Rašović, Aleksandar

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orcid::0000-0003-1740-9569
  • Rašović, Aleksandar (5)
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Author's Bibliography

Supplementary data for the article: Rašović, A.; Blagojević, V.; Baranac-Stojanović, M.; Kleinpeter, E.; Marković, R.; Minić, D. M. Quantification of the Push-Pull Effect in 2-Alkylidene-4-Oxothiazolidines by Using NMR Spectral Data and Barriers to Rotation around the CC Bond. New Journal of Chemistry 2016, 40 (7), 6364–6373. https://doi.org/10.1039/c6nj00901h

Rašović, Aleksandar; Blagojević, Vladimir A.; Baranac-Stojanović, Marija; Kleinpeter, Erich; Marković, Rade; Minić, Dragica M.

(Royal Soc Chemistry, Cambridge, 2016)

TY  - DATA
AU  - Rašović, Aleksandar
AU  - Blagojević, Vladimir A.
AU  - Baranac-Stojanović, Marija
AU  - Kleinpeter, Erich
AU  - Marković, Rade
AU  - Minić, Dragica M.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3602
PB  - Royal Soc Chemistry, Cambridge
T2  - New Journal of Chemistry
T1  - Supplementary data for the article: Rašović, A.; Blagojević, V.; Baranac-Stojanović, M.; Kleinpeter, E.; Marković, R.; Minić, D. M. Quantification of the Push-Pull Effect in 2-Alkylidene-4-Oxothiazolidines by Using NMR Spectral Data and Barriers to Rotation around the CC Bond. New Journal of Chemistry 2016, 40 (7), 6364–6373. https://doi.org/10.1039/c6nj00901h
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3602
ER  - 
@misc{
author = "Rašović, Aleksandar and Blagojević, Vladimir A. and Baranac-Stojanović, Marija and Kleinpeter, Erich and Marković, Rade and Minić, Dragica M.",
year = "2016",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "New Journal of Chemistry",
title = "Supplementary data for the article: Rašović, A.; Blagojević, V.; Baranac-Stojanović, M.; Kleinpeter, E.; Marković, R.; Minić, D. M. Quantification of the Push-Pull Effect in 2-Alkylidene-4-Oxothiazolidines by Using NMR Spectral Data and Barriers to Rotation around the CC Bond. New Journal of Chemistry 2016, 40 (7), 6364–6373. https://doi.org/10.1039/c6nj00901h",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3602"
}
Rašović, A., Blagojević, V. A., Baranac-Stojanović, M., Kleinpeter, E., Marković, R.,& Minić, D. M.. (2016). Supplementary data for the article: Rašović, A.; Blagojević, V.; Baranac-Stojanović, M.; Kleinpeter, E.; Marković, R.; Minić, D. M. Quantification of the Push-Pull Effect in 2-Alkylidene-4-Oxothiazolidines by Using NMR Spectral Data and Barriers to Rotation around the CC Bond. New Journal of Chemistry 2016, 40 (7), 6364–6373. https://doi.org/10.1039/c6nj00901h. in New Journal of Chemistry
Royal Soc Chemistry, Cambridge..
https://hdl.handle.net/21.15107/rcub_cherry_3602
Rašović A, Blagojević VA, Baranac-Stojanović M, Kleinpeter E, Marković R, Minić DM. Supplementary data for the article: Rašović, A.; Blagojević, V.; Baranac-Stojanović, M.; Kleinpeter, E.; Marković, R.; Minić, D. M. Quantification of the Push-Pull Effect in 2-Alkylidene-4-Oxothiazolidines by Using NMR Spectral Data and Barriers to Rotation around the CC Bond. New Journal of Chemistry 2016, 40 (7), 6364–6373. https://doi.org/10.1039/c6nj00901h. in New Journal of Chemistry. 2016;.
https://hdl.handle.net/21.15107/rcub_cherry_3602 .
Rašović, Aleksandar, Blagojević, Vladimir A., Baranac-Stojanović, Marija, Kleinpeter, Erich, Marković, Rade, Minić, Dragica M., "Supplementary data for the article: Rašović, A.; Blagojević, V.; Baranac-Stojanović, M.; Kleinpeter, E.; Marković, R.; Minić, D. M. Quantification of the Push-Pull Effect in 2-Alkylidene-4-Oxothiazolidines by Using NMR Spectral Data and Barriers to Rotation around the CC Bond. New Journal of Chemistry 2016, 40 (7), 6364–6373. https://doi.org/10.1039/c6nj00901h" in New Journal of Chemistry (2016),
https://hdl.handle.net/21.15107/rcub_cherry_3602 .

