Adaila, Kawther

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  • Adaila, Kawther (8)
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Synthesis and characterization of Pd(II), Co(III) and Ni(II) complexes with the condenzation derivative of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent

Adaila, Kawther

(Универзитет у Београду, Хемијски факултет, 2016)

TY  - THES
AU  - Adaila, Kawther
PY  - 2016
UR  - http://eteze.bg.ac.rs/application/showtheses?thesesId=4939
UR  - https://fedorabg.bg.ac.rs/fedora/get/o:15496/bdef:Content/download
UR  - http://vbs.rs/scripts/cobiss?command=DISPLAY&base=70036&RID=48847119
UR  - http://nardus.mpn.gov.rs/123456789/8056
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/2724
AB  - Complexes of Pd(II), Co(III) and Ni(II) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard’s T reagent were synthesized, characterized, and their antimicrobial activities and magnetic properties were evaluated. The ligand, Pd(II) and Co(III) complexes were characterized by elemental analysis, IR and NMR spectroscopy, and X-ray crystallography. Ni(II) complexes were characterized by elemental analysis, IR spectroscopy and X-ray crystallography. In Pd(II) and Co(III) complexes, the deprotonated ligand was coordinated to the metal through the phosphorus, the imine nitrogen, and the carbonyl oxygen atoms. In the octahedral Co(III) complex, two ligand molecules were coordinated to metal ion, while the square-planar environment of Pd(II) complex was constituted of one tridentate ligand and chloride in the fourth coordination place. The ligand and Pd(II) and Co(III) complexes showed moderate antibacterial activity. In all the Ni(II) complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms while the remaining coordination positions are occupied with thiocyanato anions. Coordination of deprotonated phosphine ligand results in formation of square-planar complexes, while the octahedral complex was formed with protonated ligand. Results of magnetic measurements analyzed by Curie-Weiss law show paramagnetic behavior of investigated octahedral Ni(II) complex with effective magnetic moment μeff = 3.1 μB.
AB  - Kompleksi Pd(II), Co(III) i Ni(II) sa kondenzacionim proizvodom 2-(difenilfosfino)benzaldehida i Žirarovog T reagensa su sintetisani, strukturno okarakterisani i ispitana su njihova magnetna i antimikrobna svojstva. Ligand, Pd(II) i Co(III) kompleksi su okarakterisani na osnovu rezultata elementalne analize, IC i NMR spektroskopije i rendgenske strukturne analize. Kompleksi Ni(II) su okarakterisani na osnovu rezultata elementalne analize, IC spektroskopije i rendgenske strukturne analize. U kompleksima Pd(II) i Co(III), deprotonovani ligand je koordinovan za jon metala preko atoma fosfora, azometinskog azota i karbonilnog kiseonika. U slučaju oktaedarskog kompleksa Co(III), dva molekula liganda su tridentatno koordinovana za metalni centar, dok u kvadratno-planarnom kompleksu Pd(II) okruženje oko centralnog metalnog jona čine tridentatno koordinovani ligand i hlorido ligand koji zauzima četvrto koordinaciono mesto. Ligand, Pd(II) i Co(III) kompleksi pokazuju umerenu antibakterijsku aktivnost. Kod svih Ni(II) kompleksa ligand je tridentatno koordinovan za jon metala preko P, N i O atoma, a preostala koordinaciona mesta zauzimaju izotiocijanato ligandi. Koordinacija deprotonovanog (cviter-jonskog) fosfinskog liganda dovodi do formiranja kvadratno-planarnih Ni(II) kompleksa, dok je u oktaedarskom Ni(II) kompleksu koordinovan pozitivno naelektrisani jon liganda. Rezultati magnetnih merenja ukazuju na paramagnetična svojstva ispitivanog oktaedarskog Ni(II) kompleksa čiji izmereni efektivni magnetni momenat iznosi 3,1 μB.
PB  - Универзитет у Београду, Хемијски факултет
T2  - Универзитет у Београду
T1  - Synthesis and characterization of Pd(II), Co(III) and Ni(II) complexes with the condenzation derivative of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent
ER  - 
