TY  - JOUR
AU  - Stevanović, Nevena
AU  - Mazzeo, Paolo Pio
AU  - Bacchi, Alessia
AU  - Matić, Ivana Z.
AU  - Đorđić Crnogorac, Marija
AU  - Stanojković, Tatjana
AU  - Vujčić, Miroslava
AU  - Novaković, Irena T.
AU  - Radanović, Dušanka D.
AU  - Šumar-Ristović, Maja
AU  - Sladić, Dušan
AU  - Čobeljić, Božidar
AU  - Anđelković, Katarina K.
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4673
AB  - In this work synthesis, characterization and crystal structures of 1, Zn(II) complex ([ZnL1(NCS)2]), with (E)-1-(2-oxo-2-(2-(quinolin-2-ylmethylene)hydrazinyl)ethyl)pyridin-1-ium chloride (HL1Cl) and 2, Bi(III) complex ([BiHL2Cl4] × 1/2CH3OH), with (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(thiazol-2-yl)ethylidene)hydrazinyl)ethan-1-aminium chloride (HL2Cl), have been reported. Zn(II) complex possesses a distorted trigonal bipyramidal geometry while surroundings around Bi(III) ion are extended pentagonal bipyramidal. Antimicrobial activity, brine shrimp assay and DPPH radical scavenging activity of both complexes, including previously synthesized complexes with HL2Cl ligand (Zn(II) and Ni(II)) and complexes with (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium chloride (HL3Cl) (Zn(II), Cu(II), Cd(II), Co(II), Fe(III), Ni(II)), were evaluated. For the most active complexes, cytotoxic activity against five malignant cancer cell lines (HeLa, A375, MCF7, PC-3 and A549) and normal cell line HaCaT, as well as generation of reactive oxygen species (ROS), was tested.
PB  - Springer
T2  - JBIC Journal of Biological Inorganic Chemistry
T1  - Synthesis, characterization, antimicrobial and cytotoxic activity and DNA-binding properties of d-metal complexes with hydrazones of Girard’s T and P reagents
VL  - 26
SP  - 863
EP  - 880
DO  - 10.1007/s00775-021-01893-5
ER  - 

@article{
author = "Stevanović, Nevena and Mazzeo, Paolo Pio and Bacchi, Alessia and Matić, Ivana Z. and Đorđić Crnogorac, Marija and Stanojković, Tatjana and Vujčić, Miroslava and Novaković, Irena T. and Radanović, Dušanka D. and Šumar-Ristović, Maja and Sladić, Dušan and Čobeljić, Božidar and Anđelković, Katarina K.",
year = "2021",
abstract = "In this work synthesis, characterization and crystal structures of 1, Zn(II) complex ([ZnL1(NCS)2]), with (E)-1-(2-oxo-2-(2-(quinolin-2-ylmethylene)hydrazinyl)ethyl)pyridin-1-ium chloride (HL1Cl) and 2, Bi(III) complex ([BiHL2Cl4] × 1/2CH3OH), with (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(thiazol-2-yl)ethylidene)hydrazinyl)ethan-1-aminium chloride (HL2Cl), have been reported. Zn(II) complex possesses a distorted trigonal bipyramidal geometry while surroundings around Bi(III) ion are extended pentagonal bipyramidal. Antimicrobial activity, brine shrimp assay and DPPH radical scavenging activity of both complexes, including previously synthesized complexes with HL2Cl ligand (Zn(II) and Ni(II)) and complexes with (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium chloride (HL3Cl) (Zn(II), Cu(II), Cd(II), Co(II), Fe(III), Ni(II)), were evaluated. For the most active complexes, cytotoxic activity against five malignant cancer cell lines (HeLa, A375, MCF7, PC-3 and A549) and normal cell line HaCaT, as well as generation of reactive oxygen species (ROS), was tested.",
publisher = "Springer",
journal = "JBIC Journal of Biological Inorganic Chemistry",
title = "Synthesis, characterization, antimicrobial and cytotoxic activity and DNA-binding properties of d-metal complexes with hydrazones of Girard’s T and P reagents",
volume = "26",
pages = "863-880",
doi = "10.1007/s00775-021-01893-5"
}

Stevanović, N., Mazzeo, P. P., Bacchi, A., Matić, I. Z., Đorđić Crnogorac, M., Stanojković, T., Vujčić, M., Novaković, I. T., Radanović, D. D., Šumar-Ristović, M., Sladić, D., Čobeljić, B.,& Anđelković, K. K.. (2021). Synthesis, characterization, antimicrobial and cytotoxic activity and DNA-binding properties of d-metal complexes with hydrazones of Girard’s T and P reagents. in JBIC Journal of Biological Inorganic Chemistry
Springer., 26, 863-880.
https://doi.org/10.1007/s00775-021-01893-5

Stevanović N, Mazzeo PP, Bacchi A, Matić IZ, Đorđić Crnogorac M, Stanojković T, Vujčić M, Novaković IT, Radanović DD, Šumar-Ristović M, Sladić D, Čobeljić B, Anđelković KK. Synthesis, characterization, antimicrobial and cytotoxic activity and DNA-binding properties of d-metal complexes with hydrazones of Girard’s T and P reagents. in JBIC Journal of Biological Inorganic Chemistry. 2021;26:863-880.
doi:10.1007/s00775-021-01893-5 .

Stevanović, Nevena, Mazzeo, Paolo Pio, Bacchi, Alessia, Matić, Ivana Z., Đorđić Crnogorac, Marija, Stanojković, Tatjana, Vujčić, Miroslava, Novaković, Irena T., Radanović, Dušanka D., Šumar-Ristović, Maja, Sladić, Dušan, Čobeljić, Božidar, Anđelković, Katarina K., "Synthesis, characterization, antimicrobial and cytotoxic activity and DNA-binding properties of d-metal complexes with hydrazones of Girard’s T and P reagents" in JBIC Journal of Biological Inorganic Chemistry, 26 (2021):863-880,
https://doi.org/10.1007/s00775-021-01893-5 . .

TY  - DATA
AU  - Stevanović, Nevena
AU  - Mazzeo, Paolo Pio
AU  - Bacchi, Alessia
AU  - Matić, Ivana Z.
AU  - Đorđić Crnogorac, Marija
AU  - Stanojković, Tatjana
AU  - Vujčić, Miroslava
AU  - Novaković, Irena T.
AU  - Radanović, Dušanka D.
AU  - Šumar-Ristović, Maja
AU  - Sladić, Dušan
AU  - Čobeljić, Božidar
AU  - Anđelković, Katarina K.
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4675
AB  - In this work synthesis, characterization and crystal structures of 1, Zn(II) complex ([ZnL1(NCS)2]), with (E)-1-(2-oxo-2-(2-(quinolin-2-ylmethylene)hydrazinyl)ethyl)pyridin-1-ium chloride (HL1Cl) and 2, Bi(III) complex ([BiHL2Cl4] × 1/2CH3OH), with (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(thiazol-2-yl)ethylidene)hydrazinyl)ethan-1-aminium chloride (HL2Cl), have been reported. Zn(II) complex possesses a distorted trigonal bipyramidal geometry while surroundings around Bi(III) ion are extended pentagonal bipyramidal. Antimicrobial activity, brine shrimp assay and DPPH radical scavenging activity of both complexes, including previously synthesized complexes with HL2Cl ligand (Zn(II) and Ni(II)) and complexes with (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium chloride (HL3Cl) (Zn(II), Cu(II), Cd(II), Co(II), Fe(III), Ni(II)), were evaluated. For the most active complexes, cytotoxic activity against five malignant cancer cell lines (HeLa, A375, MCF7, PC-3 and A549) and normal cell line HaCaT, as well as generation of reactive oxygen species (ROS), was tested.
PB  - Springer
T2  - JBIC Journal of Biological Inorganic Chemistry
T1  - Supplementary data for the article: Stevanović, N.; Mazzeo, P. P.; Bacchi, A.; Matić, I. Z.; Đorđić Crnogorac, M.; Stanojković, T.; Vujčić, M.; Novaković, I.; Radanović, D.; Šumar-Ristović, M.; Sladić, D.; Čobeljić, B.; Anđelković, K. Synthesis, Characterization, Antimicrobial and Cytotoxic Activity and DNA-Binding Properties of d-Metal Complexes with Hydrazones of Girard’s T and P Reagents. J Biol Inorg Chem 2021. https://doi.org/10.1007/s00775-021-01893-5.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4675
ER  - 

@misc{
author = "Stevanović, Nevena and Mazzeo, Paolo Pio and Bacchi, Alessia and Matić, Ivana Z. and Đorđić Crnogorac, Marija and Stanojković, Tatjana and Vujčić, Miroslava and Novaković, Irena T. and Radanović, Dušanka D. and Šumar-Ristović, Maja and Sladić, Dušan and Čobeljić, Božidar and Anđelković, Katarina K.",
year = "2021",
abstract = "In this work synthesis, characterization and crystal structures of 1, Zn(II) complex ([ZnL1(NCS)2]), with (E)-1-(2-oxo-2-(2-(quinolin-2-ylmethylene)hydrazinyl)ethyl)pyridin-1-ium chloride (HL1Cl) and 2, Bi(III) complex ([BiHL2Cl4] × 1/2CH3OH), with (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(thiazol-2-yl)ethylidene)hydrazinyl)ethan-1-aminium chloride (HL2Cl), have been reported. Zn(II) complex possesses a distorted trigonal bipyramidal geometry while surroundings around Bi(III) ion are extended pentagonal bipyramidal. Antimicrobial activity, brine shrimp assay and DPPH radical scavenging activity of both complexes, including previously synthesized complexes with HL2Cl ligand (Zn(II) and Ni(II)) and complexes with (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium chloride (HL3Cl) (Zn(II), Cu(II), Cd(II), Co(II), Fe(III), Ni(II)), were evaluated. For the most active complexes, cytotoxic activity against five malignant cancer cell lines (HeLa, A375, MCF7, PC-3 and A549) and normal cell line HaCaT, as well as generation of reactive oxygen species (ROS), was tested.",
publisher = "Springer",
journal = "JBIC Journal of Biological Inorganic Chemistry",
title = "Supplementary data for the article: Stevanović, N.; Mazzeo, P. P.; Bacchi, A.; Matić, I. Z.; Đorđić Crnogorac, M.; Stanojković, T.; Vujčić, M.; Novaković, I.; Radanović, D.; Šumar-Ristović, M.; Sladić, D.; Čobeljić, B.; Anđelković, K. Synthesis, Characterization, Antimicrobial and Cytotoxic Activity and DNA-Binding Properties of d-Metal Complexes with Hydrazones of Girard’s T and P Reagents. J Biol Inorg Chem 2021. https://doi.org/10.1007/s00775-021-01893-5.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4675"
}

Stevanović, N., Mazzeo, P. P., Bacchi, A., Matić, I. Z., Đorđić Crnogorac, M., Stanojković, T., Vujčić, M., Novaković, I. T., Radanović, D. D., Šumar-Ristović, M., Sladić, D., Čobeljić, B.,& Anđelković, K. K.. (2021). Supplementary data for the article: Stevanović, N.; Mazzeo, P. P.; Bacchi, A.; Matić, I. Z.; Đorđić Crnogorac, M.; Stanojković, T.; Vujčić, M.; Novaković, I.; Radanović, D.; Šumar-Ristović, M.; Sladić, D.; Čobeljić, B.; Anđelković, K. Synthesis, Characterization, Antimicrobial and Cytotoxic Activity and DNA-Binding Properties of d-Metal Complexes with Hydrazones of Girard’s T and P Reagents. J Biol Inorg Chem 2021. https://doi.org/10.1007/s00775-021-01893-5.. in JBIC Journal of Biological Inorganic Chemistry
Springer..
https://hdl.handle.net/21.15107/rcub_cherry_4675

Stevanović N, Mazzeo PP, Bacchi A, Matić IZ, Đorđić Crnogorac M, Stanojković T, Vujčić M, Novaković IT, Radanović DD, Šumar-Ristović M, Sladić D, Čobeljić B, Anđelković KK. Supplementary data for the article: Stevanović, N.; Mazzeo, P. P.; Bacchi, A.; Matić, I. Z.; Đorđić Crnogorac, M.; Stanojković, T.; Vujčić, M.; Novaković, I.; Radanović, D.; Šumar-Ristović, M.; Sladić, D.; Čobeljić, B.; Anđelković, K. Synthesis, Characterization, Antimicrobial and Cytotoxic Activity and DNA-Binding Properties of d-Metal Complexes with Hydrazones of Girard’s T and P Reagents. J Biol Inorg Chem 2021. https://doi.org/10.1007/s00775-021-01893-5.. in JBIC Journal of Biological Inorganic Chemistry. 2021;.
https://hdl.handle.net/21.15107/rcub_cherry_4675 .