Quantification of the push-pull effect in 2-alkylidene-4-oxothiazolidines by using NMR spectral data and barriers to rotation around the C=C bond

Rašović, Aleksandar; Blagojević, Vladimir A.; Baranac-Stojanović, Marija; Kleinpeter, Erich; Marković, Rade; Minić, Dragica M.

(Royal Soc Chemistry, Cambridge, 2016)

TY  - JOUR
AU  - Rašović, Aleksandar
AU  - Blagojević, Vladimir A.
AU  - Baranac-Stojanović, Marija
AU  - Kleinpeter, Erich
AU  - Marković, Rade
AU  - Minić, Dragica M.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2336
AB  - Information about the strength of donor-acceptor interactions in push-pull alkenes is valuable, as this so-called "push-pull effect'' influences their chemical reactivity and dynamic behaviour. In this paper, we discuss the applicability of NMR spectral data and barriers to rotation around the CQC double bond to quantify the push-pull effect in biologically important 2-alkylidene-4-oxothiazolidines. While olefinic proton chemical shifts and differences in C-13 NMR chemical shifts of the two carbons constituting the CQC double bond fail to give the correct trend in the electron withdrawing ability of the substituents attached to the exocyclic carbon of the double bond, barriers to rotation prove to be a reliable quantity in providing information about the extent of donor-acceptor interactions in the push-pull systems studied. In particular all relevant kinetic data, that is the Arrhenius parameters ( apparent activation energy Ea and frequency factor A) and activation parameters ( Delta S-double dagger, Delta H-double dagger and Delta G(double dagger)), were determined from the data of the experimentally studied configurational isomerization of ( E)-9a. These results were compared to previously published related data for other two compounds, ( Z)-1b and ( 2E, 5Z)-7, showing that experimentally determined Delta G(double dagger) values are a good indicator of the strength of push-pull character. Theoretical calculations of the rotational barriers of eight selected derivatives excellently correlate with the calculated CQC bond lengths and corroborate the applicability of Delta G(double dagger) for estimation of the strength of the push-pull effect in these and related systems.
PB  - Royal Soc Chemistry, Cambridge
T2  - New Journal of Chemistry
T1  - Quantification of the push-pull effect in 2-alkylidene-4-oxothiazolidines by using NMR spectral data and barriers to rotation around the C=C bond
VL  - 40
IS  - 7
SP  - 6364
EP  - 6373
DO  - 10.1039/c6nj00901h
ER  - 
@article{
author = "Rašović, Aleksandar and Blagojević, Vladimir A. and Baranac-Stojanović, Marija and Kleinpeter, Erich and Marković, Rade and Minić, Dragica M.",
year = "2016",
