TY  - JOUR
AU  - Rabab, Salih
AU  - Veličković, Zlate
AU  - Milošević, Milena
AU  - Pavlović, Vera P.
AU  - Cvijetić, Ilija
AU  - Sofrenić, Ivana V.
AU  - Gržetić, Jelena D.
AU  - Marinković, Aleksandar
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6018
AB  - Multifunctional lignin bio-based adsorbent, b-LMS, was obtained via inverse copolymerization in the suspension of acryloyl modified kraft lignin (KfL-AA) and bio-based trimethylolpropane triacrylate (bio-TMPTA). Morphological and structural characterization of KfL-AA and b-LMS was performed using BET, FTIR, Raman, NMR, TGA, SEM, and XPS techniques. The b-LMS microspheres with 253 ± 42 μm diameters, 69.4 m2 g−1 surface area, and 59% porosity efficiently adsorb Malachite Green (MG), Tartrazine (T), and Methyl Red (MR) dye. The influence of pH, pollutant concentration, temperature, and time on the removal efficiency was studied in a batch mode. Favorable and spontaneous processes with high adsorption capacities e.g. 116.8 mg g−1 for MG, 86.8 mg g−1 for T, and 68.6 mg g−1 for MR indicate the significant adsorptive potential of b-LMS. Results from diffusional and single mass transfer resistance studies indicate that pore diffusion is a rate-limiting step. Theoretical calculations confirmed a higher affinity of b-LMS to cationic dye MG compared with an anionic and neutral one, i.e. T and MR, respectively. The data fitting from a flow system, using semi-empirical equations and Pore Surface Diffusion Modelling (PSDM) provided breakthrough point determination. The results from the desorption and competitive adsorption study proved the exceptional performance of b-LMS. Moreover, sulfation of b-LMS, i.e.production of b-LMS-OSO3H, introduced high-affinity sulfate groups with respect to cationic dye and cations. Developed methodology implements the principle of sustainable development and offers concept whose results contribute to the minimization of environmental pollution.
PB  - Academic Press
T2  - Journal of Environmental Management
T1  - Lignin based microspheres for effective dyes removal: Design, synthesis and adsorption mechanism supported with theoretical study
VL  - 326
SP  - 116838
DO  - 10.1016/j.jenvman.2022.116838
ER  - 

@article{
author = "Rabab, Salih and Veličković, Zlate and Milošević, Milena and Pavlović, Vera P. and Cvijetić, Ilija and Sofrenić, Ivana V. and Gržetić, Jelena D. and Marinković, Aleksandar",
year = "2023",
abstract = "Multifunctional lignin bio-based adsorbent, b-LMS, was obtained via inverse copolymerization in the suspension of acryloyl modified kraft lignin (KfL-AA) and bio-based trimethylolpropane triacrylate (bio-TMPTA). Morphological and structural characterization of KfL-AA and b-LMS was performed using BET, FTIR, Raman, NMR, TGA, SEM, and XPS techniques. The b-LMS microspheres with 253 ± 42 μm diameters, 69.4 m2 g−1 surface area, and 59% porosity efficiently adsorb Malachite Green (MG), Tartrazine (T), and Methyl Red (MR) dye. The influence of pH, pollutant concentration, temperature, and time on the removal efficiency was studied in a batch mode. Favorable and spontaneous processes with high adsorption capacities e.g. 116.8 mg g−1 for MG, 86.8 mg g−1 for T, and 68.6 mg g−1 for MR indicate the significant adsorptive potential of b-LMS. Results from diffusional and single mass transfer resistance studies indicate that pore diffusion is a rate-limiting step. Theoretical calculations confirmed a higher affinity of b-LMS to cationic dye MG compared with an anionic and neutral one, i.e. T and MR, respectively. The data fitting from a flow system, using semi-empirical equations and Pore Surface Diffusion Modelling (PSDM) provided breakthrough point determination. The results from the desorption and competitive adsorption study proved the exceptional performance of b-LMS. Moreover, sulfation of b-LMS, i.e.production of b-LMS-OSO3H, introduced high-affinity sulfate groups with respect to cationic dye and cations. Developed methodology implements the principle of sustainable development and offers concept whose results contribute to the minimization of environmental pollution.",
publisher = "Academic Press",
journal = "Journal of Environmental Management",
title = "Lignin based microspheres for effective dyes removal: Design, synthesis and adsorption mechanism supported with theoretical study",
volume = "326",
pages = "116838",
doi = "10.1016/j.jenvman.2022.116838"
}

