Lalia-Kantouri, Maria

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  • Lalia-Kantouri, Maria (8)
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Author's Bibliography

Cadmium(II) complexes of 5-bromo-salicylaldehyde and alpha-diimines: Synthesis, structure and interaction with calf-thymus DNA and albumins

Zianna, Ariadni; Šumar-Ristović, Maja; Psomas, George; Hatzidimitriou, Antonis; Coutouli-Argyropoulou, Evdoxia; Lalia-Kantouri, Maria

(Pergamon-Elsevier Science Ltd, Oxford, 2016)

TY  - JOUR
AU  - Zianna, Ariadni
AU  - Šumar-Ristović, Maja
AU  - Psomas, George
AU  - Hatzidimitriou, Antonis
AU  - Coutouli-Argyropoulou, Evdoxia
AU  - Lalia-Kantouri, Maria
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1923
AB  - Five Cd(II) complexes, four dinuclear (1-4) and a mononuclear one (5), with the anion of 5-Br-salicylaldehyde (5-Br-salo(-)), were synthesized and characterized as [Cd(5-Br-salo)(2)(CH3OH)](2) (1), [Cd(5-Br-salo)(2) (bipy)](2) (2), [Cd(5-Br-salo)(2)(phen)](2) (3), [Cd(5-Br-salo)(neoc)(NO3)](2) (4) and [Cd(5-Br-salo)(2)(dpamH)] (5). The complexes were characterized by spectroscopy (IR, UV-vis, H-1 NMR), elemental analysis and molar conductivity measurements. The structures for three complexes (2, 3 and 5) were determined by X-ray crystallography providing different coordination modes of the 5-Br-salicylaldehydo ligand. The complexes bind to DNA mainly by intercalation, as concluded by the viscosity measurements and the EB-displacement studies from the EB-DNA complex and present high DNA-binding constants (K-b), as calculated by the Wolfe-Shimer equation and plots. The interaction of the complexes with serum albumins was studied by fluorescence emission spectroscopy and the determined binding constants exhibit relative high values. (C) 2016 Elsevier Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Cadmium(II) complexes of 5-bromo-salicylaldehyde and alpha-diimines: Synthesis, structure and interaction with calf-thymus DNA and albumins
VL  - 107
SP  - 136
EP  - 147
DO  - 10.1016/j.poly.2016.01.020
ER  - 
@article{
author = "Zianna, Ariadni and Šumar-Ristović, Maja and Psomas, George and Hatzidimitriou, Antonis and Coutouli-Argyropoulou, Evdoxia and Lalia-Kantouri, Maria",
year = "2016",
abstract = "Five Cd(II) complexes, four dinuclear (1-4) and a mononuclear one (5), with the anion of 5-Br-salicylaldehyde (5-Br-salo(-)), were synthesized and characterized as [Cd(5-Br-salo)(2)(CH3OH)](2) (1), [Cd(5-Br-salo)(2) (bipy)](2) (2), [Cd(5-Br-salo)(2)(phen)](2) (3), [Cd(5-Br-salo)(neoc)(NO3)](2) (4) and [Cd(5-Br-salo)(2)(dpamH)] (5). The complexes were characterized by spectroscopy (IR, UV-vis, H-1 NMR), elemental analysis and molar conductivity measurements. The structures for three complexes (2, 3 and 5) were determined by X-ray crystallography providing different coordination modes of the 5-Br-salicylaldehydo ligand. The complexes bind to DNA mainly by intercalation, as concluded by the viscosity measurements and the EB-displacement studies from the EB-DNA complex and present high DNA-binding constants (K-b), as calculated by the Wolfe-Shimer equation and plots. The interaction of the complexes with serum albumins was studied by fluorescence emission spectroscopy and the determined binding constants exhibit relative high values. (C) 2016 Elsevier Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Cadmium(II) complexes of 5-bromo-salicylaldehyde and alpha-diimines: Synthesis, structure and interaction with calf-thymus DNA and albumins",
volume = "107",
pages = "136-147",
doi = "10.1016/j.poly.2016.01.020"
}
Zianna, A., Šumar-Ristović, M., Psomas, G., Hatzidimitriou, A., Coutouli-Argyropoulou, E.,& Lalia-Kantouri, M.. (2016). Cadmium(II) complexes of 5-bromo-salicylaldehyde and alpha-diimines: Synthesis, structure and interaction with calf-thymus DNA and albumins. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 107, 136-147.
https://doi.org/10.1016/j.poly.2016.01.020
Zianna A, Šumar-Ristović M, Psomas G, Hatzidimitriou A, Coutouli-Argyropoulou E, Lalia-Kantouri M. Cadmium(II) complexes of 5-bromo-salicylaldehyde and alpha-diimines: Synthesis, structure and interaction with calf-thymus DNA and albumins. in Polyhedron. 2016;107:136-147.
doi:10.1016/j.poly.2016.01.020 .
Zianna, Ariadni, Šumar-Ristović, Maja, Psomas, George, Hatzidimitriou, Antonis, Coutouli-Argyropoulou, Evdoxia, Lalia-Kantouri, Maria, "Cadmium(II) complexes of 5-bromo-salicylaldehyde and alpha-diimines: Synthesis, structure and interaction with calf-thymus DNA and albumins" in Polyhedron, 107 (2016):136-147,
https://doi.org/10.1016/j.poly.2016.01.020 . .
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Interaction of dinuclear cadmium(II) 5-Cl-salicylaldehyde complexes with calf-thymus DNA

