Razvoj novih sintetičkih metoda i njihova primena u sintezi prirodnih proizvoda i biološki aktivnih jedinjenja

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Razvoj novih sintetičkih metoda i njihova primena u sintezi prirodnih proizvoda i biološki aktivnih jedinjenja (en)
Развој нових синтетичких метода и њихова примена у синтези природних производа и биолошки активних једињења (sr)
Razvoj novih sintetičkih metoda i njihova primena u sintezi prirodnih proizvoda i biološki aktivnih jedinjenja (sr_RS)
Authors

Publications

Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings

Vulović, Bojan; Bihelović, Filip; Matović, Radomir; Saičić, Radomir

(Pergamon-Elsevier Science Ltd, Oxford, 2009)

TY  - JOUR
AU  - Vulović, Bojan
AU  - Bihelović, Filip
AU  - Matović, Radomir
AU  - Saičić, Radomir
PY  - 2009
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/1031
AB  - A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Tetrahedron
T1  - Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings
VL  - 65
IS  - 50
SP  - 10485
EP  - 10494
DO  - 10.1016/j.tet.2009.10.006
ER  - 
@article{
author = "Vulović, Bojan and Bihelović, Filip and Matović, Radomir and Saičić, Radomir",
year = "2009",
url = "http://cherry.chem.bg.ac.rs/handle/123456789/1031",
abstract = "A combination of organotransition metal catalysis and organocatalysis allows for Tsuji-Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee. (C) 2009 Elsevier Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Tetrahedron",
title = "Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings",
volume = "65",
number = "50",
pages = "10485-10494",
doi = "10.1016/j.tet.2009.10.006"
}
Vulović, B., Bihelović, F., Matović, R.,& Saičić, R. (2009). Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings.
Tetrahedron
Pergamon-Elsevier Science Ltd, Oxford., 65(50), 10485-10494.
https://doi.org/10.1016/j.tet.2009.10.006
Vulović B, Bihelović F, Matović R, Saičić R. Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings. Tetrahedron. 2009;65(50):10485-10494
Vulović Bojan, Bihelović Filip, Matović Radomir, Saičić Radomir, "Organocatalyzed Tsuji-Trost reaction: a new method for the closure of five- and six-membered rings" Tetrahedron, 65, no. 50 (2009):10485-10494,
https://doi.org/10.1016/j.tet.2009.10.006 .
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49

Palladium-catalyzed cross-couplings of allylic phosphates

Maslak, Veselin; Tokić-Vujošević, Zorana; Saičić, Radomir

(Pergamon-Elsevier Science Ltd, Oxford, 2009)

TY  - JOUR
AU  - Maslak, Veselin
AU  - Tokić-Vujošević, Zorana
AU  - Saičić, Radomir
PY  - 2009
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/619
AB  - A range of palladium-catalyzed cross-coupling reactions can be performed using allylic phosphates as electrophiles. Both conventional heating and microwave irradiation can be used. (C) 2009 Elsevier Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Tetrahedron Letters
T1  - Palladium-catalyzed cross-couplings of allylic phosphates
VL  - 50
IS  - 16
SP  - 1858
EP  - 1860
DO  - 10.1016/j.tetlet.2009.02.026
ER  - 
@article{
author = "Maslak, Veselin and Tokić-Vujošević, Zorana and Saičić, Radomir",
year = "2009",
url = "http://cherry.chem.bg.ac.rs/handle/123456789/619",
abstract = "A range of palladium-catalyzed cross-coupling reactions can be performed using allylic phosphates as electrophiles. Both conventional heating and microwave irradiation can be used. (C) 2009 Elsevier Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Tetrahedron Letters",
title = "Palladium-catalyzed cross-couplings of allylic phosphates",
volume = "50",
number = "16",
pages = "1858-1860",
doi = "10.1016/j.tetlet.2009.02.026"
}
Maslak, V., Tokić-Vujošević, Z.,& Saičić, R. (2009). Palladium-catalyzed cross-couplings of allylic phosphates.
Tetrahedron Letters
Pergamon-Elsevier Science Ltd, Oxford., 50(16), 1858-1860.
https://doi.org/10.1016/j.tetlet.2009.02.026
Maslak V, Tokić-Vujošević Z, Saičić R. Palladium-catalyzed cross-couplings of allylic phosphates. Tetrahedron Letters. 2009;50(16):1858-1860
Maslak Veselin, Tokić-Vujošević Zorana, Saičić Radomir, "Palladium-catalyzed cross-couplings of allylic phosphates" Tetrahedron Letters, 50, no. 16 (2009):1858-1860,
https://doi.org/10.1016/j.tetlet.2009.02.026 .
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A useful synthetic equivalent of an acetone enolate