abstract = "Information about the strength of donor-acceptor interactions in push-pull alkenes is valuable, as this so-called "push-pull effect'' influences their chemical reactivity and dynamic behaviour. In this paper, we discuss the applicability of NMR spectral data and barriers to rotation around the CQC double bond to quantify the push-pull effect in biologically important 2-alkylidene-4-oxothiazolidines. While olefinic proton chemical shifts and differences in C-13 NMR chemical shifts of the two carbons constituting the CQC double bond fail to give the correct trend in the electron withdrawing ability of the substituents attached to the exocyclic carbon of the double bond, barriers to rotation prove to be a reliable quantity in providing information about the extent of donor-acceptor interactions in the push-pull systems studied. In particular all relevant kinetic data, that is the Arrhenius parameters ( apparent activation energy Ea and frequency factor A) and activation parameters ( Delta S-double dagger, Delta H-double dagger and Delta G(double dagger)), were determined from the data of the experimentally studied configurational isomerization of ( E)-9a. These results were compared to previously published related data for other two compounds, ( Z)-1b and ( 2E, 5Z)-7, showing that experimentally determined Delta G(double dagger) values are a good indicator of the strength of push-pull character. Theoretical calculations of the rotational barriers of eight selected derivatives excellently correlate with the calculated CQC bond lengths and corroborate the applicability of Delta G(double dagger) for estimation of the strength of the push-pull effect in these and related systems.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "New Journal of Chemistry",
title = "Quantification of the push-pull effect in 2-alkylidene-4-oxothiazolidines by using NMR spectral data and barriers to rotation around the C=C bond",
volume = "40",
number = "7",
pages = "6364-6373",
doi = "10.1039/c6nj00901h"
}
Rašović, A., Blagojević, V. A., Baranac-Stojanović, M., Kleinpeter, E., Marković, R.,& Minić, D. M.. (2016). Quantification of the push-pull effect in 2-alkylidene-4-oxothiazolidines by using NMR spectral data and barriers to rotation around the C=C bond. in New Journal of Chemistry
Royal Soc Chemistry, Cambridge., 40(7), 6364-6373.
https://doi.org/10.1039/c6nj00901h
Rašović A, Blagojević VA, Baranac-Stojanović M, Kleinpeter E, Marković R, Minić DM. Quantification of the push-pull effect in 2-alkylidene-4-oxothiazolidines by using NMR spectral data and barriers to rotation around the C=C bond. in New Journal of Chemistry. 2016;40(7):6364-6373.
doi:10.1039/c6nj00901h .
Rašović, Aleksandar, Blagojević, Vladimir A., Baranac-Stojanović, Marija, Kleinpeter, Erich, Marković, Rade, Minić, Dragica M., "Quantification of the push-pull effect in 2-alkylidene-4-oxothiazolidines by using NMR spectral data and barriers to rotation around the C=C bond" in New Journal of Chemistry, 40, no. 7 (2016):6364-6373,
https://doi.org/10.1039/c6nj00901h . .
6
4
8
7

