Juranić, N.

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  • Juranić, N. (15)
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Author's Bibliography

H-1 NMR dynamic study of thermal Z/E isomerization of 5-substituted 2-alkylidene-4-oxothiazolidine derivatives: Barriers to rotation about C=C bond

Marković, R.; Baranac-Stojanović, Marija; Juranić, N.; Macura, S.; Cekic, I.; Minić, Dragica M.

(Elsevier Science Bv, Amsterdam, 2006)

TY  - JOUR
AU  - Marković, R.
AU  - Baranac-Stojanović, Marija
AU  - Juranić, N.
AU  - Macura, S.
AU  - Cekic, I.
AU  - Minić, Dragica M.
PY  - 2006
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/813
AB  - The rotational barriers between the configurational isomers of two structurally related push-pull 4-oxothiazolidines, differing in the number of exocyclic C=C bonds, have been determined by dynamic H-1 NMR spectroscopy. The equilibrium mixture of (5-ethoxy-carbonylmethyl-4-oxothiazolidin-2-ylidene)-1-phenylethanone (1a) in CDCl3 at room temperature to 333 K consists of the E- and Z-isomers which are separated by an energy barrier Delta G(#) 98.5 kJ/mol (at 298 K). The variable-temperature H-1 NMR data for the isomerization of ethyl (5-ethoxycarbonylmethylidene-4-oxothiazolidin-2-ylidene)ethanoate (2b) in DMSO-d(6), possessing the two exocyclic C=C bonds at the C(2)- and C(5)-positions, indicate that the rotational barrier Delta G(#) separating the (2E,5Z)-2b and (2Z,5Z)-2b isomers is 100.2 kJ/mol (at 298 K). In a polar solvent-dependent equilibrium the major (2Z,5Z)-form ( gt  90%) is stabilized by the intermolecular resonance-assisted hydrogen bonding and strong 1,5-type (SO)-O-... interactions within the S-C=C-C=O entity. The C-13 NMR Delta delta(C(2)C(2')) values, ranging from 58 to 69 ppm in 1a-d and 49-58 ppm in 2a-d, correlate with the degree of the push-pull character of the exocyclic C(2)=C(2') bond, which increases with the electron withdrawing ability of the substituents at the vinylic C(2') position in the following order: COPh similar to COEt  gt  CONHPh  gt  CONHCH2CH2Ph. The decrease of the Delta delta(C(2)C(2')) values in 2a-d has been discussed for the first time in terms of an estimation of the electron donor capacity of the -S- fragment on the polarization of the C=C bonds. (c) 2006 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Journal of Molecular Structure
T1  - H-1 NMR dynamic study of thermal Z/E isomerization of 5-substituted 2-alkylidene-4-oxothiazolidine derivatives: Barriers to rotation about C=C bond
VL  - 800
IS  - 1-3
SP  - 85
EP  - 92
DO  - 10.1016/j.molstruc.2006.03.075
ER  - 
@article{
author = "Marković, R. and Baranac-Stojanović, Marija and Juranić, N. and Macura, S. and Cekic, I. and Minić, Dragica M.",
year = "2006",
abstract = "The rotational barriers between the configurational isomers of two structurally related push-pull 4-oxothiazolidines, differing in the number of exocyclic C=C bonds, have been determined by dynamic H-1 NMR spectroscopy. The equilibrium mixture of (5-ethoxy-carbonylmethyl-4-oxothiazolidin-2-ylidene)-1-phenylethanone (1a) in CDCl3 at room temperature to 333 K consists of the E- and Z-isomers which are separated by an energy barrier Delta G(#) 98.5 kJ/mol (at 298 K). The variable-temperature H-1 NMR data for the isomerization of ethyl (5-ethoxycarbonylmethylidene-4-oxothiazolidin-2-ylidene)ethanoate (2b) in DMSO-d(6), possessing the two exocyclic C=C bonds at the C(2)- and C(5)-positions, indicate that the rotational barrier Delta G(#) separating the (2E,5Z)-2b and (2Z,5Z)-2b isomers is 100.2 kJ/mol (at 298 K). In a polar solvent-dependent equilibrium the major (2Z,5Z)-form ( gt  90%) is stabilized by the intermolecular resonance-assisted hydrogen bonding and strong 1,5-type (SO)-O-... interactions within the S-C=C-C=O entity. The C-13 NMR Delta delta(C(2)C(2')) values, ranging from 58 to 69 ppm in 1a-d and 49-58 ppm in 2a-d, correlate with the degree of the push-pull character of the exocyclic C(2)=C(2') bond, which increases with the electron withdrawing ability of the substituents at the vinylic C(2') position in the following order: COPh similar to COEt  gt  CONHPh  gt  CONHCH2CH2Ph. The decrease of the Delta delta(C(2)C(2')) values in 2a-d has been discussed for the first time in terms of an estimation of the electron donor capacity of the -S- fragment on the polarization of the C=C bonds. (c) 2006 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Molecular Structure",
title = "H-1 NMR dynamic study of thermal Z/E isomerization of 5-substituted 2-alkylidene-4-oxothiazolidine derivatives: Barriers to rotation about C=C bond",
volume = "800",
number = "1-3",
pages = "85-92",
doi = "10.1016/j.molstruc.2006.03.075"
}
Marković, R., Baranac-Stojanović, M., Juranić, N., Macura, S., Cekic, I.,& Minić, D. M.. (2006). H-1 NMR dynamic study of thermal Z/E isomerization of 5-substituted 2-alkylidene-4-oxothiazolidine derivatives: Barriers to rotation about C=C bond. in Journal of Molecular Structure
Elsevier Science Bv, Amsterdam., 800(1-3), 85-92.
https://doi.org/10.1016/j.molstruc.2006.03.075
Marković R, Baranac-Stojanović M, Juranić N, Macura S, Cekic I, Minić DM. H-1 NMR dynamic study of thermal Z/E isomerization of 5-substituted 2-alkylidene-4-oxothiazolidine derivatives: Barriers to rotation about C=C bond. in Journal of Molecular Structure. 2006;800(1-3):85-92.
doi:10.1016/j.molstruc.2006.03.075 .
Marković, R., Baranac-Stojanović, Marija, Juranić, N., Macura, S., Cekic, I., Minić, Dragica M., "H-1 NMR dynamic study of thermal Z/E isomerization of 5-substituted 2-alkylidene-4-oxothiazolidine derivatives: Barriers to rotation about C=C bond" in Journal of Molecular Structure, 800, no. 1-3 (2006):85-92,
https://doi.org/10.1016/j.molstruc.2006.03.075 . .
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Conformational analysis of guaianolide-type sesquiterpene lactones by low-temperature NMR spectroscopy and semiempirical calculations

Milosavljevic, S; Juranić, Ivan O.; Bulatović, V.; Macura, S.; Juranić, N.; Limbach, HH; Weisz, K; Vajs, Vlatka; Todorović, Nevena M.