Stevanović, Nevena, Mazzeo, Paolo Pio, Bacchi, Alessia, Matić, Ivana Z., Đorđić Crnogorac, Marija, Stanojković, Tatjana, Vujčić, Miroslava, Novaković, Irena T., Radanović, Dušanka D., Šumar-Ristović, Maja, Sladić, Dušan, Čobeljić, Božidar, Anđelković, Katarina K., "Supplementary data for the article: Stevanović, N.; Mazzeo, P. P.; Bacchi, A.; Matić, I. Z.; Đorđić Crnogorac, M.; Stanojković, T.; Vujčić, M.; Novaković, I.; Radanović, D.; Šumar-Ristović, M.; Sladić, D.; Čobeljić, B.; Anđelković, K. Synthesis, Characterization, Antimicrobial and Cytotoxic Activity and DNA-Binding Properties of d-Metal Complexes with Hydrazones of Girard’s T and P Reagents. J Biol Inorg Chem 2021. https://doi.org/10.1007/s00775-021-01893-5." in JBIC Journal of Biological Inorganic Chemistry (2021),
https://hdl.handle.net/21.15107/rcub_cherry_4675 .

TY  - DATA
AU  - Stojković, Danijela
AU  - Bacchi, Alessia
AU  - Capucci, Davide
AU  - Milenković, Milica R.
AU  - Čobeljić, Božidar
AU  - Trifunović, Srećko R.
AU  - Anđelković, Katarina K.
AU  - Jevtic, Verica V.
AU  - Vuković, Nenad L.
AU  - Vukic, Milena
AU  - Sladić, Dušan
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3626
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Supplementary data for the article: Stojković, D. L. J.; Bacchi, A.; Capucci, D.; Milenković, M. R.; Čobeljić, B.; Trifunović, S. R.; Andelković, K.; Jevtić, V. V.; Vuković, N.; Vukić, M.; et al. Synthesis and Characterization of Palladium(II) Complexes with Glycine Coumarin Derivatives. Journal of the Serbian Chemical Society 2016, 81 (12), 1383–1392. https://doi.org/10.2298/JSC160915087S
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3626
ER  - 

@misc{
author = "Stojković, Danijela and Bacchi, Alessia and Capucci, Davide and Milenković, Milica R. and Čobeljić, Božidar and Trifunović, Srećko R. and Anđelković, Katarina K. and Jevtic, Verica V. and Vuković, Nenad L. and Vukic, Milena and Sladić, Dušan",
year = "2016",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Supplementary data for the article: Stojković, D. L. J.; Bacchi, A.; Capucci, D.; Milenković, M. R.; Čobeljić, B.; Trifunović, S. R.; Andelković, K.; Jevtić, V. V.; Vuković, N.; Vukić, M.; et al. Synthesis and Characterization of Palladium(II) Complexes with Glycine Coumarin Derivatives. Journal of the Serbian Chemical Society 2016, 81 (12), 1383–1392. https://doi.org/10.2298/JSC160915087S",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3626"
}

Stojković, D., Bacchi, A., Capucci, D., Milenković, M. R., Čobeljić, B., Trifunović, S. R., Anđelković, K. K., Jevtic, V. V., Vuković, N. L., Vukic, M.,& Sladić, D.. (2016). Supplementary data for the article: Stojković, D. L. J.; Bacchi, A.; Capucci, D.; Milenković, M. R.; Čobeljić, B.; Trifunović, S. R.; Andelković, K.; Jevtić, V. V.; Vuković, N.; Vukić, M.; et al. Synthesis and Characterization of Palladium(II) Complexes with Glycine Coumarin Derivatives. Journal of the Serbian Chemical Society 2016, 81 (12), 1383–1392. https://doi.org/10.2298/JSC160915087S. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade..
https://hdl.handle.net/21.15107/rcub_cherry_3626

Stojković D, Bacchi A, Capucci D, Milenković MR, Čobeljić B, Trifunović SR, Anđelković KK, Jevtic VV, Vuković NL, Vukic M, Sladić D. Supplementary data for the article: Stojković, D. L. J.; Bacchi, A.; Capucci, D.; Milenković, M. R.; Čobeljić, B.; Trifunović, S. R.; Andelković, K.; Jevtić, V. V.; Vuković, N.; Vukić, M.; et al. Synthesis and Characterization of Palladium(II) Complexes with Glycine Coumarin Derivatives. Journal of the Serbian Chemical Society 2016, 81 (12), 1383–1392. https://doi.org/10.2298/JSC160915087S. in Journal of the Serbian Chemical Society. 2016;.
https://hdl.handle.net/21.15107/rcub_cherry_3626 .

Stojković, Danijela, Bacchi, Alessia, Capucci, Davide, Milenković, Milica R., Čobeljić, Božidar, Trifunović, Srećko R., Anđelković, Katarina K., Jevtic, Verica V., Vuković, Nenad L., Vukic, Milena, Sladić, Dušan, "Supplementary data for the article: Stojković, D. L. J.; Bacchi, A.; Capucci, D.; Milenković, M. R.; Čobeljić, B.; Trifunović, S. R.; Andelković, K.; Jevtić, V. V.; Vuković, N.; Vukić, M.; et al. Synthesis and Characterization of Palladium(II) Complexes with Glycine Coumarin Derivatives. Journal of the Serbian Chemical Society 2016, 81 (12), 1383–1392. https://doi.org/10.2298/JSC160915087S" in Journal of the Serbian Chemical Society (2016),
https://hdl.handle.net/21.15107/rcub_cherry_3626 .

TY  - JOUR
AU  - Milenković, Milica R.
AU  - Cantoni, Giulia
AU  - Bacchi, Alessia
AU  - Spasojević, Vojislav
AU  - Milenković, Marina
AU  - Sladić, Dušan
AU  - Krstić, Natalija M.
AU  - Anđelković, Katarina K.
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1838
AB  - Complexes of Pd(II) and Fe(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate were synthesized, characterized, and their antimicrobial activity was evaluated. The structures of the Pd(II) and Fe(III) complexes in solid state were determined by IR, elemental analysis and X-ray analysis. The structure of Pd(II) complex in solution was determined by NMR spectroscopy. Results of magnetic measurements for Fe(III) complex were reported. In both complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms. Results of antimicrobial activity investigation indicate that the activity of the ligand is enhanced upon complexation, and that the MIC values of the iron complex to some bacterial strains are not much higher than those of cefotaxime. (C) 2014 Elsevier Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate
VL  - 80
SP  - 47
EP  - 52
DO  - 10.1016/j.poly.2014.01.022
ER  - 

@article{
author = "Milenković, Milica R. and Cantoni, Giulia and Bacchi, Alessia and Spasojević, Vojislav and Milenković, Marina and Sladić, Dušan and Krstić, Natalija M. and Anđelković, Katarina K.",
year = "2014",
abstract = "Complexes of Pd(II) and Fe(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate were synthesized, characterized, and their antimicrobial activity was evaluated. The structures of the Pd(II) and Fe(III) complexes in solid state were determined by IR, elemental analysis and X-ray analysis. The structure of Pd(II) complex in solution was determined by NMR spectroscopy. Results of magnetic measurements for Fe(III) complex were reported. In both complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms. Results of antimicrobial activity investigation indicate that the activity of the ligand is enhanced upon complexation, and that the MIC values of the iron complex to some bacterial strains are not much higher than those of cefotaxime. (C) 2014 Elsevier Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate",
volume = "80",
pages = "47-52",
doi = "10.1016/j.poly.2014.01.022"
}

Milenković, M. R., Cantoni, G., Bacchi, A., Spasojević, V., Milenković, M., Sladić, D., Krstić, N. M.,& Anđelković, K. K.. (2014). Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 80, 47-52.
https://doi.org/10.1016/j.poly.2014.01.022

Milenković MR, Cantoni G, Bacchi A, Spasojević V, Milenković M, Sladić D, Krstić NM, Anđelković KK. Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate. in Polyhedron. 2014;80:47-52.
doi:10.1016/j.poly.2014.01.022 .

Milenković, Milica R., Cantoni, Giulia, Bacchi, Alessia, Spasojević, Vojislav, Milenković, Marina, Sladić, Dušan, Krstić, Natalija M., Anđelković, Katarina K., "Synthesis, characterization and antimicrobial activity of Pd(II) and Fe(III) complexes with ethyl (2E)-2-[2-(diphenylphosphino)benzylidene]hydrazinecarboxylate" in Polyhedron, 80 (2014):47-52,
https://doi.org/10.1016/j.poly.2014.01.022 . .

TY  - JOUR
AU  - Adaila, Kawther
AU  - Milenković, Milica R.
AU  - Bacchi, Alessia
AU  - Cantoni, Giulia
AU  - Swart, Marcel
AU  - Gruden-Pavlović, Maja
AU  - Milenković, Marina
AU  - Čobeljić, Božidar
AU  - Todorović, Tamara
AU  - Anđelković, Katarina K.
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1880
AB  - Complexes of Pd(II) and Co(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard T reagent were synthesized, characterized, and their antimicrobial activities were evaluated. The ligand and the complexes were characterized by elemental analysis, IR and NMR spectroscopies, and X-ray crystallography. In both complexes, the deprotonated ligand was coordinated to the metal through the phosphorus, the imine nitrogen, and the carbonyl oxygen atoms. In the octahedral Co(III) complex, two molecules of ligands were coordinated to metal ion, while square-planar environment of Pd(II) complex was constituted of one tridentate ligand and chloride in the fourth coordination place. The ligand and complexes showed moderate antibacterial activity. The molecular structures of the obtained metal complexes and the relative stabilities of two stereoisomers of the ligand were calculated using density functional theory at the S12g/TZ2P level.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent
VL  - 67
IS  - 22
SP  - 3633
EP  - 3648
DO  - 10.1080/00958972.2014.972389
ER  - 

@article{
author = "Adaila, Kawther and Milenković, Milica R. and Bacchi, Alessia and Cantoni, Giulia and Swart, Marcel and Gruden-Pavlović, Maja and Milenković, Marina and Čobeljić, Božidar and Todorović, Tamara and Anđelković, Katarina K.",
year = "2014",
abstract = "Complexes of Pd(II) and Co(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard T reagent were synthesized, characterized, and their antimicrobial activities were evaluated. The ligand and the complexes were characterized by elemental analysis, IR and NMR spectroscopies, and X-ray crystallography. In both complexes, the deprotonated ligand was coordinated to the metal through the phosphorus, the imine nitrogen, and the carbonyl oxygen atoms. In the octahedral Co(III) complex, two molecules of ligands were coordinated to metal ion, while square-planar environment of Pd(II) complex was constituted of one tridentate ligand and chloride in the fourth coordination place. The ligand and complexes showed moderate antibacterial activity. The molecular structures of the obtained metal complexes and the relative stabilities of two stereoisomers of the ligand were calculated using density functional theory at the S12g/TZ2P level.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent",
volume = "67",
number = "22",
pages = "3633-3648",
doi = "10.1080/00958972.2014.972389"
}

Adaila, K., Milenković, M. R., Bacchi, A., Cantoni, G., Swart, M., Gruden-Pavlović, M., Milenković, M., Čobeljić, B., Todorović, T.,& Anđelković, K. K.. (2014). Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 67(22), 3633-3648.
https://doi.org/10.1080/00958972.2014.972389

Adaila K, Milenković MR, Bacchi A, Cantoni G, Swart M, Gruden-Pavlović M, Milenković M, Čobeljić B, Todorović T, Anđelković KK. Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent. in Journal of Coordination Chemistry. 2014;67(22):3633-3648.
doi:10.1080/00958972.2014.972389 .

Adaila, Kawther, Milenković, Milica R., Bacchi, Alessia, Cantoni, Giulia, Swart, Marcel, Gruden-Pavlović, Maja, Milenković, Marina, Čobeljić, Božidar, Todorović, Tamara, Anđelković, Katarina K., "Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent" in Journal of Coordination Chemistry, 67, no. 22 (2014):3633-3648,
https://doi.org/10.1080/00958972.2014.972389 . .