Thionation of N-methyl- and N-unsubstituted thiazolidine enaminones

Marković, R.; Rašović, Aleksandar; Baranac-Stojanović, Marija; Stojanović, Milovan; Steel, PJ; Jovetic, S

(Serbian Chemical Soc, Belgrade, 2004)

TY  - JOUR
AU  - Marković, R.
AU  - Rašović, Aleksandar
AU  - Baranac-Stojanović, Marija
AU  - Stojanović, Milovan
AU  - Steel, PJ
AU  - Jovetic, S
PY  - 2004
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/679
AB  - The potential of directional non-bonded 1,5-type (SO)-O-... interactions to initiate the incipient stage of an in situ rearrangement of N-unsubstituted thiazolidine enaminones to functionalized 1,2-dithioles has been demonstrated. The spectral characteristics, as well as X-ray structural analysis of a selected rearranged product, indicate that a dynamic interconversion occurs in solution between the 1,2-dithiole and the 3,3alambda(4),4-trithia-1-azapentalene bicylic form. The lack of the rearrangement in the case of a N-methyl Substituted enaminone precursor is attributed to an unfavorable methyl migration in the last reaction step.
AB  - Pokazan je potencijal usmerenih nevezivnih interakcija 1,5-tipa S···O da iniciraju početnu fazu in situ premeštanja N-nesupstituisanih tiazolidinonskih enaminona u funkcionalizovane 1,2-ditiole. Spektralne karakteristike, kao i kristalografska strukturna analiza izabranog premeštenog proizvoda, ukazuju na brzu interkonverziju između 1,2-ditiola i 3, 3aλ4,4-tritija-1-azapentalenskog bicikličnog oblika. Odsustvo premeštanja u slučaju N-metil-supstituisanog enaminomskog prekursora pripisano je nefavorizovanom premeštanju metil-grupe u završnoj fazi reakcije.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Thionation of N-methyl- and N-unsubstituted thiazolidine enaminones
T1  - Tionovanje n-metil- i n-nesupstituisanih tiazolidinonskih enaminona
VL  - 69
IS  - 11
SP  - 909
EP  - 918
DO  - 10.2298/JSC0411909M
ER  - 
@article{
author = "Marković, R. and Rašović, Aleksandar and Baranac-Stojanović, Marija and Stojanović, Milovan and Steel, PJ and Jovetic, S",
year = "2004",
abstract = "The potential of directional non-bonded 1,5-type (SO)-O-... interactions to initiate the incipient stage of an in situ rearrangement of N-unsubstituted thiazolidine enaminones to functionalized 1,2-dithioles has been demonstrated. The spectral characteristics, as well as X-ray structural analysis of a selected rearranged product, indicate that a dynamic interconversion occurs in solution between the 1,2-dithiole and the 3,3alambda(4),4-trithia-1-azapentalene bicylic form. The lack of the rearrangement in the case of a N-methyl Substituted enaminone precursor is attributed to an unfavorable methyl migration in the last reaction step., Pokazan je potencijal usmerenih nevezivnih interakcija 1,5-tipa S···O da iniciraju početnu fazu in situ premeštanja N-nesupstituisanih tiazolidinonskih enaminona u funkcionalizovane 1,2-ditiole. Spektralne karakteristike, kao i kristalografska strukturna analiza izabranog premeštenog proizvoda, ukazuju na brzu interkonverziju između 1,2-ditiola i 3, 3aλ4,4-tritija-1-azapentalenskog bicikličnog oblika. Odsustvo premeštanja u slučaju N-metil-supstituisanog enaminomskog prekursora pripisano je nefavorizovanom premeštanju metil-grupe u završnoj fazi reakcije.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Thionation of N-methyl- and N-unsubstituted thiazolidine enaminones, Tionovanje n-metil- i n-nesupstituisanih tiazolidinonskih enaminona",
volume = "69",
number = "11",
pages = "909-918",
doi = "10.2298/JSC0411909M"
}
Marković, R., Rašović, A., Baranac-Stojanović, M., Stojanović, M., Steel, P.,& Jovetic, S.. (2004). Thionation of N-methyl- and N-unsubstituted thiazolidine enaminones. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 69(11), 909-918.
https://doi.org/10.2298/JSC0411909M
Marković R, Rašović A, Baranac-Stojanović M, Stojanović M, Steel P, Jovetic S. Thionation of N-methyl- and N-unsubstituted thiazolidine enaminones. in Journal of the Serbian Chemical Society. 2004;69(11):909-918.
doi:10.2298/JSC0411909M .
Marković, R., Rašović, Aleksandar, Baranac-Stojanović, Marija, Stojanović, Milovan, Steel, PJ, Jovetic, S, "Thionation of N-methyl- and N-unsubstituted thiazolidine enaminones" in Journal of the Serbian Chemical Society, 69, no. 11 (2004):909-918,
https://doi.org/10.2298/JSC0411909M . .
11
9
10
11

Chemical composition of the brown alga Padina pavonia (L.) Gaill. from the adriatic sea

Kamenarska, Z; Gasic, MJ; Zlatović, Mario; Rašović, Aleksandar; Sladić, Dušan; Kljajic, Z; Stefanov, K; Seizova, K; Najdenski, H; Kujumgiev, A; Tsvetkova, I; Popov, S

(Walter De Gruyter & Co, Berlin, 2002)

