TY  - JOUR
AU  - Ivanovska, Aleksandra
AU  - Veljović, Sonja
AU  - Dojčinović, Biljana P.
AU  - Tadić, Nenad
AU  - Mihajlovski, Katarina
AU  - Natić, Maja
AU  - Kostić, Mirjana M.
PY  - 2021
UR  - https://www.hindawi.com/journals/ast/2021/3552300/
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4663
AB  - In this investigation, the possibility of wood waste (hardwoods such as oaks’ and alternatives’ staves from Balkan cooperage) revalorization for simultaneous cadmium removal and wastewater disinfection was examined. All samples were characterized in terms of their crystallinity index and crystallite size, amount of functional groups, and surface chemistry (determined by ATR-FTIR) as well as antibacterial activity. Mulberry is characterized by the lowest crystallinity index which can be ascribed to the highest crystallite size disabling crystallite denser packaging, while myrobalan plum has about 23% lower crystallite size that enables crystallite better packaging, thus resulting in a 42.4% higher crystallinity index compared to the mulberry. All oaks have a significantly higher amount of carboxyl groups compared to the alternatives (0.23-0.28 vs. 0.12-0.19 mmol/g). The adsorption experiments revealed that with increasing the initial cadmium concentration from 15 up to 55 mg/g, samples’ adsorption capacity increases by 89-220%. The equilibrium data fit well with the Langmuir isotherm model implying monolayer coverage of cadmium ions over a homogeneous wood surface. The relationship between the samples’ maximum adsorption capacities (ranged from 5.726 to 12.618 mg/g), their crystallinity index, and crystallite size was established. According to ATR-FTIR spectra, aldehyde, carboxyl, hydroxyl, and phenyl groups present on the wood waste surface are involved in Cd2+ adsorption which proceeds via the interplay of the complexation, cation-π interactions, and ion-exchange mechanisms. Mulberry and myrobalan plum showed about 89% and 80% of the total uptake capacity of cadmium within 60 min, while the equilibrium was attained after 240 min of contact time. Good compliance with pseudo-second kinetic order indicated that cadmium adsorption was mediated by chemical forces. Thermodynamic parameters revealed the spontaneous and exothermic character of cadmium ion adsorption onto mulberry and myrobalan plum. All studied samples provide maximum bacterial reduction (>99%) for E. coli and S. aureus. Wood waste from Balkan cooperage can be successfully used for simultaneous cadmium removal and wastewater disinfection.
PB  - SAGE
T2  - Adsorption Science & Technology
T1  - A Strategy to Revalue a Wood Waste for Simultaneous Cadmium Removal and Wastewater Disinfection
VL  - 2021
SP  - e3552300
DO  - 10.1155/2021/3552300
ER  - 