Rabab, S., Veličković, Z., Milošević, M., Pavlović, V. P., Cvijetić, I., Sofrenić, I. V., Gržetić, J. D.,& Marinković, A.. (2023). Lignin based microspheres for effective dyes removal: Design, synthesis and adsorption mechanism supported with theoretical study. in Journal of Environmental Management
Academic Press., 326, 116838.
https://doi.org/10.1016/j.jenvman.2022.116838

Rabab S, Veličković Z, Milošević M, Pavlović VP, Cvijetić I, Sofrenić IV, Gržetić JD, Marinković A. Lignin based microspheres for effective dyes removal: Design, synthesis and adsorption mechanism supported with theoretical study. in Journal of Environmental Management. 2023;326:116838.
doi:10.1016/j.jenvman.2022.116838 .

Rabab, Salih, Veličković, Zlate, Milošević, Milena, Pavlović, Vera P., Cvijetić, Ilija, Sofrenić, Ivana V., Gržetić, Jelena D., Marinković, Aleksandar, "Lignin based microspheres for effective dyes removal: Design, synthesis and adsorption mechanism supported with theoretical study" in Journal of Environmental Management, 326 (2023):116838,
https://doi.org/10.1016/j.jenvman.2022.116838 . .

TY  - JOUR
AU  - Perendija, Jovana
AU  - Veličković, Zlate
AU  - Dražević, Ljubinka
AU  - Stojiljković, Ivana N.
AU  - Milčić, Miloš K.
AU  - Milosavljević, Milutin M.
AU  - Marinković, Aleksandar
AU  - Pavlović, Vladimir B.
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4752
AB  - Magnetite (MG) modified cellulose membrane (Cell-MG), obtained by reaction of 3-aminosilane and subsequently with diethylenetriaminepentaacetic acid dianhydride functionalized waste Cell fibers (Cell-NH2 and Cell-DTPA, respectively), and amino-modified diatomite was used for Azoxystrobin and Iprodione removal from water. Cell-MG membrane was structurally and morphologically characterized using FT-IR and FE-SEM techniques. The influences of operational parameters, i.e. pH, contact time, temperature, and the mass of adsorbent on adsorption and kinetics were studied in a batch system. The calculated capacities of 35.32 and 30.16 mg g-1 for Azoxystrobin and Iprodione, respectively, were obtained from non-linear Langmuir model fitting. Weber-Morris model fitting indicates the main contribution of intra-particle diffusion to overall mass transport resistance. Thermodynamic data indicate spontaneous and endothermic adsorption. The reusability of adsorbent and results from wastewater purification showed that Cell-MG could be used as general-purpose adsorbent. The adsorbent/adsorbate surface interaction was considered from the results obtained using density functional theory (DFT) and calculation of molecular electrostatic potential (MEP). Thus, a better understanding of the relation between the adsorption performances and contribution of non-specific and specific interactions to adsorption performances and design of novel adsorbent with improved properties was deduced
PB  - Association for ETRAN Society
T2  - Science of Sintering
T1  - Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using Cell-MG hybrid adsorbent
VL  - 53
IS  - 3
SP  - 355
EP  - 378
DO  - 10.2298/SOS2103355P
ER  - 

