Developing technological processes for nonstandard copper concentrates processing with the aim to decrease pollutants emission

Link to this page

info:eu-repo/grantAgreement/MESTD/Technological Development (TD or TR)/34023/RS//

Developing technological processes for nonstandard copper concentrates processing with the aim to decrease pollutants emission (en)
Развој технолошких процеса прераде нестандардних концентрата бакра у циљу оптимизације емисије загађујућих материја (sr)
Razvoj tehnoloških procesa prerade nestandardnih koncentrata bakra u cilju optimizacije emisije zagađujućih materija (sr_RS)
Authors

Publications

Comparison of air pollution in the working environment during in site treatment of infectious medical waste by convertor and autoclave sterilization

Martinović, Biljana; Jelić, Ivana V.; Rikalović, Milena G.; Šljivić-Ivanović, Marija Z.; Radosavljević, Jelena; Kostić, Aleksandar Ž.; Adžemovic, Mesud

(Parlar Scientific Publications, 2020)

TY  - JOUR
AU  - Martinović, Biljana
AU  - Jelić, Ivana V.
AU  - Rikalović, Milena G.
AU  - Šljivić-Ivanović, Marija Z.
AU  - Radosavljević, Jelena
AU  - Kostić, Aleksandar Ž.
AU  - Adžemovic, Mesud
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4208
AB  - The aim of the present study is the comparison of ambient pollution in working environment during infectious medical waste treatment in two relevant health care institutions in the Republic of Serbia - The Blood Transfusion Institute of Serbia and The Clinical Centre of Serbia by different sterilization methods (sterilizer-convertor and autoclave, respectively). Monitoring and analysis of the following chemical compounds were performed in both institutions: water vapor, carbon dioxide, carbon monoxide, hydrochloric acid, methane, ethane, propane, hexane, formaldehyde, benzene, toluene, m-xylene, phenol, acrolein, ethanol, ethyl acetate, ethylamine, ethylene oxide, methanol, dimethyl disulphide, dimethyl sulphide, ethyl mercaptan, methyl mercaptan, freon 11 (trichlorofluoromethane), carbonyl sulphide and hydrogen chloride. The determination of vapor-phase concentrations was done by extractive Fourier transform infrared spectroscopy. Monitoring of ambient pollution during infectious medical waste sterilization has shown that mercaptans, acrolein, formaldehyde, dimethyl sulphide, and ethylene oxide are emitted in both health institutions, in concentrations which are not permitted by regulations, while increased concentrations of hydrogen chloride and phenol were found in the Clinical Centre of Serbia. A comparison of ambient pollution with two different sterilization methods has shown that higher concentrations of pollutants are emitted at higher temperatures. Considering the fact that mentioned compounds exhibit high toxicity, hence represent the risk to air quality in working and living environment, i.e. represents a risk to human health it is necessary to revise and improve the existing treatment methods.
PB  - Parlar Scientific Publications
T2  - Fresenius Environmental Bulletin
T1  - Comparison of air pollution in the working environment during in site treatment of infectious medical waste by convertor and autoclave sterilization
VL  - 29
IS  - 4
SP  - 2160
EP  - 2165
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4208
ER  - 
@article{
author = "Martinović, Biljana and Jelić, Ivana V. and Rikalović, Milena G. and Šljivić-Ivanović, Marija Z. and Radosavljević, Jelena and Kostić, Aleksandar Ž. and Adžemovic, Mesud",
year = "2020",
abstract = "The aim of the present study is the comparison of ambient pollution in working environment during infectious medical waste treatment in two relevant health care institutions in the Republic of Serbia - The Blood Transfusion Institute of Serbia and The Clinical Centre of Serbia by different sterilization methods (sterilizer-convertor and autoclave, respectively). Monitoring and analysis of the following chemical compounds were performed in both institutions: water vapor, carbon dioxide, carbon monoxide, hydrochloric acid, methane, ethane, propane, hexane, formaldehyde, benzene, toluene, m-xylene, phenol, acrolein, ethanol, ethyl acetate, ethylamine, ethylene oxide, methanol, dimethyl disulphide, dimethyl sulphide, ethyl mercaptan, methyl mercaptan, freon 11 (trichlorofluoromethane), carbonyl sulphide and hydrogen chloride. The determination of vapor-phase concentrations was done by extractive Fourier transform infrared spectroscopy. Monitoring of ambient pollution during infectious medical waste sterilization has shown that mercaptans, acrolein, formaldehyde, dimethyl sulphide, and ethylene oxide are emitted in both health institutions, in concentrations which are not permitted by regulations, while increased concentrations of hydrogen chloride and phenol were found in the Clinical Centre of Serbia. A comparison of ambient pollution with two different sterilization methods has shown that higher concentrations of pollutants are emitted at higher temperatures. Considering the fact that mentioned compounds exhibit high toxicity, hence represent the risk to air quality in working and living environment, i.e. represents a risk to human health it is necessary to revise and improve the existing treatment methods.",
publisher = "Parlar Scientific Publications",
journal = "Fresenius Environmental Bulletin",
title = "Comparison of air pollution in the working environment during in site treatment of infectious medical waste by convertor and autoclave sterilization",
volume = "29",
number = "4",
pages = "2160-2165",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4208"
}
Martinović, B., Jelić, I. V., Rikalović, M. G., Šljivić-Ivanović, M. Z., Radosavljević, J., Kostić, A. Ž.,& Adžemovic, M.. (2020). Comparison of air pollution in the working environment during in site treatment of infectious medical waste by convertor and autoclave sterilization. in Fresenius Environmental Bulletin
Parlar Scientific Publications., 29(4), 2160-2165.
https://hdl.handle.net/21.15107/rcub_cherry_4208
Martinović B, Jelić IV, Rikalović MG, Šljivić-Ivanović MZ, Radosavljević J, Kostić AŽ, Adžemovic M. Comparison of air pollution in the working environment during in site treatment of infectious medical waste by convertor and autoclave sterilization. in Fresenius Environmental Bulletin. 2020;29(4):2160-2165.
https://hdl.handle.net/21.15107/rcub_cherry_4208 .
Martinović, Biljana, Jelić, Ivana V., Rikalović, Milena G., Šljivić-Ivanović, Marija Z., Radosavljević, Jelena, Kostić, Aleksandar Ž., Adžemovic, Mesud, "Comparison of air pollution in the working environment during in site treatment of infectious medical waste by convertor and autoclave sterilization" in Fresenius Environmental Bulletin, 29, no. 4 (2020):2160-2165,
https://hdl.handle.net/21.15107/rcub_cherry_4208 .
1
1