Šumar-Ristović, Maja; Zianna, Ariadni; Psomas, George; Hatzidimitriou, Antonios G.; Coutouli-Argyropoulou, Evdoxia; Lalia-Kantouri, Maria

(Elsevier Science Bv, Amsterdam, 2016)

TY  - JOUR
AU  - Šumar-Ristović, Maja
AU  - Zianna, Ariadni
AU  - Psomas, George
AU  - Hatzidimitriou, Antonios G.
AU  - Coutouli-Argyropoulou, Evdoxia
AU  - Lalia-Kantouri, Maria
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2052
AB  - Five dinuclear Cd(II) complexes with the anion of 5-Cl-salicylaldehyde (5-Cl-saloH) were synthesized in the absence or presence of the alpha-diimines: 2,2'-bipyridine (bipy), 1,10-phenanthroline (phen), 2,9-dimethyl-1,10-henanthroline (neoc) or 2,2'-dipyridylamine (dpamH) and characterized as [Cd(5-Cl-salo)(2)(CH3OH)](2) (1), [Cd(5-Cl-salo)(2)(bipy)](2) (2), [Cd(5-Cl-salo)(2)(phen)](2) (3), [Cd(5-Cl-salo)(neoc)(ONO2)](2) (4) and [Cd(5-Cl-salo)(dpamH)(ONO2)](2) (5). The complexes were characterized by spectroscopic techniques (IR, UV-vis, H-1-NMR and C-13-NMR), elemental analysis and molar conductivity measurements. The structures of four complexes (1-3 and 5) were determined by X-ray crystallography, providing all three possible coordination modes of the ligand 5-Cl-salicylaldehyde, i.e. bidentate or tridentate chelating and/or bridging mode. The complexes bind to calf-thymus (Cr) DNA mainly by intercalation, as concluded by the viscosity measurements and present relatively high DNA-binding constants. The complexes exhibit significant ability to displace ethidium bromide (EB) from the EB-DNA complex, thus indirectly proving the intercalation as the most possible binding mode to Cr DNA. (C) 2016 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Materials Science and Engineering. C: Materials for Biological Applications
T1  - Interaction of dinuclear cadmium(II) 5-Cl-salicylaldehyde complexes with calf-thymus DNA
VL  - 61
SP  - 579
EP  - 590
DO  - 10.1016/j.msec.2015.12.054
ER  - 
@article{
author = "Šumar-Ristović, Maja and Zianna, Ariadni and Psomas, George and Hatzidimitriou, Antonios G. and Coutouli-Argyropoulou, Evdoxia and Lalia-Kantouri, Maria",
year = "2016",
abstract = "Five dinuclear Cd(II) complexes with the anion of 5-Cl-salicylaldehyde (5-Cl-saloH) were synthesized in the absence or presence of the alpha-diimines: 2,2'-bipyridine (bipy), 1,10-phenanthroline (phen), 2,9-dimethyl-1,10-henanthroline (neoc) or 2,2'-dipyridylamine (dpamH) and characterized as [Cd(5-Cl-salo)(2)(CH3OH)](2) (1), [Cd(5-Cl-salo)(2)(bipy)](2) (2), [Cd(5-Cl-salo)(2)(phen)](2) (3), [Cd(5-Cl-salo)(neoc)(ONO2)](2) (4) and [Cd(5-Cl-salo)(dpamH)(ONO2)](2) (5). The complexes were characterized by spectroscopic techniques (IR, UV-vis, H-1-NMR and C-13-NMR), elemental analysis and molar conductivity measurements. The structures of four complexes (1-3 and 5) were determined by X-ray crystallography, providing all three possible coordination modes of the ligand 5-Cl-salicylaldehyde, i.e. bidentate or tridentate chelating and/or bridging mode. The complexes bind to calf-thymus (Cr) DNA mainly by intercalation, as concluded by the viscosity measurements and present relatively high DNA-binding constants. The complexes exhibit significant ability to displace ethidium bromide (EB) from the EB-DNA complex, thus indirectly proving the intercalation as the most possible binding mode to Cr DNA. (C) 2016 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Materials Science and Engineering. C: Materials for Biological Applications",
title = "Interaction of dinuclear cadmium(II) 5-Cl-salicylaldehyde complexes with calf-thymus DNA",
volume = "61",
pages = "579-590",
doi = "10.1016/j.msec.2015.12.054"
}
Šumar-Ristović, M., Zianna, A., Psomas, G., Hatzidimitriou, A. G., Coutouli-Argyropoulou, E.,& Lalia-Kantouri, M.. (2016). Interaction of dinuclear cadmium(II) 5-Cl-salicylaldehyde complexes with calf-thymus DNA. in Materials Science and Engineering. C: Materials for Biological Applications
Elsevier Science Bv, Amsterdam., 61, 579-590.
https://doi.org/10.1016/j.msec.2015.12.054
Šumar-Ristović M, Zianna A, Psomas G, Hatzidimitriou AG, Coutouli-Argyropoulou E, Lalia-Kantouri M. Interaction of dinuclear cadmium(II) 5-Cl-salicylaldehyde complexes with calf-thymus DNA. in Materials Science and Engineering. C: Materials for Biological Applications. 2016;61:579-590.
doi:10.1016/j.msec.2015.12.054 .
Šumar-Ristović, Maja, Zianna, Ariadni, Psomas, George, Hatzidimitriou, Antonios G., Coutouli-Argyropoulou, Evdoxia, Lalia-Kantouri, Maria, "Interaction of dinuclear cadmium(II) 5-Cl-salicylaldehyde complexes with calf-thymus DNA" in Materials Science and Engineering. C: Materials for Biological Applications, 61 (2016):579-590,
https://doi.org/10.1016/j.msec.2015.12.054 . .
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Supplementary data for the article: Zianna, A.; Ristović, M. Š.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Bromo-Salicylaldehyde and α-Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA and Albumins. Polyhedron 2016, 107, 136–147. https://doi.org/10.1016/j.poly.2016.01.020

