TY  - JOUR
AU  - Korvinson, Kirill A.
AU  - Hargenrader, George N.
AU  - Stevanović, Jelena
AU  - Xie, Yun
AU  - Joseph, Jojo
AU  - Maslak, Veselin
AU  - Hadad, Christopher M.
AU  - Glušač, Ksenija D.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3541
AB  - The triplet excited-state formation efficiency in a flavin derivative was increased by the introduction of iodine into the molecular framework. The transient absorption measurements showed that the intersystem crossing rate was 1.1 X 10(10) s(-1) significantly faster than in the parent flavin compound. Furthermore, the photocatalytic efficiency of iodoflavin was evaluated using the oxidation of benzyl alcohol as a model reaction. The benzaldehyde product yields were higher when iodoflavin was used as a photocatalyst, showing that the increased triplet yield directly translates into improved photocatalysis. The iodoflavin catalyst also allowed the use of higher substrate concentrations (since the undesired electron transfer from singlet excited state was minimized), which is expected to improve the practical aspects of photocatalysis by flavins.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
T1  - Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement
VL  - 120
IS  - 37
SP  - 7294
EP  - 7300
DO  - 10.1021/acs.jpca.6b08405
ER  - 

@article{
author = "Korvinson, Kirill A. and Hargenrader, George N. and Stevanović, Jelena and Xie, Yun and Joseph, Jojo and Maslak, Veselin and Hadad, Christopher M. and Glušač, Ksenija D.",
year = "2016",
abstract = "The triplet excited-state formation efficiency in a flavin derivative was increased by the introduction of iodine into the molecular framework. The transient absorption measurements showed that the intersystem crossing rate was 1.1 X 10(10) s(-1) significantly faster than in the parent flavin compound. Furthermore, the photocatalytic efficiency of iodoflavin was evaluated using the oxidation of benzyl alcohol as a model reaction. The benzaldehyde product yields were higher when iodoflavin was used as a photocatalyst, showing that the increased triplet yield directly translates into improved photocatalysis. The iodoflavin catalyst also allowed the use of higher substrate concentrations (since the undesired electron transfer from singlet excited state was minimized), which is expected to improve the practical aspects of photocatalysis by flavins.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th",
title = "Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement",
volume = "120",
number = "37",
pages = "7294-7300",
doi = "10.1021/acs.jpca.6b08405"
}

Korvinson, K. A., Hargenrader, G. N., Stevanović, J., Xie, Y., Joseph, J., Maslak, V., Hadad, C. M.,& Glušač, K. D.. (2016). Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
Amer Chemical Soc, Washington., 120(37), 7294-7300.
https://doi.org/10.1021/acs.jpca.6b08405

Korvinson KA, Hargenrader GN, Stevanović J, Xie Y, Joseph J, Maslak V, Hadad CM, Glušač KD. Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th. 2016;120(37):7294-7300.
doi:10.1021/acs.jpca.6b08405 .

Korvinson, Kirill A., Hargenrader, George N., Stevanović, Jelena, Xie, Yun, Joseph, Jojo, Maslak, Veselin, Hadad, Christopher M., Glušač, Ksenija D., "Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement" in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th, 120, no. 37 (2016):7294-7300,
https://doi.org/10.1021/acs.jpca.6b08405 . .

TY  - DATA
AU  - Korvinson, Kirill A.
AU  - Hargenrader, George N.
AU  - Stevanović, Jelena
AU  - Xie, Yun
AU  - Joseph, Jojo
AU  - Maslak, Veselin
AU  - Hadad, Christopher M.
AU  - Glušač, Ksenija D.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3542
PB  - Amer Chemical Soc, Washington
T2  - Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
T1  - Supplementary material for the article: Korvinson, K. A.; Hargenrader, G. N.; Stevanovic, J.; Xie, Y.; Joseph, J.; Maslak, V.; Hadad, 
C. M.; Glusac, K. D. Improved Flavin-Based Catalytic Photooxidation of Alcohols through 
Intersystem Crossing Rate Enhancement. Journal of Physical Chemistry A 2016, 120 (37), 
7294–7300. https://doi.org/10.1021/acs.jpca.6b08405
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3542
ER  - 

@misc{
author = "Korvinson, Kirill A. and Hargenrader, George N. and Stevanović, Jelena and Xie, Yun and Joseph, Jojo and Maslak, Veselin and Hadad, Christopher M. and Glušač, Ksenija D.",
year = "2016",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th",
title = "Supplementary material for the article: Korvinson, K. A.; Hargenrader, G. N.; Stevanovic, J.; Xie, Y.; Joseph, J.; Maslak, V.; Hadad, 
C. M.; Glusac, K. D. Improved Flavin-Based Catalytic Photooxidation of Alcohols through 
Intersystem Crossing Rate Enhancement. Journal of Physical Chemistry A 2016, 120 (37), 
7294–7300. https://doi.org/10.1021/acs.jpca.6b08405",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3542"
}

Korvinson, K. A., Hargenrader, G. N., Stevanović, J., Xie, Y., Joseph, J., Maslak, V., Hadad, C. M.,& Glušač, K. D.. (2016). Supplementary material for the article: Korvinson, K. A.; Hargenrader, G. N.; Stevanovic, J.; Xie, Y.; Joseph, J.; Maslak, V.; Hadad, 
C. M.; Glusac, K. D. Improved Flavin-Based Catalytic Photooxidation of Alcohols through 
Intersystem Crossing Rate Enhancement. Journal of Physical Chemistry A 2016, 120 (37), 
7294–7300. https://doi.org/10.1021/acs.jpca.6b08405. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
Amer Chemical Soc, Washington..
https://hdl.handle.net/21.15107/rcub_cherry_3542