Comparison of extraction agents for metal determination in sediments from artificial lakes and rivers in Serbia

Pantović Spajić, Katarina; Sakan, Sanja M.; Đorđević, Dragana S.; Šoštarić, Tatjana D.; Lopičić, Zorica; Janićijević, Aleksandra; Stojanović, Ksenija A.

(2019)

TY  - JOUR
AU  - Pantović Spajić, Katarina
AU  - Sakan, Sanja M.
AU  - Đorđević, Dragana S.
AU  - Šoštarić, Tatjana D.
AU  - Lopičić, Zorica
AU  - Janićijević, Aleksandra
AU  - Stojanović, Ksenija A.
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3854
AB  - The purpose of this paper was to investigate the effectiveness of three different extraction agents for the extraction of 25 elements from sediment samples collected from 4 artificial lakes and 12 rivers in Serbia (33 samples in total). The extraction efficiency of the agents was evaluated by its ability to extract the highest quantity of the elements. For that purpose, three acids (1M HCl, 2M HNO3 and 0.43M CH3COOH) have been used. Inductively coupled plasma atomic emission spectrometry (ICP-OES) was used for quantitative determination of following elements: Al, As, B, Ba, Be, Bi, Ca, Cd, Cr, Co, Cu, Fe, Hg, K, Li, Mg, Mn, Ni, Na, Pb, Sb, Se, Sr, V, and Zn. The extraction with 1M HCl has shown the best results for the majority of investigated elements (especially Sr, Mn and Ca). Antimony (Sb) was detected only after extraction with 0.43M CH3COOOH, while selenium (Se) could not be detected when 2M HNO3 was applied as extraction agents. The present study could be very useful for choosing a suitable method for specific elements and also can be helpful in the evaluation of the contaminants in freshwater sediments in Serbia. This might contribute to environmental risk assessment of the present elements.
T2  - Acta Periodica Technologica
T1  - Comparison of extraction agents for metal determination in sediments from artificial lakes and rivers in Serbia
VL  - 50
SP  - 189
EP  - 196
DO  - 10.2298/APT1950189P
ER  - 
@article{
author = "Pantović Spajić, Katarina and Sakan, Sanja M. and Đorđević, Dragana S. and Šoštarić, Tatjana D. and Lopičić, Zorica and Janićijević, Aleksandra and Stojanović, Ksenija A.",
year = "2019",
abstract = "The purpose of this paper was to investigate the effectiveness of three different extraction agents for the extraction of 25 elements from sediment samples collected from 4 artificial lakes and 12 rivers in Serbia (33 samples in total). The extraction efficiency of the agents was evaluated by its ability to extract the highest quantity of the elements. For that purpose, three acids (1M HCl, 2M HNO3 and 0.43M CH3COOH) have been used. Inductively coupled plasma atomic emission spectrometry (ICP-OES) was used for quantitative determination of following elements: Al, As, B, Ba, Be, Bi, Ca, Cd, Cr, Co, Cu, Fe, Hg, K, Li, Mg, Mn, Ni, Na, Pb, Sb, Se, Sr, V, and Zn. The extraction with 1M HCl has shown the best results for the majority of investigated elements (especially Sr, Mn and Ca). Antimony (Sb) was detected only after extraction with 0.43M CH3COOOH, while selenium (Se) could not be detected when 2M HNO3 was applied as extraction agents. The present study could be very useful for choosing a suitable method for specific elements and also can be helpful in the evaluation of the contaminants in freshwater sediments in Serbia. This might contribute to environmental risk assessment of the present elements.",
journal = "Acta Periodica Technologica",
title = "Comparison of extraction agents for metal determination in sediments from artificial lakes and rivers in Serbia",
volume = "50",
pages = "189-196",
doi = "10.2298/APT1950189P"
}
Pantović Spajić, K., Sakan, S. M., Đorđević, D. S., Šoštarić, T. D., Lopičić, Z., Janićijević, A.,& Stojanović, K. A.. (2019). Comparison of extraction agents for metal determination in sediments from artificial lakes and rivers in Serbia. in Acta Periodica Technologica, 50, 189-196.
https://doi.org/10.2298/APT1950189P
Pantović Spajić K, Sakan SM, Đorđević DS, Šoštarić TD, Lopičić Z, Janićijević A, Stojanović KA. Comparison of extraction agents for metal determination in sediments from artificial lakes and rivers in Serbia. in Acta Periodica Technologica. 2019;50:189-196.
doi:10.2298/APT1950189P .
Pantović Spajić, Katarina, Sakan, Sanja M., Đorđević, Dragana S., Šoštarić, Tatjana D., Lopičić, Zorica, Janićijević, Aleksandra, Stojanović, Ksenija A., "Comparison of extraction agents for metal determination in sediments from artificial lakes and rivers in Serbia" in Acta Periodica Technologica, 50 (2019):189-196,
https://doi.org/10.2298/APT1950189P . .
1
1
1

