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CEEPUS project [CII-AT-0038-01-0506-M-2329]

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Core and shell structure of ytterbium sesquioxide nanoparticles

Vucinic-Vasic, Milica; Kremenović, Aleksandar; Nikolić, Aleksandar S.; Colomban, Philippe; Mazzerolles, Leo; Kahlenberg, Volker; Antić, Bratislav

(Elsevier Science Sa, Lausanne, 2010)

TY  - JOUR
AU  - Vucinic-Vasic, Milica
AU  - Kremenović, Aleksandar
AU  - Nikolić, Aleksandar S.
AU  - Colomban, Philippe
AU  - Mazzerolles, Leo
AU  - Kahlenberg, Volker
AU  - Antić, Bratislav
PY  - 2010
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1094
AB  - This paper reports results concerning the crystal structure of core and shell as well as microstructure of 25 nm-ytterbium sesquioxide (Yb(2)O(3)) nanoparticles synthesized using a unique method based on thermal decomposition of a 2,4 pentadione complex. Used Raman spectroscopy measurements indicate core/shell structure, with monoclinic or a mixture of monoclinic and cubic symmetry of the particle shell. In addition, XRPD and SAED confirmed bixbyite structure type for the core (space group Ia (3) over bar). Broadening of the observed Raman bands indicates structural distortions in the nanocrystalline sample. The size/strain analysis was done on XRPD data using Fullprof/MarqX approach. Anisotropy of X-ray line broadening is caused by size effects only. The resulting mean microstrain (6 x 10(-4)) points to a low concentration of defects within the crystallites. (C) 2010 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - Core and shell structure of ytterbium sesquioxide nanoparticles
VL  - 502
IS  - 1
SP  - 107
EP  - 111
DO  - 10.1016/j.jallcom.2010.03.158
ER  - 
@article{
author = "Vucinic-Vasic, Milica and Kremenović, Aleksandar and Nikolić, Aleksandar S. and Colomban, Philippe and Mazzerolles, Leo and Kahlenberg, Volker and Antić, Bratislav",
year = "2010",
abstract = "This paper reports results concerning the crystal structure of core and shell as well as microstructure of 25 nm-ytterbium sesquioxide (Yb(2)O(3)) nanoparticles synthesized using a unique method based on thermal decomposition of a 2,4 pentadione complex. Used Raman spectroscopy measurements indicate core/shell structure, with monoclinic or a mixture of monoclinic and cubic symmetry of the particle shell. In addition, XRPD and SAED confirmed bixbyite structure type for the core (space group Ia (3) over bar). Broadening of the observed Raman bands indicates structural distortions in the nanocrystalline sample. The size/strain analysis was done on XRPD data using Fullprof/MarqX approach. Anisotropy of X-ray line broadening is caused by size effects only. The resulting mean microstrain (6 x 10(-4)) points to a low concentration of defects within the crystallites. (C) 2010 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "Core and shell structure of ytterbium sesquioxide nanoparticles",
volume = "502",
number = "1",
pages = "107-111",
doi = "10.1016/j.jallcom.2010.03.158"
}
Vucinic-Vasic, M., Kremenović, A., Nikolić, A. S., Colomban, P., Mazzerolles, L., Kahlenberg, V.,& Antić, B.. (2010). Core and shell structure of ytterbium sesquioxide nanoparticles. in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 502(1), 107-111.
https://doi.org/10.1016/j.jallcom.2010.03.158
Vucinic-Vasic M, Kremenović A, Nikolić AS, Colomban P, Mazzerolles L, Kahlenberg V, Antić B. Core and shell structure of ytterbium sesquioxide nanoparticles. in Journal of Alloys and Compounds. 2010;502(1):107-111.
doi:10.1016/j.jallcom.2010.03.158 .
Vucinic-Vasic, Milica, Kremenović, Aleksandar, Nikolić, Aleksandar S., Colomban, Philippe, Mazzerolles, Leo, Kahlenberg, Volker, Antić, Bratislav, "Core and shell structure of ytterbium sesquioxide nanoparticles" in Journal of Alloys and Compounds, 502, no. 1 (2010):107-111,
https://doi.org/10.1016/j.jallcom.2010.03.158 . .
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