@article{
author = "Perendija, Jovana and Veličković, Zlate and Dražević, Ljubinka and Stojiljković, Ivana N. and Milčić, Miloš K. and Milosavljević, Milutin M. and Marinković, Aleksandar and Pavlović, Vladimir B.",
year = "2021",
abstract = "Magnetite (MG) modified cellulose membrane (Cell-MG), obtained by reaction of 3-aminosilane and subsequently with diethylenetriaminepentaacetic acid dianhydride functionalized waste Cell fibers (Cell-NH2 and Cell-DTPA, respectively), and amino-modified diatomite was used for Azoxystrobin and Iprodione removal from water. Cell-MG membrane was structurally and morphologically characterized using FT-IR and FE-SEM techniques. The influences of operational parameters, i.e. pH, contact time, temperature, and the mass of adsorbent on adsorption and kinetics were studied in a batch system. The calculated capacities of 35.32 and 30.16 mg g-1 for Azoxystrobin and Iprodione, respectively, were obtained from non-linear Langmuir model fitting. Weber-Morris model fitting indicates the main contribution of intra-particle diffusion to overall mass transport resistance. Thermodynamic data indicate spontaneous and endothermic adsorption. The reusability of adsorbent and results from wastewater purification showed that Cell-MG could be used as general-purpose adsorbent. The adsorbent/adsorbate surface interaction was considered from the results obtained using density functional theory (DFT) and calculation of molecular electrostatic potential (MEP). Thus, a better understanding of the relation between the adsorption performances and contribution of non-specific and specific interactions to adsorption performances and design of novel adsorbent with improved properties was deduced",
publisher = "Association for ETRAN Society",
journal = "Science of Sintering",
title = "Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using Cell-MG hybrid adsorbent",
volume = "53",
number = "3",
pages = "355-378",
doi = "10.2298/SOS2103355P"
}

Perendija, J., Veličković, Z., Dražević, L., Stojiljković, I. N., Milčić, M. K., Milosavljević, M. M., Marinković, A.,& Pavlović, V. B.. (2021). Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using Cell-MG hybrid adsorbent. in Science of Sintering
Association for ETRAN Society., 53(3), 355-378.
https://doi.org/10.2298/SOS2103355P

Perendija J, Veličković Z, Dražević L, Stojiljković IN, Milčić MK, Milosavljević MM, Marinković A, Pavlović VB. Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using Cell-MG hybrid adsorbent. in Science of Sintering. 2021;53(3):355-378.
doi:10.2298/SOS2103355P .

Perendija, Jovana, Veličković, Zlate, Dražević, Ljubinka, Stojiljković, Ivana N., Milčić, Miloš K., Milosavljević, Milutin M., Marinković, Aleksandar, Pavlović, Vladimir B., "Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using Cell-MG hybrid adsorbent" in Science of Sintering, 53, no. 3 (2021):355-378,
https://doi.org/10.2298/SOS2103355P . .

TY  - JOUR
AU  - Perendija, Jovana
AU  - Veličković, Zlate
AU  - Cvijetić, Ilija
AU  - Rušmirović, Jelena D.
AU  - Ugrinović, Vukašin
AU  - Marinković, Aleksandar
AU  - Onjia, Antonije E.
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4204
AB  - An optimized method is presented to make magnetite (MG) modified cellulose membrane (Cell-MG) from 3-aminopropyltriethoxysilane and diethylenetriaminepentaacetic acid dianhydride functionalized waste cell fibers; (Cell-NH2 and Cell-DTPA), and amino-modified diatomite. Functionalized Cell-NH2, Cell-DTPA fibers, and diatomite were structurally and morphologically characterized using FT-IR, Raman, and FE-SEM analysis. Amino and carboxyl group content was determined via standard volumetric methods. Response surface method was applied to rationalize the number of experiments related to Cell-MG synthesis and heavy metal ions column adsorption experiments. The effects of pH, contact time, temperature, and initial concentration of pollutants on adsorption and kinetics were studied in a batch, while initial concentration and flow rate were studied in a flow system. The calculated capacities of 88.2, 100.7, 95.8 and 78.2 mg g−1 for Ni2+, Pb2+, Cr(VI) and As(V) ions, respectively, were obtained from Langmuir model fitting. Intra-particle diffusion as a rate-limiting step was evaluated from pseudo-second-order and Weber–Morris model fitting. Thermodynamic parameters indicated spontaneous and low endothermic processes. The results from reusability study, wastewater purification and fixed-bed column study proved the high applicability of Cell-MG. Additionally, high removal capacity of four dyes together with density functional theory and molecular interaction fields, help in the establishment of relation between the adsorption performances and contribution of non-specific and specific interactions at adsorbate/adsorbent interface.
PB  - Springer
T2  - Cellulose
T1  - Batch and column adsorption of cations, oxyanions and dyes on a magnetite modified cellulose-based membrane
VL  - 27
IS  - 14
SP  - 8215
EP  - 8235
DO  - 10.1007/s10570-020-03352-x
ER  - 