Zianna, Ariadni; Šumar-Ristović, Maja; Psomas, George; Hatzidimitriou, Antonis; Coutouli-Argyropoulou, Evdoxia; Lalia-Kantouri, Maria

(Pergamon-Elsevier Science Ltd, Oxford, 2016)

TY  - DATA
AU  - Zianna, Ariadni
AU  - Šumar-Ristović, Maja
AU  - Psomas, George
AU  - Hatzidimitriou, Antonis
AU  - Coutouli-Argyropoulou, Evdoxia
AU  - Lalia-Kantouri, Maria
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3394
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Supplementary data for the article: Zianna, A.; Ristović, M. Š.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Bromo-Salicylaldehyde and α-Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA and Albumins. Polyhedron 2016, 107, 136–147. https://doi.org/10.1016/j.poly.2016.01.020
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3394
ER  - 
@misc{
author = "Zianna, Ariadni and Šumar-Ristović, Maja and Psomas, George and Hatzidimitriou, Antonis and Coutouli-Argyropoulou, Evdoxia and Lalia-Kantouri, Maria",
year = "2016",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Supplementary data for the article: Zianna, A.; Ristović, M. Š.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Bromo-Salicylaldehyde and α-Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA and Albumins. Polyhedron 2016, 107, 136–147. https://doi.org/10.1016/j.poly.2016.01.020",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3394"
}
Zianna, A., Šumar-Ristović, M., Psomas, G., Hatzidimitriou, A., Coutouli-Argyropoulou, E.,& Lalia-Kantouri, M.. (2016). Supplementary data for the article: Zianna, A.; Ristović, M. Š.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Bromo-Salicylaldehyde and α-Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA and Albumins. Polyhedron 2016, 107, 136–147. https://doi.org/10.1016/j.poly.2016.01.020. in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford..
https://hdl.handle.net/21.15107/rcub_cherry_3394
Zianna A, Šumar-Ristović M, Psomas G, Hatzidimitriou A, Coutouli-Argyropoulou E, Lalia-Kantouri M. Supplementary data for the article: Zianna, A.; Ristović, M. Š.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Bromo-Salicylaldehyde and α-Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA and Albumins. Polyhedron 2016, 107, 136–147. https://doi.org/10.1016/j.poly.2016.01.020. in Polyhedron. 2016;.
https://hdl.handle.net/21.15107/rcub_cherry_3394 .
Zianna, Ariadni, Šumar-Ristović, Maja, Psomas, George, Hatzidimitriou, Antonis, Coutouli-Argyropoulou, Evdoxia, Lalia-Kantouri, Maria, "Supplementary data for the article: Zianna, A.; Ristović, M. Š.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Bromo-Salicylaldehyde and α-Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA and Albumins. Polyhedron 2016, 107, 136–147. https://doi.org/10.1016/j.poly.2016.01.020" in Polyhedron (2016),
https://hdl.handle.net/21.15107/rcub_cherry_3394 .

