetry (TG). In all investigated ratios of AP/PIA glassy transparent films with a uniform structure were obtained. The results of elemental analysis confirmed the composition of the complexes, and FTIR spectroscopy has shown carboxylic and amide peak shifting, indicating complex formation between AP and PIA. Comparison of thermograms of AP/PIA films with different ratios of AP indicated that the increase of the amount of AP increases the thermal stability of the films by retarding the onset of the main degradation processes.
PB  - Elsevier Sci Ltd, Oxford
T2  - Carbohydrate Research
T1  - Complexation of amidated pectin with poly(itaconic acid) as a polycarboxylic polymer model compound
VL  - 346
IS  - 15
SP  - 2463
EP  - 2468
DO  - 10.1016/j.carres.2011.08.021
ER  - 

@article{
author = "Nešić, Aleksandra R. and Trifunović, Snežana S. and Grujić, Aleksandar S. and Veličković, Sava and Antonović, Dušan G.",
year = "2011",
abstract = "Complexes based on amidated pectin (AP) and poly(itaconic acid) (PIA) were prepared by casting films from solutions of AP and PIA in different ratios with the pectin amount ranging from 10% to 90% by mass. The complexes were investigated by elemental analysis, Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and thermogravimetry (TG). In all investigated ratios of AP/PIA glassy transparent films with a uniform structure were obtained. The results of elemental analysis confirmed the composition of the complexes, and FTIR spectroscopy has shown carboxylic and amide peak shifting, indicating complex formation between AP and PIA. Comparison of thermograms of AP/PIA films with different ratios of AP indicated that the increase of the amount of AP increases the thermal stability of the films by retarding the onset of the main degradation processes.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Carbohydrate Research",
title = "Complexation of amidated pectin with poly(itaconic acid) as a polycarboxylic polymer model compound",
volume = "346",
number = "15",
pages = "2463-2468",
doi = "10.1016/j.carres.2011.08.021"
}

Nešić, A. R., Trifunović, S. S., Grujić, A. S., Veličković, S.,& Antonović, D. G.. (2011). Complexation of amidated pectin with poly(itaconic acid) as a polycarboxylic polymer model compound. in Carbohydrate Research
Elsevier Sci Ltd, Oxford., 346(15), 2463-2468.
https://doi.org/10.1016/j.carres.2011.08.021

Nešić AR, Trifunović SS, Grujić AS, Veličković S, Antonović DG. Complexation of amidated pectin with poly(itaconic acid) as a polycarboxylic polymer model compound. in Carbohydrate Research. 2011;346(15):2463-2468.
doi:10.1016/j.carres.2011.08.021 .

Nešić, Aleksandra R., Trifunović, Snežana S., Grujić, Aleksandar S., Veličković, Sava, Antonović, Dušan G., "Complexation of amidated pectin with poly(itaconic acid) as a polycarboxylic polymer model compound" in Carbohydrate Research, 346, no. 15 (2011):2463-2468,
https://doi.org/10.1016/j.carres.2011.08.021 . .