Kinetics of NiO and NiCl2 Hydrogen Reduction as Precursors and Properties of Produced Ni/Al2O3 and Ni-Pd/Al2O3 Catalysts

Sokić, Miroslav; Kamberović, Željko; Nikolić, Vesna; Marković, Branislav; Korać, Marija; Anđić, Zoran; Gavrilovski, Milorad

(2015)

TY  - JOUR
AU  - Sokić, Miroslav
AU  - Kamberović, Željko
AU  - Nikolić, Vesna
AU  - Marković, Branislav
AU  - Korać, Marija
AU  - Anđić, Zoran
AU  - Gavrilovski, Milorad
PY  - 2015
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5056
AB  - The objects of this investigation were the comparative kinetic analysis of the NiO and NiCl2 reduction by hydrogen during an induction period and elimination of the calcination during the synthesis of Ni/Al2O3 catalysts.The effect of temperature and time on NiO and NiCl2 reduction degrees was studied. Avrami I equation was selected as the most favorable kinetic model and
used to determine activation energy of the NiO and NiCl2 reduction for the investigated temperature range (623–923 K) and time intervals (1–5 minutes).Theinvestigation enabled reaching conclusions about the reaction ability and rate of the reduction processes.
Afterward,Ni/Al2O3 catalystswere obtained by using oxide and chloride precursor forNi.The catalystswere supported on aluminabased foamand prepared via aerosol route. Properties of the samples before and after low-temperature hydrogen reduction (633K) were compared.Obtained results indicated that the synthesis ofNi/Al2O3 catalysts can be more efficient if chloride precursor for Ni is directly reduced by hydrogen during the synthesis process, without the calcination step. In addition, Ni-Pd/Al2O3 catalysts with different metal content were prepared by using chloride precursors. Lower reduction temperature was utilized and the chlorides were almost completely reduced at 533 K.
T2  - The Scientific World Journal
T1  - Kinetics of NiO and NiCl2 Hydrogen Reduction as Precursors and Properties of Produced Ni/Al2O3 and Ni-Pd/Al2O3 Catalysts
VL  - 2015
SP  - 1
EP  - 9
DO  - 10.1155/2015/601970
ER  - 
@article{
author = "Sokić, Miroslav and Kamberović, Željko and Nikolić, Vesna and Marković, Branislav and Korać, Marija and Anđić, Zoran and Gavrilovski, Milorad",
year = "2015",
abstract = "The objects of this investigation were the comparative kinetic analysis of the NiO and NiCl2 reduction by hydrogen during an induction period and elimination of the calcination during the synthesis of Ni/Al2O3 catalysts.The effect of temperature and time on NiO and NiCl2 reduction degrees was studied. Avrami I equation was selected as the most favorable kinetic model and
used to determine activation energy of the NiO and NiCl2 reduction for the investigated temperature range (623–923 K) and time intervals (1–5 minutes).Theinvestigation enabled reaching conclusions about the reaction ability and rate of the reduction processes.
Afterward,Ni/Al2O3 catalystswere obtained by using oxide and chloride precursor forNi.The catalystswere supported on aluminabased foamand prepared via aerosol route. Properties of the samples before and after low-temperature hydrogen reduction (633K) were compared.Obtained results indicated that the synthesis ofNi/Al2O3 catalysts can be more efficient if chloride precursor for Ni is directly reduced by hydrogen during the synthesis process, without the calcination step. In addition, Ni-Pd/Al2O3 catalysts with different metal content were prepared by using chloride precursors. Lower reduction temperature was utilized and the chlorides were almost completely reduced at 533 K.",
journal = "The Scientific World Journal",
title = "Kinetics of NiO and NiCl2 Hydrogen Reduction as Precursors and Properties of Produced Ni/Al2O3 and Ni-Pd/Al2O3 Catalysts",
volume = "2015",
pages = "1-9",
doi = "10.1155/2015/601970"
}
Sokić, M., Kamberović, Ž., Nikolić, V., Marković, B., Korać, M., Anđić, Z.,& Gavrilovski, M.. (2015). Kinetics of NiO and NiCl2 Hydrogen Reduction as Precursors and Properties of Produced Ni/Al2O3 and Ni-Pd/Al2O3 Catalysts. in The Scientific World Journal, 2015, 1-9.
https://doi.org/10.1155/2015/601970
Sokić M, Kamberović Ž, Nikolić V, Marković B, Korać M, Anđić Z, Gavrilovski M. Kinetics of NiO and NiCl2 Hydrogen Reduction as Precursors and Properties of Produced Ni/Al2O3 and Ni-Pd/Al2O3 Catalysts. in The Scientific World Journal. 2015;2015:1-9.
doi:10.1155/2015/601970 .
Sokić, Miroslav, Kamberović, Željko, Nikolić, Vesna, Marković, Branislav, Korać, Marija, Anđić, Zoran, Gavrilovski, Milorad, "Kinetics of NiO and NiCl2 Hydrogen Reduction as Precursors and Properties of Produced Ni/Al2O3 and Ni-Pd/Al2O3 Catalysts" in The Scientific World Journal, 2015 (2015):1-9,
https://doi.org/10.1155/2015/601970 . .
10
5
6