Supplementary material for the article: Ristovic, M. S.; Zianna, A.; Psomas, G.; Hatzidimitriou, A. G.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Interaction of Dinuclear Cadmium(II) 5-Cl-Salicylaldehyde Complexes with Calf-Thymus DNA. Materials Science and Engineering C 2016, 61, 579–590. https://doi.org/10.1016/j.msec.2015.12.054

Šumar-Ristović, Maja; Zianna, Ariadni; Psomas, George; Hatzidimitriou, Antonios G.; Coutouli-Argyropoulou, Evdoxia; Lalia-Kantouri, Maria

(Elsevier Science Bv, Amsterdam, 2016)

TY  - DATA
AU  - Šumar-Ristović, Maja
AU  - Zianna, Ariadni
AU  - Psomas, George
AU  - Hatzidimitriou, Antonios G.
AU  - Coutouli-Argyropoulou, Evdoxia
AU  - Lalia-Kantouri, Maria
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3544
PB  - Elsevier Science Bv, Amsterdam
T2  - Materials Science and Engineering. C: Materials for Biological Applications
T1  - Supplementary material for the article: Ristovic, M. S.; Zianna, A.; Psomas, G.; Hatzidimitriou, A. G.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Interaction of Dinuclear Cadmium(II) 5-Cl-Salicylaldehyde Complexes with Calf-Thymus DNA. Materials Science and Engineering C 2016, 61, 579–590. https://doi.org/10.1016/j.msec.2015.12.054
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3544
ER  - 
@misc{
author = "Šumar-Ristović, Maja and Zianna, Ariadni and Psomas, George and Hatzidimitriou, Antonios G. and Coutouli-Argyropoulou, Evdoxia and Lalia-Kantouri, Maria",
year = "2016",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Materials Science and Engineering. C: Materials for Biological Applications",
title = "Supplementary material for the article: Ristovic, M. S.; Zianna, A.; Psomas, G.; Hatzidimitriou, A. G.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Interaction of Dinuclear Cadmium(II) 5-Cl-Salicylaldehyde Complexes with Calf-Thymus DNA. Materials Science and Engineering C 2016, 61, 579–590. https://doi.org/10.1016/j.msec.2015.12.054",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3544"
}
Šumar-Ristović, M., Zianna, A., Psomas, G., Hatzidimitriou, A. G., Coutouli-Argyropoulou, E.,& Lalia-Kantouri, M.. (2016). Supplementary material for the article: Ristovic, M. S.; Zianna, A.; Psomas, G.; Hatzidimitriou, A. G.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Interaction of Dinuclear Cadmium(II) 5-Cl-Salicylaldehyde Complexes with Calf-Thymus DNA. Materials Science and Engineering C 2016, 61, 579–590. https://doi.org/10.1016/j.msec.2015.12.054. in Materials Science and Engineering. C: Materials for Biological Applications
Elsevier Science Bv, Amsterdam..
https://hdl.handle.net/21.15107/rcub_cherry_3544
Šumar-Ristović M, Zianna A, Psomas G, Hatzidimitriou AG, Coutouli-Argyropoulou E, Lalia-Kantouri M. Supplementary material for the article: Ristovic, M. S.; Zianna, A.; Psomas, G.; Hatzidimitriou, A. G.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Interaction of Dinuclear Cadmium(II) 5-Cl-Salicylaldehyde Complexes with Calf-Thymus DNA. Materials Science and Engineering C 2016, 61, 579–590. https://doi.org/10.1016/j.msec.2015.12.054. in Materials Science and Engineering. C: Materials for Biological Applications. 2016;.
https://hdl.handle.net/21.15107/rcub_cherry_3544 .
Šumar-Ristović, Maja, Zianna, Ariadni, Psomas, George, Hatzidimitriou, Antonios G., Coutouli-Argyropoulou, Evdoxia, Lalia-Kantouri, Maria, "Supplementary material for the article: Ristovic, M. S.; Zianna, A.; Psomas, G.; Hatzidimitriou, A. G.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Interaction of Dinuclear Cadmium(II) 5-Cl-Salicylaldehyde Complexes with Calf-Thymus DNA. Materials Science and Engineering C 2016, 61, 579–590. https://doi.org/10.1016/j.msec.2015.12.054" in Materials Science and Engineering. C: Materials for Biological Applications (2016),
https://hdl.handle.net/21.15107/rcub_cherry_3544 .

Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA

Zianna, Ariadni; Šumar-Ristović, Maja; Psomas, George; Hatzidimitriou, Antonis; Coutouli-Argyropoulou, Evdoxia; Lalia-Kantouri, Maria

(Taylor & Francis Ltd, Abingdon, 2015)

TY  - JOUR
AU  - Zianna, Ariadni
AU  - Šumar-Ristović, Maja
AU  - Psomas, George
AU  - Hatzidimitriou, Antonis
AU  - Coutouli-Argyropoulou, Evdoxia
AU  - Lalia-Kantouri, Maria
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2004
AB  - Five Cd( II) complexes with the anion of 5- NO2- salicylaldehydeH ( 5- NO2- saloH) in the absence or presence of the alpha-diimine 1,10- phenanthroline ( phen), 2,2'- dipyridylamine ( dpamH), 2,2'- dipyridine ( bipy), or 2,9- dimethyl- 1,10- phenanthroline ( neoc) were synthesized and characterized as [Cd(5- NO2- salo)(2)(CH3OH)(2)] (1), [Cd(5-NO2- salo)(2)( phen)] center dot 2CH3OH center dot H2O (2), [Cd(5- NO2- salo) 2( dpam.)] (3), [Cd-3(5-NO2- salo)(6)(bipy)(2)] (4), and [ Cd(5-NO2-salo)(neoc)(NO3)](2) (5). Based on spectroscopic results ( IR, UV, NMR), elemental analysis and conductivity measurements an octahedral geometry around cadmium metal ion is suggested, with the 5- NO2- salicylaldehyde ligand having different coordination modes. The structures determined by X-ray crystallography verified neutral mononuclear 1-3 and trinuclear 4. Simultaneous TG/DTG-DTA technique was used to analyze the thermal behavior of 1, 2, and 3. The complexes bind tightly to calf-thymus DNA mainly by intercalation, as concluded by DNA viscosity measurements and exhibit significant displacement of EB from the EB- DNA complex.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA
VL  - 68
IS  - 24
SP  - 4444
EP  - 4463
DO  - 10.1080/00958972.2015.1101075
ER  - 
@article{
author = "Zianna, Ariadni and Šumar-Ristović, Maja and Psomas, George and Hatzidimitriou, Antonis and Coutouli-Argyropoulou, Evdoxia and Lalia-Kantouri, Maria",
year = "2015",
abstract = "Five Cd( II) complexes with the anion of 5- NO2- salicylaldehydeH ( 5- NO2- saloH) in the absence or presence of the alpha-diimine 1,10- phenanthroline ( phen), 2,2'- dipyridylamine ( dpamH), 2,2'- dipyridine ( bipy), or 2,9- dimethyl- 1,10- phenanthroline ( neoc) were synthesized and characterized as [Cd(5- NO2- salo)(2)(CH3OH)(2)] (1), [Cd(5-NO2- salo)(2)( phen)] center dot 2CH3OH center dot H2O (2), [Cd(5- NO2- salo) 2( dpam.)] (3), [Cd-3(5-NO2- salo)(6)(bipy)(2)] (4), and [ Cd(5-NO2-salo)(neoc)(NO3)](2) (5). Based on spectroscopic results ( IR, UV, NMR), elemental analysis and conductivity measurements an octahedral geometry around cadmium metal ion is suggested, with the 5- NO2- salicylaldehyde ligand having different coordination modes. The structures determined by X-ray crystallography verified neutral mononuclear 1-3 and trinuclear 4. Simultaneous TG/DTG-DTA technique was used to analyze the thermal behavior of 1, 2, and 3. The complexes bind tightly to calf-thymus DNA mainly by intercalation, as concluded by DNA viscosity measurements and exhibit significant displacement of EB from the EB- DNA complex.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA",
volume = "68",
number = "24",
pages = "4444-4463",
doi = "10.1080/00958972.2015.1101075"
}
Zianna, A., Šumar-Ristović, M., Psomas, G., Hatzidimitriou, A., Coutouli-Argyropoulou, E.,& Lalia-Kantouri, M.. (2015). Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 68(24), 4444-4463.
https://doi.org/10.1080/00958972.2015.1101075
Zianna A, Šumar-Ristović M, Psomas G, Hatzidimitriou A, Coutouli-Argyropoulou E, Lalia-Kantouri M. Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA. in Journal of Coordination Chemistry. 2015;68(24):4444-4463.
doi:10.1080/00958972.2015.1101075 .
Zianna, Ariadni, Šumar-Ristović, Maja, Psomas, George, Hatzidimitriou, Antonis, Coutouli-Argyropoulou, Evdoxia, Lalia-Kantouri, Maria, "Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA" in Journal of Coordination Chemistry, 68, no. 24 (2015):4444-4463,
https://doi.org/10.1080/00958972.2015.1101075 . .
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Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA

Zianna, Ariadni; Šumar-Ristović, Maja; Psomas, George; Hatzidimitriou, Antonis; Coutouli-Argyropoulou, Evdoxia; Lalia-Kantouri, Maria

(Taylor & Francis Ltd, Abingdon, 2015)

TY  - JOUR
AU  - Zianna, Ariadni
AU  - Šumar-Ristović, Maja
AU  - Psomas, George
AU  - Hatzidimitriou, Antonis
AU  - Coutouli-Argyropoulou, Evdoxia
AU  - Lalia-Kantouri, Maria
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3350
AB  - Five Cd( II) complexes with the anion of 5- NO2- salicylaldehydeH ( 5- NO2- saloH) in the absence or presence of the alpha-diimine 1,10- phenanthroline ( phen), 2,2'- dipyridylamine ( dpamH), 2,2'- dipyridine ( bipy), or 2,9- dimethyl- 1,10- phenanthroline ( neoc) were synthesized and characterized as [Cd(5- NO2- salo)(2)(CH3OH)(2)] (1), [Cd(5-NO2- salo)(2)( phen)] center dot 2CH3OH center dot H2O (2), [Cd(5- NO2- salo) 2( dpam.)] (3), [Cd-3(5-NO2- salo)(6)(bipy)(2)] (4), and [ Cd(5-NO2-salo)(neoc)(NO3)](2) (5). Based on spectroscopic results ( IR, UV, NMR), elemental analysis and conductivity measurements an octahedral geometry around cadmium metal ion is suggested, with the 5- NO2- salicylaldehyde ligand having different coordination modes. The structures determined by X-ray crystallography verified neutral mononuclear 1-3 and trinuclear 4. Simultaneous TG/DTG-DTA technique was used to analyze the thermal behavior of 1, 2, and 3. The complexes bind tightly to calf-thymus DNA mainly by intercalation, as concluded by DNA viscosity measurements and exhibit significant displacement of EB from the EB- DNA complex.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA
VL  - 68
IS  - 24
SP  - 4444
EP  - 4463
DO  - 10.1080/00958972.2015.1101075
ER  - 
@article{
author = "Zianna, Ariadni and Šumar-Ristović, Maja and Psomas, George and Hatzidimitriou, Antonis and Coutouli-Argyropoulou, Evdoxia and Lalia-Kantouri, Maria",
year = "2015",
abstract = "Five Cd( II) complexes with the anion of 5- NO2- salicylaldehydeH ( 5- NO2- saloH) in the absence or presence of the alpha-diimine 1,10- phenanthroline ( phen), 2,2'- dipyridylamine ( dpamH), 2,2'- dipyridine ( bipy), or 2,9- dimethyl- 1,10- phenanthroline ( neoc) were synthesized and characterized as [Cd(5- NO2- salo)(2)(CH3OH)(2)] (1), [Cd(5-NO2- salo)(2)( phen)] center dot 2CH3OH center dot H2O (2), [Cd(5- NO2- salo) 2( dpam.)] (3), [Cd-3(5-NO2- salo)(6)(bipy)(2)] (4), and [ Cd(5-NO2-salo)(neoc)(NO3)](2) (5). Based on spectroscopic results ( IR, UV, NMR), elemental analysis and conductivity measurements an octahedral geometry around cadmium metal ion is suggested, with the 5- NO2- salicylaldehyde ligand having different coordination modes. The structures determined by X-ray crystallography verified neutral mononuclear 1-3 and trinuclear 4. Simultaneous TG/DTG-DTA technique was used to analyze the thermal behavior of 1, 2, and 3. The complexes bind tightly to calf-thymus DNA mainly by intercalation, as concluded by DNA viscosity measurements and exhibit significant displacement of EB from the EB- DNA complex.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA",
volume = "68",
number = "24",
pages = "4444-4463",
doi = "10.1080/00958972.2015.1101075"
}
Zianna, A., Šumar-Ristović, M., Psomas, G., Hatzidimitriou, A., Coutouli-Argyropoulou, E.,& Lalia-Kantouri, M.. (2015). Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 68(24), 4444-4463.
https://doi.org/10.1080/00958972.2015.1101075
Zianna A, Šumar-Ristović M, Psomas G, Hatzidimitriou A, Coutouli-Argyropoulou E, Lalia-Kantouri M. Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA. in Journal of Coordination Chemistry. 2015;68(24):4444-4463.
doi:10.1080/00958972.2015.1101075 .
Zianna, Ariadni, Šumar-Ristović, Maja, Psomas, George, Hatzidimitriou, Antonis, Coutouli-Argyropoulou, Evdoxia, Lalia-Kantouri, Maria, "Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA" in Journal of Coordination Chemistry, 68, no. 24 (2015):4444-4463,
https://doi.org/10.1080/00958972.2015.1101075 . .
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Supplementary data for article: Zianna, A.; Sumar Ristovic, M.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Nitro-Salicylaldehyde and α -Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA. Journal of Coordination Chemistry 2015, 68 (24), 4444–4463. https://doi.org/10.1080/00958972.2015.1101075