@phdthesis{
author = "Adaila, Kawther",
year = "2016",
abstract = "Complexes of Pd(II), Co(III) and Ni(II) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard’s T reagent were synthesized, characterized, and their antimicrobial activities and magnetic properties were evaluated. The ligand, Pd(II) and Co(III) complexes were characterized by elemental analysis, IR and NMR spectroscopy, and X-ray crystallography. Ni(II) complexes were characterized by elemental analysis, IR spectroscopy and X-ray crystallography. In Pd(II) and Co(III) complexes, the deprotonated ligand was coordinated to the metal through the phosphorus, the imine nitrogen, and the carbonyl oxygen atoms. In the octahedral Co(III) complex, two ligand molecules were coordinated to metal ion, while the square-planar environment of Pd(II) complex was constituted of one tridentate ligand and chloride in the fourth coordination place. The ligand and Pd(II) and Co(III) complexes showed moderate antibacterial activity. In all the Ni(II) complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms while the remaining coordination positions are occupied with thiocyanato anions. Coordination of deprotonated phosphine ligand results in formation of square-planar complexes, while the octahedral complex was formed with protonated ligand. Results of magnetic measurements analyzed by Curie-Weiss law show paramagnetic behavior of investigated octahedral Ni(II) complex with effective magnetic moment μeff = 3.1 μB., Kompleksi Pd(II), Co(III) i Ni(II) sa kondenzacionim proizvodom 2-(difenilfosfino)benzaldehida i Žirarovog T reagensa su sintetisani, strukturno okarakterisani i ispitana su njihova magnetna i antimikrobna svojstva. Ligand, Pd(II) i Co(III) kompleksi su okarakterisani na osnovu rezultata elementalne analize, IC i NMR spektroskopije i rendgenske strukturne analize. Kompleksi Ni(II) su okarakterisani na osnovu rezultata elementalne analize, IC spektroskopije i rendgenske strukturne analize. U kompleksima Pd(II) i Co(III), deprotonovani ligand je koordinovan za jon metala preko atoma fosfora, azometinskog azota i karbonilnog kiseonika. U slučaju oktaedarskog kompleksa Co(III), dva molekula liganda su tridentatno koordinovana za metalni centar, dok u kvadratno-planarnom kompleksu Pd(II) okruženje oko centralnog metalnog jona čine tridentatno koordinovani ligand i hlorido ligand koji zauzima četvrto koordinaciono mesto. Ligand, Pd(II) i Co(III) kompleksi pokazuju umerenu antibakterijsku aktivnost. Kod svih Ni(II) kompleksa ligand je tridentatno koordinovan za jon metala preko P, N i O atoma, a preostala koordinaciona mesta zauzimaju izotiocijanato ligandi. Koordinacija deprotonovanog (cviter-jonskog) fosfinskog liganda dovodi do formiranja kvadratno-planarnih Ni(II) kompleksa, dok je u oktaedarskom Ni(II) kompleksu koordinovan pozitivno naelektrisani jon liganda. Rezultati magnetnih merenja ukazuju na paramagnetična svojstva ispitivanog oktaedarskog Ni(II) kompleksa čiji izmereni efektivni magnetni momenat iznosi 3,1 μB.",
publisher = "Универзитет у Београду, Хемијски факултет",
journal = "Универзитет у Београду",
title = "Synthesis and characterization of Pd(II), Co(III) and Ni(II) complexes with the condenzation derivative of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent"
}
Adaila, K.. (2016). Synthesis and characterization of Pd(II), Co(III) and Ni(II) complexes with the condenzation derivative of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent. in Универзитет у Београду
Универзитет у Београду, Хемијски факултет..
Adaila K. Synthesis and characterization of Pd(II), Co(III) and Ni(II) complexes with the condenzation derivative of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent. in Универзитет у Београду. 2016;..
Adaila, Kawther, "Synthesis and characterization of Pd(II), Co(III) and Ni(II) complexes with the condenzation derivative of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent" in Универзитет у Београду (2016).

Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)

Brađan, Gabrijela; Čobeljić, Božidar; Pevec, Andrej; Turel, Iztok; Milenković, Marina; Radanović, Dušanka D.; Šumar-Ristović, Maja; Adaila, Kawther; Milenković, Milica R.; Anđelković, Katarina K.

(Taylor & Francis Ltd, Abingdon, 2016)

TY  - JOUR
AU  - Brađan, Gabrijela
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Milenković, Marina
AU  - Radanović, Dušanka D.
AU  - Šumar-Ristović, Maja
AU  - Adaila, Kawther
AU  - Milenković, Milica R.
AU  - Anđelković, Katarina K.
PY  - 2016
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/3635
AB  - Pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized and characterized by elemental analyses, IR and UV-vis spectra, molar conductivity, and magnetic susceptibility. Crystal structures of the Co(II) and Ni(II) complexes were also determined. Antimicrobial activities of the ligand and metal complexes were examined. [GRAPHICS] .
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)
ER  - 
@article{
author = "Brađan, Gabrijela and Čobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Milenković, Marina and Radanović, Dušanka D. and Šumar-Ristović, Maja and Adaila, Kawther and Milenković, Milica R. and Anđelković, Katarina K.",
year = "2016",
abstract = "Pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized and characterized by elemental analyses, IR and UV-vis spectra, molar conductivity, and magnetic susceptibility. Crystal structures of the Co(II) and Ni(II) complexes were also determined. Antimicrobial activities of the ligand and metal complexes were examined. [GRAPHICS] .",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)"
}
Brađan, G., Čobeljić, B., Pevec, A., Turel, I., Milenković, M., Radanović, D. D., Šumar-Ristović, M., Adaila, K., Milenković, M. R.,& Anđelković, K. K.. (2016). Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone). in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon..
Brađan G, Čobeljić B, Pevec A, Turel I, Milenković M, Radanović DD, Šumar-Ristović M, Adaila K, Milenković MR, Anđelković KK. Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone). in Journal of Coordination Chemistry. 2016;..
Brađan, Gabrijela, Čobeljić, Božidar, Pevec, Andrej, Turel, Iztok, Milenković, Marina, Radanović, Dušanka D., Šumar-Ristović, Maja, Adaila, Kawther, Milenković, Milica R., Anđelković, Katarina K., "Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)" in Journal of Coordination Chemistry (2016).

Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)

Brađan, Gabrijela; Čobeljić, Božidar; Pevec, Andrej; Turel, Iztok; Milenković, Marina; Radanović, Dušanka D.; Šumar-Ristović, Maja; Adaila, Kawther; Milenković, Milica R.; Anđelković, Katarina K.

(Taylor & Francis Ltd, Abingdon, 2016)

TY  - JOUR
AU  - Brađan, Gabrijela
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Milenković, Marina
AU  - Radanović, Dušanka D.
AU  - Šumar-Ristović, Maja
AU  - Adaila, Kawther
AU  - Milenković, Milica R.
AU  - Anđelković, Katarina K.
PY  - 2016
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/1907
AB  - Pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized and characterized by elemental analyses, IR and UV-vis spectra, molar conductivity, and magnetic susceptibility. Crystal structures of the Co(II) and Ni(II) complexes were also determined. Antimicrobial activities of the ligand and metal complexes were examined. [GRAPHICS] .
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)
VL  - 69
IS  - 5
SP  - 801
EP  - 811
DO  - 10.1080/00958972.2016.1139702
UR  - Kon_3026
ER  - 
@article{
author = "Brađan, Gabrijela and Čobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Milenković, Marina and Radanović, Dušanka D. and Šumar-Ristović, Maja and Adaila, Kawther and Milenković, Milica R. and Anđelković, Katarina K.",
year = "2016",
abstract = "Pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with condensation product of 2,6-diacetylpyridine and trimethylammoniumacetohydrazide (Girard's T reagent) were synthesized and characterized by elemental analyses, IR and UV-vis spectra, molar conductivity, and magnetic susceptibility. Crystal structures of the Co(II) and Ni(II) complexes were also determined. Antimicrobial activities of the ligand and metal complexes were examined. [GRAPHICS] .",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)",
volume = "69",
number = "5",
pages = "801-811",
doi = "10.1080/00958972.2016.1139702",
url = "Kon_3026"
}
Brađan, G., Čobeljić, B., Pevec, A., Turel, I., Milenković, M., Radanović, D. D., Šumar-Ristović, M., Adaila, K., Milenković, M. R.,& Anđelković, K. K.. (2016). Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone). in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 69(5), 801-811.
https://doi.org/10.1080/00958972.2016.1139702
Kon_3026
Brađan G, Čobeljić B, Pevec A, Turel I, Milenković M, Radanović DD, Šumar-Ristović M, Adaila K, Milenković MR, Anđelković KK. Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone). in Journal of Coordination Chemistry. 2016;69(5):801-811.
doi:10.1080/00958972.2016.1139702
Kon_3026 .
Brađan, Gabrijela, Čobeljić, Božidar, Pevec, Andrej, Turel, Iztok, Milenković, Marina, Radanović, Dušanka D., Šumar-Ristović, Maja, Adaila, Kawther, Milenković, Milica R., Anđelković, Katarina K., "Synthesis, characterization and antimicrobial activity of pentagonal-bipyramidal isothiocyanato Co(II) and Ni(II) complexes with 2,6-diacetylpyridine bis(trimethylammoniumacetohydrazone)" in Journal of Coordination Chemistry, 69, no. 5 (2016):801-811,
https://doi.org/10.1080/00958972.2016.1139702 .,
Kon_3026 .
7
7
7

Supplementary data for the article: Čobeljić, B.; Pevec, A.; Stepanović, S.; Spasojević, V.; Milenković, M.; Turel, I.; Swart, M.; Gruden-Pavlović, M.; Adaila, K.; Anelković, K. Experimental and Theoretical Investigation of Octahedral and Square-Planar Isothiocyanato Complexes of Ni(II) with Acylhydrazones of 2-(Diphenylphosphino)Benzaldehyde. Polyhedron 2015, 89, 271–279. https://doi.org/10.1016/j.poly.2015.01.024

Čobeljić, Božidar; Pevec, Andrej; Stepanović, Stepan; Spasojević, Vojislav; Milenković, Milica R.; Turel, Iztok; Swart, Marcel; Gruden-Pavlović, Maja; Adaila, Kawther; Anđelković, Katarina K.