@article{
author = "Ivanovska, Aleksandra and Veljović, Sonja and Dojčinović, Biljana P. and Tadić, Nenad and Mihajlovski, Katarina and Natić, Maja and Kostić, Mirjana M.",
year = "2021",
abstract = "In this investigation, the possibility of wood waste (hardwoods such as oaks’ and alternatives’ staves from Balkan cooperage) revalorization for simultaneous cadmium removal and wastewater disinfection was examined. All samples were characterized in terms of their crystallinity index and crystallite size, amount of functional groups, and surface chemistry (determined by ATR-FTIR) as well as antibacterial activity. Mulberry is characterized by the lowest crystallinity index which can be ascribed to the highest crystallite size disabling crystallite denser packaging, while myrobalan plum has about 23% lower crystallite size that enables crystallite better packaging, thus resulting in a 42.4% higher crystallinity index compared to the mulberry. All oaks have a significantly higher amount of carboxyl groups compared to the alternatives (0.23-0.28 vs. 0.12-0.19 mmol/g). The adsorption experiments revealed that with increasing the initial cadmium concentration from 15 up to 55 mg/g, samples’ adsorption capacity increases by 89-220%. The equilibrium data fit well with the Langmuir isotherm model implying monolayer coverage of cadmium ions over a homogeneous wood surface. The relationship between the samples’ maximum adsorption capacities (ranged from 5.726 to 12.618 mg/g), their crystallinity index, and crystallite size was established. According to ATR-FTIR spectra, aldehyde, carboxyl, hydroxyl, and phenyl groups present on the wood waste surface are involved in Cd2+ adsorption which proceeds via the interplay of the complexation, cation-π interactions, and ion-exchange mechanisms. Mulberry and myrobalan plum showed about 89% and 80% of the total uptake capacity of cadmium within 60 min, while the equilibrium was attained after 240 min of contact time. Good compliance with pseudo-second kinetic order indicated that cadmium adsorption was mediated by chemical forces. Thermodynamic parameters revealed the spontaneous and exothermic character of cadmium ion adsorption onto mulberry and myrobalan plum. All studied samples provide maximum bacterial reduction (>99%) for E. coli and S. aureus. Wood waste from Balkan cooperage can be successfully used for simultaneous cadmium removal and wastewater disinfection.",
publisher = "SAGE",
journal = "Adsorption Science & Technology",
title = "A Strategy to Revalue a Wood Waste for Simultaneous Cadmium Removal and Wastewater Disinfection",
volume = "2021",
pages = "e3552300",
doi = "10.1155/2021/3552300"
}

Ivanovska, A., Veljović, S., Dojčinović, B. P., Tadić, N., Mihajlovski, K., Natić, M.,& Kostić, M. M.. (2021). A Strategy to Revalue a Wood Waste for Simultaneous Cadmium Removal and Wastewater Disinfection. in Adsorption Science & Technology
SAGE., 2021, e3552300.
https://doi.org/10.1155/2021/3552300

Ivanovska A, Veljović S, Dojčinović BP, Tadić N, Mihajlovski K, Natić M, Kostić MM. A Strategy to Revalue a Wood Waste for Simultaneous Cadmium Removal and Wastewater Disinfection. in Adsorption Science & Technology. 2021;2021:e3552300.
doi:10.1155/2021/3552300 .

Ivanovska, Aleksandra, Veljović, Sonja, Dojčinović, Biljana P., Tadić, Nenad, Mihajlovski, Katarina, Natić, Maja, Kostić, Mirjana M., "A Strategy to Revalue a Wood Waste for Simultaneous Cadmium Removal and Wastewater Disinfection" in Adsorption Science & Technology, 2021 (2021):e3552300,
https://doi.org/10.1155/2021/3552300 . .

TY  - JOUR
AU  - Ivanovska, Aleksandra
AU  - Lađarević, Jelena
AU  - Pavun, Leposava
AU  - Dojčinović, Biljana P.
AU  - Cvijetić, Ilija
AU  - Mijin, Dušan
AU  - Kostić, Mirjana M.
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4744
AB  - The objective of this investigation was to obtain jute fabrics with enhanced sorption properties (by using simple and cost-effective alkali and oxidative modifications) and a long life cycle. The applied alkali modifications lead to hemicellulose removal and decreased the fibers’ crystallinity, both contributing to enhanced fibers’ sorption properties, i.e., water retention power and degree of fibers’ swelling up to 49 % and 70 %, respectively. A connection between cellulose polymorphs’ (cellulose I and cellulose II) contents (determined by XRD), fibers’ surface morphology (verified by FESEM), fabrics’ crimp, and capillarity of jute fabrics modified with 17.5 % NaOH was established. During the oxidative modifications, significant changes in jute fibers’ chemical composition and structure (i.e., lignin removal and more homogeneous middle lamellae) occurred which further resulted in enhanced jute fabrics’ water retention power and capillarity as well as fibers’ swelling up to 80 %, 75 %, and 54 %, compared to the raw jute, respectively. In order to move towards a circular economy and to ensure the recycling and re-use of recycled fabrics, the jute fabrics with enhanced sorption properties were evaluated as biosorbents for anthraquinone dye C. I. Acid Blue 111. The obtained results revealed that the jute fabrics’ maximum biosorption capacities for this dye ranged from 12.94 to 18.97 mg/g, while the equilibrium adsorption data were highly consistent with the Langmuir isotherm model. Moreover, based on the predicted dye pKa values, the fabric zeta potential, content of carboxyl and aldehyde groups as well as hydrogen bond intensity (determined by ATR-FTIR), a possible mechanism of the dye biosorption onto jute fabric waste was proposed.
PB  - Elsevier
T2  - Industrial Crops and Products
T1  - Obtaining jute fabrics with enhanced sorption properties and “closing the loop” of their lifecycle
VL  - 171
SP  - 113913
DO  - 10.1016/j.indcrop.2021.113913
ER  - 

