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Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]

Filipović, Nenad R.; Borna, Marija; Klisurić, Olivera; Pregelj, Matej; Jagodić, Marko; Anđelković, Katarina K.; Todorović, Tamara

(Taylor & Francis Ltd, Abingdon, 2013)

TY  - JOUR
AU  - Filipović, Nenad R.
AU  - Borna, Marija
AU  - Klisurić, Olivera
AU  - Pregelj, Matej
AU  - Jagodić, Marko
AU  - Anđelković, Katarina K.
AU  - Todorović, Tamara
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1639
AB  - Copper(II) and zinc(II) complexes with the condensation derivative of 2-acetylpyridine and hydrolyzed ethyl hydrazinoacetate were synthesized in a one pot reaction. Crystal structure of the zinc(II) complex was determined by single-crystal X-ray diffraction. In this binuclear complex, the ligand is coordinated via pyridine and imine nitrogen, while carboxylate oxygen is a bridge between metal centers. The fifth coordination site is occupied by a chloride, giving a distorted square pyramidal geometry around each zinc(II). The molecular structure of the copper(II) complex was determined from elemental analysis, infrared and electron paramagnetic resonance spectroscopy, molar conductivity, mass spectrometry, and measurements of the magnetic moment. Thermal behavior of both complexes was studied by thermogravimetric analysis coupled with mass spectrometer.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]
VL  - 66
IS  - 9
SP  - 1549
EP  - 1560
DO  - 10.1080/00958972.2013.786052
ER  - 
@article{
author = "Filipović, Nenad R. and Borna, Marija and Klisurić, Olivera and Pregelj, Matej and Jagodić, Marko and Anđelković, Katarina K. and Todorović, Tamara",
year = "2013",
abstract = "Copper(II) and zinc(II) complexes with the condensation derivative of 2-acetylpyridine and hydrolyzed ethyl hydrazinoacetate were synthesized in a one pot reaction. Crystal structure of the zinc(II) complex was determined by single-crystal X-ray diffraction. In this binuclear complex, the ligand is coordinated via pyridine and imine nitrogen, while carboxylate oxygen is a bridge between metal centers. The fifth coordination site is occupied by a chloride, giving a distorted square pyramidal geometry around each zinc(II). The molecular structure of the copper(II) complex was determined from elemental analysis, infrared and electron paramagnetic resonance spectroscopy, molar conductivity, mass spectrometry, and measurements of the magnetic moment. Thermal behavior of both complexes was studied by thermogravimetric analysis coupled with mass spectrometer.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]",
volume = "66",
number = "9",
pages = "1549-1560",
doi = "10.1080/00958972.2013.786052"
}
Filipović, N. R., Borna, M., Klisurić, O., Pregelj, M., Jagodić, M., Anđelković, K. K.,& Todorović, T.. (2013). Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 66(9), 1549-1560.
https://doi.org/10.1080/00958972.2013.786052
Filipović NR, Borna M, Klisurić O, Pregelj M, Jagodić M, Anđelković KK, Todorović T. Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]. in Journal of Coordination Chemistry. 2013;66(9):1549-1560.
doi:10.1080/00958972.2013.786052 .
Filipović, Nenad R., Borna, Marija, Klisurić, Olivera, Pregelj, Matej, Jagodić, Marko, Anđelković, Katarina K., Todorović, Tamara, "Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]" in Journal of Coordination Chemistry, 66, no. 9 (2013):1549-1560,
https://doi.org/10.1080/00958972.2013.786052 . .
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Supplementary data for article: Filipović, N. R.; Borna, M.; Klisurić, O.; Pregelj, M.; Jagodić, M.; Anđelković, K. K.; Todorović, T. Synthesis, Characterization, and Thermal Behavior of Cu(II) and Zn(II) Complexes with (E)-2-[N-(1-Pyridin-2-Yl-Ethylidene)Hydrazino]Acetic Acid (AphaOH). Crystal Structure of [Zn-2(AphaO)(2)Cl-2]. Journal of Coordination Chemistry 2013, 66 (9), 1549–1560. https://doi.org/10.1080/00958972.2013.786052

Filipović, Nenad R.; Borna, Marija; Klisurić, Olivera; Pregelj, Matej; Jagodić, Marko; Anđelković, Katarina K.; Todorović, Tamara

