Nikolovski, Zlatko

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  • Nikolovski, Zlatko (4)
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Author's Bibliography

Some examples of interactions between certain rare earth elements and soil

Nikolovski, Zlatko; Isailović, Jelena; Jeremić, Dejan; Kovač, Sabina; Brčeski, Ilija

(Belgrade : Serbian Chemical Society, 2022)

TY  - JOUR
AU  - Nikolovski, Zlatko
AU  - Isailović, Jelena
AU  - Jeremić, Dejan
AU  - Kovač, Sabina
AU  - Brčeski, Ilija
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5034
AB  - The rare earth elements represent an increasingly more and more
important industrial resource. The increased use may result in waste generation, and their impact upon the environment quality has not been studied
sufficiently. Their interaction with soil has been studied in this paper. The
Freundlich adsorption isotherm has been determined for lanthanum, erbium
and gadolinium at three different soil types (humus, clay and sand type),
whereas the sequential extraction at these soil types has been applied for lanthanum and neodymium. The interaction of certain rare earth elements with
soil components has been tested as well as the quantity in which these elements
are bound to soil and later on extracted in solutions. The objective was to determine the soil capacity for disposal, first of all, of the electronic waste that contains these elements and to assume their fate in the environment.
PB  - Belgrade : Serbian Chemical Society
T2  - Journal of the Serbian Chemical Society
T1  - Some examples of interactions between certain rare earth elements and soil
VL  - 87
IS  - 1
SP  - 83
EP  - 94
DO  - 10.2298/JSC211006095N
ER  - 
@article{
author = "Nikolovski, Zlatko and Isailović, Jelena and Jeremić, Dejan and Kovač, Sabina and Brčeski, Ilija",
year = "2022",
abstract = "The rare earth elements represent an increasingly more and more
important industrial resource. The increased use may result in waste generation, and their impact upon the environment quality has not been studied
sufficiently. Their interaction with soil has been studied in this paper. The
Freundlich adsorption isotherm has been determined for lanthanum, erbium
and gadolinium at three different soil types (humus, clay and sand type),
whereas the sequential extraction at these soil types has been applied for lanthanum and neodymium. The interaction of certain rare earth elements with
soil components has been tested as well as the quantity in which these elements
are bound to soil and later on extracted in solutions. The objective was to determine the soil capacity for disposal, first of all, of the electronic waste that contains these elements and to assume their fate in the environment.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Journal of the Serbian Chemical Society",
title = "Some examples of interactions between certain rare earth elements and soil",
volume = "87",
number = "1",
pages = "83-94",
doi = "10.2298/JSC211006095N"
}
Nikolovski, Z., Isailović, J., Jeremić, D., Kovač, S.,& Brčeski, I.. (2022). Some examples of interactions between certain rare earth elements and soil. in Journal of the Serbian Chemical Society
Belgrade : Serbian Chemical Society., 87(1), 83-94.
https://doi.org/10.2298/JSC211006095N
Nikolovski Z, Isailović J, Jeremić D, Kovač S, Brčeski I. Some examples of interactions between certain rare earth elements and soil. in Journal of the Serbian Chemical Society. 2022;87(1):83-94.
doi:10.2298/JSC211006095N .
Nikolovski, Zlatko, Isailović, Jelena, Jeremić, Dejan, Kovač, Sabina, Brčeski, Ilija, "Some examples of interactions between certain rare earth elements and soil" in Journal of the Serbian Chemical Society, 87, no. 1 (2022):83-94,
https://doi.org/10.2298/JSC211006095N . .