Zianna, Ariadni; Šumar-Ristović, Maja; Psomas, George; Hatzidimitriou, Antonis; Coutouli-Argyropoulou, Evdoxia; Lalia-Kantouri, Maria

(Taylor & Francis Ltd, Abingdon, 2015)

TY  - DATA
AU  - Zianna, Ariadni
AU  - Šumar-Ristović, Maja
AU  - Psomas, George
AU  - Hatzidimitriou, Antonis
AU  - Coutouli-Argyropoulou, Evdoxia
AU  - Lalia-Kantouri, Maria
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3351
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Supplementary data for article: Zianna, A.; Sumar Ristovic, M.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Nitro-Salicylaldehyde and α -Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA. Journal of Coordination Chemistry 2015, 68 (24), 4444–4463. https://doi.org/10.1080/00958972.2015.1101075
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3351
ER  - 
@misc{
author = "Zianna, Ariadni and Šumar-Ristović, Maja and Psomas, George and Hatzidimitriou, Antonis and Coutouli-Argyropoulou, Evdoxia and Lalia-Kantouri, Maria",
year = "2015",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Supplementary data for article: Zianna, A.; Sumar Ristovic, M.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Nitro-Salicylaldehyde and α -Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA. Journal of Coordination Chemistry 2015, 68 (24), 4444–4463. https://doi.org/10.1080/00958972.2015.1101075",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3351"
}
Zianna, A., Šumar-Ristović, M., Psomas, G., Hatzidimitriou, A., Coutouli-Argyropoulou, E.,& Lalia-Kantouri, M.. (2015). Supplementary data for article: Zianna, A.; Sumar Ristovic, M.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Nitro-Salicylaldehyde and α -Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA. Journal of Coordination Chemistry 2015, 68 (24), 4444–4463. https://doi.org/10.1080/00958972.2015.1101075. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon..
https://hdl.handle.net/21.15107/rcub_cherry_3351
Zianna A, Šumar-Ristović M, Psomas G, Hatzidimitriou A, Coutouli-Argyropoulou E, Lalia-Kantouri M. Supplementary data for article: Zianna, A.; Sumar Ristovic, M.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Nitro-Salicylaldehyde and α -Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA. Journal of Coordination Chemistry 2015, 68 (24), 4444–4463. https://doi.org/10.1080/00958972.2015.1101075. in Journal of Coordination Chemistry. 2015;.
https://hdl.handle.net/21.15107/rcub_cherry_3351 .
Zianna, Ariadni, Šumar-Ristović, Maja, Psomas, George, Hatzidimitriou, Antonis, Coutouli-Argyropoulou, Evdoxia, Lalia-Kantouri, Maria, "Supplementary data for article: Zianna, A.; Sumar Ristovic, M.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Nitro-Salicylaldehyde and α -Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA. Journal of Coordination Chemistry 2015, 68 (24), 4444–4463. https://doi.org/10.1080/00958972.2015.1101075" in Journal of Coordination Chemistry (2015),
https://hdl.handle.net/21.15107/rcub_cherry_3351 .

Synthesis, thermal analysis, and spectroscopic and structural characterizations of tetranuclear nickel(II) cubane-type clusters with 2-hydroxybenzaldehydes or 2-hydroxyphenones

Zianna, Ariadni; Šumar-Ristović, Maja; Hatzidimitriou, Antonis; Papadopoulos, Christos D.; Lalia-Kantouri, Maria

(Springer, Dordrecht, 2014)