TY  - JOUR
AU  - Milenković, Milica R.
AU  - Bacchi, Alessia
AU  - Cantoni, Giulia
AU  - Radulović, Siniša
AU  - Gligorijević, Nevenka
AU  - Aranđelović, Sandra
AU  - Sladić, Dušan
AU  - Vujčić, Miroslava
AU  - Mitić, Dragana
AU  - Anđelković, Katarina K.
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1618
AB  - A cobalt(III) complex with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and ethyl carbazate was synthesized. X-ray crystal structure was determined for both the ligand and the complex. In the cobalt(III) complex two deprotonated ligand molecules coordinate the metal atom in a distorted octahedral geometry by chelation through the PNO donor system formed by the phosphorus, the imine nitrogen and the carbonyl oxygen. The complex showed a moderate antibacterial activity and a strong cytotoxic activity, stronger than cisplatin. Based on cell cycle progression, apoptotic assays, spectroscopic and electrophoretic studies, it was shown that high cytotoxicity and moderate potential of induction of apoptosis are not consequence of interactions with DNA.
PB  - Elsevier Science Sa, Lausanne
T2  - Inorganica Chimica Acta
T1  - Synthesis, characterisation and biological activity of Co(III) complex with the condensation product of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate
VL  - 395
SP  - 33
EP  - 43
DO  - 10.1016/j.ica.2012.09.043
ER  - 

@article{
author = "Milenković, Milica R. and Bacchi, Alessia and Cantoni, Giulia and Radulović, Siniša and Gligorijević, Nevenka and Aranđelović, Sandra and Sladić, Dušan and Vujčić, Miroslava and Mitić, Dragana and Anđelković, Katarina K.",
year = "2013",
abstract = "A cobalt(III) complex with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and ethyl carbazate was synthesized. X-ray crystal structure was determined for both the ligand and the complex. In the cobalt(III) complex two deprotonated ligand molecules coordinate the metal atom in a distorted octahedral geometry by chelation through the PNO donor system formed by the phosphorus, the imine nitrogen and the carbonyl oxygen. The complex showed a moderate antibacterial activity and a strong cytotoxic activity, stronger than cisplatin. Based on cell cycle progression, apoptotic assays, spectroscopic and electrophoretic studies, it was shown that high cytotoxicity and moderate potential of induction of apoptosis are not consequence of interactions with DNA.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Inorganica Chimica Acta",
title = "Synthesis, characterisation and biological activity of Co(III) complex with the condensation product of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate",
volume = "395",
pages = "33-43",
doi = "10.1016/j.ica.2012.09.043"
}

Milenković, M. R., Bacchi, A., Cantoni, G., Radulović, S., Gligorijević, N., Aranđelović, S., Sladić, D., Vujčić, M., Mitić, D.,& Anđelković, K. K.. (2013). Synthesis, characterisation and biological activity of Co(III) complex with the condensation product of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate. in Inorganica Chimica Acta
Elsevier Science Sa, Lausanne., 395, 33-43.
https://doi.org/10.1016/j.ica.2012.09.043

Milenković MR, Bacchi A, Cantoni G, Radulović S, Gligorijević N, Aranđelović S, Sladić D, Vujčić M, Mitić D, Anđelković KK. Synthesis, characterisation and biological activity of Co(III) complex with the condensation product of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate. in Inorganica Chimica Acta. 2013;395:33-43.
doi:10.1016/j.ica.2012.09.043 .

Milenković, Milica R., Bacchi, Alessia, Cantoni, Giulia, Radulović, Siniša, Gligorijević, Nevenka, Aranđelović, Sandra, Sladić, Dušan, Vujčić, Miroslava, Mitić, Dragana, Anđelković, Katarina K., "Synthesis, characterisation and biological activity of Co(III) complex with the condensation product of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate" in Inorganica Chimica Acta, 395 (2013):33-43,
https://doi.org/10.1016/j.ica.2012.09.043 . .

TY  - DATA
AU  - Milenković, Milica R.
AU  - Bacchi, Alessia
AU  - Cantoni, Giulia
AU  - Radulović, Siniša
AU  - Gligorijević, Nevenka
AU  - Aranđelović, Sandra
AU  - Sladić, Dušan
AU  - Vujčić, Miroslava
AU  - Mitić, Dragana
AU  - Anđelković, Katarina K.
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3533
PB  - Elsevier Science Sa, Lausanne
T2  - Inorganica Chimica Acta
T1  - Supplementary data for article: Milenković, M. R.; Bacchi, A.; Cantoni, G.; Radulović, S. S.; Gligorijević, N.; Aranđelović, S.; Sladić, D.; Vujčić, M.; Mitić, D.; Anđelković, K. K. Synthesis, Characterisation and Biological Activity of Co(III) Complex with the Condensation Product of 2-(Diphenylphosphino)Benzaldehyde and Ethyl Carbazate. Inorganica Chimica Acta 2013, 395, 33–43. https://doi.org/10.1016/j.ica.2012.09.043
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3533
ER  - 

@misc{
author = "Milenković, Milica R. and Bacchi, Alessia and Cantoni, Giulia and Radulović, Siniša and Gligorijević, Nevenka and Aranđelović, Sandra and Sladić, Dušan and Vujčić, Miroslava and Mitić, Dragana and Anđelković, Katarina K.",
year = "2013",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Inorganica Chimica Acta",
title = "Supplementary data for article: Milenković, M. R.; Bacchi, A.; Cantoni, G.; Radulović, S. S.; Gligorijević, N.; Aranđelović, S.; Sladić, D.; Vujčić, M.; Mitić, D.; Anđelković, K. K. Synthesis, Characterisation and Biological Activity of Co(III) Complex with the Condensation Product of 2-(Diphenylphosphino)Benzaldehyde and Ethyl Carbazate. Inorganica Chimica Acta 2013, 395, 33–43. https://doi.org/10.1016/j.ica.2012.09.043",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3533"
}

Milenković, M. R., Bacchi, A., Cantoni, G., Radulović, S., Gligorijević, N., Aranđelović, S., Sladić, D., Vujčić, M., Mitić, D.,& Anđelković, K. K.. (2013). Supplementary data for article: Milenković, M. R.; Bacchi, A.; Cantoni, G.; Radulović, S. S.; Gligorijević, N.; Aranđelović, S.; Sladić, D.; Vujčić, M.; Mitić, D.; Anđelković, K. K. Synthesis, Characterisation and Biological Activity of Co(III) Complex with the Condensation Product of 2-(Diphenylphosphino)Benzaldehyde and Ethyl Carbazate. Inorganica Chimica Acta 2013, 395, 33–43. https://doi.org/10.1016/j.ica.2012.09.043. in Inorganica Chimica Acta
Elsevier Science Sa, Lausanne..
https://hdl.handle.net/21.15107/rcub_cherry_3533

Milenković MR, Bacchi A, Cantoni G, Radulović S, Gligorijević N, Aranđelović S, Sladić D, Vujčić M, Mitić D, Anđelković KK. Supplementary data for article: Milenković, M. R.; Bacchi, A.; Cantoni, G.; Radulović, S. S.; Gligorijević, N.; Aranđelović, S.; Sladić, D.; Vujčić, M.; Mitić, D.; Anđelković, K. K. Synthesis, Characterisation and Biological Activity of Co(III) Complex with the Condensation Product of 2-(Diphenylphosphino)Benzaldehyde and Ethyl Carbazate. Inorganica Chimica Acta 2013, 395, 33–43. https://doi.org/10.1016/j.ica.2012.09.043. in Inorganica Chimica Acta. 2013;.
https://hdl.handle.net/21.15107/rcub_cherry_3533 .

Milenković, Milica R., Bacchi, Alessia, Cantoni, Giulia, Radulović, Siniša, Gligorijević, Nevenka, Aranđelović, Sandra, Sladić, Dušan, Vujčić, Miroslava, Mitić, Dragana, Anđelković, Katarina K., "Supplementary data for article: Milenković, M. R.; Bacchi, A.; Cantoni, G.; Radulović, S. S.; Gligorijević, N.; Aranđelović, S.; Sladić, D.; Vujčić, M.; Mitić, D.; Anđelković, K. K. Synthesis, Characterisation and Biological Activity of Co(III) Complex with the Condensation Product of 2-(Diphenylphosphino)Benzaldehyde and Ethyl Carbazate. Inorganica Chimica Acta 2013, 395, 33–43. https://doi.org/10.1016/j.ica.2012.09.043" in Inorganica Chimica Acta (2013),
https://hdl.handle.net/21.15107/rcub_cherry_3533 .

TY  - DATA
AU  - Milenković, Milica R.
AU  - Bacchi, Alessia
AU  - Cantoni, Giulia
AU  - Vilipić, Jovana
AU  - Sladić, Dušan
AU  - Vujčić, Miroslava
AU  - Gligorijević, Nevenka
AU  - Jovanović, Katarina
AU  - Radulović, Siniša
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3536
PB  - Elsevier France-Editions Scientifiques Medicales Elsevier, Paris
T2  - European Journal of Medicinal Chemistry
T1  - Supplementary data for article: Milenković, M. R.; Bacchi, A.; Cantoni, G.; Vilipić, J.; Sladić, D.; Vujčić, M.; Gligorijević, N.; Jovanovic, K.; Radulović, S. S. Synthesis, Characterization and Biological Activity of Three Square-Planar Complexes of Ni(II) with Ethyl (2E)-2-[2-(Diphenylphosphino) Benzylidene]Hydrazinecarboxylate and Monodentate Pseudohalides. European Journal of Medicinal Chemistry 2013, 68, 111–120. https://doi.org/10.1016/j.ejmech.2013.07.039
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3536
ER  - 

@misc{
author = "Milenković, Milica R. and Bacchi, Alessia and Cantoni, Giulia and Vilipić, Jovana and Sladić, Dušan and Vujčić, Miroslava and Gligorijević, Nevenka and Jovanović, Katarina and Radulović, Siniša",
year = "2013",
publisher = "Elsevier France-Editions Scientifiques Medicales Elsevier, Paris",
journal = "European Journal of Medicinal Chemistry",
title = "Supplementary data for article: Milenković, M. R.; Bacchi, A.; Cantoni, G.; Vilipić, J.; Sladić, D.; Vujčić, M.; Gligorijević, N.; Jovanovic, K.; Radulović, S. S. Synthesis, Characterization and Biological Activity of Three Square-Planar Complexes of Ni(II) with Ethyl (2E)-2-[2-(Diphenylphosphino) Benzylidene]Hydrazinecarboxylate and Monodentate Pseudohalides. European Journal of Medicinal Chemistry 2013, 68, 111–120. https://doi.org/10.1016/j.ejmech.2013.07.039",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3536"
}

Milenković, M. R., Bacchi, A., Cantoni, G., Vilipić, J., Sladić, D., Vujčić, M., Gligorijević, N., Jovanović, K.,& Radulović, S.. (2013). Supplementary data for article: Milenković, M. R.; Bacchi, A.; Cantoni, G.; Vilipić, J.; Sladić, D.; Vujčić, M.; Gligorijević, N.; Jovanovic, K.; Radulović, S. S. Synthesis, Characterization and Biological Activity of Three Square-Planar Complexes of Ni(II) with Ethyl (2E)-2-[2-(Diphenylphosphino) Benzylidene]Hydrazinecarboxylate and Monodentate Pseudohalides. European Journal of Medicinal Chemistry 2013, 68, 111–120. https://doi.org/10.1016/j.ejmech.2013.07.039. in European Journal of Medicinal Chemistry
Elsevier France-Editions Scientifiques Medicales Elsevier, Paris..
https://hdl.handle.net/21.15107/rcub_cherry_3536

Milenković MR, Bacchi A, Cantoni G, Vilipić J, Sladić D, Vujčić M, Gligorijević N, Jovanović K, Radulović S. Supplementary data for article: Milenković, M. R.; Bacchi, A.; Cantoni, G.; Vilipić, J.; Sladić, D.; Vujčić, M.; Gligorijević, N.; Jovanovic, K.; Radulović, S. S. Synthesis, Characterization and Biological Activity of Three Square-Planar Complexes of Ni(II) with Ethyl (2E)-2-[2-(Diphenylphosphino) Benzylidene]Hydrazinecarboxylate and Monodentate Pseudohalides. European Journal of Medicinal Chemistry 2013, 68, 111–120. https://doi.org/10.1016/j.ejmech.2013.07.039. in European Journal of Medicinal Chemistry. 2013;.
https://hdl.handle.net/21.15107/rcub_cherry_3536 .

Milenković, Milica R., Bacchi, Alessia, Cantoni, Giulia, Vilipić, Jovana, Sladić, Dušan, Vujčić, Miroslava, Gligorijević, Nevenka, Jovanović, Katarina, Radulović, Siniša, "Supplementary data for article: Milenković, M. R.; Bacchi, A.; Cantoni, G.; Vilipić, J.; Sladić, D.; Vujčić, M.; Gligorijević, N.; Jovanovic, K.; Radulović, S. S. Synthesis, Characterization and Biological Activity of Three Square-Planar Complexes of Ni(II) with Ethyl (2E)-2-[2-(Diphenylphosphino) Benzylidene]Hydrazinecarboxylate and Monodentate Pseudohalides. European Journal of Medicinal Chemistry 2013, 68, 111–120. https://doi.org/10.1016/j.ejmech.2013.07.039" in European Journal of Medicinal Chemistry (2013),
https://hdl.handle.net/21.15107/rcub_cherry_3536 .