Utilization properties of Ni-Pd/Al2O3 catalyst supported on alumina based foam

Nikolić, Vesna; Kamberović, Željko; Korać, Marija; Sokić, Miroslav; Anđić, Zoran

(Association of Metallurgical Engineers of Serbia AMES, 2015)

TY  - CONF
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Korać, Marija
AU  - Sokić, Miroslav
AU  - Anđić, Zoran
PY  - 2015
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5311
AB  - The aim of this study was to examine utilization properties of Ni-Pd/Al2O3
catalyst supported on α-Al2O3 based foam in the dry methane reforming. The
catalyst was synthesized by using aerosol route. Non-calcined chloride precursors
for Ni and Pd were reduced by hydrogen at very low temperature of 533 K. The
reforming test was carried out for 3 h. Standing time was set to 1 h for each of the
following temperatures: 873, 973 and 1023 K. Yields of CO and H2 were
determined and conclusions on selectivity, catalytic activity and stability were made
on the basis of obtained results.
PB  - Association of Metallurgical Engineers of Serbia AMES
C3  - Proceedings of Metallurgical & Materials Engineering Congress of South-East Europe, June 5, 2015
T1  - Utilization properties of Ni-Pd/Al2O3 catalyst supported on alumina based foam
SP  - 153
EP  - 158
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5311
ER  - 
@conference{
author = "Nikolić, Vesna and Kamberović, Željko and Korać, Marija and Sokić, Miroslav and Anđić, Zoran",
year = "2015",
abstract = "The aim of this study was to examine utilization properties of Ni-Pd/Al2O3
catalyst supported on α-Al2O3 based foam in the dry methane reforming. The
catalyst was synthesized by using aerosol route. Non-calcined chloride precursors
for Ni and Pd were reduced by hydrogen at very low temperature of 533 K. The
reforming test was carried out for 3 h. Standing time was set to 1 h for each of the
following temperatures: 873, 973 and 1023 K. Yields of CO and H2 were
determined and conclusions on selectivity, catalytic activity and stability were made
on the basis of obtained results.",
publisher = "Association of Metallurgical Engineers of Serbia AMES",
journal = "Proceedings of Metallurgical & Materials Engineering Congress of South-East Europe, June 5, 2015",
title = "Utilization properties of Ni-Pd/Al2O3 catalyst supported on alumina based foam",
pages = "153-158",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5311"
}
Nikolić, V., Kamberović, Ž., Korać, M., Sokić, M.,& Anđić, Z.. (2015). Utilization properties of Ni-Pd/Al2O3 catalyst supported on alumina based foam. in Proceedings of Metallurgical & Materials Engineering Congress of South-East Europe, June 5, 2015
Association of Metallurgical Engineers of Serbia AMES., 153-158.
https://hdl.handle.net/21.15107/rcub_cherry_5311
Nikolić V, Kamberović Ž, Korać M, Sokić M, Anđić Z. Utilization properties of Ni-Pd/Al2O3 catalyst supported on alumina based foam. in Proceedings of Metallurgical & Materials Engineering Congress of South-East Europe, June 5, 2015. 2015;:153-158.
https://hdl.handle.net/21.15107/rcub_cherry_5311 .
Nikolić, Vesna, Kamberović, Željko, Korać, Marija, Sokić, Miroslav, Anđić, Zoran, "Utilization properties of Ni-Pd/Al2O3 catalyst supported on alumina based foam" in Proceedings of Metallurgical & Materials Engineering Congress of South-East Europe, June 5, 2015 (2015):153-158,
https://hdl.handle.net/21.15107/rcub_cherry_5311 .