TY  - JOUR
AU  - Zianna, Ariadni
AU  - Šumar-Ristović, Maja
AU  - Hatzidimitriou, Antonis
AU  - Papadopoulos, Christos D.
AU  - Lalia-Kantouri, Maria
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1879
AB  - In this study, three novel tetranuclear nickel(II) cubane-type clusters with the general formula [Ni-4(L)(4)(mu(3)-CH3O)(4)(CH3OH)(4)] [L: the anion of 5-methyl-2-hydroxybenzaldehyde (1), 2-hydroxypropiophenone (2), and 2-hydroxybenzophenone (3)] were synthesized and characterized by single-crystal X-ray diffraction analysis. The crystal structure of each compound contains a tetranuclear cubane core [Ni4O4] based on an approximately cubic array of altering nickel and oxygen atoms with intracluster metal-metal separations of 3.04-3.14 . Each Ni(II) atom is surrounded by two oxygen atoms from the ligand (L) and by the mu(3)-CH3O oxygen atom that bridges three Ni atoms of the cubane core. The coordination sphere of Ni is completed with one methanol molecule and making six-coordinate with a distorted octahedral geometry. These complexes were characterized also by spectroscopy (IR and UV-Vis). Simultaneous TG/DTG-DTA techniques were used to analyze their thermal behavior under inert atmosphere, with particular attention to determine their thermal degradation pathways, which was found to be a multi-step decomposition accompanied by the release of the ligand molecules. Finally, the kinetic analysis of the decomposition processes was performed for the first step of complex (3), since only this verifies the requirement of applying an isoconversional method like Kissinger-Akahira-Sunose (KAS). For this step, we found the average value E (a) = 107.8 +/- A 4.5 kJ mol(-1).
PB  - Springer, Dordrecht
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Synthesis, thermal analysis, and spectroscopic and structural characterizations of tetranuclear nickel(II) cubane-type clusters with 2-hydroxybenzaldehydes or 2-hydroxyphenones
VL  - 118
IS  - 3
SP  - 1431
EP  - 1440
DO  - 10.1007/s10973-014-4035-5
ER  - 
@article{
author = "Zianna, Ariadni and Šumar-Ristović, Maja and Hatzidimitriou, Antonis and Papadopoulos, Christos D. and Lalia-Kantouri, Maria",
year = "2014",
abstract = "In this study, three novel tetranuclear nickel(II) cubane-type clusters with the general formula [Ni-4(L)(4)(mu(3)-CH3O)(4)(CH3OH)(4)] [L: the anion of 5-methyl-2-hydroxybenzaldehyde (1), 2-hydroxypropiophenone (2), and 2-hydroxybenzophenone (3)] were synthesized and characterized by single-crystal X-ray diffraction analysis. The crystal structure of each compound contains a tetranuclear cubane core [Ni4O4] based on an approximately cubic array of altering nickel and oxygen atoms with intracluster metal-metal separations of 3.04-3.14 . Each Ni(II) atom is surrounded by two oxygen atoms from the ligand (L) and by the mu(3)-CH3O oxygen atom that bridges three Ni atoms of the cubane core. The coordination sphere of Ni is completed with one methanol molecule and making six-coordinate with a distorted octahedral geometry. These complexes were characterized also by spectroscopy (IR and UV-Vis). Simultaneous TG/DTG-DTA techniques were used to analyze their thermal behavior under inert atmosphere, with particular attention to determine their thermal degradation pathways, which was found to be a multi-step decomposition accompanied by the release of the ligand molecules. Finally, the kinetic analysis of the decomposition processes was performed for the first step of complex (3), since only this verifies the requirement of applying an isoconversional method like Kissinger-Akahira-Sunose (KAS). For this step, we found the average value E (a) = 107.8 +/- A 4.5 kJ mol(-1).",
publisher = "Springer, Dordrecht",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Synthesis, thermal analysis, and spectroscopic and structural characterizations of tetranuclear nickel(II) cubane-type clusters with 2-hydroxybenzaldehydes or 2-hydroxyphenones",
volume = "118",
number = "3",
pages = "1431-1440",
doi = "10.1007/s10973-014-4035-5"
}
Zianna, A., Šumar-Ristović, M., Hatzidimitriou, A., Papadopoulos, C. D.,& Lalia-Kantouri, M.. (2014). Synthesis, thermal analysis, and spectroscopic and structural characterizations of tetranuclear nickel(II) cubane-type clusters with 2-hydroxybenzaldehydes or 2-hydroxyphenones. in Journal of Thermal Analysis and Calorimetry
Springer, Dordrecht., 118(3), 1431-1440.
https://doi.org/10.1007/s10973-014-4035-5
Zianna A, Šumar-Ristović M, Hatzidimitriou A, Papadopoulos CD, Lalia-Kantouri M. Synthesis, thermal analysis, and spectroscopic and structural characterizations of tetranuclear nickel(II) cubane-type clusters with 2-hydroxybenzaldehydes or 2-hydroxyphenones. in Journal of Thermal Analysis and Calorimetry. 2014;118(3):1431-1440.
doi:10.1007/s10973-014-4035-5 .
Zianna, Ariadni, Šumar-Ristović, Maja, Hatzidimitriou, Antonis, Papadopoulos, Christos D., Lalia-Kantouri, Maria, "Synthesis, thermal analysis, and spectroscopic and structural characterizations of tetranuclear nickel(II) cubane-type clusters with 2-hydroxybenzaldehydes or 2-hydroxyphenones" in Journal of Thermal Analysis and Calorimetry, 118, no. 3 (2014):1431-1440,
https://doi.org/10.1007/s10973-014-4035-5 . .
4
4
4
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