TY  - JOUR
AU  - Milenković, Milica R.
AU  - Bacchi, Alessia
AU  - Cantoni, Giulia
AU  - Vilipić, Jovana
AU  - Sladić, Dušan
AU  - Vujčić, Miroslava
AU  - Gligorijević, Nevenka
AU  - Jovanović, Katarina
AU  - Radulović, Siniša
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1436
AB  - Three square-planar complexes of nickel(II) with the tridentate condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate, and monodentate pseudohalides, have been synthesized. Their crystal structures have been determined. All the complexes showed a significant antifungal activity, while only the azido complex displayed antibacterial activity. All the complexes were cytotoxic to a panel of six tumor cell lines, the azido complex showing a similar activity as cisplatin to leukemia cell line K562 and lower toxicity to normal MRC-5 cells than that anticancer agent. The complexes interfered with cell cycle of tumor cells and induced plasmid DNA cleavage.
PB  - Elsevier France-Editions Scientifiques Medicales Elsevier, Paris
T2  - European Journal of Medicinal Chemistry
T1  - Synthesis, characterization and biological activity of three square-planar complexes of Ni(II) with ethyl (2E)-2-[2-(diphenylphosphino) benzylidene]hydrazinecarboxylate and monodentate pseudohalides
VL  - 68
SP  - 111
EP  - 120
DO  - 10.1016/j.ejmech.2013.07.039
ER  - 

@article{
author = "Milenković, Milica R. and Bacchi, Alessia and Cantoni, Giulia and Vilipić, Jovana and Sladić, Dušan and Vujčić, Miroslava and Gligorijević, Nevenka and Jovanović, Katarina and Radulović, Siniša",
year = "2013",
abstract = "Three square-planar complexes of nickel(II) with the tridentate condensation derivative of 2-(diphenylphosphino)benzaldehyde and ethyl carbazate, and monodentate pseudohalides, have been synthesized. Their crystal structures have been determined. All the complexes showed a significant antifungal activity, while only the azido complex displayed antibacterial activity. All the complexes were cytotoxic to a panel of six tumor cell lines, the azido complex showing a similar activity as cisplatin to leukemia cell line K562 and lower toxicity to normal MRC-5 cells than that anticancer agent. The complexes interfered with cell cycle of tumor cells and induced plasmid DNA cleavage.",
publisher = "Elsevier France-Editions Scientifiques Medicales Elsevier, Paris",
journal = "European Journal of Medicinal Chemistry",
title = "Synthesis, characterization and biological activity of three square-planar complexes of Ni(II) with ethyl (2E)-2-[2-(diphenylphosphino) benzylidene]hydrazinecarboxylate and monodentate pseudohalides",
volume = "68",
pages = "111-120",
doi = "10.1016/j.ejmech.2013.07.039"
}

Milenković, M. R., Bacchi, A., Cantoni, G., Vilipić, J., Sladić, D., Vujčić, M., Gligorijević, N., Jovanović, K.,& Radulović, S.. (2013). Synthesis, characterization and biological activity of three square-planar complexes of Ni(II) with ethyl (2E)-2-[2-(diphenylphosphino) benzylidene]hydrazinecarboxylate and monodentate pseudohalides. in European Journal of Medicinal Chemistry
Elsevier France-Editions Scientifiques Medicales Elsevier, Paris., 68, 111-120.
https://doi.org/10.1016/j.ejmech.2013.07.039

Milenković MR, Bacchi A, Cantoni G, Vilipić J, Sladić D, Vujčić M, Gligorijević N, Jovanović K, Radulović S. Synthesis, characterization and biological activity of three square-planar complexes of Ni(II) with ethyl (2E)-2-[2-(diphenylphosphino) benzylidene]hydrazinecarboxylate and monodentate pseudohalides. in European Journal of Medicinal Chemistry. 2013;68:111-120.
doi:10.1016/j.ejmech.2013.07.039 .

Milenković, Milica R., Bacchi, Alessia, Cantoni, Giulia, Vilipić, Jovana, Sladić, Dušan, Vujčić, Miroslava, Gligorijević, Nevenka, Jovanović, Katarina, Radulović, Siniša, "Synthesis, characterization and biological activity of three square-planar complexes of Ni(II) with ethyl (2E)-2-[2-(diphenylphosphino) benzylidene]hydrazinecarboxylate and monodentate pseudohalides" in European Journal of Medicinal Chemistry, 68 (2013):111-120,
https://doi.org/10.1016/j.ejmech.2013.07.039 . .

TY  - JOUR
AU  - Bjelogrlić, Snežana K.
AU  - Todorović, Tamara
AU  - Bacchi, Alessia
AU  - Zec, Manja
AU  - Sladić, Dušan
AU  - Srdić-Rajić, Tatjana
AU  - Radanović, Dušanka D.
AU  - Radulović, Siniša
AU  - Pelizzi, Giancarlo
AU  - Anđelković, Katarina K.
PY  - 2010
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1081
AB  - Two novel Cd(II) and Zn(II) complexes with the condensation product of 2-formylpyridine and selenosemicarbazide were synthesized. The structure of Cd(II) complex was determined by X-ray crystallography. The ligand is coordinated in a neutral form via pyridine and azomethine nitrogen atoms and the selenium donor. The cadmium ion completes its five-coordination by two chloride ligands, forming a square-pyramidal geometry. The structure of Zn(II) complex was established by analysis of spectroscopic data, which indicated coordination of the ligand as a bidentate via the selenium and the azomethine nitrogen atoms. The cytotoxic activity of the newly synthesized complexes, as well as if five structurally related complexes and the ligand evaluated against eight tumor cell lines. The new Cd(II) complex showed the highest activity similar to cisplatin with IC50 less than 10 mu M for all cell lines. Cell cycle distribution and apoptosis study showed that Cd(II) complex and cisplatin might have some similarity in anticancer activity, which was not the case for cisplatin and other studied complexes. Effects of the complexes on matrix metalloproteinases (MMPs) MMP-9 and MMP-2 was also studied. Cd(II) and Zn(II) complexes and cisplatin increased MMP-2 activity in supernatants of tested cells. while Ni(II) complex with the same ligand decreased the activity, implying a possible activity in preventing tumor invasion and metastasis processes. (C) 2010 Elsevier Inc. All rights reserved.
PB  - Elsevier Science Inc, New York
T2  - Journal of Inorganic Biochemistry
T1  - Synthesis, structure and characterization of novel Cd(II) and Zn(II) complexes with the condensation product of 2-formylpyridine and selenosemicarbazide Antiproliferative activity of the synthesized complexes and related selenosemicarbazone complexes
VL  - 104
IS  - 6
SP  - 673
EP  - 682
DO  - 10.1016/j.jinorgbio.2010.02.009
ER  - 

@article{
author = "Bjelogrlić, Snežana K. and Todorović, Tamara and Bacchi, Alessia and Zec, Manja and Sladić, Dušan and Srdić-Rajić, Tatjana and Radanović, Dušanka D. and Radulović, Siniša and Pelizzi, Giancarlo and Anđelković, Katarina K.",
year = "2010",
abstract = "Two novel Cd(II) and Zn(II) complexes with the condensation product of 2-formylpyridine and selenosemicarbazide were synthesized. The structure of Cd(II) complex was determined by X-ray crystallography. The ligand is coordinated in a neutral form via pyridine and azomethine nitrogen atoms and the selenium donor. The cadmium ion completes its five-coordination by two chloride ligands, forming a square-pyramidal geometry. The structure of Zn(II) complex was established by analysis of spectroscopic data, which indicated coordination of the ligand as a bidentate via the selenium and the azomethine nitrogen atoms. The cytotoxic activity of the newly synthesized complexes, as well as if five structurally related complexes and the ligand evaluated against eight tumor cell lines. The new Cd(II) complex showed the highest activity similar to cisplatin with IC50 less than 10 mu M for all cell lines. Cell cycle distribution and apoptosis study showed that Cd(II) complex and cisplatin might have some similarity in anticancer activity, which was not the case for cisplatin and other studied complexes. Effects of the complexes on matrix metalloproteinases (MMPs) MMP-9 and MMP-2 was also studied. Cd(II) and Zn(II) complexes and cisplatin increased MMP-2 activity in supernatants of tested cells. while Ni(II) complex with the same ligand decreased the activity, implying a possible activity in preventing tumor invasion and metastasis processes. (C) 2010 Elsevier Inc. All rights reserved.",
publisher = "Elsevier Science Inc, New York",
journal = "Journal of Inorganic Biochemistry",
title = "Synthesis, structure and characterization of novel Cd(II) and Zn(II) complexes with the condensation product of 2-formylpyridine and selenosemicarbazide Antiproliferative activity of the synthesized complexes and related selenosemicarbazone complexes",
volume = "104",
number = "6",
pages = "673-682",
doi = "10.1016/j.jinorgbio.2010.02.009"
}

Bjelogrlić, S. K., Todorović, T., Bacchi, A., Zec, M., Sladić, D., Srdić-Rajić, T., Radanović, D. D., Radulović, S., Pelizzi, G.,& Anđelković, K. K.. (2010). Synthesis, structure and characterization of novel Cd(II) and Zn(II) complexes with the condensation product of 2-formylpyridine and selenosemicarbazide Antiproliferative activity of the synthesized complexes and related selenosemicarbazone complexes. in Journal of Inorganic Biochemistry
Elsevier Science Inc, New York., 104(6), 673-682.
https://doi.org/10.1016/j.jinorgbio.2010.02.009

Bjelogrlić SK, Todorović T, Bacchi A, Zec M, Sladić D, Srdić-Rajić T, Radanović DD, Radulović S, Pelizzi G, Anđelković KK. Synthesis, structure and characterization of novel Cd(II) and Zn(II) complexes with the condensation product of 2-formylpyridine and selenosemicarbazide Antiproliferative activity of the synthesized complexes and related selenosemicarbazone complexes. in Journal of Inorganic Biochemistry. 2010;104(6):673-682.
doi:10.1016/j.jinorgbio.2010.02.009 .

Bjelogrlić, Snežana K., Todorović, Tamara, Bacchi, Alessia, Zec, Manja, Sladić, Dušan, Srdić-Rajić, Tatjana, Radanović, Dušanka D., Radulović, Siniša, Pelizzi, Giancarlo, Anđelković, Katarina K., "Synthesis, structure and characterization of novel Cd(II) and Zn(II) complexes with the condensation product of 2-formylpyridine and selenosemicarbazide Antiproliferative activity of the synthesized complexes and related selenosemicarbazone complexes" in Journal of Inorganic Biochemistry, 104, no. 6 (2010):673-682,
https://doi.org/10.1016/j.jinorgbio.2010.02.009 . .

TY  - JOUR
AU  - Todorović, Tamara
AU  - Bacchi, Alessia
AU  - Sladić, Dušan
AU  - Todorović, Nina
AU  - Božić, Tatjana T.
AU  - Radanović, Dušanka D.
AU  - Filipović, Nenad R.
AU  - Pelizzi, Giancarlo
AU  - Anđelković, Katarina K.
PY  - 2009
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/873
AB  - Five new complexes of Pt(II), Pd(II), Co(III) and Ni(II) with 2-pyridine(quinoline) carboxaldehyde selenose-micarbazones were synthesized and characterized. Crystal structures of Pt(II) complex with the pyridine derivative and Co(III) complex with the quinoline derivative were determined. In all complexes the ligands were coordinated through N(2)Se donor atom set forming either square-planar (Pt, Pd) or octahedral (Co, Ni) geometry. All complexes showed biological activity. (C) 2009 Elsevier B. V. All rights reserved.
PB  - Elsevier Science Sa, Lausanne
T2  - Inorganica Chimica Acta
T1  - Synthesis, characterization and biological activity evaluation of Pt(II), Pd(II), Co(III) and Ni(II) complexes with N-heteroaromatic selenosemicarbazones
VL  - 362
IS  - 10
SP  - 3813
EP  - 3820
DO  - 10.1016/j.ica.2009.04.047
ER  - 

@article{
author = "Todorović, Tamara and Bacchi, Alessia and Sladić, Dušan and Todorović, Nina and Božić, Tatjana T. and Radanović, Dušanka D. and Filipović, Nenad R. and Pelizzi, Giancarlo and Anđelković, Katarina K.",
year = "2009",
abstract = "Five new complexes of Pt(II), Pd(II), Co(III) and Ni(II) with 2-pyridine(quinoline) carboxaldehyde selenose-micarbazones were synthesized and characterized. Crystal structures of Pt(II) complex with the pyridine derivative and Co(III) complex with the quinoline derivative were determined. In all complexes the ligands were coordinated through N(2)Se donor atom set forming either square-planar (Pt, Pd) or octahedral (Co, Ni) geometry. All complexes showed biological activity. (C) 2009 Elsevier B. V. All rights reserved.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Inorganica Chimica Acta",
title = "Synthesis, characterization and biological activity evaluation of Pt(II), Pd(II), Co(III) and Ni(II) complexes with N-heteroaromatic selenosemicarbazones",
volume = "362",
number = "10",
pages = "3813-3820",
doi = "10.1016/j.ica.2009.04.047"
}

Todorović, T., Bacchi, A., Sladić, D., Todorović, N., Božić, T. T., Radanović, D. D., Filipović, N. R., Pelizzi, G.,& Anđelković, K. K.. (2009). Synthesis, characterization and biological activity evaluation of Pt(II), Pd(II), Co(III) and Ni(II) complexes with N-heteroaromatic selenosemicarbazones. in Inorganica Chimica Acta
Elsevier Science Sa, Lausanne., 362(10), 3813-3820.
https://doi.org/10.1016/j.ica.2009.04.047

Todorović T, Bacchi A, Sladić D, Todorović N, Božić TT, Radanović DD, Filipović NR, Pelizzi G, Anđelković KK. Synthesis, characterization and biological activity evaluation of Pt(II), Pd(II), Co(III) and Ni(II) complexes with N-heteroaromatic selenosemicarbazones. in Inorganica Chimica Acta. 2009;362(10):3813-3820.
doi:10.1016/j.ica.2009.04.047 .