(Taylor & Francis Ltd, Abingdon, 2013)

TY  - DATA
AU  - Filipović, Nenad R.
AU  - Borna, Marija
AU  - Klisurić, Olivera
AU  - Pregelj, Matej
AU  - Jagodić, Marko
AU  - Anđelković, Katarina K.
AU  - Todorović, Tamara
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3538
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Supplementary data for article: Filipović, N. R.; Borna, M.; Klisurić, O.; Pregelj, M.; Jagodić, M.; Anđelković, K. K.; Todorović, T. Synthesis, Characterization, and Thermal Behavior of Cu(II) and Zn(II) Complexes with (E)-2-[N-(1-Pyridin-2-Yl-Ethylidene)Hydrazino]Acetic Acid (AphaOH). Crystal Structure of [Zn-2(AphaO)(2)Cl-2]. Journal of Coordination Chemistry 2013, 66 (9), 1549–1560. https://doi.org/10.1080/00958972.2013.786052
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3538
ER  - 
@misc{
author = "Filipović, Nenad R. and Borna, Marija and Klisurić, Olivera and Pregelj, Matej and Jagodić, Marko and Anđelković, Katarina K. and Todorović, Tamara",
year = "2013",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Supplementary data for article: Filipović, N. R.; Borna, M.; Klisurić, O.; Pregelj, M.; Jagodić, M.; Anđelković, K. K.; Todorović, T. Synthesis, Characterization, and Thermal Behavior of Cu(II) and Zn(II) Complexes with (E)-2-[N-(1-Pyridin-2-Yl-Ethylidene)Hydrazino]Acetic Acid (AphaOH). Crystal Structure of [Zn-2(AphaO)(2)Cl-2]. Journal of Coordination Chemistry 2013, 66 (9), 1549–1560. https://doi.org/10.1080/00958972.2013.786052",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3538"
}
Filipović, N. R., Borna, M., Klisurić, O., Pregelj, M., Jagodić, M., Anđelković, K. K.,& Todorović, T.. (2013). Supplementary data for article: Filipović, N. R.; Borna, M.; Klisurić, O.; Pregelj, M.; Jagodić, M.; Anđelković, K. K.; Todorović, T. Synthesis, Characterization, and Thermal Behavior of Cu(II) and Zn(II) Complexes with (E)-2-[N-(1-Pyridin-2-Yl-Ethylidene)Hydrazino]Acetic Acid (AphaOH). Crystal Structure of [Zn-2(AphaO)(2)Cl-2]. Journal of Coordination Chemistry 2013, 66 (9), 1549–1560. https://doi.org/10.1080/00958972.2013.786052. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon..
https://hdl.handle.net/21.15107/rcub_cherry_3538
Filipović NR, Borna M, Klisurić O, Pregelj M, Jagodić M, Anđelković KK, Todorović T. Supplementary data for article: Filipović, N. R.; Borna, M.; Klisurić, O.; Pregelj, M.; Jagodić, M.; Anđelković, K. K.; Todorović, T. Synthesis, Characterization, and Thermal Behavior of Cu(II) and Zn(II) Complexes with (E)-2-[N-(1-Pyridin-2-Yl-Ethylidene)Hydrazino]Acetic Acid (AphaOH). Crystal Structure of [Zn-2(AphaO)(2)Cl-2]. Journal of Coordination Chemistry 2013, 66 (9), 1549–1560. https://doi.org/10.1080/00958972.2013.786052. in Journal of Coordination Chemistry. 2013;.
https://hdl.handle.net/21.15107/rcub_cherry_3538 .
Filipović, Nenad R., Borna, Marija, Klisurić, Olivera, Pregelj, Matej, Jagodić, Marko, Anđelković, Katarina K., Todorović, Tamara, "Supplementary data for article: Filipović, N. R.; Borna, M.; Klisurić, O.; Pregelj, M.; Jagodić, M.; Anđelković, K. K.; Todorović, T. Synthesis, Characterization, and Thermal Behavior of Cu(II) and Zn(II) Complexes with (E)-2-[N-(1-Pyridin-2-Yl-Ethylidene)Hydrazino]Acetic Acid (AphaOH). Crystal Structure of [Zn-2(AphaO)(2)Cl-2]. Journal of Coordination Chemistry 2013, 66 (9), 1549–1560. https://doi.org/10.1080/00958972.2013.786052" in Journal of Coordination Chemistry (2013),
https://hdl.handle.net/21.15107/rcub_cherry_3538 .

Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity

Filipović, Nenad R.; Borrmann, Horst; Todorović, Tamara; Borna, Marija; Spasojević, Vojislav; Sladić, Dušan; Novaković, Irena T.; Anđelković, Katarina K.

(Elsevier Science Sa, Lausanne, 2009)

TY  - JOUR
AU  - Filipović, Nenad R.
AU  - Borrmann, Horst
AU  - Todorović, Tamara
AU  - Borna, Marija
AU  - Spasojević, Vojislav
AU  - Sladić, Dušan
AU  - Novaković, Irena T.
AU  - Anđelković, Katarina K.
PY  - 2009
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/629
AB  - Three novel copper(II) complexes as condensation derivatives of 2-pyridinecarboxaldehyde, 2-acetylpyridine or 2-quinolinecarboxaldehyde with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of all three complexes were determined. Crystallographic data indicate a common basis of the structures with some major differences. Both pyridine derivatives form complexes of the type [CuCl2L] with distorted square-planar geometry around copper(II), but show a decisive difference in the side chain orientation. The quinoline derivative forms a dimeric complex of type [Cu2Cl4L2] with distorted trigonal bipyramidal geometry around copper(II), but a rather short Cu center dot center dot center dot Cu contact, which is reflected in its magnetic properties. All three complexes showed antibacterial activity. (c) 2008 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Sa, Lausanne
T2  - Inorganica Chimica Acta
T1  - Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity
VL  - 362
IS  - 6
SP  - 1996
EP  - 2000
DO  - 10.1016/j.ica.2008.09.019
ER  - 
@article{
author = "Filipović, Nenad R. and Borrmann, Horst and Todorović, Tamara and Borna, Marija and Spasojević, Vojislav and Sladić, Dušan and Novaković, Irena T. and Anđelković, Katarina K.",
year = "2009",
abstract = "Three novel copper(II) complexes as condensation derivatives of 2-pyridinecarboxaldehyde, 2-acetylpyridine or 2-quinolinecarboxaldehyde with ethyl hydrazinoacetate hydrochloride were synthesized. X-ray crystal structures of all three complexes were determined. Crystallographic data indicate a common basis of the structures with some major differences. Both pyridine derivatives form complexes of the type [CuCl2L] with distorted square-planar geometry around copper(II), but show a decisive difference in the side chain orientation. The quinoline derivative forms a dimeric complex of type [Cu2Cl4L2] with distorted trigonal bipyramidal geometry around copper(II), but a rather short Cu center dot center dot center dot Cu contact, which is reflected in its magnetic properties. All three complexes showed antibacterial activity. (c) 2008 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Inorganica Chimica Acta",
title = "Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity",
volume = "362",
number = "6",
pages = "1996-2000",
doi = "10.1016/j.ica.2008.09.019"
}
Filipović, N. R., Borrmann, H., Todorović, T., Borna, M., Spasojević, V., Sladić, D., Novaković, I. T.,& Anđelković, K. K.. (2009). Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity. in Inorganica Chimica Acta
Elsevier Science Sa, Lausanne., 362(6), 1996-2000.
https://doi.org/10.1016/j.ica.2008.09.019
Filipović NR, Borrmann H, Todorović T, Borna M, Spasojević V, Sladić D, Novaković IT, Anđelković KK. Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity. in Inorganica Chimica Acta. 2009;362(6):1996-2000.
doi:10.1016/j.ica.2008.09.019 .
Filipović, Nenad R., Borrmann, Horst, Todorović, Tamara, Borna, Marija, Spasojević, Vojislav, Sladić, Dušan, Novaković, Irena T., Anđelković, Katarina K., "Copper(II) complexes of N-heteroaromatic hydrazones: Synthesis, X-ray structure, magnetic behavior, and antibacterial activity" in Inorganica Chimica Acta, 362, no. 6 (2009):1996-2000,
https://doi.org/10.1016/j.ica.2008.09.019 . .
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