Influence of Electrolyte Impurities from E-Waste Electrorefining on Copper Extraction Recovery

Đokić, Jovana; Radovanović, Dragana; Nikolovski, Zlatko; Anđić, Zoran; Kamberović, Željko

(2021)

TY  - JOUR
AU  - Đokić, Jovana
AU  - Radovanović, Dragana
AU  - Nikolovski, Zlatko
AU  - Anđić, Zoran
AU  - Kamberović, Željko
PY  - 2021
UR  - https://www.mdpi.com/2075-4701/11/9/1383
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4666
AB  - In order to reflect possible issues in future sole e-waste processing, an electrolyte of complex chemical composition reflecting system of sole e-waste processing was obtained by following a specially designed pyro-electrometallurgical method. The obtained non-standard electrolyte was further used for the purpose of comprehensive metal interference evaluation on the copper solvent extraction (SX) process. Optimization of the process included a variation of several process parameters, allowing determination of the effect of the most abundant and potentially the most influential impurities (Ni, Sn, Fe, and Zn) and 14 other trace elements. Moreover, comparing three commercial extractants of different active chelating groups, it was determined that branched aldoxime reagent is favorable for Cu extraction from the chemically complex system, as can be expected in future e-waste recycling. The results of this study showed that, under optimal conditions of 20 vol.% extractant concentration, feed pH 1.5, O/A ratio 3, and 10-min phase contact time, 88.1% of one stage Cu extraction was achieved. Co-extraction of the Fe, Zn, Ni, and Sn was under 8%, while Pb and trace elements were negligible. Optimal conditions (H2SO4 180 g/L, O/A = 2, and contact time 5 min) enabled 95.3% Cu stripping and under 6% of the most influential impurities. In addition, an impurity monitoring and distribution methodology enabled a better understanding and design of the process for the more efficient valorization of metals from e-waste.
T2  - Metals
T1  - Influence of Electrolyte Impurities from E-Waste Electrorefining on Copper Extraction Recovery
VL  - 11
IS  - 9
SP  - 1383
DO  - 10.3390/met11091383
ER  - 
@article{
author = "Đokić, Jovana and Radovanović, Dragana and Nikolovski, Zlatko and Anđić, Zoran and Kamberović, Željko",
year = "2021",
abstract = "In order to reflect possible issues in future sole e-waste processing, an electrolyte of complex chemical composition reflecting system of sole e-waste processing was obtained by following a specially designed pyro-electrometallurgical method. The obtained non-standard electrolyte was further used for the purpose of comprehensive metal interference evaluation on the copper solvent extraction (SX) process. Optimization of the process included a variation of several process parameters, allowing determination of the effect of the most abundant and potentially the most influential impurities (Ni, Sn, Fe, and Zn) and 14 other trace elements. Moreover, comparing three commercial extractants of different active chelating groups, it was determined that branched aldoxime reagent is favorable for Cu extraction from the chemically complex system, as can be expected in future e-waste recycling. The results of this study showed that, under optimal conditions of 20 vol.% extractant concentration, feed pH 1.5, O/A ratio 3, and 10-min phase contact time, 88.1% of one stage Cu extraction was achieved. Co-extraction of the Fe, Zn, Ni, and Sn was under 8%, while Pb and trace elements were negligible. Optimal conditions (H2SO4 180 g/L, O/A = 2, and contact time 5 min) enabled 95.3% Cu stripping and under 6% of the most influential impurities. In addition, an impurity monitoring and distribution methodology enabled a better understanding and design of the process for the more efficient valorization of metals from e-waste.",
journal = "Metals",
title = "Influence of Electrolyte Impurities from E-Waste Electrorefining on Copper Extraction Recovery",
volume = "11",
number = "9",
pages = "1383",
doi = "10.3390/met11091383"
}
Đokić, J., Radovanović, D., Nikolovski, Z., Anđić, Z.,& Kamberović, Ž.. (2021). Influence of Electrolyte Impurities from E-Waste Electrorefining on Copper Extraction Recovery. in Metals, 11(9), 1383.
https://doi.org/10.3390/met11091383
Đokić J, Radovanović D, Nikolovski Z, Anđić Z, Kamberović Ž. Influence of Electrolyte Impurities from E-Waste Electrorefining on Copper Extraction Recovery. in Metals. 2021;11(9):1383.
doi:10.3390/met11091383 .
Đokić, Jovana, Radovanović, Dragana, Nikolovski, Zlatko, Anđić, Zoran, Kamberović, Željko, "Influence of Electrolyte Impurities from E-Waste Electrorefining on Copper Extraction Recovery" in Metals, 11, no. 9 (2021):1383,
https://doi.org/10.3390/met11091383 . .
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Sekvencijalna ekstrakcija lantana i neodimijuma iz zemljišta