Ni-Pd/Al(2)O(3) Catalyst Supported on Reticulated Ceramic Foam for Dry Methane Reforming

Nikolić, Vesna; Kamberović, Željko; Korać, Marija; Sokic, Miroslav; Anđić, Zoran; Tomovic, Aleksandar

(Assoc Metallurgical Engineers Serbia, Belgrade, 2015)

TY  - JOUR
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Korać, Marija
AU  - Sokic, Miroslav
AU  - Anđić, Zoran
AU  - Tomovic, Aleksandar
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/578
AB  - In the present study, Ni-Pd/Al2O3 catalyst supported on alpha-Al2O3 based foam was prepared and evaluated in the dry methane reforming process. Corresponding metal chlorides were deposited to the foam surface by impregnation of the foam with ultrasonically aerosolized salt solutions at 473 K and drying at that temperature. Calcination step was excluded and the catalyst was reduced at very low temperature 533 K. The reforming experiment lasted for 3 h, with standing time of 1 h at the following temperatures: 873, 973 and 1023 K. Conclusions on selectivity, catalytic activity and stability were reached on the basis of CO and H-2 yields.
PB  - Assoc Metallurgical Engineers Serbia, Belgrade
T2  - Metallurgical and Materials Engineering
T1  - Ni-Pd/Al(2)O(3) Catalyst Supported on Reticulated Ceramic Foam for Dry Methane Reforming
VL  - 21
IS  - 1
SP  - 57
EP  - 63
DO  - 10.30544/133
ER  - 
@article{
author = "Nikolić, Vesna and Kamberović, Željko and Korać, Marija and Sokic, Miroslav and Anđić, Zoran and Tomovic, Aleksandar",
year = "2015",
abstract = "In the present study, Ni-Pd/Al2O3 catalyst supported on alpha-Al2O3 based foam was prepared and evaluated in the dry methane reforming process. Corresponding metal chlorides were deposited to the foam surface by impregnation of the foam with ultrasonically aerosolized salt solutions at 473 K and drying at that temperature. Calcination step was excluded and the catalyst was reduced at very low temperature 533 K. The reforming experiment lasted for 3 h, with standing time of 1 h at the following temperatures: 873, 973 and 1023 K. Conclusions on selectivity, catalytic activity and stability were reached on the basis of CO and H-2 yields.",
publisher = "Assoc Metallurgical Engineers Serbia, Belgrade",
journal = "Metallurgical and Materials Engineering",
title = "Ni-Pd/Al(2)O(3) Catalyst Supported on Reticulated Ceramic Foam for Dry Methane Reforming",
volume = "21",
number = "1",
pages = "57-63",
doi = "10.30544/133"
}
Nikolić, V., Kamberović, Ž., Korać, M., Sokic, M., Anđić, Z.,& Tomovic, A.. (2015). Ni-Pd/Al(2)O(3) Catalyst Supported on Reticulated Ceramic Foam for Dry Methane Reforming. in Metallurgical and Materials Engineering
Assoc Metallurgical Engineers Serbia, Belgrade., 21(1), 57-63.
https://doi.org/10.30544/133
Nikolić V, Kamberović Ž, Korać M, Sokic M, Anđić Z, Tomovic A. Ni-Pd/Al(2)O(3) Catalyst Supported on Reticulated Ceramic Foam for Dry Methane Reforming. in Metallurgical and Materials Engineering. 2015;21(1):57-63.
doi:10.30544/133 .
Nikolić, Vesna, Kamberović, Željko, Korać, Marija, Sokic, Miroslav, Anđić, Zoran, Tomovic, Aleksandar, "Ni-Pd/Al(2)O(3) Catalyst Supported on Reticulated Ceramic Foam for Dry Methane Reforming" in Metallurgical and Materials Engineering, 21, no. 1 (2015):57-63,
https://doi.org/10.30544/133 . .
1

Exploitation Properties of Ni-Pd/Al2o3 Catalyst Supported on Ceramic Foam

Nikolić, Vesna; Kamberović, Željko; Anđić, Zoran; Korać, Marija; Sokic, Miroslav; Gajić, Nataša; Jovanovic, Nikola

(Assoc Metallurgical Engineers Serbia, Belgrade, 2015)