@article{
author = "Ivanovska, Aleksandra and Lađarević, Jelena and Pavun, Leposava and Dojčinović, Biljana P. and Cvijetić, Ilija and Mijin, Dušan and Kostić, Mirjana M.",
year = "2021",
abstract = "The objective of this investigation was to obtain jute fabrics with enhanced sorption properties (by using simple and cost-effective alkali and oxidative modifications) and a long life cycle. The applied alkali modifications lead to hemicellulose removal and decreased the fibers’ crystallinity, both contributing to enhanced fibers’ sorption properties, i.e., water retention power and degree of fibers’ swelling up to 49 % and 70 %, respectively. A connection between cellulose polymorphs’ (cellulose I and cellulose II) contents (determined by XRD), fibers’ surface morphology (verified by FESEM), fabrics’ crimp, and capillarity of jute fabrics modified with 17.5 % NaOH was established. During the oxidative modifications, significant changes in jute fibers’ chemical composition and structure (i.e., lignin removal and more homogeneous middle lamellae) occurred which further resulted in enhanced jute fabrics’ water retention power and capillarity as well as fibers’ swelling up to 80 %, 75 %, and 54 %, compared to the raw jute, respectively. In order to move towards a circular economy and to ensure the recycling and re-use of recycled fabrics, the jute fabrics with enhanced sorption properties were evaluated as biosorbents for anthraquinone dye C. I. Acid Blue 111. The obtained results revealed that the jute fabrics’ maximum biosorption capacities for this dye ranged from 12.94 to 18.97 mg/g, while the equilibrium adsorption data were highly consistent with the Langmuir isotherm model. Moreover, based on the predicted dye pKa values, the fabric zeta potential, content of carboxyl and aldehyde groups as well as hydrogen bond intensity (determined by ATR-FTIR), a possible mechanism of the dye biosorption onto jute fabric waste was proposed.",
publisher = "Elsevier",
journal = "Industrial Crops and Products",
title = "Obtaining jute fabrics with enhanced sorption properties and “closing the loop” of their lifecycle",
volume = "171",
pages = "113913",
doi = "10.1016/j.indcrop.2021.113913"
}

Ivanovska, A., Lađarević, J., Pavun, L., Dojčinović, B. P., Cvijetić, I., Mijin, D.,& Kostić, M. M.. (2021). Obtaining jute fabrics with enhanced sorption properties and “closing the loop” of their lifecycle. in Industrial Crops and Products
Elsevier., 171, 113913.
https://doi.org/10.1016/j.indcrop.2021.113913

Ivanovska A, Lađarević J, Pavun L, Dojčinović BP, Cvijetić I, Mijin D, Kostić MM. Obtaining jute fabrics with enhanced sorption properties and “closing the loop” of their lifecycle. in Industrial Crops and Products. 2021;171:113913.
doi:10.1016/j.indcrop.2021.113913 .