Nikolovski, Zlatko

(2021)

TY  - THES
AU  - Nikolovski, Zlatko
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4352
AB  - Cilj ovog rada jeste primena metode sekvencijalne ekstrakcije i ICP-OES analize metalnih jona radi određivanja koncentracije ekstrahovanih metalnih jona, interakcija sa ekstrakcionim rastvorima i razmatranja pogodnosti nametnutih uslova za ekstrakciju ovih elemenata iz zemljišta. Kasnije se ovim omogućava predviđanje njihovog ponašanja u životnoj sredini. Odabir ovih elemenata je bio takav da imamo jednog tipičnog predstavnika lantanoida, lantana (La), i element koji se pojavljuje u magnetima visokih performansi i optičkim sočivima, neodimijum (Nd).
T1  - Sekvencijalna ekstrakcija lantana i neodimijuma iz zemljišta
SP  - 1
EP  - 36
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4352
ER  - 
@mastersthesis{
author = "Nikolovski, Zlatko",
year = "2021",
abstract = "Cilj ovog rada jeste primena metode sekvencijalne ekstrakcije i ICP-OES analize metalnih jona radi određivanja koncentracije ekstrahovanih metalnih jona, interakcija sa ekstrakcionim rastvorima i razmatranja pogodnosti nametnutih uslova za ekstrakciju ovih elemenata iz zemljišta. Kasnije se ovim omogućava predviđanje njihovog ponašanja u životnoj sredini. Odabir ovih elemenata je bio takav da imamo jednog tipičnog predstavnika lantanoida, lantana (La), i element koji se pojavljuje u magnetima visokih performansi i optičkim sočivima, neodimijum (Nd).",
title = "Sekvencijalna ekstrakcija lantana i neodimijuma iz zemljišta",
pages = "1-36",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4352"
}
Nikolovski, Z.. (2021). Sekvencijalna ekstrakcija lantana i neodimijuma iz zemljišta. , 1-36.
https://hdl.handle.net/21.15107/rcub_cherry_4352
Nikolovski Z. Sekvencijalna ekstrakcija lantana i neodimijuma iz zemljišta. 2021;:1-36.
https://hdl.handle.net/21.15107/rcub_cherry_4352 .
Nikolovski, Zlatko, "Sekvencijalna ekstrakcija lantana i neodimijuma iz zemljišta" (2021):1-36,
https://hdl.handle.net/21.15107/rcub_cherry_4352 .

Saturated biomarkers in the estimation of organic geochemical homogeneity of crude oils from four oil fields in Libya

Saheed, Ramadan Musbah M.; Šolević-Knudsen, Tatjana; Faraj, Musbah Abduljalil M.; Nikolovski, Zlatko; Nytoft, Hans Peter; Jovančićević, Branimir

(2020)