(Kluwer Academic/Plenum Publ, New York, 2004)

TY  - JOUR
AU  - Milosavljevic, S
AU  - Juranić, Ivan O.
AU  - Bulatović, V.
AU  - Macura, S.
AU  - Juranić, N.
AU  - Limbach, HH
AU  - Weisz, K
AU  - Vajs, Vlatka
AU  - Todorović, Nevena M.
PY  - 2004
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/581
AB  - Conformational analysis of 9alpha-acetoxycumambrine A 1 and 8-O-isobutiryl-9alpha-acetoxycumambrine B 2 was carried out by low-temperature NMR studies. Results suggested that lactones 1 and 2 are mixtures of two distinctive conformers, I and II. Based on low-temperature H-1 NMR spectra, in four solvents, the thermodynamic parameters of I reversible arrow II exchange process were assessed. Energy of activation of I -- gt  II reaction was obtained by dynamic NMR simulations for both compounds. Results revealed that conformational exchange of lactones 1 and 2 occurs due to "chair reversible arrow twisted chair" interconversion of a heptane ring. The same PM3 semiempirical method was applied for geometry optimization of lactones 1 and 2, as well as of 9alpha-hydroxycumambrine A 3, 9alpha-acetoxycumambrine B 4, and cumambrine B 5.
PB  - Kluwer Academic/Plenum Publ, New York
T2  - Structural Chemistry
T1  - Conformational analysis of guaianolide-type sesquiterpene lactones by low-temperature NMR spectroscopy and semiempirical calculations
VL  - 15
IS  - 3
SP  - 237
EP  - 245
DO  - 10.1023/B:STUC.0000021533.65546.57
ER  - 
@article{
author = "Milosavljevic, S and Juranić, Ivan O. and Bulatović, V. and Macura, S. and Juranić, N. and Limbach, HH and Weisz, K and Vajs, Vlatka and Todorović, Nevena M.",
year = "2004",
abstract = "Conformational analysis of 9alpha-acetoxycumambrine A 1 and 8-O-isobutiryl-9alpha-acetoxycumambrine B 2 was carried out by low-temperature NMR studies. Results suggested that lactones 1 and 2 are mixtures of two distinctive conformers, I and II. Based on low-temperature H-1 NMR spectra, in four solvents, the thermodynamic parameters of I reversible arrow II exchange process were assessed. Energy of activation of I -- gt  II reaction was obtained by dynamic NMR simulations for both compounds. Results revealed that conformational exchange of lactones 1 and 2 occurs due to "chair reversible arrow twisted chair" interconversion of a heptane ring. The same PM3 semiempirical method was applied for geometry optimization of lactones 1 and 2, as well as of 9alpha-hydroxycumambrine A 3, 9alpha-acetoxycumambrine B 4, and cumambrine B 5.",
publisher = "Kluwer Academic/Plenum Publ, New York",
journal = "Structural Chemistry",
title = "Conformational analysis of guaianolide-type sesquiterpene lactones by low-temperature NMR spectroscopy and semiempirical calculations",
volume = "15",
number = "3",
pages = "237-245",
doi = "10.1023/B:STUC.0000021533.65546.57"
}
Milosavljevic, S., Juranić, I. O., Bulatović, V., Macura, S., Juranić, N., Limbach, H., Weisz, K., Vajs, V.,& Todorović, N. M.. (2004). Conformational analysis of guaianolide-type sesquiterpene lactones by low-temperature NMR spectroscopy and semiempirical calculations. in Structural Chemistry
Kluwer Academic/Plenum Publ, New York., 15(3), 237-245.
https://doi.org/10.1023/B:STUC.0000021533.65546.57
Milosavljevic S, Juranić IO, Bulatović V, Macura S, Juranić N, Limbach H, Weisz K, Vajs V, Todorović NM. Conformational analysis of guaianolide-type sesquiterpene lactones by low-temperature NMR spectroscopy and semiempirical calculations. in Structural Chemistry. 2004;15(3):237-245.
doi:10.1023/B:STUC.0000021533.65546.57 .
Milosavljevic, S, Juranić, Ivan O., Bulatović, V., Macura, S., Juranić, N., Limbach, HH, Weisz, K, Vajs, Vlatka, Todorović, Nevena M., "Conformational analysis of guaianolide-type sesquiterpene lactones by low-temperature NMR spectroscopy and semiempirical calculations" in Structural Chemistry, 15, no. 3 (2004):237-245,
https://doi.org/10.1023/B:STUC.0000021533.65546.57 . .
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Sesquiterpene lactones from the aerial parts of Inula oculus-christi

Vajs, Vlatka; Nevescanin, M; Macura, S.; Juranić, N.; Menković, N.; Milosavljevic, S

(Elsevier Science Bv, Amsterdam, 2003)

TY  - JOUR
AU  - Vajs, Vlatka
AU  - Nevescanin, M
AU  - Macura, S.
AU  - Juranić, N.
AU  - Menković, N.
AU  - Milosavljevic, S
PY  - 2003
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/143
AB  - Pulchellin E (1) and gaillardin (2) were isolated from the aerial parts of Inula oculus-christi, along with the flavone hispidulin. The C-13-NMR chemical shifts of 1 and 2 are reported. (C) 2003 Elsevier Science B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Fitoterapia
T1  - Sesquiterpene lactones from the aerial parts of Inula oculus-christi
VL  - 74
IS  - 5
SP  - 508
EP  - 510
DO  - 10.1016/S0367-326X(03)00115-1
ER  - 
@article{
author = "Vajs, Vlatka and Nevescanin, M and Macura, S. and Juranić, N. and Menković, N. and Milosavljevic, S",
year = "2003",
abstract = "Pulchellin E (1) and gaillardin (2) were isolated from the aerial parts of Inula oculus-christi, along with the flavone hispidulin. The C-13-NMR chemical shifts of 1 and 2 are reported. (C) 2003 Elsevier Science B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Fitoterapia",
title = "Sesquiterpene lactones from the aerial parts of Inula oculus-christi",
volume = "74",
number = "5",
pages = "508-510",
doi = "10.1016/S0367-326X(03)00115-1"
}
Vajs, V., Nevescanin, M., Macura, S., Juranić, N., Menković, N.,& Milosavljevic, S.. (2003). Sesquiterpene lactones from the aerial parts of Inula oculus-christi. in Fitoterapia
Elsevier Science Bv, Amsterdam., 74(5), 508-510.
https://doi.org/10.1016/S0367-326X(03)00115-1
Vajs V, Nevescanin M, Macura S, Juranić N, Menković N, Milosavljevic S. Sesquiterpene lactones from the aerial parts of Inula oculus-christi. in Fitoterapia. 2003;74(5):508-510.
doi:10.1016/S0367-326X(03)00115-1 .
Vajs, Vlatka, Nevescanin, M, Macura, S., Juranić, N., Menković, N., Milosavljevic, S, "Sesquiterpene lactones from the aerial parts of Inula oculus-christi" in Fitoterapia, 74, no. 5 (2003):508-510,
https://doi.org/10.1016/S0367-326X(03)00115-1 . .
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Further degradation product of hyperforin from Hypericum perforatum (St. John's Wort)

Vajs, Vlatka; Vugdelija, S; Trifunović, Snežana S.; Karadžić, Ivanka M.; Juranić, N.; Macura, S.; Milosavljevic, S

(Elsevier Science Bv, Amsterdam, 2003)