Todorović, Tamara, Bacchi, Alessia, Sladić, Dušan, Todorović, Nina, Božić, Tatjana T., Radanović, Dušanka D., Filipović, Nenad R., Pelizzi, Giancarlo, Anđelković, Katarina K., "Synthesis, characterization and biological activity evaluation of Pt(II), Pd(II), Co(III) and Ni(II) complexes with N-heteroaromatic selenosemicarbazones" in Inorganica Chimica Acta, 362, no. 10 (2009):3813-3820,
https://doi.org/10.1016/j.ica.2009.04.047 . .

TY  - JOUR
AU  - Filipović, Nenad R.
AU  - Bacchi, Alessia
AU  - Lazić, Milan
AU  - Pelizzi, Giancarlo
AU  - Radulović, Siniša
AU  - Sladić, Dušan
AU  - Todorović, Tamara
AU  - Anđelković, Katarina K.
PY  - 2008
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/913
AB  - A new dinuclear complex of Cd(II) with N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide (H2L) was synthesized and its crystal structure determined. The basic structural unit of the complex is the binuclear [Cd-2(H2O)(2)(H2L)(2)](4+) cation, where each cadmium atom is heptacoordinated by two tridentate H2L ligands, by means of the NNO chelating system, and one water molecule. A 12-membered macrocycle is defined at the core of the binuclear cation. The complex showed a pronounced cytotoxic activity to murine melanoma B16 cells and human cervical cancer HeLa cells. (c) 2007 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Inorganic Chemistry Communications
T1  - Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide
VL  - 11
IS  - 1
SP  - 47
EP  - 50
DO  - 10.1016/j.inoche.2007.10.013
ER  - 

@article{
author = "Filipović, Nenad R. and Bacchi, Alessia and Lazić, Milan and Pelizzi, Giancarlo and Radulović, Siniša and Sladić, Dušan and Todorović, Tamara and Anđelković, Katarina K.",
year = "2008",
abstract = "A new dinuclear complex of Cd(II) with N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide (H2L) was synthesized and its crystal structure determined. The basic structural unit of the complex is the binuclear [Cd-2(H2O)(2)(H2L)(2)](4+) cation, where each cadmium atom is heptacoordinated by two tridentate H2L ligands, by means of the NNO chelating system, and one water molecule. A 12-membered macrocycle is defined at the core of the binuclear cation. The complex showed a pronounced cytotoxic activity to murine melanoma B16 cells and human cervical cancer HeLa cells. (c) 2007 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Inorganic Chemistry Communications",
title = "Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide",
volume = "11",
number = "1",
pages = "47-50",
doi = "10.1016/j.inoche.2007.10.013"
}

Filipović, N. R., Bacchi, A., Lazić, M., Pelizzi, G., Radulović, S., Sladić, D., Todorović, T.,& Anđelković, K. K.. (2008). Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. in Inorganic Chemistry Communications
Elsevier Science Bv, Amsterdam., 11(1), 47-50.
https://doi.org/10.1016/j.inoche.2007.10.013

Filipović NR, Bacchi A, Lazić M, Pelizzi G, Radulović S, Sladić D, Todorović T, Anđelković KK. Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. in Inorganic Chemistry Communications. 2008;11(1):47-50.
doi:10.1016/j.inoche.2007.10.013 .

Filipović, Nenad R., Bacchi, Alessia, Lazić, Milan, Pelizzi, Giancarlo, Radulović, Siniša, Sladić, Dušan, Todorović, Tamara, Anđelković, Katarina K., "Synthesis, structure and cytotoxic activity evaluation of a dinuclear complex of Cd(II) with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide" in Inorganic Chemistry Communications, 11, no. 1 (2008):47-50,
https://doi.org/10.1016/j.inoche.2007.10.013 . .

TY  - JOUR
AU  - Todorović, Tamara
AU  - Bacchi, Alessia
AU  - Juranic, Nenad O.
AU  - Sladić, Dušan
AU  - Pelizzi, Giancarlo
AU  - Božić, Tatjana T.
AU  - Filipović, Nenad R.
AU  - Anđelković, Katarina K.
PY  - 2007
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/859
AB  - New complexes of Cd(II), Zn(II) and Ni(II) with 2-quinolinecarboxaldehyde selenosernicarbazone (Hqasesc) were synthesized and structurally characterized. The structure of the ligand, Cd(II) and Zn(II) complexes was determined by NMR and IR spectroscopy, elemental microanalysis and molar conductivity measurements. Both complexes occur in solution in two forms, the major tetrahedral and minor octahedral. In the major Cd(II) complex one qasesc(-) ligand is coordinated as a tridentate, the fourth coordination site being occupied by acetate, while in the major Zn(II) complex two qasesc- ligands are coordinated as bidentates. In both minor complexes two qasesc- ligands are coordinated as tridentates forming the octahedral geometry around the central metal ion. The only paramagnetic complex in the series is Ni(II) complex for which X-ray structure analysis was performed. The complex has the angularly distorted octahedral geometry with two qasesc- ligands coordinated as tridentates, in a similar way as in the minor complexes of Cd(11) and Zn(11). (c) 2007 Elsevier Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Synthesis and characterization of novel Cd(II), Zn(II) and Ni(II) complexes with 2-quinolinecarboxaldehyde selenosemicarbazone. Crystal structure of bis(2-quinolinecarboxaldehyde selenosemicarbazonato)nickel(II)
VL  - 26
IS  - 13
SP  - 3428
EP  - 3436
DO  - 10.1016/j.poly.2007.03.023
ER  - 

@article{
author = "Todorović, Tamara and Bacchi, Alessia and Juranic, Nenad O. and Sladić, Dušan and Pelizzi, Giancarlo and Božić, Tatjana T. and Filipović, Nenad R. and Anđelković, Katarina K.",
year = "2007",
abstract = "New complexes of Cd(II), Zn(II) and Ni(II) with 2-quinolinecarboxaldehyde selenosernicarbazone (Hqasesc) were synthesized and structurally characterized. The structure of the ligand, Cd(II) and Zn(II) complexes was determined by NMR and IR spectroscopy, elemental microanalysis and molar conductivity measurements. Both complexes occur in solution in two forms, the major tetrahedral and minor octahedral. In the major Cd(II) complex one qasesc(-) ligand is coordinated as a tridentate, the fourth coordination site being occupied by acetate, while in the major Zn(II) complex two qasesc- ligands are coordinated as bidentates. In both minor complexes two qasesc- ligands are coordinated as tridentates forming the octahedral geometry around the central metal ion. The only paramagnetic complex in the series is Ni(II) complex for which X-ray structure analysis was performed. The complex has the angularly distorted octahedral geometry with two qasesc- ligands coordinated as tridentates, in a similar way as in the minor complexes of Cd(11) and Zn(11). (c) 2007 Elsevier Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Synthesis and characterization of novel Cd(II), Zn(II) and Ni(II) complexes with 2-quinolinecarboxaldehyde selenosemicarbazone. Crystal structure of bis(2-quinolinecarboxaldehyde selenosemicarbazonato)nickel(II)",
volume = "26",
number = "13",
pages = "3428-3436",
doi = "10.1016/j.poly.2007.03.023"
}

Todorović, T., Bacchi, A., Juranic, N. O., Sladić, D., Pelizzi, G., Božić, T. T., Filipović, N. R.,& Anđelković, K. K.. (2007). Synthesis and characterization of novel Cd(II), Zn(II) and Ni(II) complexes with 2-quinolinecarboxaldehyde selenosemicarbazone. Crystal structure of bis(2-quinolinecarboxaldehyde selenosemicarbazonato)nickel(II). in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 26(13), 3428-3436.
https://doi.org/10.1016/j.poly.2007.03.023

Todorović T, Bacchi A, Juranic NO, Sladić D, Pelizzi G, Božić TT, Filipović NR, Anđelković KK. Synthesis and characterization of novel Cd(II), Zn(II) and Ni(II) complexes with 2-quinolinecarboxaldehyde selenosemicarbazone. Crystal structure of bis(2-quinolinecarboxaldehyde selenosemicarbazonato)nickel(II). in Polyhedron. 2007;26(13):3428-3436.
doi:10.1016/j.poly.2007.03.023 .

Todorović, Tamara, Bacchi, Alessia, Juranic, Nenad O., Sladić, Dušan, Pelizzi, Giancarlo, Božić, Tatjana T., Filipović, Nenad R., Anđelković, Katarina K., "Synthesis and characterization of novel Cd(II), Zn(II) and Ni(II) complexes with 2-quinolinecarboxaldehyde selenosemicarbazone. Crystal structure of bis(2-quinolinecarboxaldehyde selenosemicarbazonato)nickel(II)" in Polyhedron, 26, no. 13 (2007):3428-3436,
https://doi.org/10.1016/j.poly.2007.03.023 . .

TY  - JOUR
AU  - Todorović, Tamara
AU  - Bacchi, Alessia
AU  - Pelizzi, Giancarlo
AU  - Juranic, Nenad O.
AU  - Sladić, Dušan
AU  - Brčeski, Ilija
AU  - Anđelković, Katarina K.
PY  - 2006
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/793
AB  - A novel ligand 2,6-diacetylpyridine-bis(selenosemicarbazone) was synthesized and coordinated with Zn(II), Cd(II) and Ni(II). With Zn(II) and Cd(II), the bideprotonated ligand was coordinated as a quinquedentate in trigonal bipyramidal geometry. With Ni(II) during coordination the ligand was modified by elimination of hydrogen selenide and the product was coordinated as a quadridentate forming a square planar complex, the structure of which was determined by X-ray analysis. (C) 2006 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Inorganic Chemistry Communications
T1  - Synthesis and characterization of Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(selenosemicarbazone). Crystal structure of a Ni(II) complex with a modified 2.6-diacetylpyridine-bis(selenosemicarbazone)
VL  - 9
IS  - 8
SP  - 862
EP  - 865
DO  - 10.1016/j.inoche.2006.05.011
ER  - 

@article{
author = "Todorović, Tamara and Bacchi, Alessia and Pelizzi, Giancarlo and Juranic, Nenad O. and Sladić, Dušan and Brčeski, Ilija and Anđelković, Katarina K.",
year = "2006",
abstract = "A novel ligand 2,6-diacetylpyridine-bis(selenosemicarbazone) was synthesized and coordinated with Zn(II), Cd(II) and Ni(II). With Zn(II) and Cd(II), the bideprotonated ligand was coordinated as a quinquedentate in trigonal bipyramidal geometry. With Ni(II) during coordination the ligand was modified by elimination of hydrogen selenide and the product was coordinated as a quadridentate forming a square planar complex, the structure of which was determined by X-ray analysis. (C) 2006 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Inorganic Chemistry Communications",
title = "Synthesis and characterization of Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(selenosemicarbazone). Crystal structure of a Ni(II) complex with a modified 2.6-diacetylpyridine-bis(selenosemicarbazone)",
volume = "9",
number = "8",
pages = "862-865",
doi = "10.1016/j.inoche.2006.05.011"
}

Todorović, T., Bacchi, A., Pelizzi, G., Juranic, N. O., Sladić, D., Brčeski, I.,& Anđelković, K. K.. (2006). Synthesis and characterization of Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(selenosemicarbazone). Crystal structure of a Ni(II) complex with a modified 2.6-diacetylpyridine-bis(selenosemicarbazone). in Inorganic Chemistry Communications
Elsevier Science Bv, Amsterdam., 9(8), 862-865.
https://doi.org/10.1016/j.inoche.2006.05.011

Todorović T, Bacchi A, Pelizzi G, Juranic NO, Sladić D, Brčeski I, Anđelković KK. Synthesis and characterization of Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(selenosemicarbazone). Crystal structure of a Ni(II) complex with a modified 2.6-diacetylpyridine-bis(selenosemicarbazone). in Inorganic Chemistry Communications. 2006;9(8):862-865.
doi:10.1016/j.inoche.2006.05.011 .

Todorović, Tamara, Bacchi, Alessia, Pelizzi, Giancarlo, Juranic, Nenad O., Sladić, Dušan, Brčeski, Ilija, Anđelković, Katarina K., "Synthesis and characterization of Zn(II) and Cd(II) complexes with 2,6-diacetylpyridine-bis(selenosemicarbazone). Crystal structure of a Ni(II) complex with a modified 2.6-diacetylpyridine-bis(selenosemicarbazone)" in Inorganic Chemistry Communications, 9, no. 8 (2006):862-865,
https://doi.org/10.1016/j.inoche.2006.05.011 . .