TY  - JOUR
AU  - Kamenarska, Z
AU  - Gasic, MJ
AU  - Zlatović, Mario
AU  - Rašović, Aleksandar
AU  - Sladić, Dušan
AU  - Kljajic, Z
AU  - Stefanov, K
AU  - Seizova, K
AU  - Najdenski, H
AU  - Kujumgiev, A
AU  - Tsvetkova, I
AU  - Popov, S
PY  - 2002
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/498
AB  - The chemical composition of the brown alga Padina pavonia (L.) Gaill. from the southern Adriatic Sea was investigated. Twelve sterols were identified in the sterol fraction, the main ones being cholesterol and fucosterol. The main fatty acids in the lipids were also identified.The most abundant fatty acid was palmitic acid, followed by oleic and myristic acids.The concentration of polyunsaturated fatty acids was unusually low for a marine alga. By GC/MS analysis of the volatile and polar fractions, 40 compounds were identified. Some of them probably possess defensive functions. In the volatile fraction free fatty acids, aromatic esters, benzyl alcohol and benzaldehyde predominated. Low concentrations of terpenoids, phenols and sulfur containing compounds were also identified.The nbutanol extract contained mainly fatty acids and polyols. Some of the extracts had an antibacterial activity.
PB  - Walter De Gruyter & Co, Berlin
T2  - Botanica Marina
T1  - Chemical composition of the brown alga Padina pavonia (L.) Gaill. from the adriatic sea
VL  - 45
IS  - 4
SP  - 339
EP  - 345
DO  - 10.1515/BOT.2002.034
ER  - 
@article{
author = "Kamenarska, Z and Gasic, MJ and Zlatović, Mario and Rašović, Aleksandar and Sladić, Dušan and Kljajic, Z and Stefanov, K and Seizova, K and Najdenski, H and Kujumgiev, A and Tsvetkova, I and Popov, S",
year = "2002",
abstract = "The chemical composition of the brown alga Padina pavonia (L.) Gaill. from the southern Adriatic Sea was investigated. Twelve sterols were identified in the sterol fraction, the main ones being cholesterol and fucosterol. The main fatty acids in the lipids were also identified.The most abundant fatty acid was palmitic acid, followed by oleic and myristic acids.The concentration of polyunsaturated fatty acids was unusually low for a marine alga. By GC/MS analysis of the volatile and polar fractions, 40 compounds were identified. Some of them probably possess defensive functions. In the volatile fraction free fatty acids, aromatic esters, benzyl alcohol and benzaldehyde predominated. Low concentrations of terpenoids, phenols and sulfur containing compounds were also identified.The nbutanol extract contained mainly fatty acids and polyols. Some of the extracts had an antibacterial activity.",
publisher = "Walter De Gruyter & Co, Berlin",
journal = "Botanica Marina",
title = "Chemical composition of the brown alga Padina pavonia (L.) Gaill. from the adriatic sea",
volume = "45",
number = "4",
pages = "339-345",
doi = "10.1515/BOT.2002.034"
}
Kamenarska, Z., Gasic, M., Zlatović, M., Rašović, A., Sladić, D., Kljajic, Z., Stefanov, K., Seizova, K., Najdenski, H., Kujumgiev, A., Tsvetkova, I.,& Popov, S.. (2002). Chemical composition of the brown alga Padina pavonia (L.) Gaill. from the adriatic sea. in Botanica Marina
Walter De Gruyter & Co, Berlin., 45(4), 339-345.
https://doi.org/10.1515/BOT.2002.034
Kamenarska Z, Gasic M, Zlatović M, Rašović A, Sladić D, Kljajic Z, Stefanov K, Seizova K, Najdenski H, Kujumgiev A, Tsvetkova I, Popov S. Chemical composition of the brown alga Padina pavonia (L.) Gaill. from the adriatic sea. in Botanica Marina. 2002;45(4):339-345.
doi:10.1515/BOT.2002.034 .
Kamenarska, Z, Gasic, MJ, Zlatović, Mario, Rašović, Aleksandar, Sladić, Dušan, Kljajic, Z, Stefanov, K, Seizova, K, Najdenski, H, Kujumgiev, A, Tsvetkova, I, Popov, S, "Chemical composition of the brown alga Padina pavonia (L.) Gaill. from the adriatic sea" in Botanica Marina, 45, no. 4 (2002):339-345,
https://doi.org/10.1515/BOT.2002.034 . .
47
31
48
41