TY  - JOUR
AU  - Vajs, Vlatka
AU  - Vugdelija, S
AU  - Trifunović, Snežana S.
AU  - Karadžić, Ivanka M.
AU  - Juranić, N.
AU  - Macura, S.
AU  - Milosavljevic, S
PY  - 2003
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/142
AB  - Repeated examination of the aerial parts of Hypericum Perfomtum yielded a new degradation product of hyperforin (1) namely deoxyfurohyperforin A (2), together with the previously identified furohyperforin (3), furoadhyperforin (4), furohyperforin A (5a and 5b), pyrano[7,28-b]hyperforin (6) and 3-methyl-4,6-di(3-methyl-2-butenyl)-2-(2-methyl-1-oxopropyl)-3-(4-methyl-3-pentenyl)-cyclohexanone (7). The antimicrobial activity of the compounds 3, 5a and 5b, 6 and 7 was tested against Staphylococcus aureus, Candida albicans, Bacillus subtilis and Escherichia coli. (C) 2003 Elsevier Science B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Fitoterapia
T1  - Further degradation product of hyperforin from Hypericum perforatum (St. John's Wort)
VL  - 74
IS  - 5
SP  - 439
EP  - 444
DO  - 10.1016/S0367-326X(03)00114-X
ER  - 
@article{
author = "Vajs, Vlatka and Vugdelija, S and Trifunović, Snežana S. and Karadžić, Ivanka M. and Juranić, N. and Macura, S. and Milosavljevic, S",
year = "2003",
abstract = "Repeated examination of the aerial parts of Hypericum Perfomtum yielded a new degradation product of hyperforin (1) namely deoxyfurohyperforin A (2), together with the previously identified furohyperforin (3), furoadhyperforin (4), furohyperforin A (5a and 5b), pyrano[7,28-b]hyperforin (6) and 3-methyl-4,6-di(3-methyl-2-butenyl)-2-(2-methyl-1-oxopropyl)-3-(4-methyl-3-pentenyl)-cyclohexanone (7). The antimicrobial activity of the compounds 3, 5a and 5b, 6 and 7 was tested against Staphylococcus aureus, Candida albicans, Bacillus subtilis and Escherichia coli. (C) 2003 Elsevier Science B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Fitoterapia",
title = "Further degradation product of hyperforin from Hypericum perforatum (St. John's Wort)",
volume = "74",
number = "5",
pages = "439-444",
doi = "10.1016/S0367-326X(03)00114-X"
}
Vajs, V., Vugdelija, S., Trifunović, S. S., Karadžić, I. M., Juranić, N., Macura, S.,& Milosavljevic, S.. (2003). Further degradation product of hyperforin from Hypericum perforatum (St. John's Wort). in Fitoterapia
Elsevier Science Bv, Amsterdam., 74(5), 439-444.
https://doi.org/10.1016/S0367-326X(03)00114-X
Vajs V, Vugdelija S, Trifunović SS, Karadžić IM, Juranić N, Macura S, Milosavljevic S. Further degradation product of hyperforin from Hypericum perforatum (St. John's Wort). in Fitoterapia. 2003;74(5):439-444.
doi:10.1016/S0367-326X(03)00114-X .
Vajs, Vlatka, Vugdelija, S, Trifunović, Snežana S., Karadžić, Ivanka M., Juranić, N., Macura, S., Milosavljevic, S, "Further degradation product of hyperforin from Hypericum perforatum (St. John's Wort)" in Fitoterapia, 74, no. 5 (2003):439-444,
https://doi.org/10.1016/S0367-326X(03)00114-X . .
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Mixed cobalt(III) complexes with aromatic amino acids and diamine. Part IV. Influence of noncovalent intraand interligand interactions on rotamer population of the S-phenylalaninato and S-tyrosinato side groups in (1,2-diaminoethane)bis(S-aminocarboxylato

Miodragović Đenana U.; Milosavljević, Slobodan M.; Malinar, M.J.; Celap, MB; Todorović, Nevena M.; Juranić, N.

(Taylor & Francis Ltd, Abingdon, 2002)

TY  - JOUR
AU  - Miodragović Đenana U.
AU  - Milosavljević, Slobodan M.
AU  - Malinar, M.J.
AU  - Celap, MB
AU  - Todorović, Nevena M.
AU  - Juranić, N.
PY  - 2002
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/537
AB  - Rotamer population of S-tyrosinato and S-phenylalaninato ligands side groups in diastereomers of (1,2-diaminoethane)bis(S-aminocarboxylato)cobalt(III) complexes is calculated by vicinal alpha and beta proton coupling constant analysis. The effect of noncovalent intra- and interligand interactions on the population of rotamers in D2O solution is discussed. It has been established that in all the complexes investigated the most abundant is rotamer t, in which aromatic voluminous moiety and carboxylic group are in an anti position. In almost all complexes the lowest content is of rotamer g, in which these two groups are in the nearest position. Relatively high population of rotamer b in complex 5 tyr, in spite of high steric hindrances, is due to intra- and interligand NH... pi interactions.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Enantiomer
T1  - Mixed cobalt(III) complexes with aromatic amino acids and diamine. Part IV. Influence of noncovalent intraand interligand interactions on rotamer population of the S-phenylalaninato and S-tyrosinato side groups in (1,2-diaminoethane)bis(S-aminocarboxylato
VL  - 7
IS  - 6
SP  - 375
EP  - 382
DO  - 10.1080/10242430215714
ER  - 
@article{
author = "Miodragović Đenana U. and Milosavljević, Slobodan M. and Malinar, M.J. and Celap, MB and Todorović, Nevena M. and Juranić, N.",
year = "2002",
abstract = "Rotamer population of S-tyrosinato and S-phenylalaninato ligands side groups in diastereomers of (1,2-diaminoethane)bis(S-aminocarboxylato)cobalt(III) complexes is calculated by vicinal alpha and beta proton coupling constant analysis. The effect of noncovalent intra- and interligand interactions on the population of rotamers in D2O solution is discussed. It has been established that in all the complexes investigated the most abundant is rotamer t, in which aromatic voluminous moiety and carboxylic group are in an anti position. In almost all complexes the lowest content is of rotamer g, in which these two groups are in the nearest position. Relatively high population of rotamer b in complex 5 tyr, in spite of high steric hindrances, is due to intra- and interligand NH... pi interactions.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Enantiomer",
title = "Mixed cobalt(III) complexes with aromatic amino acids and diamine. Part IV. Influence of noncovalent intraand interligand interactions on rotamer population of the S-phenylalaninato and S-tyrosinato side groups in (1,2-diaminoethane)bis(S-aminocarboxylato",
volume = "7",
number = "6",
pages = "375-382",
doi = "10.1080/10242430215714"
}
Miodragović Đenana U., Milosavljević, S. M., Malinar, M.J., Celap, M., Todorović, N. M.,& Juranić, N.. (2002). Mixed cobalt(III) complexes with aromatic amino acids and diamine. Part IV. Influence of noncovalent intraand interligand interactions on rotamer population of the S-phenylalaninato and S-tyrosinato side groups in (1,2-diaminoethane)bis(S-aminocarboxylato. in Enantiomer
Taylor & Francis Ltd, Abingdon., 7(6), 375-382.
https://doi.org/10.1080/10242430215714
Miodragović Đenana U., Milosavljević SM, Malinar M, Celap M, Todorović NM, Juranić N. Mixed cobalt(III) complexes with aromatic amino acids and diamine. Part IV. Influence of noncovalent intraand interligand interactions on rotamer population of the S-phenylalaninato and S-tyrosinato side groups in (1,2-diaminoethane)bis(S-aminocarboxylato. in Enantiomer. 2002;7(6):375-382.
doi:10.1080/10242430215714 .
Miodragović Đenana U., Milosavljević, Slobodan M., Malinar, M.J., Celap, MB, Todorović, Nevena M., Juranić, N., "Mixed cobalt(III) complexes with aromatic amino acids and diamine. Part IV. Influence of noncovalent intraand interligand interactions on rotamer population of the S-phenylalaninato and S-tyrosinato side groups in (1,2-diaminoethane)bis(S-aminocarboxylato" in Enantiomer, 7, no. 6 (2002):375-382,
https://doi.org/10.1080/10242430215714 . .
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5

Xanthones from Swertia punctata

Menković, N.; Savikin-Fodulovic, K; Bulatović, V.; Aljančić, Ivana; Juranić, N.; Macura, S.; Vajs, Vlatka; Milosavljevic, S