Maslak, Veselin; Tokić-Vujošević, Zorana; Ferjančić, Zorana; Saičić, Radomir

(Pergamon-Elsevier Science Ltd, Oxford, 2009)

TY  - JOUR
AU  - Maslak, Veselin
AU  - Tokić-Vujošević, Zorana
AU  - Ferjančić, Zorana
AU  - Saičić, Radomir
PY  - 2009
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/1026
AB  - 2-Methoxymethoxy-3-chloropropene derived organometallics act as synthetic equivalents of an acetone enolate. Indium-promoted reaction of this reagent with aldehydes affords aldol adducts in moderate to excellent yields. When the reaction was performed with zinc, aldol products were isolated in protected form as the corresponding MOM-enol ethers. (C) 2009 Elsevier Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Tetrahedron Letters
T1  - A useful synthetic equivalent of an acetone enolate
VL  - 50
IS  - 48
SP  - 6709
EP  - 6711
DO  - 10.1016/j.tetlet.2009.09.113
ER  - 
@article{
author = "Maslak, Veselin and Tokić-Vujošević, Zorana and Ferjančić, Zorana and Saičić, Radomir",
year = "2009",
url = "http://cherry.chem.bg.ac.rs/handle/123456789/1026",
abstract = "2-Methoxymethoxy-3-chloropropene derived organometallics act as synthetic equivalents of an acetone enolate. Indium-promoted reaction of this reagent with aldehydes affords aldol adducts in moderate to excellent yields. When the reaction was performed with zinc, aldol products were isolated in protected form as the corresponding MOM-enol ethers. (C) 2009 Elsevier Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Tetrahedron Letters",
title = "A useful synthetic equivalent of an acetone enolate",
volume = "50",
number = "48",
pages = "6709-6711",
doi = "10.1016/j.tetlet.2009.09.113"
}
Maslak, V., Tokić-Vujošević, Z., Ferjančić, Z.,& Saičić, R. (2009). A useful synthetic equivalent of an acetone enolate.
Tetrahedron Letters
Pergamon-Elsevier Science Ltd, Oxford., 50(48), 6709-6711.
https://doi.org/10.1016/j.tetlet.2009.09.113
Maslak V, Tokić-Vujošević Z, Ferjančić Z, Saičić R. A useful synthetic equivalent of an acetone enolate. Tetrahedron Letters. 2009;50(48):6709-6711
Maslak Veselin, Tokić-Vujošević Zorana, Ferjančić Zorana, Saičić Radomir, "A useful synthetic equivalent of an acetone enolate" Tetrahedron Letters, 50, no. 48 (2009):6709-6711,
https://doi.org/10.1016/j.tetlet.2009.09.113 .
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5
5

Radical reactions of xanthates: annulation of the cyclopentene ring

Elheshi, Ahmed Mohamed; Maslak, Veselin; Saičić, Radomir

(Serbian Chemical Soc, Belgrade, 2007)