TY  - JOUR
AU  - Radulovic, Vesna
AU  - Bacchi, Alessia
AU  - Pelizzi, Giancarlo
AU  - Sladić, Dušan
AU  - Brčeski, Ilija
AU  - Anđelković, Katarina K.
PY  - 2006
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/796
AB  - Complexes of Pt(II), Pd(II), and Ni(II) with the condensation derivative of 2-(diphenylphosphino)benzaidehydeand semioxamazide were synthesized, characterized, and their antimicrobial activity was evaluated. The ligand and the complexes were characterized by spectroscopic methods with the particular accent on NMR spectral analysis. For the palladium(II) complex, the crystal structure was determined by X-ray analysis. In all the complexes the ligand is coordinated as a tridentate via a P, N, O donor set. The Pd(II) and Pt(II) complexes have a square planar geometry, whereas the geometry of the Ni(II) complex is tetrahedral. The ligand showed antibacterial and antifungal activity, which was enhanced upon complexation.
PB  - Springer Wien, Wien
T2  - Monatshefte Fur Chemie
T1  - Synthesis, structure, and antimicrobial activity of complexes of Pt(II), Pd(II), and Ni(II) with the condensation product of 2-(diphenylphosphino)benzaldehyde and semioxamazide
VL  - 137
IS  - 6
SP  - 681
EP  - 691
DO  - 10.1007/s00706-005-0478-5
ER  - 

@article{
author = "Radulovic, Vesna and Bacchi, Alessia and Pelizzi, Giancarlo and Sladić, Dušan and Brčeski, Ilija and Anđelković, Katarina K.",
year = "2006",
abstract = "Complexes of Pt(II), Pd(II), and Ni(II) with the condensation derivative of 2-(diphenylphosphino)benzaidehydeand semioxamazide were synthesized, characterized, and their antimicrobial activity was evaluated. The ligand and the complexes were characterized by spectroscopic methods with the particular accent on NMR spectral analysis. For the palladium(II) complex, the crystal structure was determined by X-ray analysis. In all the complexes the ligand is coordinated as a tridentate via a P, N, O donor set. The Pd(II) and Pt(II) complexes have a square planar geometry, whereas the geometry of the Ni(II) complex is tetrahedral. The ligand showed antibacterial and antifungal activity, which was enhanced upon complexation.",
publisher = "Springer Wien, Wien",
journal = "Monatshefte Fur Chemie",
title = "Synthesis, structure, and antimicrobial activity of complexes of Pt(II), Pd(II), and Ni(II) with the condensation product of 2-(diphenylphosphino)benzaldehyde and semioxamazide",
volume = "137",
number = "6",
pages = "681-691",
doi = "10.1007/s00706-005-0478-5"
}

Radulovic, V., Bacchi, A., Pelizzi, G., Sladić, D., Brčeski, I.,& Anđelković, K. K.. (2006). Synthesis, structure, and antimicrobial activity of complexes of Pt(II), Pd(II), and Ni(II) with the condensation product of 2-(diphenylphosphino)benzaldehyde and semioxamazide. in Monatshefte Fur Chemie
Springer Wien, Wien., 137(6), 681-691.
https://doi.org/10.1007/s00706-005-0478-5

Radulovic V, Bacchi A, Pelizzi G, Sladić D, Brčeski I, Anđelković KK. Synthesis, structure, and antimicrobial activity of complexes of Pt(II), Pd(II), and Ni(II) with the condensation product of 2-(diphenylphosphino)benzaldehyde and semioxamazide. in Monatshefte Fur Chemie. 2006;137(6):681-691.
doi:10.1007/s00706-005-0478-5 .

Radulovic, Vesna, Bacchi, Alessia, Pelizzi, Giancarlo, Sladić, Dušan, Brčeski, Ilija, Anđelković, Katarina K., "Synthesis, structure, and antimicrobial activity of complexes of Pt(II), Pd(II), and Ni(II) with the condensation product of 2-(diphenylphosphino)benzaldehyde and semioxamazide" in Monatshefte Fur Chemie, 137, no. 6 (2006):681-691,
https://doi.org/10.1007/s00706-005-0478-5 . .

TY  - JOUR
AU  - Anđelković, Katarina K.
AU  - Sladić, Dušan
AU  - Bacchi, Alessia
AU  - Pelizzi, G
AU  - Filipović, Nenad R.
AU  - Rajkovic, M
PY  - 2005
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/694
AB  - Complexes of zinc and iron with N', N'(2)- bis[(1E)-1-(2-pyridyl) ethylidene] ethanedihydrazide (H(2)L1) and N', N'(2)-bis[( 1E)-1-(2-pyridyl) ethylidene] propanedihydrazide (H(2)L2) were prepared. Zn-II complexes with both ligands have an octahedral geometry. In the complex of Zn-II with H(2)L1, the ligand is coordinated as a tridentate species in the monoanionic form, building two five-membered rings around Zn-II. Three remaining coordination sites are occupied by water molecules, and in the outer sphere there is a ClO4- ion. In the other Zn-II complex, the H(2)L2 ligand is coordinated in the enol form as a tetradenate species, forming a five-memebered, a six-membered and a seven-membered ring, the remaining coordination sites being occupied by water molecules, while in the outer sphere there are two ClO4- ions. The Fe-III complex with H(2)L2 is a high-spin octahedral complex. The ligand is coordinated in the enol form, in a tetradentate fashion via pyridine and hydrazone nitrogens. The remaining two coordination sites in the complex are occupied by water molecules and a Cl) ion, and in the outer sphere there are two Cl) anions. The octahedral Fe-III complex obtained from the reaction of FeCl(3)center dot 6H(2)O and H(2)L1 in absolute ethanol has the formula [Fe(HL1) Cl-2(H(2)0)] center dot 1.5H(2)O. However, during coordination of the H(2)L1 ligand to Fe-III in water, oxidative degradation of the side chain ( - CO - CO -) and reduction of Fe-III to Fe-II occurs, affording octahedral tris(1-(2-pyridyl) ethylidenehydrazine] iron(II) perchlorate, as confirmed by X-ray structure analysis.
PB  - Springer, Dordrecht
T2  - Transition Metal Chemistry
T1  - Complexes of iron(II), iron(III) and zinc(II) with condensation derivatives of 2-acetylpyridine and oxalic or malonic dihydrazide. Crystal structure of tris[(1-(2-pyridyl)ethylidene)hydrazine]iron(II) perchlorate
VL  - 30
IS  - 2
SP  - 243
EP  - 250
DO  - 10.1007/s11243-004-3173-1
ER  - 

@article{
author = "Anđelković, Katarina K. and Sladić, Dušan and Bacchi, Alessia and Pelizzi, G and Filipović, Nenad R. and Rajkovic, M",
year = "2005",
abstract = "Complexes of zinc and iron with N', N'(2)- bis[(1E)-1-(2-pyridyl) ethylidene] ethanedihydrazide (H(2)L1) and N', N'(2)-bis[( 1E)-1-(2-pyridyl) ethylidene] propanedihydrazide (H(2)L2) were prepared. Zn-II complexes with both ligands have an octahedral geometry. In the complex of Zn-II with H(2)L1, the ligand is coordinated as a tridentate species in the monoanionic form, building two five-membered rings around Zn-II. Three remaining coordination sites are occupied by water molecules, and in the outer sphere there is a ClO4- ion. In the other Zn-II complex, the H(2)L2 ligand is coordinated in the enol form as a tetradenate species, forming a five-memebered, a six-membered and a seven-membered ring, the remaining coordination sites being occupied by water molecules, while in the outer sphere there are two ClO4- ions. The Fe-III complex with H(2)L2 is a high-spin octahedral complex. The ligand is coordinated in the enol form, in a tetradentate fashion via pyridine and hydrazone nitrogens. The remaining two coordination sites in the complex are occupied by water molecules and a Cl) ion, and in the outer sphere there are two Cl) anions. The octahedral Fe-III complex obtained from the reaction of FeCl(3)center dot 6H(2)O and H(2)L1 in absolute ethanol has the formula [Fe(HL1) Cl-2(H(2)0)] center dot 1.5H(2)O. However, during coordination of the H(2)L1 ligand to Fe-III in water, oxidative degradation of the side chain ( - CO - CO -) and reduction of Fe-III to Fe-II occurs, affording octahedral tris(1-(2-pyridyl) ethylidenehydrazine] iron(II) perchlorate, as confirmed by X-ray structure analysis.",
publisher = "Springer, Dordrecht",
journal = "Transition Metal Chemistry",
title = "Complexes of iron(II), iron(III) and zinc(II) with condensation derivatives of 2-acetylpyridine and oxalic or malonic dihydrazide. Crystal structure of tris[(1-(2-pyridyl)ethylidene)hydrazine]iron(II) perchlorate",
volume = "30",
number = "2",
pages = "243-250",
doi = "10.1007/s11243-004-3173-1"
}

Anđelković, K. K., Sladić, D., Bacchi, A., Pelizzi, G., Filipović, N. R.,& Rajkovic, M.. (2005). Complexes of iron(II), iron(III) and zinc(II) with condensation derivatives of 2-acetylpyridine and oxalic or malonic dihydrazide. Crystal structure of tris[(1-(2-pyridyl)ethylidene)hydrazine]iron(II) perchlorate. in Transition Metal Chemistry
Springer, Dordrecht., 30(2), 243-250.
https://doi.org/10.1007/s11243-004-3173-1

Anđelković KK, Sladić D, Bacchi A, Pelizzi G, Filipović NR, Rajkovic M. Complexes of iron(II), iron(III) and zinc(II) with condensation derivatives of 2-acetylpyridine and oxalic or malonic dihydrazide. Crystal structure of tris[(1-(2-pyridyl)ethylidene)hydrazine]iron(II) perchlorate. in Transition Metal Chemistry. 2005;30(2):243-250.
doi:10.1007/s11243-004-3173-1 .

Anđelković, Katarina K., Sladić, Dušan, Bacchi, Alessia, Pelizzi, G, Filipović, Nenad R., Rajkovic, M, "Complexes of iron(II), iron(III) and zinc(II) with condensation derivatives of 2-acetylpyridine and oxalic or malonic dihydrazide. Crystal structure of tris[(1-(2-pyridyl)ethylidene)hydrazine]iron(II) perchlorate" in Transition Metal Chemistry, 30, no. 2 (2005):243-250,
https://doi.org/10.1007/s11243-004-3173-1 . .

TY  - JOUR
AU  - Filipović, Nenad R.
AU  - Bacchi, Alessia
AU  - Pelizzi, G
AU  - Marković, R.
AU  - Mitić, D
AU  - Anđelković, Katarina K.
PY  - 2005
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/738
AB  - Four Co(III), Zn(II), Pd(II) and Cd(II) complexes with ligands derived in situ from acetylpyridine and ethyl hydrazinoacetate or hydrolysed ethyl hydrazinoacetate were prepared. An X-ray structural analysis showed that the Co(III) complex is octahedral with two tridentate (E)-2-[N'-(1-pyridin-2-yl-ethylidene) hydrazino] acetate (apha) ligands, each forming two five-membered rings with the metal ion. In the tetrahedral Zn(II) complex, only a single apha ligand was coordinated, in the same way as that in the Co(III) complex. In the case of the tetrahedral Cd(II) complex the non-hydrolysed form of (E)-2-[N'-(1-pyridin2-yl-ethylidene)hydrazino]acetic acid ethyl ester (aphaoet) coordinated as a bidentate and the two remaining coordination sites were occupied by Cl- and CH3COO- ions. In addition, the square-planar neutral Pd(II) complex was synthesized, having the same bidentate as in the Cd(II) complex and two Cl- ions in the remaining coordination sites. Due to their being diamagnetic, all four complexes were characterized by H-1-NMR and C-13-NMR spectroscopy.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate: X-ray structure analysis of mer-bis{(E)-2-[N '-(1-pyridin-2-yl-ethylidene)hydrazin
VL  - 58
IS  - 17
SP  - 1541
EP  - 1550
DO  - 10.1080/00958970500240383
ER  - 

@article{
author = "Filipović, Nenad R. and Bacchi, Alessia and Pelizzi, G and Marković, R. and Mitić, D and Anđelković, Katarina K.",
year = "2005",
abstract = "Four Co(III), Zn(II), Pd(II) and Cd(II) complexes with ligands derived in situ from acetylpyridine and ethyl hydrazinoacetate or hydrolysed ethyl hydrazinoacetate were prepared. An X-ray structural analysis showed that the Co(III) complex is octahedral with two tridentate (E)-2-[N'-(1-pyridin-2-yl-ethylidene) hydrazino] acetate (apha) ligands, each forming two five-membered rings with the metal ion. In the tetrahedral Zn(II) complex, only a single apha ligand was coordinated, in the same way as that in the Co(III) complex. In the case of the tetrahedral Cd(II) complex the non-hydrolysed form of (E)-2-[N'-(1-pyridin2-yl-ethylidene)hydrazino]acetic acid ethyl ester (aphaoet) coordinated as a bidentate and the two remaining coordination sites were occupied by Cl- and CH3COO- ions. In addition, the square-planar neutral Pd(II) complex was synthesized, having the same bidentate as in the Cd(II) complex and two Cl- ions in the remaining coordination sites. Due to their being diamagnetic, all four complexes were characterized by H-1-NMR and C-13-NMR spectroscopy.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate: X-ray structure analysis of mer-bis{(E)-2-[N '-(1-pyridin-2-yl-ethylidene)hydrazin",
volume = "58",
number = "17",
pages = "1541-1550",
doi = "10.1080/00958970500240383"
}

Filipović, N. R., Bacchi, A., Pelizzi, G., Marković, R., Mitić, D.,& Anđelković, K. K.. (2005). Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate: X-ray structure analysis of mer-bis{(E)-2-[N '-(1-pyridin-2-yl-ethylidene)hydrazin. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 58(17), 1541-1550.
https://doi.org/10.1080/00958970500240383

Filipović NR, Bacchi A, Pelizzi G, Marković R, Mitić D, Anđelković KK. Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate: X-ray structure analysis of mer-bis{(E)-2-[N '-(1-pyridin-2-yl-ethylidene)hydrazin. in Journal of Coordination Chemistry. 2005;58(17):1541-1550.
doi:10.1080/00958970500240383 .