@article{
author = "Perendija, Jovana and Veličković, Zlate and Cvijetić, Ilija and Rušmirović, Jelena D. and Ugrinović, Vukašin and Marinković, Aleksandar and Onjia, Antonije E.",
year = "2020",
abstract = "An optimized method is presented to make magnetite (MG) modified cellulose membrane (Cell-MG) from 3-aminopropyltriethoxysilane and diethylenetriaminepentaacetic acid dianhydride functionalized waste cell fibers; (Cell-NH2 and Cell-DTPA), and amino-modified diatomite. Functionalized Cell-NH2, Cell-DTPA fibers, and diatomite were structurally and morphologically characterized using FT-IR, Raman, and FE-SEM analysis. Amino and carboxyl group content was determined via standard volumetric methods. Response surface method was applied to rationalize the number of experiments related to Cell-MG synthesis and heavy metal ions column adsorption experiments. The effects of pH, contact time, temperature, and initial concentration of pollutants on adsorption and kinetics were studied in a batch, while initial concentration and flow rate were studied in a flow system. The calculated capacities of 88.2, 100.7, 95.8 and 78.2 mg g−1 for Ni2+, Pb2+, Cr(VI) and As(V) ions, respectively, were obtained from Langmuir model fitting. Intra-particle diffusion as a rate-limiting step was evaluated from pseudo-second-order and Weber–Morris model fitting. Thermodynamic parameters indicated spontaneous and low endothermic processes. The results from reusability study, wastewater purification and fixed-bed column study proved the high applicability of Cell-MG. Additionally, high removal capacity of four dyes together with density functional theory and molecular interaction fields, help in the establishment of relation between the adsorption performances and contribution of non-specific and specific interactions at adsorbate/adsorbent interface.",
publisher = "Springer",
journal = "Cellulose",
title = "Batch and column adsorption of cations, oxyanions and dyes on a magnetite modified cellulose-based membrane",
volume = "27",
number = "14",
pages = "8215-8235",
doi = "10.1007/s10570-020-03352-x"
}

Perendija, J., Veličković, Z., Cvijetić, I., Rušmirović, J. D., Ugrinović, V., Marinković, A.,& Onjia, A. E.. (2020). Batch and column adsorption of cations, oxyanions and dyes on a magnetite modified cellulose-based membrane. in Cellulose
Springer., 27(14), 8215-8235.
https://doi.org/10.1007/s10570-020-03352-x

Perendija J, Veličković Z, Cvijetić I, Rušmirović JD, Ugrinović V, Marinković A, Onjia AE. Batch and column adsorption of cations, oxyanions and dyes on a magnetite modified cellulose-based membrane. in Cellulose. 2020;27(14):8215-8235.
doi:10.1007/s10570-020-03352-x .

Perendija, Jovana, Veličković, Zlate, Cvijetić, Ilija, Rušmirović, Jelena D., Ugrinović, Vukašin, Marinković, Aleksandar, Onjia, Antonije E., "Batch and column adsorption of cations, oxyanions and dyes on a magnetite modified cellulose-based membrane" in Cellulose, 27, no. 14 (2020):8215-8235,
https://doi.org/10.1007/s10570-020-03352-x . .