(Pergamon-Elsevier Science Ltd, Oxford, 2002)

TY  - JOUR
AU  - Menković, N.
AU  - Savikin-Fodulovic, K
AU  - Bulatović, V.
AU  - Aljančić, Ivana
AU  - Juranić, N.
AU  - Macura, S.
AU  - Vajs, Vlatka
AU  - Milosavljevic, S
PY  - 2002
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/515
AB  - Isolation of 1-O-primeverosyl-3,8-dihydroxy-5-methoxyxanthone and 1-O-gentiobiosyl- 3,7-dimethoxy-8-hydroxyxanthone, along with five known xanthones, isobellidifolin, methylbellidifolin, isoswertianin, methylswertianin and norswertianin-1-O-beta-D-glucoside, from the roots of Swertia punctata is reported. In the aerial parts four xanthones, bellidifolin, methylbellidifolin, swertianolin and mangiferin, and flavone-C-gluco side, isoorientin were identified. The chemotaxonomic and pharmacological significance of these results is discussed. (C) 2002 Elsevier Science Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Phytochemistry
T1  - Xanthones from Swertia punctata
VL  - 61
IS  - 4
SP  - 415
EP  - 420
DO  - 10.1016/S0031-9422(02)00231-5
ER  - 
@article{
author = "Menković, N. and Savikin-Fodulovic, K and Bulatović, V. and Aljančić, Ivana and Juranić, N. and Macura, S. and Vajs, Vlatka and Milosavljevic, S",
year = "2002",
abstract = "Isolation of 1-O-primeverosyl-3,8-dihydroxy-5-methoxyxanthone and 1-O-gentiobiosyl- 3,7-dimethoxy-8-hydroxyxanthone, along with five known xanthones, isobellidifolin, methylbellidifolin, isoswertianin, methylswertianin and norswertianin-1-O-beta-D-glucoside, from the roots of Swertia punctata is reported. In the aerial parts four xanthones, bellidifolin, methylbellidifolin, swertianolin and mangiferin, and flavone-C-gluco side, isoorientin were identified. The chemotaxonomic and pharmacological significance of these results is discussed. (C) 2002 Elsevier Science Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Phytochemistry",
title = "Xanthones from Swertia punctata",
volume = "61",
number = "4",
pages = "415-420",
doi = "10.1016/S0031-9422(02)00231-5"
}
Menković, N., Savikin-Fodulovic, K., Bulatović, V., Aljančić, I., Juranić, N., Macura, S., Vajs, V.,& Milosavljevic, S.. (2002). Xanthones from Swertia punctata. in Phytochemistry
Pergamon-Elsevier Science Ltd, Oxford., 61(4), 415-420.
https://doi.org/10.1016/S0031-9422(02)00231-5
Menković N, Savikin-Fodulovic K, Bulatović V, Aljančić I, Juranić N, Macura S, Vajs V, Milosavljevic S. Xanthones from Swertia punctata. in Phytochemistry. 2002;61(4):415-420.
doi:10.1016/S0031-9422(02)00231-5 .
Menković, N., Savikin-Fodulovic, K, Bulatović, V., Aljančić, Ivana, Juranić, N., Macura, S., Vajs, Vlatka, Milosavljevic, S, "Xanthones from Swertia punctata" in Phytochemistry, 61, no. 4 (2002):415-420,
https://doi.org/10.1016/S0031-9422(02)00231-5 . .
35
35
41
32

Mixed cobalt(III) complexes with aromatic amino acids and diamine. Part II. Synthesis and configuration of (1,2-diaminoethane)bis(L-tyrosinato)-cobalt(III)complex diastereomers. The crystal structure of the Delta-C-1-cis(O) diastereomer

Miodragović Đenana U.; Bogdanović, Goran A.; Milosavljević, Slobodan M.; Malinar, M.J.; Celap, MB; Spasojevic-de Bire, A; Macura, S.; Juranić, N.

(Gordon Breach Publishing, Taylor & Francis Group, Philadelphia, 2001)

TY  - JOUR
AU  - Miodragović Đenana U.
AU  - Bogdanović, Goran A.
AU  - Milosavljević, Slobodan M.
AU  - Malinar, M.J.
AU  - Celap, MB
AU  - Spasojevic-de Bire, A
AU  - Macura, S.
AU  - Juranić, N.
PY  - 2001
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/476
AB  - In the reaction of trans-[CoCl2(en)(2)](+) with L-tyrosine all six theoretically possible diastereomers of the (1,2-diaminoethane)bis(L-tyrosinato)cobalt(III) complex were formed. The following five were isolated: Delta -trans(O); and Lambda- and Delta -C-2-cis(O) and Lambda- and Delta -C-1-cis(O) diastereomers, while the Delta -trans(O) diastereomer was only detected in the corresponding eluate. Separation of the obtained diastereomers was performed by chromatography on a Dowex 1 x 4 column. Characterization of the isolated diastereomers was carried out by means of elemental analysis, electronic absorption, circular dichroic, H-1 and C-13 NMR spectra, and by x-ray crystal structure analysis in the case of the Delta -C-1-cis(O) diastereomer. We established the general rule of preference of diasteromers formation in complexes of [Co(L-aa)(2)diamine](+) (L-aa = L-amino acid anion; diamine = 1,2-diaminoethane or 1,3-diaminopropane) type.
PB  - Gordon Breach Publishing, Taylor & Francis Group, Philadelphia
T2  - Enantiomer
T1  - Mixed cobalt(III) complexes with aromatic amino acids and diamine. Part II. Synthesis and configuration of (1,2-diaminoethane)bis(L-tyrosinato)-cobalt(III)complex diastereomers. The crystal structure of the Delta-C-1-cis(O) diastereomer
VL  - 6
IS  - 5
SP  - 299
EP  - 308
UR  - https://hdl.handle.net/21.15107/rcub_cherry_476
ER  - 
@article{
author = "Miodragović Đenana U. and Bogdanović, Goran A. and Milosavljević, Slobodan M. and Malinar, M.J. and Celap, MB and Spasojevic-de Bire, A and Macura, S. and Juranić, N.",
year = "2001",
abstract = "In the reaction of trans-[CoCl2(en)(2)](+) with L-tyrosine all six theoretically possible diastereomers of the (1,2-diaminoethane)bis(L-tyrosinato)cobalt(III) complex were formed. The following five were isolated: Delta -trans(O); and Lambda- and Delta -C-2-cis(O) and Lambda- and Delta -C-1-cis(O) diastereomers, while the Delta -trans(O) diastereomer was only detected in the corresponding eluate. Separation of the obtained diastereomers was performed by chromatography on a Dowex 1 x 4 column. Characterization of the isolated diastereomers was carried out by means of elemental analysis, electronic absorption, circular dichroic, H-1 and C-13 NMR spectra, and by x-ray crystal structure analysis in the case of the Delta -C-1-cis(O) diastereomer. We established the general rule of preference of diasteromers formation in complexes of [Co(L-aa)(2)diamine](+) (L-aa = L-amino acid anion; diamine = 1,2-diaminoethane or 1,3-diaminopropane) type.",
publisher = "Gordon Breach Publishing, Taylor & Francis Group, Philadelphia",
journal = "Enantiomer",
title = "Mixed cobalt(III) complexes with aromatic amino acids and diamine. Part II. Synthesis and configuration of (1,2-diaminoethane)bis(L-tyrosinato)-cobalt(III)complex diastereomers. The crystal structure of the Delta-C-1-cis(O) diastereomer",
volume = "6",
number = "5",
pages = "299-308",
url = "https://hdl.handle.net/21.15107/rcub_cherry_476"
}
Miodragović Đenana U., Bogdanović, G. A., Milosavljević, S. M., Malinar, M.J., Celap, M., Spasojevic-de Bire, A., Macura, S.,& Juranić, N.. (2001). Mixed cobalt(III) complexes with aromatic amino acids and diamine. Part II. Synthesis and configuration of (1,2-diaminoethane)bis(L-tyrosinato)-cobalt(III)complex diastereomers. The crystal structure of the Delta-C-1-cis(O) diastereomer. in Enantiomer
Gordon Breach Publishing, Taylor & Francis Group, Philadelphia., 6(5), 299-308.
https://hdl.handle.net/21.15107/rcub_cherry_476
Miodragović Đenana U., Bogdanović GA, Milosavljević SM, Malinar M, Celap M, Spasojevic-de Bire A, Macura S, Juranić N. Mixed cobalt(III) complexes with aromatic amino acids and diamine. Part II. Synthesis and configuration of (1,2-diaminoethane)bis(L-tyrosinato)-cobalt(III)complex diastereomers. The crystal structure of the Delta-C-1-cis(O) diastereomer. in Enantiomer. 2001;6(5):299-308.
https://hdl.handle.net/21.15107/rcub_cherry_476 .
Miodragović Đenana U., Bogdanović, Goran A., Milosavljević, Slobodan M., Malinar, M.J., Celap, MB, Spasojevic-de Bire, A, Macura, S., Juranić, N., "Mixed cobalt(III) complexes with aromatic amino acids and diamine. Part II. Synthesis and configuration of (1,2-diaminoethane)bis(L-tyrosinato)-cobalt(III)complex diastereomers. The crystal structure of the Delta-C-1-cis(O) diastereomer" in Enantiomer, 6, no. 5 (2001):299-308,
https://hdl.handle.net/21.15107/rcub_cherry_476 .
8
7