Filipović, Nenad R., Bacchi, Alessia, Pelizzi, G, Marković, R., Mitić, D, Anđelković, Katarina K., "Cobalt(III), zinc(II), cadmium(II) and palladium(II) complexes with the hydrolysed and non-hydrolysed condensation products of 2-acetylpyridine with ethyl hydrazinoacetate: X-ray structure analysis of mer-bis{(E)-2-[N '-(1-pyridin-2-yl-ethylidene)hydrazin" in Journal of Coordination Chemistry, 58, no. 17 (2005):1541-1550,
https://doi.org/10.1080/00958970500240383 . .

TY  - JOUR
AU  - Bacchi, Alessia
AU  - Pelizzi, G
AU  - Jeremić, Dejan
AU  - Sladić, Dušan
AU  - Gruden-Pavlović, Maja
AU  - Anđelković, Katarina K.
PY  - 2003
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/159
AB  - The octahedral copper(II) complex with two 2'-[1-(2-pyridinyl) ethylidene] oxalohydrazide molecules was synthesized from bis(acetylacetonato) copper(II) and 2'-[1-(2-pyridinyl) ethylidene] oxamohydrazide (Hapsox). The complex is unstable when not in solution. X-ray analysis confirmed the tridentate coordination of the ligands in the monoanionic form. In addition, the stable tetrahedral copper(II) complex with one ligand molecule coordinated as a tridentate in the dianionic form was prepared by direct synthesis from Cu(NO3)(2) . 3H(2)O and Hapsox, and characterized by elemental analysis, magnetic measurements and by i.r. and u.v./vis. spectrophotometry.
PB  - Kluwer Academic Publ, Dordrecht
T2  - Transition Metal Chemistry
T1  - Synthesis and structural characterization of copper(II) complexes with the 2 '-[1-(2-pyridinyl)ethylidene]oxalohydrazide ligand
VL  - 28
IS  - 8
SP  - 935
EP  - 938
DO  - 10.1023/A:1026316611296
ER  - 

@article{
author = "Bacchi, Alessia and Pelizzi, G and Jeremić, Dejan and Sladić, Dušan and Gruden-Pavlović, Maja and Anđelković, Katarina K.",
year = "2003",
abstract = "The octahedral copper(II) complex with two 2'-[1-(2-pyridinyl) ethylidene] oxalohydrazide molecules was synthesized from bis(acetylacetonato) copper(II) and 2'-[1-(2-pyridinyl) ethylidene] oxamohydrazide (Hapsox). The complex is unstable when not in solution. X-ray analysis confirmed the tridentate coordination of the ligands in the monoanionic form. In addition, the stable tetrahedral copper(II) complex with one ligand molecule coordinated as a tridentate in the dianionic form was prepared by direct synthesis from Cu(NO3)(2) . 3H(2)O and Hapsox, and characterized by elemental analysis, magnetic measurements and by i.r. and u.v./vis. spectrophotometry.",
publisher = "Kluwer Academic Publ, Dordrecht",
journal = "Transition Metal Chemistry",
title = "Synthesis and structural characterization of copper(II) complexes with the 2 '-[1-(2-pyridinyl)ethylidene]oxalohydrazide ligand",
volume = "28",
number = "8",
pages = "935-938",
doi = "10.1023/A:1026316611296"
}

Bacchi, A., Pelizzi, G., Jeremić, D., Sladić, D., Gruden-Pavlović, M.,& Anđelković, K. K.. (2003). Synthesis and structural characterization of copper(II) complexes with the 2 '-[1-(2-pyridinyl)ethylidene]oxalohydrazide ligand. in Transition Metal Chemistry
Kluwer Academic Publ, Dordrecht., 28(8), 935-938.
https://doi.org/10.1023/A:1026316611296

Bacchi A, Pelizzi G, Jeremić D, Sladić D, Gruden-Pavlović M, Anđelković KK. Synthesis and structural characterization of copper(II) complexes with the 2 '-[1-(2-pyridinyl)ethylidene]oxalohydrazide ligand. in Transition Metal Chemistry. 2003;28(8):935-938.
doi:10.1023/A:1026316611296 .

Bacchi, Alessia, Pelizzi, G, Jeremić, Dejan, Sladić, Dušan, Gruden-Pavlović, Maja, Anđelković, Katarina K., "Synthesis and structural characterization of copper(II) complexes with the 2 '-[1-(2-pyridinyl)ethylidene]oxalohydrazide ligand" in Transition Metal Chemistry, 28, no. 8 (2003):935-938,
https://doi.org/10.1023/A:1026316611296 . .

TY  - JOUR
AU  - Anđelković, Katarina K.
AU  - Bacchi, Alessia
AU  - Pelizzi, G
AU  - Jeremić, Dejan
AU  - Ivanović-Burmazović, Ivana
PY  - 2002
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/539
AB  - The title compound was prepared by a template synthesis from 2,6-diacetylpyridine, dioxamohydrazide and Fe(ClO4)(3) . 6H(2)O (mol ratio 1: 2: 1) in MeOH/H2O (3:1) solution and its structure determined by single-crystal X-ray diffraction; triclinic, space group P (1) over bar, a= 7.5186(7), b = 10.9730(9), c = 14.6110(10) Angstrom, alpha = 95.866(1), beta = 100.252(1), gamma = 92.895(1), z = 2. The polydentate ligand is coordinated as a dianionic pentadentate while water molecules occupy apical positions in the structure. This is the first example of a monomeric, pentagonal bipyramidal structure of an Fe(III) complex with a dianionic bis(acylhydrazone) derivative of 2,6-diacetylpyridine.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2 ',2 ''-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide]iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)(2)]ClO4 center dot 3H(2)O
VL  - 55
IS  - 12
SP  - 1385
EP  - 1392
DO  - 10.1080/0095897021000058600
ER  - 

@article{
author = "Anđelković, Katarina K. and Bacchi, Alessia and Pelizzi, G and Jeremić, Dejan and Ivanović-Burmazović, Ivana",
year = "2002",
abstract = "The title compound was prepared by a template synthesis from 2,6-diacetylpyridine, dioxamohydrazide and Fe(ClO4)(3) . 6H(2)O (mol ratio 1: 2: 1) in MeOH/H2O (3:1) solution and its structure determined by single-crystal X-ray diffraction; triclinic, space group P (1) over bar, a= 7.5186(7), b = 10.9730(9), c = 14.6110(10) Angstrom, alpha = 95.866(1), beta = 100.252(1), gamma = 92.895(1), z = 2. The polydentate ligand is coordinated as a dianionic pentadentate while water molecules occupy apical positions in the structure. This is the first example of a monomeric, pentagonal bipyramidal structure of an Fe(III) complex with a dianionic bis(acylhydrazone) derivative of 2,6-diacetylpyridine.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2 ',2 ''-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide]iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)(2)]ClO4 center dot 3H(2)O",
volume = "55",
number = "12",
pages = "1385-1392",
doi = "10.1080/0095897021000058600"
}

Anđelković, K. K., Bacchi, A., Pelizzi, G., Jeremić, D.,& Ivanović-Burmazović, I.. (2002). An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2 ',2 ''-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide]iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)(2)]ClO4 center dot 3H(2)O. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 55(12), 1385-1392.
https://doi.org/10.1080/0095897021000058600

Anđelković KK, Bacchi A, Pelizzi G, Jeremić D, Ivanović-Burmazović I. An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2 ',2 ''-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide]iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)(2)]ClO4 center dot 3H(2)O. in Journal of Coordination Chemistry. 2002;55(12):1385-1392.
doi:10.1080/0095897021000058600 .

Anđelković, Katarina K., Bacchi, Alessia, Pelizzi, G, Jeremić, Dejan, Ivanović-Burmazović, Ivana, "An Fe(III) complex with the dianionic form of 2,6-diacetylpyridine bis(acylhydrazone). The crystal structure of [diaqua-2 ',2 ''-(2,6-pyridinediyldiethylidyne)dioxamo-hydrazide]iron(III) perchlorate trihydrate, [Fe(dapsox)(H2O)(2)]ClO4 center dot 3H(2)O" in Journal of Coordination Chemistry, 55, no. 12 (2002):1385-1392,
https://doi.org/10.1080/0095897021000058600 . .

TY  - JOUR
AU  - Bacchi, Alessia
AU  - Ivanović-Burmazović, Ivana
AU  - Pelizzi, G
AU  - Anđelković, Katarina K.
PY  - 2001
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/450
AB  - The synthesis of two Fe(III) complexes with a doubly deprotonated polydentate of the acylhydrazone class is described. The first complex was obtained by hydrolyzing the previously synthesized high-spin pentagonal-bipyramidal (PBP) [Fe(Hdapsox)Cl-2] (H(2)dapsox = 2',2"'-(2,6-pyridindiyldiethylidene)dioxamohydrazide); the second was obtained by a template synthesis in a base medium starting from iron(III) chloride, 2,6-diacetylpyridine (dap) and semioxamazide (sox) (in a 1:1:2 molar ratio). Hydrolysis, during which the semioxamazide amide group changed into a carboxyl group, resulted in the mu -oxo-diiron(III) complex [Fe(dapoamh)(H2O)(2)O . 3H(2)O (H(2)dapoamh = dioxo-2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene)diacetic acid) with a doubly deprotonated acylhydrazone that retained its PBP geometry. The [Fe(dapsox)Cl].H2O complex obtained in the latter case has a square-pyramidal geometry with an asymmetrically coordinated, but still doubly deprotonated dapsox as a tetradentate. The structure of the [Fe(dapoamh)(H2O)(2)O . 3H(2)O complex determined by single-crystal X-ray analysis in this work represents the first mu -oxo-dimer of a PBP geometry with an acyclic polydentate. This is also the first diamagnetic Cl-oxo-diiron(III) complex ever obtained; this not only points to the super-exchange interaction over an ore-oxygen, but also to a significant interaction between the two low-spin Fe(III) ion d-orbitals. Based on the EPR spectra, it has been established that the monomer [Fe(dapsox)Cl].H2O complex is among the rare Fe(III) complexes with an intermediate spin state S = 3/2, and that a temperature decrease causes it to change to a low-spin complex, i.e. it demonstrates a cross-over (S = 3/2 reversible arrow S = 1/2). Further characterization has been done by IR and UV-VIS spectroscopy, and also by measuring the magnetic momentum at 293, 195 and 77 K. The results of this work, as well as of the previously synthesized Cu(II), Co(II) and Ni(II) complexes with H(2)dapsox, Hdapsox(-) and dapsox(2-), have led us to the conclusion that the doubly deprotonated acylhydrazone ligand has a considerably stronger field than its neutral or monoanionic forms. (C) 2001 Elsevier Science B.V. All rights reserved.
PB  - Elsevier Science Sa, Lausanne
T2  - Inorganica Chimica Acta
T1  - The Fe(III) complexes with a doubly deprotonated polydentate acylhydrazone: crystal structure of the first diamagnetic mu-oxo-diiron(III) complex
VL  - 313
IS  - 1-2
SP  - 109
EP  - 119
DO  - 10.1016/S0020-1693(00)00377-7
ER  - 