TY  - JOUR
AU  - Elheshi, Ahmed Mohamed
AU  - Maslak, Veselin
AU  - Saičić, Radomir
PY  - 2007
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/900
AB  - Homoallylic radicals, generated from the corresponding xanthates, react with terminal alkynes to give cyclopentene derivatives in moderate yields.
AB  - Homoalilni radikali, nastali iz odgovarajućih ksantata, reaguju sa terminalnim alkinima i daju derivate ciklopentena u umerenim prinosima.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Radical reactions of xanthates: annulation of the cyclopentene ring
T1  - Radikalske reakcije ksantata - anelacija ciklopentenovog prstena
VL  - 72
IS  - 12
SP  - 1173
EP  - 1179
DO  - 10.2298/JSC0712173E
ER  - 
@article{
author = "Elheshi, Ahmed Mohamed and Maslak, Veselin and Saičić, Radomir",
year = "2007",
url = "http://cherry.chem.bg.ac.rs/handle/123456789/900",
abstract = "Homoallylic radicals, generated from the corresponding xanthates, react with terminal alkynes to give cyclopentene derivatives in moderate yields., Homoalilni radikali, nastali iz odgovarajućih ksantata, reaguju sa terminalnim alkinima i daju derivate ciklopentena u umerenim prinosima.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Radical reactions of xanthates: annulation of the cyclopentene ring, Radikalske reakcije ksantata - anelacija ciklopentenovog prstena",
volume = "72",
number = "12",
pages = "1173-1179",
doi = "10.2298/JSC0712173E"
}
Elheshi, A. M., Maslak, V.,& Saičić, R. (2007). Radikalske reakcije ksantata - anelacija ciklopentenovog prstena.
Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 72(12), 1173-1179.
https://doi.org/10.2298/JSC0712173E
Elheshi AM, Maslak V, Saičić R. Radikalske reakcije ksantata - anelacija ciklopentenovog prstena. Journal of the Serbian Chemical Society. 2007;72(12):1173-1179
Elheshi Ahmed Mohamed, Maslak Veselin, Saičić Radomir, "Radikalske reakcije ksantata - anelacija ciklopentenovog prstena" Journal of the Serbian Chemical Society, 72, no. 12 (2007):1173-1179,
https://doi.org/10.2298/JSC0712173E .
1

Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C

Matović, Radomir; Ivkovic, Aleksandar; Manojlović, Marija; Tokić-Vujošević, Zorana; Saičić, Radomir

(Amer Chemical Soc, Washington, 2006)

TY  - JOUR
AU  - Matović, Radomir
AU  - Ivkovic, Aleksandar
AU  - Manojlović, Marija
AU  - Tokić-Vujošević, Zorana
AU  - Saičić, Radomir
PY  - 2006
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/808
AB  - The combination of ring closing metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium ring cycloalkenes. The fragmentation step can be effected under anionic or radical conditions. The versatility of this method is demonstrated by the total synthesis of (+/-)-periplanone C - a macrocyclic pheromone of Periplaneta americana.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Organic Chemistry
T1  - Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C
VL  - 71
IS  - 25
SP  - 9411
EP  - 9419
DO  - 10.1021/jo061790j
ER  - 
@article{
author = "Matović, Radomir and Ivkovic, Aleksandar and Manojlović, Marija and Tokić-Vujošević, Zorana and Saičić, Radomir",
year = "2006",
url = "http://cherry.chem.bg.ac.rs/handle/123456789/808",
abstract = "The combination of ring closing metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium ring cycloalkenes. The fragmentation step can be effected under anionic or radical conditions. The versatility of this method is demonstrated by the total synthesis of (+/-)-periplanone C - a macrocyclic pheromone of Periplaneta americana.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Organic Chemistry",
title = "Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C",
volume = "71",
number = "25",
pages = "9411-9419",
doi = "10.1021/jo061790j"
}
Matović, R., Ivkovic, A., Manojlović, M., Tokić-Vujošević, Z.,& Saičić, R. (2006). Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C.
Journal of Organic Chemistry
Amer Chemical Soc, Washington., 71(25), 9411-9419.
https://doi.org/10.1021/jo061790j
Matović R, Ivkovic A, Manojlović M, Tokić-Vujošević Z, Saičić R. Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C. Journal of Organic Chemistry. 2006;71(25):9411-9419
Matović Radomir, Ivkovic Aleksandar, Manojlović Marija, Tokić-Vujošević Zorana, Saičić Radomir, "Ring closing metathesis/fragmentation route to (Z)-configured medium ring cycloalkenes. Total synthesis of (+/-)-periplanone C" Journal of Organic Chemistry, 71, no. 25 (2006):9411-9419,
https://doi.org/10.1021/jo061790j .
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