TY  - JOUR
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Anđić, Zoran
AU  - Korać, Marija
AU  - Sokic, Miroslav
AU  - Gajić, Nataša
AU  - Jovanovic, Nikola
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/579
AB  - The goal of this research was to examine exploitation properties of Ni-Pd/Al2O3 catalyst supported on alpha-Al2O3 based foam in the dry methane reforming. The catalyst was prepared by using aerosol method. Chloride precursors for Ni and Pd were reduced by hydrogen at low temperature of 533 K, without previous calcination. The reforming experiment was performed for 3 h, with standing time of 1 h for each of the following temperatures: 873, 973 and 1023 K. Conclusions on selectivity, catalytic activity and stability were made on the basis of CO and H-2 yields.
PB  - Assoc Metallurgical Engineers Serbia, Belgrade
T2  - Metallurgical and Materials Engineering
T1  - Exploitation Properties of Ni-Pd/Al2o3 Catalyst Supported on Ceramic Foam
VL  - 21
IS  - 4
SP  - 277
EP  - 282
DO  - 10.30544/74
ER  - 
@article{
author = "Nikolić, Vesna and Kamberović, Željko and Anđić, Zoran and Korać, Marija and Sokic, Miroslav and Gajić, Nataša and Jovanovic, Nikola",
year = "2015",
abstract = "The goal of this research was to examine exploitation properties of Ni-Pd/Al2O3 catalyst supported on alpha-Al2O3 based foam in the dry methane reforming. The catalyst was prepared by using aerosol method. Chloride precursors for Ni and Pd were reduced by hydrogen at low temperature of 533 K, without previous calcination. The reforming experiment was performed for 3 h, with standing time of 1 h for each of the following temperatures: 873, 973 and 1023 K. Conclusions on selectivity, catalytic activity and stability were made on the basis of CO and H-2 yields.",
publisher = "Assoc Metallurgical Engineers Serbia, Belgrade",
journal = "Metallurgical and Materials Engineering",
title = "Exploitation Properties of Ni-Pd/Al2o3 Catalyst Supported on Ceramic Foam",
volume = "21",
number = "4",
pages = "277-282",
doi = "10.30544/74"
}
Nikolić, V., Kamberović, Ž., Anđić, Z., Korać, M., Sokic, M., Gajić, N.,& Jovanovic, N.. (2015). Exploitation Properties of Ni-Pd/Al2o3 Catalyst Supported on Ceramic Foam. in Metallurgical and Materials Engineering
Assoc Metallurgical Engineers Serbia, Belgrade., 21(4), 277-282.
https://doi.org/10.30544/74
Nikolić V, Kamberović Ž, Anđić Z, Korać M, Sokic M, Gajić N, Jovanovic N. Exploitation Properties of Ni-Pd/Al2o3 Catalyst Supported on Ceramic Foam. in Metallurgical and Materials Engineering. 2015;21(4):277-282.
doi:10.30544/74 .
Nikolić, Vesna, Kamberović, Željko, Anđić, Zoran, Korać, Marija, Sokic, Miroslav, Gajić, Nataša, Jovanovic, Nikola, "Exploitation Properties of Ni-Pd/Al2o3 Catalyst Supported on Ceramic Foam" in Metallurgical and Materials Engineering, 21, no. 4 (2015):277-282,
https://doi.org/10.30544/74 . .

Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts

Sokić, M.; Kamberović, Željko; Nikolić, Vladimir; Marković, Bojan D.; Korać, Marija; Anić, Z.; Gavrilovski, Milorad

(2015)