Further sesquiterpene lactones from Anthemis carpatica

Vajs, Vlatka; Todorović, Nevena M.; Bulatović, V.; Menković, N.; Macura, S.; Juranić, N.; Milosavljevic, S

(Pergamon-Elsevier Science Ltd, Oxford, 2000)

TY  - JOUR
AU  - Vajs, Vlatka
AU  - Todorović, Nevena M.
AU  - Bulatović, V.
AU  - Menković, N.
AU  - Macura, S.
AU  - Juranić, N.
AU  - Milosavljevic, S
PY  - 2000
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/440
AB  - A new germacranolide, (E)-1 alpha, 10 beta-opoxy-3 beta-acetoxy-6 alpha-hydroxygermacra-4,11(13)-dien-12,8 alpha-oxide, together with nine new highly oxygenated guaiadien-12,6 alpha-olides of anthemolide, and cumambrin type were identified in the repealed examination of the aerial parts of the flowering Anthemis carpatica. In addition, six known guaianolides belonging to the same groups. also isolated previously from A. carpatica, along with two guaianolides, 2 beta-hydroxyepiligustrin and cumambrin B, not found before in this species, were isolated this time. (C) 2000 Elsevier Science Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Phytochemistry
T1  - Further sesquiterpene lactones from Anthemis carpatica
VL  - 54
IS  - 6
SP  - 625
EP  - 633
DO  - 10.1016/S0031-9422(00)00160-6
ER  - 
@article{
author = "Vajs, Vlatka and Todorović, Nevena M. and Bulatović, V. and Menković, N. and Macura, S. and Juranić, N. and Milosavljevic, S",
year = "2000",
abstract = "A new germacranolide, (E)-1 alpha, 10 beta-opoxy-3 beta-acetoxy-6 alpha-hydroxygermacra-4,11(13)-dien-12,8 alpha-oxide, together with nine new highly oxygenated guaiadien-12,6 alpha-olides of anthemolide, and cumambrin type were identified in the repealed examination of the aerial parts of the flowering Anthemis carpatica. In addition, six known guaianolides belonging to the same groups. also isolated previously from A. carpatica, along with two guaianolides, 2 beta-hydroxyepiligustrin and cumambrin B, not found before in this species, were isolated this time. (C) 2000 Elsevier Science Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Phytochemistry",
title = "Further sesquiterpene lactones from Anthemis carpatica",
volume = "54",
number = "6",
pages = "625-633",
doi = "10.1016/S0031-9422(00)00160-6"
}
Vajs, V., Todorović, N. M., Bulatović, V., Menković, N., Macura, S., Juranić, N.,& Milosavljevic, S.. (2000). Further sesquiterpene lactones from Anthemis carpatica. in Phytochemistry
Pergamon-Elsevier Science Ltd, Oxford., 54(6), 625-633.
https://doi.org/10.1016/S0031-9422(00)00160-6
Vajs V, Todorović NM, Bulatović V, Menković N, Macura S, Juranić N, Milosavljevic S. Further sesquiterpene lactones from Anthemis carpatica. in Phytochemistry. 2000;54(6):625-633.
doi:10.1016/S0031-9422(00)00160-6 .
Vajs, Vlatka, Todorović, Nevena M., Bulatović, V., Menković, N., Macura, S., Juranić, N., Milosavljevic, S, "Further sesquiterpene lactones from Anthemis carpatica" in Phytochemistry, 54, no. 6 (2000):625-633,
https://doi.org/10.1016/S0031-9422(00)00160-6 . .
19
24
24
16

Flavones and sesquiterpene lactones from Achillea atrata subsp multifida: Antimicrobial activity

Aljančić, Ivana; Vajs, Vlatka; Menković, N.; Karadžić, Ivanka M.; Juranić, N.; Milosavljevic, S; Macura, S.

(Amer Chemical Soc, Washington, 1999)

TY  - JOUR
AU  - Aljančić, Ivana
AU  - Vajs, Vlatka
AU  - Menković, N.
AU  - Karadžić, Ivanka M.
AU  - Juranić, N.
AU  - Milosavljevic, S
AU  - Macura, S.
PY  - 1999
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/384
AB  - Four flavones (1-4) and nine sesquiterpene lactones (5-13), one of them (5) a new compound, were isolated from the aerial parts of Achillea atrata L. subsp. multifida. Although the crude extract demonstrated in vitro inhibitory activity against Candida albicans and Bacillus subtilis, all isolated flavones were active against B. subtilis. Flavones 1, 2, and 3 were also active against C. albicans, while 1 and 3 exhibited activity against E. coli, as well. None of the tested lactones (7, 9, 12, and 13) showed any antimicrobial activity.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Natural Products
T1  - Flavones and sesquiterpene lactones from Achillea atrata subsp multifida: Antimicrobial activity
VL  - 62
IS  - 6
SP  - 909
EP  - 911
DO  - 10.1021/np980536m
ER  - 
@article{
author = "Aljančić, Ivana and Vajs, Vlatka and Menković, N. and Karadžić, Ivanka M. and Juranić, N. and Milosavljevic, S and Macura, S.",
year = "1999",
abstract = "Four flavones (1-4) and nine sesquiterpene lactones (5-13), one of them (5) a new compound, were isolated from the aerial parts of Achillea atrata L. subsp. multifida. Although the crude extract demonstrated in vitro inhibitory activity against Candida albicans and Bacillus subtilis, all isolated flavones were active against B. subtilis. Flavones 1, 2, and 3 were also active against C. albicans, while 1 and 3 exhibited activity against E. coli, as well. None of the tested lactones (7, 9, 12, and 13) showed any antimicrobial activity.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Natural Products",
title = "Flavones and sesquiterpene lactones from Achillea atrata subsp multifida: Antimicrobial activity",
volume = "62",
number = "6",
pages = "909-911",
doi = "10.1021/np980536m"
}
Aljančić, I., Vajs, V., Menković, N., Karadžić, I. M., Juranić, N., Milosavljevic, S.,& Macura, S.. (1999). Flavones and sesquiterpene lactones from Achillea atrata subsp multifida: Antimicrobial activity. in Journal of Natural Products
Amer Chemical Soc, Washington., 62(6), 909-911.
https://doi.org/10.1021/np980536m
Aljančić I, Vajs V, Menković N, Karadžić IM, Juranić N, Milosavljevic S, Macura S. Flavones and sesquiterpene lactones from Achillea atrata subsp multifida: Antimicrobial activity. in Journal of Natural Products. 1999;62(6):909-911.
doi:10.1021/np980536m .
Aljančić, Ivana, Vajs, Vlatka, Menković, N., Karadžić, Ivanka M., Juranić, N., Milosavljevic, S, Macura, S., "Flavones and sesquiterpene lactones from Achillea atrata subsp multifida: Antimicrobial activity" in Journal of Natural Products, 62, no. 6 (1999):909-911,
https://doi.org/10.1021/np980536m . .
79
80
95
65