TY  - DATA
AU  - Perendija, Jovana
AU  - Veličković, Zlate
AU  - Cvijetić, Ilija
AU  - Rušmirović, Jelena D.
AU  - Ugrinović, Vukašin
AU  - Marinković, Aleksandar
AU  - Onjia, Antonije E.
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4205
PB  - Springer
T2  - Cellulose
T1  - Supplementary data for the article: Perendija, J.; Veličković, Z. S.; Cvijetić, I.; Rusmirović, J. D.; Ugrinović, V.; Marinković, A. D.; Onjia, A. Batch and Column Adsorption of Cations, Oxyanions and Dyes on a Magnetite Modified Cellulose-Based Membrane. Cellulose 2020, 27 (14), 8215–8235. https://doi.org/10.1007/s10570-020-03352-x
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4205
ER  - 

@misc{
author = "Perendija, Jovana and Veličković, Zlate and Cvijetić, Ilija and Rušmirović, Jelena D. and Ugrinović, Vukašin and Marinković, Aleksandar and Onjia, Antonije E.",
year = "2020",
publisher = "Springer",
journal = "Cellulose",
title = "Supplementary data for the article: Perendija, J.; Veličković, Z. S.; Cvijetić, I.; Rusmirović, J. D.; Ugrinović, V.; Marinković, A. D.; Onjia, A. Batch and Column Adsorption of Cations, Oxyanions and Dyes on a Magnetite Modified Cellulose-Based Membrane. Cellulose 2020, 27 (14), 8215–8235. https://doi.org/10.1007/s10570-020-03352-x",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4205"
}

Perendija, J., Veličković, Z., Cvijetić, I., Rušmirović, J. D., Ugrinović, V., Marinković, A.,& Onjia, A. E.. (2020). Supplementary data for the article: Perendija, J.; Veličković, Z. S.; Cvijetić, I.; Rusmirović, J. D.; Ugrinović, V.; Marinković, A. D.; Onjia, A. Batch and Column Adsorption of Cations, Oxyanions and Dyes on a Magnetite Modified Cellulose-Based Membrane. Cellulose 2020, 27 (14), 8215–8235. https://doi.org/10.1007/s10570-020-03352-x. in Cellulose
Springer..
https://hdl.handle.net/21.15107/rcub_cherry_4205

Perendija J, Veličković Z, Cvijetić I, Rušmirović JD, Ugrinović V, Marinković A, Onjia AE. Supplementary data for the article: Perendija, J.; Veličković, Z. S.; Cvijetić, I.; Rusmirović, J. D.; Ugrinović, V.; Marinković, A. D.; Onjia, A. Batch and Column Adsorption of Cations, Oxyanions and Dyes on a Magnetite Modified Cellulose-Based Membrane. Cellulose 2020, 27 (14), 8215–8235. https://doi.org/10.1007/s10570-020-03352-x. in Cellulose. 2020;.
https://hdl.handle.net/21.15107/rcub_cherry_4205 .

Perendija, Jovana, Veličković, Zlate, Cvijetić, Ilija, Rušmirović, Jelena D., Ugrinović, Vukašin, Marinković, Aleksandar, Onjia, Antonije E., "Supplementary data for the article: Perendija, J.; Veličković, Z. S.; Cvijetić, I.; Rusmirović, J. D.; Ugrinović, V.; Marinković, A. D.; Onjia, A. Batch and Column Adsorption of Cations, Oxyanions and Dyes on a Magnetite Modified Cellulose-Based Membrane. Cellulose 2020, 27 (14), 8215–8235. https://doi.org/10.1007/s10570-020-03352-x" in Cellulose (2020),
https://hdl.handle.net/21.15107/rcub_cherry_4205 .