Ivanovska, Aleksandra, Lađarević, Jelena, Pavun, Leposava, Dojčinović, Biljana P., Cvijetić, Ilija, Mijin, Dušan, Kostić, Mirjana M., "Obtaining jute fabrics with enhanced sorption properties and “closing the loop” of their lifecycle" in Industrial Crops and Products, 171 (2021):113913,
https://doi.org/10.1016/j.indcrop.2021.113913 . .

TY  - DATA
AU  - Ivanovska, Aleksandra
AU  - Lađarević, Jelena
AU  - Pavun, Leposava
AU  - Dojčinović, Biljana P.
AU  - Cvijetić, Ilija
AU  - Mijin, Dušan
AU  - Kostić, Mirjana M.
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4745
PB  - Elsevier
T2  - Industrial Crops and Products
T1  - Supplementary data for the article: Ivanovska, A.; Lađarević, J.; Pavun, L.; Dojčinović, B.; Cvijetić, I.; Mijin, D.; Kostić, M. Obtaining Jute Fabrics with Enhanced Sorption Properties and “Closing the Loop” of Their Lifecycle. Industrial Crops and Products 2021, 171, 113913. https://doi.org/10.1016/j.indcrop.2021.113913.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4745
ER  - 

@misc{
author = "Ivanovska, Aleksandra and Lađarević, Jelena and Pavun, Leposava and Dojčinović, Biljana P. and Cvijetić, Ilija and Mijin, Dušan and Kostić, Mirjana M.",
year = "2021",
publisher = "Elsevier",
journal = "Industrial Crops and Products",
title = "Supplementary data for the article: Ivanovska, A.; Lađarević, J.; Pavun, L.; Dojčinović, B.; Cvijetić, I.; Mijin, D.; Kostić, M. Obtaining Jute Fabrics with Enhanced Sorption Properties and “Closing the Loop” of Their Lifecycle. Industrial Crops and Products 2021, 171, 113913. https://doi.org/10.1016/j.indcrop.2021.113913.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4745"
}

Ivanovska, A., Lađarević, J., Pavun, L., Dojčinović, B. P., Cvijetić, I., Mijin, D.,& Kostić, M. M.. (2021). Supplementary data for the article: Ivanovska, A.; Lađarević, J.; Pavun, L.; Dojčinović, B.; Cvijetić, I.; Mijin, D.; Kostić, M. Obtaining Jute Fabrics with Enhanced Sorption Properties and “Closing the Loop” of Their Lifecycle. Industrial Crops and Products 2021, 171, 113913. https://doi.org/10.1016/j.indcrop.2021.113913.. in Industrial Crops and Products
Elsevier..
https://hdl.handle.net/21.15107/rcub_cherry_4745

Ivanovska A, Lađarević J, Pavun L, Dojčinović BP, Cvijetić I, Mijin D, Kostić MM. Supplementary data for the article: Ivanovska, A.; Lađarević, J.; Pavun, L.; Dojčinović, B.; Cvijetić, I.; Mijin, D.; Kostić, M. Obtaining Jute Fabrics with Enhanced Sorption Properties and “Closing the Loop” of Their Lifecycle. Industrial Crops and Products 2021, 171, 113913. https://doi.org/10.1016/j.indcrop.2021.113913.. in Industrial Crops and Products. 2021;.
https://hdl.handle.net/21.15107/rcub_cherry_4745 .

Ivanovska, Aleksandra, Lađarević, Jelena, Pavun, Leposava, Dojčinović, Biljana P., Cvijetić, Ilija, Mijin, Dušan, Kostić, Mirjana M., "Supplementary data for the article: Ivanovska, A.; Lađarević, J.; Pavun, L.; Dojčinović, B.; Cvijetić, I.; Mijin, D.; Kostić, M. Obtaining Jute Fabrics with Enhanced Sorption Properties and “Closing the Loop” of Their Lifecycle. Industrial Crops and Products 2021, 171, 113913. https://doi.org/10.1016/j.indcrop.2021.113913." in Industrial Crops and Products (2021),
https://hdl.handle.net/21.15107/rcub_cherry_4745 .