Highly oxygenated guaianolides from Anthemis cretica subsp. cretica

Vajs, Vlatka; Bulatović, V.; Fodulovic-Savikin, K; Menković, N.; Macura, S.; Juranić, N.; Milosavljevic, S

(Pergamon-Elsevier Science Ltd, Oxford, 1999)

TY  - JOUR
AU  - Vajs, Vlatka
AU  - Bulatović, V.
AU  - Fodulovic-Savikin, K
AU  - Menković, N.
AU  - Macura, S.
AU  - Juranić, N.
AU  - Milosavljevic, S
PY  - 1999
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/408
AB  - Two new guaianolides, i.e. anthemolide B and 8-O-angeloyl-9-O-acetylanethemolide B, in addition to 12 known closely related guaianolides were identified in the aerial parts of the flowering plant Anthemis cretica subsp. cretica. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Phytochemistry
T1  - Highly oxygenated guaianolides from Anthemis cretica subsp. cretica
VL  - 50
IS  - 2
SP  - 287
EP  - 291
DO  - 10.1016/S0031-9422(98)00504-4
ER  - 
@article{
author = "Vajs, Vlatka and Bulatović, V. and Fodulovic-Savikin, K and Menković, N. and Macura, S. and Juranić, N. and Milosavljevic, S",
year = "1999",
abstract = "Two new guaianolides, i.e. anthemolide B and 8-O-angeloyl-9-O-acetylanethemolide B, in addition to 12 known closely related guaianolides were identified in the aerial parts of the flowering plant Anthemis cretica subsp. cretica. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Phytochemistry",
title = "Highly oxygenated guaianolides from Anthemis cretica subsp. cretica",
volume = "50",
number = "2",
pages = "287-291",
doi = "10.1016/S0031-9422(98)00504-4"
}
Vajs, V., Bulatović, V., Fodulovic-Savikin, K., Menković, N., Macura, S., Juranić, N.,& Milosavljevic, S.. (1999). Highly oxygenated guaianolides from Anthemis cretica subsp. cretica. in Phytochemistry
Pergamon-Elsevier Science Ltd, Oxford., 50(2), 287-291.
https://doi.org/10.1016/S0031-9422(98)00504-4
Vajs V, Bulatović V, Fodulovic-Savikin K, Menković N, Macura S, Juranić N, Milosavljevic S. Highly oxygenated guaianolides from Anthemis cretica subsp. cretica. in Phytochemistry. 1999;50(2):287-291.
doi:10.1016/S0031-9422(98)00504-4 .
Vajs, Vlatka, Bulatović, V., Fodulovic-Savikin, K, Menković, N., Macura, S., Juranić, N., Milosavljevic, S, "Highly oxygenated guaianolides from Anthemis cretica subsp. cretica" in Phytochemistry, 50, no. 2 (1999):287-291,
https://doi.org/10.1016/S0031-9422(98)00504-4 . .
29
22
26
26

Method for the preparation of Ni-ferrites from beta-diketonato complex compounds

Nikolić, Aleksandar S.; Maricic, ZB; Sabo, Tibor; Kuraica, Milorad M.; Djuric, S; Juranić, N.

(Serbian Chemical Soc, Belgrade, 1999)

TY  - JOUR
AU  - Nikolić, Aleksandar S.
AU  - Maricic, ZB
AU  - Sabo, Tibor
AU  - Kuraica, Milorad M.
AU  - Djuric, S
AU  - Juranić, N.
PY  - 1999
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/413
AB  - The thermal decomposition of Fe(III) and Ni(II) complex compounds with beta-diketonato ligands i.e., acetylacetone (AA), benzoylacetone (BA) and dibenzoylmethane (DBM), were investigated. The goal was to produce ultrafine metalic oxide powders (NiOxFe(2)O(3)) as precursors for the preparation of nickel-ferrite (NiFe2O4). The thermal decomposition of these materials wets carried out by simultaneous TG/DTG/DTA analysis. The materials produced by this method were characterized by X-ray powder diffraction and transmission electron microscopy (TEM). Within the interpretation of results, the formation of nickel-ferrite (NiFe2O4) in comparison to the production of single oxides (NiO and Fe2O3) was especially interesting. At low temperatures (below 600 degrees C), the ultrafine ferrite materials were obtained from complex compounds as precursors. The ferritization rate increases in the series from DBM, BA to AA. The materials formed by the thermal decomposition of the complex compoounds mixtures, with AA as the ligand, with average particle size of Ig nm shaw favorable physico-chemical properties.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Method for the preparation of Ni-ferrites from beta-diketonato complex compounds
VL  - 64
IS  - 4
SP  - 297
EP  - 302
UR  - https://hdl.handle.net/21.15107/rcub_cherry_413
ER  - 
@article{
author = "Nikolić, Aleksandar S. and Maricic, ZB and Sabo, Tibor and Kuraica, Milorad M. and Djuric, S and Juranić, N.",
year = "1999",
abstract = "The thermal decomposition of Fe(III) and Ni(II) complex compounds with beta-diketonato ligands i.e., acetylacetone (AA), benzoylacetone (BA) and dibenzoylmethane (DBM), were investigated. The goal was to produce ultrafine metalic oxide powders (NiOxFe(2)O(3)) as precursors for the preparation of nickel-ferrite (NiFe2O4). The thermal decomposition of these materials wets carried out by simultaneous TG/DTG/DTA analysis. The materials produced by this method were characterized by X-ray powder diffraction and transmission electron microscopy (TEM). Within the interpretation of results, the formation of nickel-ferrite (NiFe2O4) in comparison to the production of single oxides (NiO and Fe2O3) was especially interesting. At low temperatures (below 600 degrees C), the ultrafine ferrite materials were obtained from complex compounds as precursors. The ferritization rate increases in the series from DBM, BA to AA. The materials formed by the thermal decomposition of the complex compoounds mixtures, with AA as the ligand, with average particle size of Ig nm shaw favorable physico-chemical properties.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Method for the preparation of Ni-ferrites from beta-diketonato complex compounds",
volume = "64",
number = "4",
pages = "297-302",
url = "https://hdl.handle.net/21.15107/rcub_cherry_413"
}
Nikolić, A. S., Maricic, Z., Sabo, T., Kuraica, M. M., Djuric, S.,& Juranić, N.. (1999). Method for the preparation of Ni-ferrites from beta-diketonato complex compounds. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 64(4), 297-302.
https://hdl.handle.net/21.15107/rcub_cherry_413
Nikolić AS, Maricic Z, Sabo T, Kuraica MM, Djuric S, Juranić N. Method for the preparation of Ni-ferrites from beta-diketonato complex compounds. in Journal of the Serbian Chemical Society. 1999;64(4):297-302.
https://hdl.handle.net/21.15107/rcub_cherry_413 .
Nikolić, Aleksandar S., Maricic, ZB, Sabo, Tibor, Kuraica, Milorad M., Djuric, S, Juranić, N., "Method for the preparation of Ni-ferrites from beta-diketonato complex compounds" in Journal of the Serbian Chemical Society, 64, no. 4 (1999):297-302,
https://hdl.handle.net/21.15107/rcub_cherry_413 .
3
3