(Pergamon-Elsevier Science Ltd, Oxford, 2015)

TY  - DATA
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Stepanović, Stepan
AU  - Spasojević, Vojislav
AU  - Milenković, Milica R.
AU  - Turel, Iztok
AU  - Swart, Marcel
AU  - Gruden-Pavlović, Maja
AU  - Adaila, Kawther
AU  - Anđelković, Katarina K.
PY  - 2015
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/2904
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Supplementary data for the article: Čobeljić, B.; Pevec, A.; Stepanović, S.; Spasojević, V.; Milenković, M.; Turel, I.; Swart, M.; Gruden-Pavlović, M.; Adaila, K.; Anelković, K. Experimental and Theoretical Investigation of Octahedral and Square-Planar Isothiocyanato Complexes of Ni(II) with Acylhydrazones of 2-(Diphenylphosphino)Benzaldehyde. Polyhedron 2015, 89, 271–279. https://doi.org/10.1016/j.poly.2015.01.024
UR  - Kon_2833
ER  - 
@misc{
author = "Čobeljić, Božidar and Pevec, Andrej and Stepanović, Stepan and Spasojević, Vojislav and Milenković, Milica R. and Turel, Iztok and Swart, Marcel and Gruden-Pavlović, Maja and Adaila, Kawther and Anđelković, Katarina K.",
year = "2015",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Supplementary data for the article: Čobeljić, B.; Pevec, A.; Stepanović, S.; Spasojević, V.; Milenković, M.; Turel, I.; Swart, M.; Gruden-Pavlović, M.; Adaila, K.; Anelković, K. Experimental and Theoretical Investigation of Octahedral and Square-Planar Isothiocyanato Complexes of Ni(II) with Acylhydrazones of 2-(Diphenylphosphino)Benzaldehyde. Polyhedron 2015, 89, 271–279. https://doi.org/10.1016/j.poly.2015.01.024",
url = "Kon_2833"
}
Čobeljić, B., Pevec, A., Stepanović, S., Spasojević, V., Milenković, M. R., Turel, I., Swart, M., Gruden-Pavlović, M., Adaila, K.,& Anđelković, K. K.. (2015). Supplementary data for the article: Čobeljić, B.; Pevec, A.; Stepanović, S.; Spasojević, V.; Milenković, M.; Turel, I.; Swart, M.; Gruden-Pavlović, M.; Adaila, K.; Anelković, K. Experimental and Theoretical Investigation of Octahedral and Square-Planar Isothiocyanato Complexes of Ni(II) with Acylhydrazones of 2-(Diphenylphosphino)Benzaldehyde. Polyhedron 2015, 89, 271–279. https://doi.org/10.1016/j.poly.2015.01.024. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford..
Kon_2833
Čobeljić B, Pevec A, Stepanović S, Spasojević V, Milenković MR, Turel I, Swart M, Gruden-Pavlović M, Adaila K, Anđelković KK. Supplementary data for the article: Čobeljić, B.; Pevec, A.; Stepanović, S.; Spasojević, V.; Milenković, M.; Turel, I.; Swart, M.; Gruden-Pavlović, M.; Adaila, K.; Anelković, K. Experimental and Theoretical Investigation of Octahedral and Square-Planar Isothiocyanato Complexes of Ni(II) with Acylhydrazones of 2-(Diphenylphosphino)Benzaldehyde. Polyhedron 2015, 89, 271–279. https://doi.org/10.1016/j.poly.2015.01.024. in Polyhedron. 2015;.
Kon_2833 .
Čobeljić, Božidar, Pevec, Andrej, Stepanović, Stepan, Spasojević, Vojislav, Milenković, Milica R., Turel, Iztok, Swart, Marcel, Gruden-Pavlović, Maja, Adaila, Kawther, Anđelković, Katarina K., "Supplementary data for the article: Čobeljić, B.; Pevec, A.; Stepanović, S.; Spasojević, V.; Milenković, M.; Turel, I.; Swart, M.; Gruden-Pavlović, M.; Adaila, K.; Anelković, K. Experimental and Theoretical Investigation of Octahedral and Square-Planar Isothiocyanato Complexes of Ni(II) with Acylhydrazones of 2-(Diphenylphosphino)Benzaldehyde. Polyhedron 2015, 89, 271–279. https://doi.org/10.1016/j.poly.2015.01.024" in Polyhedron (2015),
Kon_2833 .

Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde

Čobeljić, Božidar; Pevec, Andrej; Stepanović, Stepan; Spasojević, Vojislav; Milenković, Milica R.; Turel, Iztok; Swart, Marcel; Gruden-Pavlović, Maja; Adaila, Kawther; Anđelković, Katarina K.

(Pergamon-Elsevier Science Ltd, Oxford, 2015)

TY  - JOUR
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Stepanović, Stepan
AU  - Spasojević, Vojislav
AU  - Milenković, Milica R.
AU  - Turel, Iztok
AU  - Swart, Marcel
AU  - Gruden-Pavlović, Maja
AU  - Adaila, Kawther
AU  - Anđelković, Katarina K.
PY  - 2015
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/3021
AB  - Octahedral and square-planar isothiocyanato complexes of Ni(II) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent were synthesized and characterized by elemental analysis, IR spectroscopy and X-ray crystallography. Results of magnetic measurements for octahedral Ni(II) complex were also reported. In all the complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms while the remaining coordination positions are occupied with thiocyanato anions. Coordination of deprotonated phosphine ligand results in formation of square-planar complexes, while the octahedral complex was formed with protonated ligand. Reaction energetics with both forms of ligand were studied by the means of DFT and results were in complete agreement with experimental observations. Furthermore, ligand field splitting analysis gave the deeper insight in the relationship of the isolated complex coordination environment and protonation of the ligand.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde
VL  - 89
SP  - 271
EP  - 279
DO  - 10.1016/j.poly.2015.01.024
ER  - 
@article{
author = "Čobeljić, Božidar and Pevec, Andrej and Stepanović, Stepan and Spasojević, Vojislav and Milenković, Milica R. and Turel, Iztok and Swart, Marcel and Gruden-Pavlović, Maja and Adaila, Kawther and Anđelković, Katarina K.",
year = "2015",
abstract = "Octahedral and square-planar isothiocyanato complexes of Ni(II) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent were synthesized and characterized by elemental analysis, IR spectroscopy and X-ray crystallography. Results of magnetic measurements for octahedral Ni(II) complex were also reported. In all the complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms while the remaining coordination positions are occupied with thiocyanato anions. Coordination of deprotonated phosphine ligand results in formation of square-planar complexes, while the octahedral complex was formed with protonated ligand. Reaction energetics with both forms of ligand were studied by the means of DFT and results were in complete agreement with experimental observations. Furthermore, ligand field splitting analysis gave the deeper insight in the relationship of the isolated complex coordination environment and protonation of the ligand.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde",
volume = "89",
pages = "271-279",
doi = "10.1016/j.poly.2015.01.024"
}
Čobeljić, B., Pevec, A., Stepanović, S., Spasojević, V., Milenković, M. R., Turel, I., Swart, M., Gruden-Pavlović, M., Adaila, K.,& Anđelković, K. K.. (2015). Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 89, 271-279.
https://doi.org/10.1016/j.poly.2015.01.024
Čobeljić B, Pevec A, Stepanović S, Spasojević V, Milenković MR, Turel I, Swart M, Gruden-Pavlović M, Adaila K, Anđelković KK. Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde. in Polyhedron. 2015;89:271-279.
doi:10.1016/j.poly.2015.01.024 .
Čobeljić, Božidar, Pevec, Andrej, Stepanović, Stepan, Spasojević, Vojislav, Milenković, Milica R., Turel, Iztok, Swart, Marcel, Gruden-Pavlović, Maja, Adaila, Kawther, Anđelković, Katarina K., "Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde" in Polyhedron, 89 (2015):271-279,
https://doi.org/10.1016/j.poly.2015.01.024 . .
10
7
11

Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde

Čobeljić, Božidar; Pevec, Andrej; Stepanović, Stepan; Spasojević, Vojislav; Milenković, Milica R.; Turel, Iztok; Swart, Marcel; Gruden-Pavlović, Maja; Adaila, Kawther; Anđelković, Katarina K.