Korvinson KA, Hargenrader GN, Stevanović J, Xie Y, Joseph J, Maslak V, Hadad CM, Glušač KD. Supplementary material for the article: Korvinson, K. A.; Hargenrader, G. N.; Stevanovic, J.; Xie, Y.; Joseph, J.; Maslak, V.; Hadad, 
C. M.; Glusac, K. D. Improved Flavin-Based Catalytic Photooxidation of Alcohols through 
Intersystem Crossing Rate Enhancement. Journal of Physical Chemistry A 2016, 120 (37), 
7294–7300. https://doi.org/10.1021/acs.jpca.6b08405. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th. 2016;.
https://hdl.handle.net/21.15107/rcub_cherry_3542 .

Korvinson, Kirill A., Hargenrader, George N., Stevanović, Jelena, Xie, Yun, Joseph, Jojo, Maslak, Veselin, Hadad, Christopher M., Glušač, Ksenija D., "Supplementary material for the article: Korvinson, K. A.; Hargenrader, G. N.; Stevanovic, J.; Xie, Y.; Joseph, J.; Maslak, V.; Hadad, 
C. M.; Glusac, K. D. Improved Flavin-Based Catalytic Photooxidation of Alcohols through 
Intersystem Crossing Rate Enhancement. Journal of Physical Chemistry A 2016, 120 (37), 
7294–7300. https://doi.org/10.1021/acs.jpca.6b08405" in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th (2016),
https://hdl.handle.net/21.15107/rcub_cherry_3542 .

TY  - JOUR
AU  - Korvinson, Kirill A.
AU  - Hargenrader, George N.
AU  - Stevanović, Jelena
AU  - Xie, Yun
AU  - Joseph, Jojo
AU  - Maslak, Veselin
AU  - Hadad, Christopher M.
AU  - Glušač, Ksenija D.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2315
AB  - The triplet excited-state formation efficiency in a flavin derivative was increased by the introduction of iodine into the molecular framework. The transient absorption measurements showed that the intersystem crossing rate was 1.1 X 10(10) s(-1) significantly faster than in the parent flavin compound. Furthermore, the photocatalytic efficiency of iodoflavin was evaluated using the oxidation of benzyl alcohol as a model reaction. The benzaldehyde product yields were higher when iodoflavin was used as a photocatalyst, showing that the increased triplet yield directly translates into improved photocatalysis. The iodoflavin catalyst also allowed the use of higher substrate concentrations (since the undesired electron transfer from singlet excited state was minimized), which is expected to improve the practical aspects of photocatalysis by flavins.
PB  - Amer Chemical Soc, Washington
T2  - Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
T1  - Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement
VL  - 120
IS  - 37
SP  - 7294
EP  - 7300
DO  - 10.1021/acs.jpca.6b08405
ER  - 

@article{
author = "Korvinson, Kirill A. and Hargenrader, George N. and Stevanović, Jelena and Xie, Yun and Joseph, Jojo and Maslak, Veselin and Hadad, Christopher M. and Glušač, Ksenija D.",
year = "2016",
abstract = "The triplet excited-state formation efficiency in a flavin derivative was increased by the introduction of iodine into the molecular framework. The transient absorption measurements showed that the intersystem crossing rate was 1.1 X 10(10) s(-1) significantly faster than in the parent flavin compound. Furthermore, the photocatalytic efficiency of iodoflavin was evaluated using the oxidation of benzyl alcohol as a model reaction. The benzaldehyde product yields were higher when iodoflavin was used as a photocatalyst, showing that the increased triplet yield directly translates into improved photocatalysis. The iodoflavin catalyst also allowed the use of higher substrate concentrations (since the undesired electron transfer from singlet excited state was minimized), which is expected to improve the practical aspects of photocatalysis by flavins.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th",
title = "Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement",
volume = "120",
number = "37",
pages = "7294-7300",
doi = "10.1021/acs.jpca.6b08405"
}

Korvinson, K. A., Hargenrader, G. N., Stevanović, J., Xie, Y., Joseph, J., Maslak, V., Hadad, C. M.,& Glušač, K. D.. (2016). Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th
Amer Chemical Soc, Washington., 120(37), 7294-7300.
https://doi.org/10.1021/acs.jpca.6b08405

Korvinson KA, Hargenrader GN, Stevanović J, Xie Y, Joseph J, Maslak V, Hadad CM, Glušač KD. Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement. in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th. 2016;120(37):7294-7300.
doi:10.1021/acs.jpca.6b08405 .

Korvinson, Kirill A., Hargenrader, George N., Stevanović, Jelena, Xie, Yun, Joseph, Jojo, Maslak, Veselin, Hadad, Christopher M., Glušač, Ksenija D., "Improved Flavin-Based Catalytic Photooxidation of Alcohols through Intersystem Crossing Rate Enhancement" in Journal of Physical Chemistry. Part A: Molecules, Spectroscopy, Kinetics, Environment and General Th, 120, no. 37 (2016):7294-7300,
https://doi.org/10.1021/acs.jpca.6b08405 . .