Application of biological markers for the identification of oil-type pollutants in recent sediments: Alluvial formation of the Danube river, Oil refinery Pančevo

Rašović, Aleksandar; Jovančićević, Branimir; Sladić, Dušan; Kljajić, Zoran V.; Scheeder, Georg; Wehner, Hermann

(2002)

TY  - JOUR
AU  - Rašović, Aleksandar
AU  - Jovančićević, Branimir
AU  - Sladić, Dušan
AU  - Kljajić, Zoran V.
AU  - Scheeder, Georg
AU  - Wehner, Hermann
PY  - 2002
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/84
AB  - The purpose of this paper was to examine to which extent the abundance and distribution of certain biological markers may be used for the identification of oil-type pollutants in recent sediments and ground waters. The samples were taken from the area of the Oil Refinery Pančevo (alluvial formation of the Danube River). The organic matter of the investigated samples was isolated using an extraction method with chloroform. The group composition and usual biological markers were analyzed in the obtained extracts. n-Alkanes and acyclic isoprenoids, pristane and phytane were analyzed using gas chromatographie (GC) analysis of saturated hydrocarbons. Polycyclic alkanes of the sterane and terpane type were analyzed using gas chromatography-mass spectrometry (GC-MS), i.e. by analyzing the carbamide non-adduct of the total alkane fraction (Single Ion Monitoring SIM-technique). The obtained results indicate that n-alkanes can be used for the identification of oil-type pollutants (for example, if the oil-pollutant is biodegraded or present in very low concentrations), and steranes and triterpanes can be used as very reliable indicators of oil-type pollution in recent sediments and ground waters.
AB  - Cilj ovog rada bio je da se utvrdi u kolikoj mjeri se obilnosti i raspodjele pojedinih bioloških markera mogu upotrijebiti za identifikaciju zagađivača naftnog tipa u recentnim sedimentima i podzemnim vodama. Ispitivani su uzorci sa lokaliteta Rafinerije nafte Pančevo (aluvijalna formacija rijeke Dunav). Organska supstanca ispitivanih uzoraka izolovana je ekstrakcijom pomoću hloroforma. U dobivenim ekstraktima određen je grupni sastav i analizirani su najpoznatiji biološki markeri. n-Alkani i aciklični izoprenoidni alkani, pristan i fitan, analizirani su gasnohromatografskom (GC) analizom frakcije zasićenih ugljovodonika, a policiklični alkani tipa sterana i triterpana primjenom gasnohromato-grafsko-masenospekrometrijske (GC-MS) analize karbamidnog neadukta ukupnih alkana (Single Ion Monitoring SIM, tehnika), Dobiveni rezultati pokazali su da u slučajevima kada se n-alkani ne mogu upotrijebiti u identifikaciji zagađivača naftnog tipa (na primjer, ukoliko je naftni zagađivač biodegradovan i/ili prisutan u veoma niskim koncentracijama), sterani i triterpani mogu poslužiti kao veoma pouzdani indikatori prisustva ovog zagađivača u recentnim sedimentima i podzemnim vodama.
T2  - Hemijska industrija
T1  - Application of biological markers for the identification of oil-type pollutants in recent sediments: Alluvial formation of the Danube river, Oil refinery Pančevo
T1  - Primjena bioloških markera u identifikaciji zagađivača naftnog tipa u recentnim sedimentima - aluvijalna formacija rijeke Dunav, Rafinerija nafte Pančevo
VL  - 56
IS  - 1
SP  - 17
EP  - 24
DO  - 10.2298/HEMIND0201017R
ER  - 
@article{
author = "Rašović, Aleksandar and Jovančićević, Branimir and Sladić, Dušan and Kljajić, Zoran V. and Scheeder, Georg and Wehner, Hermann",
year = "2002",