TY  - JOUR
AU  - Saheed, Ramadan Musbah M.
AU  - Šolević-Knudsen, Tatjana
AU  - Faraj, Musbah Abduljalil M.
AU  - Nikolovski, Zlatko
AU  - Nytoft, Hans Peter
AU  - Jovančićević, Branimir
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4303
AB  - Seven crude oils from four oil fields in the Sirte and Murzuq Basins in Libya were investigated in order to estimate their organic geochemical homogeneity. Saturated biomarkers (n-alkanes and isoprenoids) were analyzed using gas chromatography–mass spectrometry (GC–MS). The parameters calculated from the distributions of n-alkanes and isoprenoid aliphatic alkanes, pristane and phytane were used to interpret the organic geochemical characteristics of the oils. Based on the high relative concentration of lower n-alkane homologues in the C11–C16 range and high API values, the oils were classified as light oils. These results also implied that the oils were not biodegraded. The parameters calculated from the distributions of saturated biomarkers indicated that all investigated oils were generated from source rocks containing organic matter of a similar marine origin but with a contribution of terrestrial organic matter. The results also demonstrated that these source rocks were deposited in an oxic environment. The same source rock or the same type of source rocks for all seven samples were postulated. It was concluded that, if the crude oils from these distant basins originated from the same source rocks, they must have had different lengths of their migration pathways.
T2  - Journal of the Serbian Chemical Society
T1  - Saturated biomarkers in the estimation of organic geochemical homogeneity of crude oils from four oil fields in Libya
VL  - 85
IS  - 11
SP  - 1489
EP  - 1499
DO  - 10.2298/JSC200501055S
ER  - 
@article{
author = "Saheed, Ramadan Musbah M. and Šolević-Knudsen, Tatjana and Faraj, Musbah Abduljalil M. and Nikolovski, Zlatko and Nytoft, Hans Peter and Jovančićević, Branimir",
year = "2020",
abstract = "Seven crude oils from four oil fields in the Sirte and Murzuq Basins in Libya were investigated in order to estimate their organic geochemical homogeneity. Saturated biomarkers (n-alkanes and isoprenoids) were analyzed using gas chromatography–mass spectrometry (GC–MS). The parameters calculated from the distributions of n-alkanes and isoprenoid aliphatic alkanes, pristane and phytane were used to interpret the organic geochemical characteristics of the oils. Based on the high relative concentration of lower n-alkane homologues in the C11–C16 range and high API values, the oils were classified as light oils. These results also implied that the oils were not biodegraded. The parameters calculated from the distributions of saturated biomarkers indicated that all investigated oils were generated from source rocks containing organic matter of a similar marine origin but with a contribution of terrestrial organic matter. The results also demonstrated that these source rocks were deposited in an oxic environment. The same source rock or the same type of source rocks for all seven samples were postulated. It was concluded that, if the crude oils from these distant basins originated from the same source rocks, they must have had different lengths of their migration pathways.",
journal = "Journal of the Serbian Chemical Society",
title = "Saturated biomarkers in the estimation of organic geochemical homogeneity of crude oils from four oil fields in Libya",
volume = "85",
number = "11",
pages = "1489-1499",
doi = "10.2298/JSC200501055S"
}
Saheed, R. M. M., Šolević-Knudsen, T., Faraj, M. A. M., Nikolovski, Z., Nytoft, H. P.,& Jovančićević, B.. (2020). Saturated biomarkers in the estimation of organic geochemical homogeneity of crude oils from four oil fields in Libya. in Journal of the Serbian Chemical Society, 85(11), 1489-1499.
https://doi.org/10.2298/JSC200501055S
Saheed RMM, Šolević-Knudsen T, Faraj MAM, Nikolovski Z, Nytoft HP, Jovančićević B. Saturated biomarkers in the estimation of organic geochemical homogeneity of crude oils from four oil fields in Libya. in Journal of the Serbian Chemical Society. 2020;85(11):1489-1499.
doi:10.2298/JSC200501055S .
Saheed, Ramadan Musbah M., Šolević-Knudsen, Tatjana, Faraj, Musbah Abduljalil M., Nikolovski, Zlatko, Nytoft, Hans Peter, Jovančićević, Branimir, "Saturated biomarkers in the estimation of organic geochemical homogeneity of crude oils from four oil fields in Libya" in Journal of the Serbian Chemical Society, 85, no. 11 (2020):1489-1499,
https://doi.org/10.2298/JSC200501055S . .
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