TY  - JOUR
AU  - Karkalić, Radovan
AU  - Maslak, Veselin
AU  - Nikolić, Aleksandar S.
AU  - Kostić, Mirjana M.
AU  - Jovanović, Dalibor
AU  - Senić, Željko
AU  - Veličković, Zlate
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/167
AB  - The new concept of chemical, biological, radiological and nuclear combat clothing offers the opportunity of substantial cost savings by eliminating the need for additional, CBRN over garments, whose high weight and poor breathability may cause a physiological overload of the soldier. These specific clothing made of filtrosorption material has been designed for modern soldier, increasing his efficiency and reducing total costs. Textile materials embedded in the suit have excellent physical and mechanical properties, air and moisture permeability after climatic treatment and practical usage. During testing of chemical protective over garment's physiologic suitability the ergometric indicators were determined.
AB  - Novi koncept NHB zaštitne odeće pruža mogućnost velike uštede, eliminišući potrebu za primenu dodatnih NHB zaštitnih sredstava, čija velika masa i loša propustljivost vazduha mogu dovesti do fizioloških preopterećenja vojnika. Ova specijalna zaštitna odeća, izrađena od filtrosorpcionih materijala, je dizajnirana za savremenog vojnika, što mu povećava efikasnost i redukuje ukupne troškove proizvodnje zaštitne odeće. Tekstilni materijali koji su ugrađeni u ovu odeću poseduju dobra fizičko-mehanička svojstava, propustljivi su za vazduh i vodenu paru nakon klimatskih tretmana i tokom praktične upotrebe. Tokom ispitivanja zaštitnih svojstava i karakteristika fiziološke podobnosti određeni su i neki ergometrijski indikatori.
T2  - Zaštita materijala
T1  - Application of permeable materials for CBRN protective equipment
T1  - Primena filtrosorpcionih materijala za NHB zaštitnu opremu
VL  - 56
IS  - 2
SP  - 239
EP  - 242
DO  - 10.5937/ZasMat1502239K
ER  - 

@article{
author = "Karkalić, Radovan and Maslak, Veselin and Nikolić, Aleksandar S. and Kostić, Mirjana M. and Jovanović, Dalibor and Senić, Željko and Veličković, Zlate",
year = "2015",
abstract = "The new concept of chemical, biological, radiological and nuclear combat clothing offers the opportunity of substantial cost savings by eliminating the need for additional, CBRN over garments, whose high weight and poor breathability may cause a physiological overload of the soldier. These specific clothing made of filtrosorption material has been designed for modern soldier, increasing his efficiency and reducing total costs. Textile materials embedded in the suit have excellent physical and mechanical properties, air and moisture permeability after climatic treatment and practical usage. During testing of chemical protective over garment's physiologic suitability the ergometric indicators were determined., Novi koncept NHB zaštitne odeće pruža mogućnost velike uštede, eliminišući potrebu za primenu dodatnih NHB zaštitnih sredstava, čija velika masa i loša propustljivost vazduha mogu dovesti do fizioloških preopterećenja vojnika. Ova specijalna zaštitna odeća, izrađena od filtrosorpcionih materijala, je dizajnirana za savremenog vojnika, što mu povećava efikasnost i redukuje ukupne troškove proizvodnje zaštitne odeće. Tekstilni materijali koji su ugrađeni u ovu odeću poseduju dobra fizičko-mehanička svojstava, propustljivi su za vazduh i vodenu paru nakon klimatskih tretmana i tokom praktične upotrebe. Tokom ispitivanja zaštitnih svojstava i karakteristika fiziološke podobnosti određeni su i neki ergometrijski indikatori.",
journal = "Zaštita materijala",
title = "Application of permeable materials for CBRN protective equipment, Primena filtrosorpcionih materijala za NHB zaštitnu opremu",
volume = "56",
number = "2",
pages = "239-242",
doi = "10.5937/ZasMat1502239K"
}

Karkalić, R., Maslak, V., Nikolić, A. S., Kostić, M. M., Jovanović, D., Senić, Ž.,& Veličković, Z.. (2015). Application of permeable materials for CBRN protective equipment. in Zaštita materijala, 56(2), 239-242.
https://doi.org/10.5937/ZasMat1502239K

Karkalić R, Maslak V, Nikolić AS, Kostić MM, Jovanović D, Senić Ž, Veličković Z. Application of permeable materials for CBRN protective equipment. in Zaštita materijala. 2015;56(2):239-242.
doi:10.5937/ZasMat1502239K .

Karkalić, Radovan, Maslak, Veselin, Nikolić, Aleksandar S., Kostić, Mirjana M., Jovanović, Dalibor, Senić, Željko, Veličković, Zlate, "Application of permeable materials for CBRN protective equipment" in Zaštita materijala, 56, no. 2 (2015):239-242,
https://doi.org/10.5937/ZasMat1502239K . .