@article{
author = "Bacchi, Alessia and Ivanović-Burmazović, Ivana and Pelizzi, G and Anđelković, Katarina K.",
year = "2001",
abstract = "The synthesis of two Fe(III) complexes with a doubly deprotonated polydentate of the acylhydrazone class is described. The first complex was obtained by hydrolyzing the previously synthesized high-spin pentagonal-bipyramidal (PBP) [Fe(Hdapsox)Cl-2] (H(2)dapsox = 2',2"'-(2,6-pyridindiyldiethylidene)dioxamohydrazide); the second was obtained by a template synthesis in a base medium starting from iron(III) chloride, 2,6-diacetylpyridine (dap) and semioxamazide (sox) (in a 1:1:2 molar ratio). Hydrolysis, during which the semioxamazide amide group changed into a carboxyl group, resulted in the mu -oxo-diiron(III) complex [Fe(dapoamh)(H2O)(2)O . 3H(2)O (H(2)dapoamh = dioxo-2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene)diacetic acid) with a doubly deprotonated acylhydrazone that retained its PBP geometry. The [Fe(dapsox)Cl].H2O complex obtained in the latter case has a square-pyramidal geometry with an asymmetrically coordinated, but still doubly deprotonated dapsox as a tetradentate. The structure of the [Fe(dapoamh)(H2O)(2)O . 3H(2)O complex determined by single-crystal X-ray analysis in this work represents the first mu -oxo-dimer of a PBP geometry with an acyclic polydentate. This is also the first diamagnetic Cl-oxo-diiron(III) complex ever obtained; this not only points to the super-exchange interaction over an ore-oxygen, but also to a significant interaction between the two low-spin Fe(III) ion d-orbitals. Based on the EPR spectra, it has been established that the monomer [Fe(dapsox)Cl].H2O complex is among the rare Fe(III) complexes with an intermediate spin state S = 3/2, and that a temperature decrease causes it to change to a low-spin complex, i.e. it demonstrates a cross-over (S = 3/2 reversible arrow S = 1/2). Further characterization has been done by IR and UV-VIS spectroscopy, and also by measuring the magnetic momentum at 293, 195 and 77 K. The results of this work, as well as of the previously synthesized Cu(II), Co(II) and Ni(II) complexes with H(2)dapsox, Hdapsox(-) and dapsox(2-), have led us to the conclusion that the doubly deprotonated acylhydrazone ligand has a considerably stronger field than its neutral or monoanionic forms. (C) 2001 Elsevier Science B.V. All rights reserved.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Inorganica Chimica Acta",
title = "The Fe(III) complexes with a doubly deprotonated polydentate acylhydrazone: crystal structure of the first diamagnetic mu-oxo-diiron(III) complex",
volume = "313",
number = "1-2",
pages = "109-119",
doi = "10.1016/S0020-1693(00)00377-7"
}

Bacchi, A., Ivanović-Burmazović, I., Pelizzi, G.,& Anđelković, K. K.. (2001). The Fe(III) complexes with a doubly deprotonated polydentate acylhydrazone: crystal structure of the first diamagnetic mu-oxo-diiron(III) complex. in Inorganica Chimica Acta
Elsevier Science Sa, Lausanne., 313(1-2), 109-119.
https://doi.org/10.1016/S0020-1693(00)00377-7

Bacchi A, Ivanović-Burmazović I, Pelizzi G, Anđelković KK. The Fe(III) complexes with a doubly deprotonated polydentate acylhydrazone: crystal structure of the first diamagnetic mu-oxo-diiron(III) complex. in Inorganica Chimica Acta. 2001;313(1-2):109-119.
doi:10.1016/S0020-1693(00)00377-7 .

Bacchi, Alessia, Ivanović-Burmazović, Ivana, Pelizzi, G, Anđelković, Katarina K., "The Fe(III) complexes with a doubly deprotonated polydentate acylhydrazone: crystal structure of the first diamagnetic mu-oxo-diiron(III) complex" in Inorganica Chimica Acta, 313, no. 1-2 (2001):109-119,
https://doi.org/10.1016/S0020-1693(00)00377-7 . .

TY  - JOUR
AU  - Pelizzi, G
AU  - Bacchi, Alessia
AU  - Ivanović-Burmazović, Ivana
AU  - Gruden-Pavlović, Maja
AU  - Anđelković, Katarina K.
PY  - 2001
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/458
AB  - The octahedral Ni(II) complex with dioxo-2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene)diacetic acid (H(2)dapoamh) was synthesized and X-ray analysis confirmed the tridentate coordination for the neutral ligand. Besides, the square planar Ni(II) complex with dianion 2 ', 2 ' ' '-(2,6-pyridinediyldiethylidyne)dioxamohydrazide (H(2)dapsox) was synthesized and characterized. (C) 2001 Elsevier Science B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Inorganic Chemistry Communications
T1  - Ni(II) complexes with neutral and dianionic form of 2,6-diacetylpyridine bis(acylhydrazones). Crystal structure of bis[dioxo-2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene) diacetic acid]nickel(II) perchlorate
VL  - 4
IS  - 6
SP  - 311
EP  - 314
DO  - 10.1016/S1387-7003(01)00161-7
ER  - 

@article{
author = "Pelizzi, G and Bacchi, Alessia and Ivanović-Burmazović, Ivana and Gruden-Pavlović, Maja and Anđelković, Katarina K.",
year = "2001",
abstract = "The octahedral Ni(II) complex with dioxo-2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene)diacetic acid (H(2)dapoamh) was synthesized and X-ray analysis confirmed the tridentate coordination for the neutral ligand. Besides, the square planar Ni(II) complex with dianion 2 ', 2 ' ' '-(2,6-pyridinediyldiethylidyne)dioxamohydrazide (H(2)dapsox) was synthesized and characterized. (C) 2001 Elsevier Science B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Inorganic Chemistry Communications",
title = "Ni(II) complexes with neutral and dianionic form of 2,6-diacetylpyridine bis(acylhydrazones). Crystal structure of bis[dioxo-2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene) diacetic acid]nickel(II) perchlorate",
volume = "4",
number = "6",
pages = "311-314",
doi = "10.1016/S1387-7003(01)00161-7"
}

Pelizzi, G., Bacchi, A., Ivanović-Burmazović, I., Gruden-Pavlović, M.,& Anđelković, K. K.. (2001). Ni(II) complexes with neutral and dianionic form of 2,6-diacetylpyridine bis(acylhydrazones). Crystal structure of bis[dioxo-2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene) diacetic acid]nickel(II) perchlorate. in Inorganic Chemistry Communications
Elsevier Science Bv, Amsterdam., 4(6), 311-314.
https://doi.org/10.1016/S1387-7003(01)00161-7

Pelizzi G, Bacchi A, Ivanović-Burmazović I, Gruden-Pavlović M, Anđelković KK. Ni(II) complexes with neutral and dianionic form of 2,6-diacetylpyridine bis(acylhydrazones). Crystal structure of bis[dioxo-2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene) diacetic acid]nickel(II) perchlorate. in Inorganic Chemistry Communications. 2001;4(6):311-314.
doi:10.1016/S1387-7003(01)00161-7 .

Pelizzi, G, Bacchi, Alessia, Ivanović-Burmazović, Ivana, Gruden-Pavlović, Maja, Anđelković, Katarina K., "Ni(II) complexes with neutral and dianionic form of 2,6-diacetylpyridine bis(acylhydrazones). Crystal structure of bis[dioxo-2,6-pyridinediylbis(ethylidyne-1-hydrazinyl-2-ylidene) diacetic acid]nickel(II) perchlorate" in Inorganic Chemistry Communications, 4, no. 6 (2001):311-314,
https://doi.org/10.1016/S1387-7003(01)00161-7 . .

TY  - JOUR
AU  - Ivanović-Burmazović, Ivana
AU  - Bacchi, Alessia
AU  - Pelizzi, G
AU  - Leovac, Vukadin M.
AU  - Anđelković, Katarina K.
PY  - 1998
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/405
AB  - Starting from Cu(II) and Ni(II) perchlorate and Fe(III) chloride in the presence of 2,6-diacetylpyridine (dap) and semioxamazide (sox), the [Cu(Hdapsox)H2O]ClO4 (I), [Ni(Hdapsox)(MeOH)(2)]ClO4 (II) and [Fe(Hdapsox)Cl-2]. 1/2H(2)O (III) complexes with a singly deprotonated ligand Hdapsox(-) of the acyl hydrazone class (with H(2)dapsox = 2',2'''-(2,6-pyridindiyldiethylidene)dioxamohydrazide) have been obtained and characterized for the first time by a template synthesis. The previously assumed [1] square-pyramidal structure of the Cu(II) complex with an asymmetrical coordination of Hdapsox(-) has been confirmed by a single-crystal X-ray analysis. In II Hdapsox(-) is octahedrally coordinated around a Ni(II) ion, while III is found to be a pentagonal-bipyramidal complex with a symmetrically bonded Hdapsox(-). Causes of a ligand deprotonation occurring in a very acid medium (pH = 0) and of a different coordination pattern in the case of Cu(II), NI(II) and Fe(III) are interpreted by a d(n) configuration and an effective nuclear charge of the central metal ion (crystal field effects). (C) 1998 Elsevier Science Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Cu(II), Ni(II) and Fe(III) complexes with 2 ',2 '''-(2,6-pyridindiyldiethylidene)-dioxamohydrazide in a monoanionic form. The crystal structure of aqua-2 ',2 '''-(2,6-pyridindiyldiethylidene)-dioxamohydrazidecopper(II) perchlorate
VL  - 18
IS  - 1-2
SP  - 119
EP  - 127
DO  - 10.1016/S0277-5387(98)00274-5
ER  - 

@article{
author = "Ivanović-Burmazović, Ivana and Bacchi, Alessia and Pelizzi, G and Leovac, Vukadin M. and Anđelković, Katarina K.",
year = "1998",
abstract = "Starting from Cu(II) and Ni(II) perchlorate and Fe(III) chloride in the presence of 2,6-diacetylpyridine (dap) and semioxamazide (sox), the [Cu(Hdapsox)H2O]ClO4 (I), [Ni(Hdapsox)(MeOH)(2)]ClO4 (II) and [Fe(Hdapsox)Cl-2]. 1/2H(2)O (III) complexes with a singly deprotonated ligand Hdapsox(-) of the acyl hydrazone class (with H(2)dapsox = 2',2'''-(2,6-pyridindiyldiethylidene)dioxamohydrazide) have been obtained and characterized for the first time by a template synthesis. The previously assumed [1] square-pyramidal structure of the Cu(II) complex with an asymmetrical coordination of Hdapsox(-) has been confirmed by a single-crystal X-ray analysis. In II Hdapsox(-) is octahedrally coordinated around a Ni(II) ion, while III is found to be a pentagonal-bipyramidal complex with a symmetrically bonded Hdapsox(-). Causes of a ligand deprotonation occurring in a very acid medium (pH = 0) and of a different coordination pattern in the case of Cu(II), NI(II) and Fe(III) are interpreted by a d(n) configuration and an effective nuclear charge of the central metal ion (crystal field effects). (C) 1998 Elsevier Science Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Cu(II), Ni(II) and Fe(III) complexes with 2 ',2 '''-(2,6-pyridindiyldiethylidene)-dioxamohydrazide in a monoanionic form. The crystal structure of aqua-2 ',2 '''-(2,6-pyridindiyldiethylidene)-dioxamohydrazidecopper(II) perchlorate",
volume = "18",
number = "1-2",
pages = "119-127",
doi = "10.1016/S0277-5387(98)00274-5"
}

Ivanović-Burmazović, I., Bacchi, A., Pelizzi, G., Leovac, V. M.,& Anđelković, K. K.. (1998). Cu(II), Ni(II) and Fe(III) complexes with 2 ',2 '''-(2,6-pyridindiyldiethylidene)-dioxamohydrazide in a monoanionic form. The crystal structure of aqua-2 ',2 '''-(2,6-pyridindiyldiethylidene)-dioxamohydrazidecopper(II) perchlorate. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 18(1-2), 119-127.
https://doi.org/10.1016/S0277-5387(98)00274-5

Ivanović-Burmazović I, Bacchi A, Pelizzi G, Leovac VM, Anđelković KK. Cu(II), Ni(II) and Fe(III) complexes with 2 ',2 '''-(2,6-pyridindiyldiethylidene)-dioxamohydrazide in a monoanionic form. The crystal structure of aqua-2 ',2 '''-(2,6-pyridindiyldiethylidene)-dioxamohydrazidecopper(II) perchlorate. in Polyhedron. 1998;18(1-2):119-127.
doi:10.1016/S0277-5387(98)00274-5 .

Ivanović-Burmazović, Ivana, Bacchi, Alessia, Pelizzi, G, Leovac, Vukadin M., Anđelković, Katarina K., "Cu(II), Ni(II) and Fe(III) complexes with 2 ',2 '''-(2,6-pyridindiyldiethylidene)-dioxamohydrazide in a monoanionic form. The crystal structure of aqua-2 ',2 '''-(2,6-pyridindiyldiethylidene)-dioxamohydrazidecopper(II) perchlorate" in Polyhedron, 18, no. 1-2 (1998):119-127,
https://doi.org/10.1016/S0277-5387(98)00274-5 . .