TY  - JOUR
AU  - Argay, C
AU  - Kalman, A
AU  - Parkanyi, L
AU  - Leovac, Vukadin M.
AU  - Brčeski, Ilija
AU  - Radivojsa, PN
PY  - 2000
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/436
AB  - The preparation and physical characterization of two copper(I) complexes Cu(HL)NO3 and [Cu(HL)(2)]NO3 . MeOH formed with a newly synthesized tridentate [S,N,P] HL = 2-(diphenylphosphino)benzaldehyde thiosemicarbazone ligand and the crystal structure analysis of the latter have been carried out. An X-ray study of [Cu(HL)(2)]NO3 . MeOH revealed a copper(I) ion coordinated tetrahedrally to S,N,P,P atoms donated by two HL ligands. One is tridentate [S,N,P], whereas the second HL ligand is monodentate, ligating only its phosphorus atom to the copper. The geometry around the four-coordinate Cu(I) is comparable with Cu{N,S,P,X} tetrahedra (X = N, P, or S) retrieved from the Cambridge Structural Database. In addition, with a restriction to Cu{N,P,X,X} (X = C, N, P) tetrahedra - S is excluded - ca. 60 structures against three or four cases were found to be maintained by Cu(I) ions substantiating the principal role of the phosphorus ligands in the reduction of Cu(II) to Cu(I).
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Transition metal complexes with thiosemicarbazide-based ligands. part 37. Synthesis and study of the first thiosemi-carbazide-derived copper(I) complexes: Crystal structure of [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(-l)] copper(I)nitrate-me
VL  - 51
IS  - 1
SP  - 9
EP  - 19
UR  - https://hdl.handle.net/21.15107/rcub_cherry_436
ER  - 

@article{
author = "Argay, C and Kalman, A and Parkanyi, L and Leovac, Vukadin M. and Brčeski, Ilija and Radivojsa, PN",
year = "2000",
abstract = "The preparation and physical characterization of two copper(I) complexes Cu(HL)NO3 and [Cu(HL)(2)]NO3 . MeOH formed with a newly synthesized tridentate [S,N,P] HL = 2-(diphenylphosphino)benzaldehyde thiosemicarbazone ligand and the crystal structure analysis of the latter have been carried out. An X-ray study of [Cu(HL)(2)]NO3 . MeOH revealed a copper(I) ion coordinated tetrahedrally to S,N,P,P atoms donated by two HL ligands. One is tridentate [S,N,P], whereas the second HL ligand is monodentate, ligating only its phosphorus atom to the copper. The geometry around the four-coordinate Cu(I) is comparable with Cu{N,S,P,X} tetrahedra (X = N, P, or S) retrieved from the Cambridge Structural Database. In addition, with a restriction to Cu{N,P,X,X} (X = C, N, P) tetrahedra - S is excluded - ca. 60 structures against three or four cases were found to be maintained by Cu(I) ions substantiating the principal role of the phosphorus ligands in the reduction of Cu(II) to Cu(I).",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Transition metal complexes with thiosemicarbazide-based ligands. part 37. Synthesis and study of the first thiosemi-carbazide-derived copper(I) complexes: Crystal structure of [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(-l)] copper(I)nitrate-me",
volume = "51",
number = "1",
pages = "9-19",
url = "https://hdl.handle.net/21.15107/rcub_cherry_436"
}

Argay, C., Kalman, A., Parkanyi, L., Leovac, V. M., Brčeski, I.,& Radivojsa, P.. (2000). Transition metal complexes with thiosemicarbazide-based ligands. part 37. Synthesis and study of the first thiosemi-carbazide-derived copper(I) complexes: Crystal structure of [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(-l)] copper(I)nitrate-me. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 51(1), 9-19.
https://hdl.handle.net/21.15107/rcub_cherry_436

Argay C, Kalman A, Parkanyi L, Leovac VM, Brčeski I, Radivojsa P. Transition metal complexes with thiosemicarbazide-based ligands. part 37. Synthesis and study of the first thiosemi-carbazide-derived copper(I) complexes: Crystal structure of [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(-l)] copper(I)nitrate-me. in Journal of Coordination Chemistry. 2000;51(1):9-19.
https://hdl.handle.net/21.15107/rcub_cherry_436 .

Argay, C, Kalman, A, Parkanyi, L, Leovac, Vukadin M., Brčeski, Ilija, Radivojsa, PN, "Transition metal complexes with thiosemicarbazide-based ligands. part 37. Synthesis and study of the first thiosemi-carbazide-derived copper(I) complexes: Crystal structure of [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(-l)] copper(I)nitrate-me" in Journal of Coordination Chemistry, 51, no. 1 (2000):9-19,
https://hdl.handle.net/21.15107/rcub_cherry_436 .