abstract = "The purpose of this paper was to examine to which extent the abundance and distribution of certain biological markers may be used for the identification of oil-type pollutants in recent sediments and ground waters. The samples were taken from the area of the Oil Refinery Pančevo (alluvial formation of the Danube River). The organic matter of the investigated samples was isolated using an extraction method with chloroform. The group composition and usual biological markers were analyzed in the obtained extracts. n-Alkanes and acyclic isoprenoids, pristane and phytane were analyzed using gas chromatographie (GC) analysis of saturated hydrocarbons. Polycyclic alkanes of the sterane and terpane type were analyzed using gas chromatography-mass spectrometry (GC-MS), i.e. by analyzing the carbamide non-adduct of the total alkane fraction (Single Ion Monitoring SIM-technique). The obtained results indicate that n-alkanes can be used for the identification of oil-type pollutants (for example, if the oil-pollutant is biodegraded or present in very low concentrations), and steranes and triterpanes can be used as very reliable indicators of oil-type pollution in recent sediments and ground waters., Cilj ovog rada bio je da se utvrdi u kolikoj mjeri se obilnosti i raspodjele pojedinih bioloških markera mogu upotrijebiti za identifikaciju zagađivača naftnog tipa u recentnim sedimentima i podzemnim vodama. Ispitivani su uzorci sa lokaliteta Rafinerije nafte Pančevo (aluvijalna formacija rijeke Dunav). Organska supstanca ispitivanih uzoraka izolovana je ekstrakcijom pomoću hloroforma. U dobivenim ekstraktima određen je grupni sastav i analizirani su najpoznatiji biološki markeri. n-Alkani i aciklični izoprenoidni alkani, pristan i fitan, analizirani su gasnohromatografskom (GC) analizom frakcije zasićenih ugljovodonika, a policiklični alkani tipa sterana i triterpana primjenom gasnohromato-grafsko-masenospekrometrijske (GC-MS) analize karbamidnog neadukta ukupnih alkana (Single Ion Monitoring SIM, tehnika), Dobiveni rezultati pokazali su da u slučajevima kada se n-alkani ne mogu upotrijebiti u identifikaciji zagađivača naftnog tipa (na primjer, ukoliko je naftni zagađivač biodegradovan i/ili prisutan u veoma niskim koncentracijama), sterani i triterpani mogu poslužiti kao veoma pouzdani indikatori prisustva ovog zagađivača u recentnim sedimentima i podzemnim vodama.",
journal = "Hemijska industrija",
title = "Application of biological markers for the identification of oil-type pollutants in recent sediments: Alluvial formation of the Danube river, Oil refinery Pančevo, Primjena bioloških markera u identifikaciji zagađivača naftnog tipa u recentnim sedimentima - aluvijalna formacija rijeke Dunav, Rafinerija nafte Pančevo",
volume = "56",
number = "1",
pages = "17-24",
doi = "10.2298/HEMIND0201017R"
}
Rašović, A., Jovančićević, B., Sladić, D., Kljajić, Z. V., Scheeder, G.,& Wehner, H.. (2002). Application of biological markers for the identification of oil-type pollutants in recent sediments: Alluvial formation of the Danube river, Oil refinery Pančevo. in Hemijska industrija, 56(1), 17-24.
https://doi.org/10.2298/HEMIND0201017R
Rašović A, Jovančićević B, Sladić D, Kljajić ZV, Scheeder G, Wehner H. Application of biological markers for the identification of oil-type pollutants in recent sediments: Alluvial formation of the Danube river, Oil refinery Pančevo. in Hemijska industrija. 2002;56(1):17-24.
doi:10.2298/HEMIND0201017R .
Rašović, Aleksandar, Jovančićević, Branimir, Sladić, Dušan, Kljajić, Zoran V., Scheeder, Georg, Wehner, Hermann, "Application of biological markers for the identification of oil-type pollutants in recent sediments: Alluvial formation of the Danube river, Oil refinery Pančevo" in Hemijska industrija, 56, no. 1 (2002):17-24,
https://doi.org/10.2298/HEMIND0201017R . .