Oxidation products of hyperforin from Hypericum perforatum

Trifunović, Snežana S.; Vajs, Vlatka; Macura, S.; Juranić, N.; Djarmati, Z; Jankov, Ratko M.; Milosavljevic, S

(Pergamon-Elsevier Science Ltd, Oxford, 1998)

TY  - JOUR
AU  - Trifunović, Snežana S.
AU  - Vajs, Vlatka
AU  - Macura, S.
AU  - Juranić, N.
AU  - Djarmati, Z
AU  - Jankov, Ratko M.
AU  - Milosavljevic, S
PY  - 1998
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/400
AB  - The isolation of two oxidation products of hyperforin from the aerial parts of Hypericum perforatum and their structure determination by means of 2D NMR methods is reported. The products had the same 1-(2-methyl-1-oxopropyl)-2,12-dioxo-3,10 beta-bis(3-methyl-2-butenyl)-11 beta-methyl-11 alpha-(4-methyl-3-pentenyl)-5-oxatricyclo[6.3.1.0(4.8)]-3-dodecene skeleton. In addition, one of them, with the same number of carbons as hyperforin (C35H52O5), contained a 1-methyl-1-hydroxyethyl group in the 6 beta-position, whereas the other compound (a hemiacetal, C32H46O5), presumably a degradation product of hyperforin, exhibited a 6-hydroxy function. The latter was an inseparable mixture of 6 alpha- and 6 beta-hydroxy epimers undergoing (according to phase sensitive NOESY) mutual :interconversion. (C) 1998 Elsevier Science Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Phytochemistry
T1  - Oxidation products of hyperforin from Hypericum perforatum
VL  - 49
IS  - 5
SP  - 1305
EP  - 1310
DO  - 10.1016/S0031-9422(97)00903-5
ER  - 
@article{
author = "Trifunović, Snežana S. and Vajs, Vlatka and Macura, S. and Juranić, N. and Djarmati, Z and Jankov, Ratko M. and Milosavljevic, S",
year = "1998",
abstract = "The isolation of two oxidation products of hyperforin from the aerial parts of Hypericum perforatum and their structure determination by means of 2D NMR methods is reported. The products had the same 1-(2-methyl-1-oxopropyl)-2,12-dioxo-3,10 beta-bis(3-methyl-2-butenyl)-11 beta-methyl-11 alpha-(4-methyl-3-pentenyl)-5-oxatricyclo[6.3.1.0(4.8)]-3-dodecene skeleton. In addition, one of them, with the same number of carbons as hyperforin (C35H52O5), contained a 1-methyl-1-hydroxyethyl group in the 6 beta-position, whereas the other compound (a hemiacetal, C32H46O5), presumably a degradation product of hyperforin, exhibited a 6-hydroxy function. The latter was an inseparable mixture of 6 alpha- and 6 beta-hydroxy epimers undergoing (according to phase sensitive NOESY) mutual :interconversion. (C) 1998 Elsevier Science Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Phytochemistry",
title = "Oxidation products of hyperforin from Hypericum perforatum",
volume = "49",
number = "5",
pages = "1305-1310",
doi = "10.1016/S0031-9422(97)00903-5"
}
Trifunović, S. S., Vajs, V., Macura, S., Juranić, N., Djarmati, Z., Jankov, R. M.,& Milosavljevic, S.. (1998). Oxidation products of hyperforin from Hypericum perforatum. in Phytochemistry
Pergamon-Elsevier Science Ltd, Oxford., 49(5), 1305-1310.
https://doi.org/10.1016/S0031-9422(97)00903-5
Trifunović SS, Vajs V, Macura S, Juranić N, Djarmati Z, Jankov RM, Milosavljevic S. Oxidation products of hyperforin from Hypericum perforatum. in Phytochemistry. 1998;49(5):1305-1310.
doi:10.1016/S0031-9422(97)00903-5 .
Trifunović, Snežana S., Vajs, Vlatka, Macura, S., Juranić, N., Djarmati, Z, Jankov, Ratko M., Milosavljevic, S, "Oxidation products of hyperforin from Hypericum perforatum" in Phytochemistry, 49, no. 5 (1998):1305-1310,
https://doi.org/10.1016/S0031-9422(97)00903-5 . .
3
58
62
63
25

Highly oxygenated guaianolides from Anthemis carpatica

Bulatović, V.; Vajs, Vlatka; Macura, S.; Juranić, N.; Milosavljevic, S

(Amer Chemical Soc, Washington, 1997)

TY  - JOUR
AU  - Bulatović, V.
AU  - Vajs, Vlatka
AU  - Macura, S.
AU  - Juranić, N.
AU  - Milosavljevic, S
PY  - 1997
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/362
AB  - The genus Anthemis L. (family Asteraceae, tribe Anthemidae) comprises about 130 species that commonly occur in the Mediterranean, although some also can be found in southwest Asia and South Africa.(1) In Serbia nine species are known.(2) Three main classes of compounds of chemosystematic interest, such as polyacetylenes, flavonoids, and sesquiterpene lactones, typical for Anthemidae, have been detected in the genus Anthemis.(3,4) Among the sesquiterpene lactones, only three types, that is, germacranolides (and seco-germacranolides),(5-15) eudesmanolides,(16,17) and guaianolides,(5,14,18,19) 19 have been isolated from the genus. The exception is an allergenic lactone with unusual structure (anthecotuloide), the constituent of A. cotula.(20,21) Continuing our chemotaxonomic examinations of the Yugoslavian flora belonging to Asteraceae and our search for new compounds of pharmacological interest, we now report the investigation of the aerial parts of Anthemis carpatica Willd, a species usually occurring at elevated, shady and grassy, sandy terrains of the Balkan Peninsula, eastern Alps, and east Carpathian Mountains.(2) A flavonoid quercetin(22) (leaves) and polyacetylenes(4) (roots) are the only secondary metabolites reported for A. carpatica.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Natural Products
T1  - Highly oxygenated guaianolides from Anthemis carpatica
VL  - 60
IS  - 12
SP  - 1222
EP  - 1228
DO  - 10.1021/np970185w
ER  - 
@article{
author = "Bulatović, V. and Vajs, Vlatka and Macura, S. and Juranić, N. and Milosavljevic, S",
year = "1997",
abstract = "The genus Anthemis L. (family Asteraceae, tribe Anthemidae) comprises about 130 species that commonly occur in the Mediterranean, although some also can be found in southwest Asia and South Africa.(1) In Serbia nine species are known.(2) Three main classes of compounds of chemosystematic interest, such as polyacetylenes, flavonoids, and sesquiterpene lactones, typical for Anthemidae, have been detected in the genus Anthemis.(3,4) Among the sesquiterpene lactones, only three types, that is, germacranolides (and seco-germacranolides),(5-15) eudesmanolides,(16,17) and guaianolides,(5,14,18,19) 19 have been isolated from the genus. The exception is an allergenic lactone with unusual structure (anthecotuloide), the constituent of A. cotula.(20,21) Continuing our chemotaxonomic examinations of the Yugoslavian flora belonging to Asteraceae and our search for new compounds of pharmacological interest, we now report the investigation of the aerial parts of Anthemis carpatica Willd, a species usually occurring at elevated, shady and grassy, sandy terrains of the Balkan Peninsula, eastern Alps, and east Carpathian Mountains.(2) A flavonoid quercetin(22) (leaves) and polyacetylenes(4) (roots) are the only secondary metabolites reported for A. carpatica.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Natural Products",
title = "Highly oxygenated guaianolides from Anthemis carpatica",
volume = "60",
number = "12",
pages = "1222-1228",
doi = "10.1021/np970185w"
}
Bulatović, V., Vajs, V., Macura, S., Juranić, N.,& Milosavljevic, S.. (1997). Highly oxygenated guaianolides from Anthemis carpatica. in Journal of Natural Products
Amer Chemical Soc, Washington., 60(12), 1222-1228.
https://doi.org/10.1021/np970185w
Bulatović V, Vajs V, Macura S, Juranić N, Milosavljevic S. Highly oxygenated guaianolides from Anthemis carpatica. in Journal of Natural Products. 1997;60(12):1222-1228.
doi:10.1021/np970185w .
Bulatović, V., Vajs, Vlatka, Macura, S., Juranić, N., Milosavljevic, S, "Highly oxygenated guaianolides from Anthemis carpatica" in Journal of Natural Products, 60, no. 12 (1997):1222-1228,
https://doi.org/10.1021/np970185w . .
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16

Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine

Sovilj, Sofija P.; Vuković, G; Babic, K; Sabo, Tibor; Macura, S.; Juranić, N.

(Gordon Breach Sci Publ Ltd, Reading, 1997)

TY  - JOUR
AU  - Sovilj, Sofija P.
AU  - Vuković, G
AU  - Babic, K
AU  - Sabo, Tibor
AU  - Macura, S.
AU  - Juranić, N.
PY  - 1997
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2590
AB  - 4-Morpholine-, piperidine-, 4-piperazine- and N-methyl- piperazine-dithiocarbamate complexes of Cobalt (III) with 1, 4, 8, 11-tetraazacyclotetradecane, of general formula [Co(Rdtc)cyclam] (ClO4)(2), have been prepared and have been characterized. The complexes adopt cis-octahedral geometry with folded macrocyclic ligand and with the dithiocarbamate bound as a bidentate. trans-influence of the dithiocarbamate ligands was studied by NMR spectroscopy and established the order piperidine-dtc  gt 4-morpholine-dtc gt N-methyl-piperazine-dtc.
PB  - Gordon Breach Sci Publ Ltd, Reading
T2  - Journal of Coordination Chemistry
T1  - Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine
VL  - 41
IS  - 1-2
SP  - 19
EP  - 25
DO  - 10.1080/00958979708027954
ER  - 
@article{
author = "Sovilj, Sofija P. and Vuković, G and Babic, K and Sabo, Tibor and Macura, S. and Juranić, N.",
year = "1997",
abstract = "4-Morpholine-, piperidine-, 4-piperazine- and N-methyl- piperazine-dithiocarbamate complexes of Cobalt (III) with 1, 4, 8, 11-tetraazacyclotetradecane, of general formula [Co(Rdtc)cyclam] (ClO4)(2), have been prepared and have been characterized. The complexes adopt cis-octahedral geometry with folded macrocyclic ligand and with the dithiocarbamate bound as a bidentate. trans-influence of the dithiocarbamate ligands was studied by NMR spectroscopy and established the order piperidine-dtc  gt 4-morpholine-dtc gt N-methyl-piperazine-dtc.",
publisher = "Gordon Breach Sci Publ Ltd, Reading",
journal = "Journal of Coordination Chemistry",
title = "Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine",
volume = "41",
number = "1-2",
pages = "19-25",
doi = "10.1080/00958979708027954"
}
Sovilj, S. P., Vuković, G., Babic, K., Sabo, T., Macura, S.,& Juranić, N.. (1997). Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine. in Journal of Coordination Chemistry
Gordon Breach Sci Publ Ltd, Reading., 41(1-2), 19-25.
https://doi.org/10.1080/00958979708027954
Sovilj SP, Vuković G, Babic K, Sabo T, Macura S, Juranić N. Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine. in Journal of Coordination Chemistry. 1997;41(1-2):19-25.
doi:10.1080/00958979708027954 .
Sovilj, Sofija P., Vuković, G, Babic, K, Sabo, Tibor, Macura, S., Juranić, N., "Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine" in Journal of Coordination Chemistry, 41, no. 1-2 (1997):19-25,
https://doi.org/10.1080/00958979708027954 . .
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26

Diterpenes from Achillea clypeolata

Aljančić, Ivana; Macura, S.; Juranić, N.; Andjelkovic, S; Ranđelović, N; Milosavljevic, S

(Pergamon-Elsevier Science Ltd, Oxford, 1996)

TY  - JOUR
AU  - Aljančić, Ivana
AU  - Macura, S.
AU  - Juranić, N.
AU  - Andjelkovic, S
AU  - Ranđelović, N
AU  - Milosavljevic, S
PY  - 1996
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2247
AB  - The isolation of 16 alpha,17-epoxy-ent-kaurane (a known compound), 3 alpha-acetoxy-16 alpha,17-epoxy-ent-kaurane and 19-acetoxy-16 alpha,17-epoxy-ent-kaurane from roots of Achillea clypeolata is reported. Copyright (C) 1996 Elsevier Science Ltd
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Phytochemistry
T1  - Diterpenes from Achillea clypeolata
VL  - 43
IS  - 1
SP  - 169
EP  - 171
DO  - 10.1016/0031-9422(96)00271-3
ER  - 
@article{
author = "Aljančić, Ivana and Macura, S. and Juranić, N. and Andjelkovic, S and Ranđelović, N and Milosavljevic, S",
year = "1996",
abstract = "The isolation of 16 alpha,17-epoxy-ent-kaurane (a known compound), 3 alpha-acetoxy-16 alpha,17-epoxy-ent-kaurane and 19-acetoxy-16 alpha,17-epoxy-ent-kaurane from roots of Achillea clypeolata is reported. Copyright (C) 1996 Elsevier Science Ltd",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Phytochemistry",
title = "Diterpenes from Achillea clypeolata",
volume = "43",
number = "1",
pages = "169-171",
doi = "10.1016/0031-9422(96)00271-3"
}
Aljančić, I., Macura, S., Juranić, N., Andjelkovic, S., Ranđelović, N.,& Milosavljevic, S.. (1996). Diterpenes from Achillea clypeolata. in Phytochemistry
Pergamon-Elsevier Science Ltd, Oxford., 43(1), 169-171.
https://doi.org/10.1016/0031-9422(96)00271-3
Aljančić I, Macura S, Juranić N, Andjelkovic S, Ranđelović N, Milosavljevic S. Diterpenes from Achillea clypeolata. in Phytochemistry. 1996;43(1):169-171.
doi:10.1016/0031-9422(96)00271-3 .
Aljančić, Ivana, Macura, S., Juranić, N., Andjelkovic, S, Ranđelović, N, Milosavljevic, S, "Diterpenes from Achillea clypeolata" in Phytochemistry, 43, no. 1 (1996):169-171,
https://doi.org/10.1016/0031-9422(96)00271-3 . .
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