(Pergamon-Elsevier Science Ltd, Oxford, 2015)

TY  - JOUR
AU  - Čobeljić, Božidar
AU  - Pevec, Andrej
AU  - Stepanović, Stepan
AU  - Spasojević, Vojislav
AU  - Milenković, Milica R.
AU  - Turel, Iztok
AU  - Swart, Marcel
AU  - Gruden-Pavlović, Maja
AU  - Adaila, Kawther
AU  - Anđelković, Katarina K.
PY  - 2015
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/1687
AB  - Octahedral and square-planar isothiocyanato complexes of Ni(II) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent were synthesized and characterized by elemental analysis, IR spectroscopy and X-ray crystallography. Results of magnetic measurements for octahedral Ni(II) complex were also reported. In all the complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms while the remaining coordination positions are occupied with thiocyanato anions. Coordination of deprotonated phosphine ligand results in formation of square-planar complexes, while the octahedral complex was formed with protonated ligand. Reaction energetics with both forms of ligand were studied by the means of DFT and results were in complete agreement with experimental observations. Furthermore, ligand field splitting analysis gave the deeper insight in the relationship of the isolated complex coordination environment and protonation of the ligand. (C) 2015 Elsevier Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde
VL  - 89
SP  - 271
EP  - 279
EP  - Peer-reviewed manuscript: [http://cherry.chem.bg.ac.rs/handle/123456789/3021]
DO  - 10.1016/j.poly.2015.01.024
UR  - Kon_2833
ER  - 
@article{
author = "Čobeljić, Božidar and Pevec, Andrej and Stepanović, Stepan and Spasojević, Vojislav and Milenković, Milica R. and Turel, Iztok and Swart, Marcel and Gruden-Pavlović, Maja and Adaila, Kawther and Anđelković, Katarina K.",
year = "2015",
abstract = "Octahedral and square-planar isothiocyanato complexes of Ni(II) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent were synthesized and characterized by elemental analysis, IR spectroscopy and X-ray crystallography. Results of magnetic measurements for octahedral Ni(II) complex were also reported. In all the complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms while the remaining coordination positions are occupied with thiocyanato anions. Coordination of deprotonated phosphine ligand results in formation of square-planar complexes, while the octahedral complex was formed with protonated ligand. Reaction energetics with both forms of ligand were studied by the means of DFT and results were in complete agreement with experimental observations. Furthermore, ligand field splitting analysis gave the deeper insight in the relationship of the isolated complex coordination environment and protonation of the ligand. (C) 2015 Elsevier Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde",
volume = "89",
pages = "271-279-Peer-reviewed manuscript: [http://cherry.chem.bg.ac.rs/handle/123456789/3021]",
doi = "10.1016/j.poly.2015.01.024",
url = "Kon_2833"
}
Čobeljić, B., Pevec, A., Stepanović, S., Spasojević, V., Milenković, M. R., Turel, I., Swart, M., Gruden-Pavlović, M., Adaila, K.,& Anđelković, K. K.. (2015). Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 89, 271-279.
https://doi.org/10.1016/j.poly.2015.01.024
Kon_2833
Čobeljić B, Pevec A, Stepanović S, Spasojević V, Milenković MR, Turel I, Swart M, Gruden-Pavlović M, Adaila K, Anđelković KK. Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde. in Polyhedron. 2015;89:271-279.
doi:10.1016/j.poly.2015.01.024
Kon_2833 .
Čobeljić, Božidar, Pevec, Andrej, Stepanović, Stepan, Spasojević, Vojislav, Milenković, Milica R., Turel, Iztok, Swart, Marcel, Gruden-Pavlović, Maja, Adaila, Kawther, Anđelković, Katarina K., "Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde" in Polyhedron, 89 (2015):271-279,
https://doi.org/10.1016/j.poly.2015.01.024 .,
Kon_2833 .
10
7
11

Synthesis, characterization, DFT calculation and biological activity of square-planar Ni(II) complexes with tridentate PNO ligands and monodentate pseudohalides. Part II

Milenković, Milica R.; Pevec, Andrej; Turel, Iztok; Vujčić, Miroslava; Milenković, Marina; Jovanović, Katarina; Gligorijević, Nevenka; Radulović, Siniša; Swart, Marcel; Gruden-Pavlović, Maja; Adaila, Kawther; Čobeljić, Božidar; Anđelković, Katarina K.

(Elsevier France-Editions Scientifiques Medicales Elsevier, Paris, 2014)

