TY  - JOUR
AU  - Kamberović, Željko
AU  - Sokić, Miroslav
AU  - Matković, Vladislav
AU  - Anđić, Zoran
AU  - Korać, Marija
AU  - Nikolić, Vesna
PY  - 2012
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5340
AB  - Catalysts based on nickel, as active component, exhibit suitable properties in various heterogeneous catalysis processes;
however, they quickly deactivate due to deposits formation during exploitation and sintering at elevated temperatures. Considering
that catalysts with several catalytic components possess enhanced catalytic properties, in present study the influence of temperature,
time and additives (PdCl2, FeCl2 and CuCl2) on the reduction degree of nickel(II)-chloride by hydrogen have been investigated. The
objectives of the study were selection of an appropriate catalytic activity modifier and development of a new synthesis method for
nanocomposite catalysts production, which are characterized by enhanced properties compared to the commercial Ni/Al2O3
catalysts. Obtained experimental results clearly indicate that the best effect was achieved with addition of 0.1 wt. % PdCl2, whereby
NiCl2 reduction degree was 58.16% at 653 K and Pd significantly increased the reduction rate. According to the obtained results,
new technological synthesis method of nanocomposite Ni-Pd/Al2O3 catalysts was proposed, where Ni and Pd, as catalytically active
components, are homogeneously dispersed in monolithic Al2O3 based ceramic foam.
PB  - Editura Stiintifica F. M. R.
T2  - Metalurgia International
T1  - Effects of additives on nickel(II)-chloride hydrogen reduction for production of nanocomposite catalysts
VL  - XVII
IS  - 5
SP  - 37
EP  - 41
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5340
ER  - 

@article{
author = "Kamberović, Željko and Sokić, Miroslav and Matković, Vladislav and Anđić, Zoran and Korać, Marija and Nikolić, Vesna",
year = "2012",
abstract = "Catalysts based on nickel, as active component, exhibit suitable properties in various heterogeneous catalysis processes;
however, they quickly deactivate due to deposits formation during exploitation and sintering at elevated temperatures. Considering
that catalysts with several catalytic components possess enhanced catalytic properties, in present study the influence of temperature,
time and additives (PdCl2, FeCl2 and CuCl2) on the reduction degree of nickel(II)-chloride by hydrogen have been investigated. The
objectives of the study were selection of an appropriate catalytic activity modifier and development of a new synthesis method for
nanocomposite catalysts production, which are characterized by enhanced properties compared to the commercial Ni/Al2O3
catalysts. Obtained experimental results clearly indicate that the best effect was achieved with addition of 0.1 wt. % PdCl2, whereby
NiCl2 reduction degree was 58.16% at 653 K and Pd significantly increased the reduction rate. According to the obtained results,
new technological synthesis method of nanocomposite Ni-Pd/Al2O3 catalysts was proposed, where Ni and Pd, as catalytically active
components, are homogeneously dispersed in monolithic Al2O3 based ceramic foam.",
publisher = "Editura Stiintifica F. M. R.",
journal = "Metalurgia International",
title = "Effects of additives on nickel(II)-chloride hydrogen reduction for production of nanocomposite catalysts",
volume = "XVII",
number = "5",
pages = "37-41",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5340"
}

Kamberović, Ž., Sokić, M., Matković, V., Anđić, Z., Korać, M.,& Nikolić, V.. (2012). Effects of additives on nickel(II)-chloride hydrogen reduction for production of nanocomposite catalysts. in Metalurgia International
Editura Stiintifica F. M. R.., XVII(5), 37-41.
https://hdl.handle.net/21.15107/rcub_cherry_5340

Kamberović Ž, Sokić M, Matković V, Anđić Z, Korać M, Nikolić V. Effects of additives on nickel(II)-chloride hydrogen reduction for production of nanocomposite catalysts. in Metalurgia International. 2012;XVII(5):37-41.
https://hdl.handle.net/21.15107/rcub_cherry_5340 .

Kamberović, Željko, Sokić, Miroslav, Matković, Vladislav, Anđić, Zoran, Korać, Marija, Nikolić, Vesna, "Effects of additives on nickel(II)-chloride hydrogen reduction for production of nanocomposite catalysts" in Metalurgia International, XVII, no. 5 (2012):37-41,
https://hdl.handle.net/21.15107/rcub_cherry_5340 .