TY  - JOUR
AU  - Leovac, Vukadin M.
AU  - Ribar, B
AU  - Argay, G
AU  - Kalman, A
AU  - Brčeski, Ilija
PY  - 1996
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2245
AB  - The synthesis and crystal structure analysis of the diamagnetic complex [Ni(L)Py]NO3 (L = the monoanion of the newly synthesized ligand 2-(diphenylphosphino)benzaldehyde thiosemicarbazone) are reported. The complex crystallizes in the space group P2(1)/n (No. 14) with a = 8.533(1), b = 29.123(3), c = 10.627(a) Angstrom, beta = 110.36(1)degrees, V = 2597.8(5) Angstrom(3). As revealed X-ray analysis, the 2-(diphenylphosphino)benzaldehyde thiosemicarbazone ligand deprotonated at N(3) acts as a monoanionic tridentate donor, coordinating through SNP. The core of the bulky {Ni[(C6H5)(2)P-(C6H4CH=N-N=CS-NH2).]}(+) cation is a slightly puckered quadrangle formed around Ni2+ by SNP accompanied by a pyridine nitrogen. The dihedral angle of the atomic triangles S/N(4)/N(41) and P(2)/N(4)/N(41) is 18.0(4)degrees. The NO3- anions are well separated from the cations which may account for the observed disorder of the oxygen atoms.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Transition metal complexes with thiosemicarbazide-based ligands .28. Synthesis and x-ray crystal structure of the first phosphorus-bonded thiosemicarbazide complex: [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(1-)]pyridinenickel(II)-nitrate
VL  - 39
IS  - 1
SP  - 11
EP  - 19
DO  - 10.1080/00958979608028171
ER  - 

@article{
author = "Leovac, Vukadin M. and Ribar, B and Argay, G and Kalman, A and Brčeski, Ilija",
year = "1996",
abstract = "The synthesis and crystal structure analysis of the diamagnetic complex [Ni(L)Py]NO3 (L = the monoanion of the newly synthesized ligand 2-(diphenylphosphino)benzaldehyde thiosemicarbazone) are reported. The complex crystallizes in the space group P2(1)/n (No. 14) with a = 8.533(1), b = 29.123(3), c = 10.627(a) Angstrom, beta = 110.36(1)degrees, V = 2597.8(5) Angstrom(3). As revealed X-ray analysis, the 2-(diphenylphosphino)benzaldehyde thiosemicarbazone ligand deprotonated at N(3) acts as a monoanionic tridentate donor, coordinating through SNP. The core of the bulky {Ni[(C6H5)(2)P-(C6H4CH=N-N=CS-NH2).]}(+) cation is a slightly puckered quadrangle formed around Ni2+ by SNP accompanied by a pyridine nitrogen. The dihedral angle of the atomic triangles S/N(4)/N(41) and P(2)/N(4)/N(41) is 18.0(4)degrees. The NO3- anions are well separated from the cations which may account for the observed disorder of the oxygen atoms.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Transition metal complexes with thiosemicarbazide-based ligands .28. Synthesis and x-ray crystal structure of the first phosphorus-bonded thiosemicarbazide complex: [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(1-)]pyridinenickel(II)-nitrate",
volume = "39",
number = "1",
pages = "11-19",
doi = "10.1080/00958979608028171"
}

Leovac, V. M., Ribar, B., Argay, G., Kalman, A.,& Brčeski, I.. (1996). Transition metal complexes with thiosemicarbazide-based ligands .28. Synthesis and x-ray crystal structure of the first phosphorus-bonded thiosemicarbazide complex: [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(1-)]pyridinenickel(II)-nitrate. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 39(1), 11-19.
https://doi.org/10.1080/00958979608028171

Leovac VM, Ribar B, Argay G, Kalman A, Brčeski I. Transition metal complexes with thiosemicarbazide-based ligands .28. Synthesis and x-ray crystal structure of the first phosphorus-bonded thiosemicarbazide complex: [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(1-)]pyridinenickel(II)-nitrate. in Journal of Coordination Chemistry. 1996;39(1):11-19.
doi:10.1080/00958979608028171 .

Leovac, Vukadin M., Ribar, B, Argay, G, Kalman, A, Brčeski, Ilija, "Transition metal complexes with thiosemicarbazide-based ligands .28. Synthesis and x-ray crystal structure of the first phosphorus-bonded thiosemicarbazide complex: [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(1-)]pyridinenickel(II)-nitrate" in Journal of Coordination Chemistry, 39, no. 1 (1996):11-19,
https://doi.org/10.1080/00958979608028171 . .