TY  - JOUR
AU  - Milenković, Milica R.
AU  - Pevec, Andrej
AU  - Turel, Iztok
AU  - Vujčić, Miroslava
AU  - Milenković, Marina
AU  - Jovanović, Katarina
AU  - Gligorijević, Nevenka
AU  - Radulović, Siniša
AU  - Swart, Marcel
AU  - Gruden-Pavlović, Maja
AU  - Adaila, Kawther
AU  - Čobeljić, Božidar
AU  - Anđelković, Katarina K.
PY  - 2014
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/1986
AB  - Three square-planar complexes of Ni(II) with condensation derivative of 2-(diphenylphosphino)benzaldehyde and 4-phenylsemicarbazide and monodentate pseudohalides have been synthesized and characterized on the basis of the results of X-ray. NMR and IR spectroscopy and elemental analysis. Investigated complexes exhibited moderate antibacterial and cytotoxic activity. The most pronounced cytotoxic activity (in the range of cisplatin) to HeLa cell line was observed for ligand and all the complexes. Azido complex and ligand induced concentration dependent cell cycle arrest in the S phase, as well as decrease of percentage of cells in G1 phase, without significant increase of apoptotic fraction of cells. The interaction of the azido complex and ligand with CT-DNA results in changes in UV-Vis spectra typical for non-covalent bonding. The observed intrinsic binding constant of azido complex CT-DNA and ligand-CT-DNA were 3.22 x 10(5) M-1 and 2.79 x 10(5) M-1. The results of DNA cleavage experiments showed that azido complex nicked supercoiled plasmid DNA. (C) 2014 Elsevier Masson SAS. All rights reserved.
PB  - Elsevier France-Editions Scientifiques Medicales Elsevier, Paris
T2  - European Journal of Medicinal Chemistry
T1  - Synthesis, characterization, DFT calculation and biological activity of square-planar Ni(II) complexes with tridentate PNO ligands and monodentate pseudohalides. Part II
VL  - 87
SP  - 284
EP  - 297
DO  - 10.1016/j.ejmech.2014.06.079
UR  - Kon_2941
ER  - 
@article{
author = "Milenković, Milica R. and Pevec, Andrej and Turel, Iztok and Vujčić, Miroslava and Milenković, Marina and Jovanović, Katarina and Gligorijević, Nevenka and Radulović, Siniša and Swart, Marcel and Gruden-Pavlović, Maja and Adaila, Kawther and Čobeljić, Božidar and Anđelković, Katarina K.",
year = "2014",
abstract = "Three square-planar complexes of Ni(II) with condensation derivative of 2-(diphenylphosphino)benzaldehyde and 4-phenylsemicarbazide and monodentate pseudohalides have been synthesized and characterized on the basis of the results of X-ray. NMR and IR spectroscopy and elemental analysis. Investigated complexes exhibited moderate antibacterial and cytotoxic activity. The most pronounced cytotoxic activity (in the range of cisplatin) to HeLa cell line was observed for ligand and all the complexes. Azido complex and ligand induced concentration dependent cell cycle arrest in the S phase, as well as decrease of percentage of cells in G1 phase, without significant increase of apoptotic fraction of cells. The interaction of the azido complex and ligand with CT-DNA results in changes in UV-Vis spectra typical for non-covalent bonding. The observed intrinsic binding constant of azido complex CT-DNA and ligand-CT-DNA were 3.22 x 10(5) M-1 and 2.79 x 10(5) M-1. The results of DNA cleavage experiments showed that azido complex nicked supercoiled plasmid DNA. (C) 2014 Elsevier Masson SAS. All rights reserved.",
publisher = "Elsevier France-Editions Scientifiques Medicales Elsevier, Paris",
journal = "European Journal of Medicinal Chemistry",
title = "Synthesis, characterization, DFT calculation and biological activity of square-planar Ni(II) complexes with tridentate PNO ligands and monodentate pseudohalides. Part II",
volume = "87",
pages = "284-297",
doi = "10.1016/j.ejmech.2014.06.079",
url = "Kon_2941"
}
Milenković, M. R., Pevec, A., Turel, I., Vujčić, M., Milenković, M., Jovanović, K., Gligorijević, N., Radulović, S., Swart, M., Gruden-Pavlović, M., Adaila, K., Čobeljić, B.,& Anđelković, K. K.. (2014). Synthesis, characterization, DFT calculation and biological activity of square-planar Ni(II) complexes with tridentate PNO ligands and monodentate pseudohalides. Part II. in European Journal of Medicinal Chemistry
Elsevier France-Editions Scientifiques Medicales Elsevier, Paris., 87, 284-297.
https://doi.org/10.1016/j.ejmech.2014.06.079
Kon_2941
Milenković MR, Pevec A, Turel I, Vujčić M, Milenković M, Jovanović K, Gligorijević N, Radulović S, Swart M, Gruden-Pavlović M, Adaila K, Čobeljić B, Anđelković KK. Synthesis, characterization, DFT calculation and biological activity of square-planar Ni(II) complexes with tridentate PNO ligands and monodentate pseudohalides. Part II. in European Journal of Medicinal Chemistry. 2014;87:284-297.
doi:10.1016/j.ejmech.2014.06.079
Kon_2941 .
Milenković, Milica R., Pevec, Andrej, Turel, Iztok, Vujčić, Miroslava, Milenković, Marina, Jovanović, Katarina, Gligorijević, Nevenka, Radulović, Siniša, Swart, Marcel, Gruden-Pavlović, Maja, Adaila, Kawther, Čobeljić, Božidar, Anđelković, Katarina K., "Synthesis, characterization, DFT calculation and biological activity of square-planar Ni(II) complexes with tridentate PNO ligands and monodentate pseudohalides. Part II" in European Journal of Medicinal Chemistry, 87 (2014):284-297,
https://doi.org/10.1016/j.ejmech.2014.06.079 .,
Kon_2941 .
16
17
17

Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent

Adaila, Kawther; Milenković, Milica R.; Bacchi, Alessia; Cantoni, Giulia; Swart, Marcel; Gruden-Pavlović, Maja; Milenković, Marina; Čobeljić, Božidar; Todorović, Tamara; Anđelković, Katarina K.

