@misc{
author = "Ferjančić, Zorana and Kukuruzar, Andrej and Bihelović, Filip",
year = "2022",
abstract = "An enantioselective total synthesis of (+)-alstonlarsine A (1), a monoterpenoid indole alkaloid possessing a unique pentacyclic skeleton as well as a rare biological activity, is achieved. The key step is an efficient domino sequence, comprising enamine formation followed by an inverse-electron-demand intramolecular dearomative Diels–Alder cycloaddition for the construction of 9-azatricyclo[4.3.1.03,8]decane core. The key intermediate for this domino sequence was synthesized by a newly developed methodology, relying on indole C(2)-H bond functionalization, combined with intramolecular Horner–Wadsworth–Emmons reaction. This tactical combination offers a new general entry into other (privileged) tricyclic frameworks possessing indole ring fused to 6-, 7- or 8-membered rings.",
publisher = "Wiley",
journal = "Angewandte Chemie International Edition",
title = "Supplementary material for: Ferjančić, Z., Kukuruzar, A.,& Bihelović, F.. (2022). Total Synthesis of (+)-Alstonlarsine A. in Angewandte Chemie International Edition Wiley., 61(39), e202210297. https://doi.org/10.1002/anie.202210297",
volume = "61",
number = "39",
pages = "e202210297",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5844"
}