(Taylor & Francis Ltd, Abingdon, 2014)

TY  - JOUR
AU  - Adaila, Kawther
AU  - Milenković, Milica R.
AU  - Bacchi, Alessia
AU  - Cantoni, Giulia
AU  - Swart, Marcel
AU  - Gruden-Pavlović, Maja
AU  - Milenković, Marina
AU  - Čobeljić, Božidar
AU  - Todorović, Tamara
AU  - Anđelković, Katarina K.
PY  - 2014
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/1880
AB  - Complexes of Pd(II) and Co(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard T reagent were synthesized, characterized, and their antimicrobial activities were evaluated. The ligand and the complexes were characterized by elemental analysis, IR and NMR spectroscopies, and X-ray crystallography. In both complexes, the deprotonated ligand was coordinated to the metal through the phosphorus, the imine nitrogen, and the carbonyl oxygen atoms. In the octahedral Co(III) complex, two molecules of ligands were coordinated to metal ion, while square-planar environment of Pd(II) complex was constituted of one tridentate ligand and chloride in the fourth coordination place. The ligand and complexes showed moderate antibacterial activity. The molecular structures of the obtained metal complexes and the relative stabilities of two stereoisomers of the ligand were calculated using density functional theory at the S12g/TZ2P level.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent
VL  - 67
IS  - 22
SP  - 3633
EP  - 3648
DO  - 10.1080/00958972.2014.972389
UR  - Kon_2763
ER  - 
@article{
author = "Adaila, Kawther and Milenković, Milica R. and Bacchi, Alessia and Cantoni, Giulia and Swart, Marcel and Gruden-Pavlović, Maja and Milenković, Marina and Čobeljić, Božidar and Todorović, Tamara and Anđelković, Katarina K.",
year = "2014",
abstract = "Complexes of Pd(II) and Co(III) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girard T reagent were synthesized, characterized, and their antimicrobial activities were evaluated. The ligand and the complexes were characterized by elemental analysis, IR and NMR spectroscopies, and X-ray crystallography. In both complexes, the deprotonated ligand was coordinated to the metal through the phosphorus, the imine nitrogen, and the carbonyl oxygen atoms. In the octahedral Co(III) complex, two molecules of ligands were coordinated to metal ion, while square-planar environment of Pd(II) complex was constituted of one tridentate ligand and chloride in the fourth coordination place. The ligand and complexes showed moderate antibacterial activity. The molecular structures of the obtained metal complexes and the relative stabilities of two stereoisomers of the ligand were calculated using density functional theory at the S12g/TZ2P level.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent",
volume = "67",
number = "22",
pages = "3633-3648",
doi = "10.1080/00958972.2014.972389",
url = "Kon_2763"
}
Adaila, K., Milenković, M. R., Bacchi, A., Cantoni, G., Swart, M., Gruden-Pavlović, M., Milenković, M., Čobeljić, B., Todorović, T.,& Anđelković, K. K.. (2014). Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 67(22), 3633-3648.
https://doi.org/10.1080/00958972.2014.972389
Kon_2763
Adaila K, Milenković MR, Bacchi A, Cantoni G, Swart M, Gruden-Pavlović M, Milenković M, Čobeljić B, Todorović T, Anđelković KK. Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent. in Journal of Coordination Chemistry. 2014;67(22):3633-3648.
doi:10.1080/00958972.2014.972389
Kon_2763 .
Adaila, Kawther, Milenković, Milica R., Bacchi, Alessia, Cantoni, Giulia, Swart, Marcel, Gruden-Pavlović, Maja, Milenković, Marina, Čobeljić, Božidar, Todorović, Tamara, Anđelković, Katarina K., "Synthesis, characterization, DFT calculations, and antimicrobial activity of Pd(II) and Co(III) complexes with the condensation derivative of 2-(diphenylphosphino) benzaldehyde and Girard's T reagent" in Journal of Coordination Chemistry, 67, no. 22 (2014):3633-3648,
https://doi.org/10.1080/00958972.2014.972389 .,
Kon_2763 .
6
5
6