TY  - JOUR
AU  - Sokić, M.
AU  - Kamberović, Željko
AU  - Nikolić, Vladimir
AU  - Marković, Bojan D.
AU  - Korać, Marija
AU  - Anić, Z.
AU  - Gavrilovski, Milorad
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/287
AB  - The objects of this investigation were the comparative kinetic analysis of the NiO and NiCl2 reduction by hydrogen during an induction period and elimination of the calcination during the synthesis of Ni/Al2O3 catalysts. The effect of temperature and time on NiO and NiCl2 reduction degrees was studied. Avrami I equation was selected as the most favorable kinetic model and used to determine activation energy of the NiO and NiCl2 reduction for the investigated temperature range (623-923 K) and time intervals (1-5 minutes). The investigation enabled reaching conclusions about the reaction ability and rate of the reduction processes. Afterward, Ni/Al2O3 catalysts were obtained by using oxide and chloride precursor for Ni. The catalysts were supported on alumina-based foam and prepared via aerosol route. Properties of the samples before and after low-temperature hydrogen reduction (633 K) were compared. Obtained results indicated that the synthesis of Ni/Al2O3 catalysts can be more efficient if chloride precursor for Ni is directly reduced by hydrogen during the synthesis process, without the calcination step. In addition, Ni-Pd/Al2O3 catalysts with different metal content were prepared by using chloride precursors. Lower reduction temperature was utilized and the chlorides were almost completely reduced at 533 K. © 2015 Miroslav Sokić et al.
T2  - Scientific World Journal
T1  - Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts
VL  - 2015
SP  - 601970
DO  - 10.1155/2015/601970
ER  - 
@article{
author = "Sokić, M. and Kamberović, Željko and Nikolić, Vladimir and Marković, Bojan D. and Korać, Marija and Anić, Z. and Gavrilovski, Milorad",
year = "2015",
abstract = "The objects of this investigation were the comparative kinetic analysis of the NiO and NiCl2 reduction by hydrogen during an induction period and elimination of the calcination during the synthesis of Ni/Al2O3 catalysts. The effect of temperature and time on NiO and NiCl2 reduction degrees was studied. Avrami I equation was selected as the most favorable kinetic model and used to determine activation energy of the NiO and NiCl2 reduction for the investigated temperature range (623-923 K) and time intervals (1-5 minutes). The investigation enabled reaching conclusions about the reaction ability and rate of the reduction processes. Afterward, Ni/Al2O3 catalysts were obtained by using oxide and chloride precursor for Ni. The catalysts were supported on alumina-based foam and prepared via aerosol route. Properties of the samples before and after low-temperature hydrogen reduction (633 K) were compared. Obtained results indicated that the synthesis of Ni/Al2O3 catalysts can be more efficient if chloride precursor for Ni is directly reduced by hydrogen during the synthesis process, without the calcination step. In addition, Ni-Pd/Al2O3 catalysts with different metal content were prepared by using chloride precursors. Lower reduction temperature was utilized and the chlorides were almost completely reduced at 533 K. © 2015 Miroslav Sokić et al.",
journal = "Scientific World Journal",
title = "Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts",
volume = "2015",
pages = "601970",
doi = "10.1155/2015/601970"
}
Sokić, M., Kamberović, Ž., Nikolić, V., Marković, B. D., Korać, M., Anić, Z.,& Gavrilovski, M.. (2015). Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts. in Scientific World Journal, 2015, 601970.
https://doi.org/10.1155/2015/601970
Sokić M, Kamberović Ž, Nikolić V, Marković BD, Korać M, Anić Z, Gavrilovski M. Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts. in Scientific World Journal. 2015;2015:601970.
doi:10.1155/2015/601970 .
Sokić, M., Kamberović, Željko, Nikolić, Vladimir, Marković, Bojan D., Korać, Marija, Anić, Z., Gavrilovski, Milorad, "Kinetics of NiO and NiCl2 hydrogen reduction as precursors and properties of produced Ni/Al2O3 and Ni-Pd/Al2O3 catalysts" in Scientific World Journal, 2015 (2015):601970,
https://doi.org/10.1155/2015/601970 . .
10
5
6

Synthesis of Alpha-Al2o3 Based Foams with Improved Properties as Catalyst Carriers

Nikolić, Vesna; Kamberović, Željko; Anđić, Zoran; Korać, Marija; Sokic, Miroslav

(Inst Za Kovinske Materiale I In Tehnologie, Ljubjana, 2014)

TY  - JOUR
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Anđić, Zoran
AU  - Korać, Marija
AU  - Sokic, Miroslav
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1505
AB  - This paper explores the possibility of synthesising catalyst supports with improved properties. Alumina foams were produced with the polymer replication technique. Representative high- and low-temperature sintering ceramics were selected. Suitable suspension amounts, the clay addition and sintering temperature were determined. A lower sintering temperature was used for an economic enhancement of the process. The sintering was conducted at the temperatures from 1573 K to 1773 K for 60 min. A comparative analysis of the studied systems shows that the best compressive strength of 6.2 MPa was achieved with the system based on the alpha-Al2O3-25 clay (mass fractions, w/%), polyester foam with 10 PPI, sintered at 1673 K.
PB  - Inst Za Kovinske Materiale I In Tehnologie, Ljubjana
T2  - Materials and Technology = Materiali in Tehnologije
T1  - Synthesis of Alpha-Al2o3 Based Foams with Improved Properties as Catalyst Carriers
VL  - 48
IS  - 1
SP  - 45
EP  - 50
UR  - https://hdl.handle.net/21.15107/rcub_cherry_1505
ER  - 
@article{
author = "Nikolić, Vesna and Kamberović, Željko and Anđić, Zoran and Korać, Marija and Sokic, Miroslav",
year = "2014",
abstract = "This paper explores the possibility of synthesising catalyst supports with improved properties. Alumina foams were produced with the polymer replication technique. Representative high- and low-temperature sintering ceramics were selected. Suitable suspension amounts, the clay addition and sintering temperature were determined. A lower sintering temperature was used for an economic enhancement of the process. The sintering was conducted at the temperatures from 1573 K to 1773 K for 60 min. A comparative analysis of the studied systems shows that the best compressive strength of 6.2 MPa was achieved with the system based on the alpha-Al2O3-25 clay (mass fractions, w/%), polyester foam with 10 PPI, sintered at 1673 K.",
publisher = "Inst Za Kovinske Materiale I In Tehnologie, Ljubjana",
journal = "Materials and Technology = Materiali in Tehnologije",
title = "Synthesis of Alpha-Al2o3 Based Foams with Improved Properties as Catalyst Carriers",
volume = "48",
number = "1",
pages = "45-50",
url = "https://hdl.handle.net/21.15107/rcub_cherry_1505"
}
Nikolić, V., Kamberović, Ž., Anđić, Z., Korać, M.,& Sokic, M.. (2014). Synthesis of Alpha-Al2o3 Based Foams with Improved Properties as Catalyst Carriers. in Materials and Technology = Materiali in Tehnologije
Inst Za Kovinske Materiale I In Tehnologie, Ljubjana., 48(1), 45-50.
https://hdl.handle.net/21.15107/rcub_cherry_1505
Nikolić V, Kamberović Ž, Anđić Z, Korać M, Sokic M. Synthesis of Alpha-Al2o3 Based Foams with Improved Properties as Catalyst Carriers. in Materials and Technology = Materiali in Tehnologije. 2014;48(1):45-50.
https://hdl.handle.net/21.15107/rcub_cherry_1505 .
Nikolić, Vesna, Kamberović, Željko, Anđić, Zoran, Korać, Marija, Sokic, Miroslav, "Synthesis of Alpha-Al2o3 Based Foams with Improved Properties as Catalyst Carriers" in Materials and Technology = Materiali in Tehnologije, 48, no. 1 (2014):45-50,
https://hdl.handle.net/21.15107/rcub_cherry_1505 .
8
8

Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams

Nikolić, Vesna; Kamberović, Željko; Anđić, Zoran; Korać, Marija; Sokic, Miroslav; Maksimovic, Vesna

(Springer, New York, 2014)

TY  - JOUR
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Anđić, Zoran
AU  - Korać, Marija
AU  - Sokic, Miroslav
AU  - Maksimovic, Vesna
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1826
AB  - A method of synthesizing Ni-based catalysts supported on alpha-Al2O3-based foams was developed. The foams were impregnated with aqueous solutions of metal chlorides under an air atmosphere using an aerosol route. Separate procedures involved calcination to form oxides and drying to obtain chlorides on the foam surface. The synthesized samples were subsequently reduced with hydrogen. With respect to the Ni/Al2O3 catalysts, the chloride reduction route enabled the formation of a Ni coating without agglomerates or cracks. Further research included catalyst modification by the addition of Pd, Cu, and Fe. The influences of the additives on the degree of reduction and on the low-temperature reduction effectiveness (533 and 633 K) were examined and compared for the catalysts obtained from oxides and chlorides. Greater degrees of reduction were achieved with chlorides, whereas Pd was the most effective modifier among those investigated. The reduction process was nearly complete at 533 K in the sample that contained 0.1wt% Pd. A lower reduction temperature was utilized, and the calcination step was avoided, which may enhance the economical and technological aspects of the developed catalyst production method.
PB  - Springer, New York
T2  - International Journal of Minerals, Metallurgy and Materials
T1  - Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams
VL  - 21
IS  - 8
SP  - 806
EP  - 812
DO  - 10.1007/s12613-014-0974-x
ER  - 
@article{
author = "Nikolić, Vesna and Kamberović, Željko and Anđić, Zoran and Korać, Marija and Sokic, Miroslav and Maksimovic, Vesna",
year = "2014",
abstract = "A method of synthesizing Ni-based catalysts supported on alpha-Al2O3-based foams was developed. The foams were impregnated with aqueous solutions of metal chlorides under an air atmosphere using an aerosol route. Separate procedures involved calcination to form oxides and drying to obtain chlorides on the foam surface. The synthesized samples were subsequently reduced with hydrogen. With respect to the Ni/Al2O3 catalysts, the chloride reduction route enabled the formation of a Ni coating without agglomerates or cracks. Further research included catalyst modification by the addition of Pd, Cu, and Fe. The influences of the additives on the degree of reduction and on the low-temperature reduction effectiveness (533 and 633 K) were examined and compared for the catalysts obtained from oxides and chlorides. Greater degrees of reduction were achieved with chlorides, whereas Pd was the most effective modifier among those investigated. The reduction process was nearly complete at 533 K in the sample that contained 0.1wt% Pd. A lower reduction temperature was utilized, and the calcination step was avoided, which may enhance the economical and technological aspects of the developed catalyst production method.",
publisher = "Springer, New York",
journal = "International Journal of Minerals, Metallurgy and Materials",
title = "Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams",
volume = "21",
number = "8",
pages = "806-812",
doi = "10.1007/s12613-014-0974-x"
}
Nikolić, V., Kamberović, Ž., Anđić, Z., Korać, M., Sokic, M.,& Maksimovic, V.. (2014). Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams. in International Journal of Minerals, Metallurgy and Materials
Springer, New York., 21(8), 806-812.
https://doi.org/10.1007/s12613-014-0974-x
Nikolić V, Kamberović Ž, Anđić Z, Korać M, Sokic M, Maksimovic V. Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams. in International Journal of Minerals, Metallurgy and Materials. 2014;21(8):806-812.
doi:10.1007/s12613-014-0974-x .
Nikolić, Vesna, Kamberović, Željko, Anđić, Zoran, Korać, Marija, Sokic, Miroslav, Maksimovic, Vesna, "Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams" in International Journal of Minerals, Metallurgy and Materials, 21, no. 8 (2014):806-812,
https://doi.org/10.1007/s12613-014-0974-x . .
5
6
6
1

Effects of Additives on Nickel (Ii)-Chloride Hydrogen Reduction for Production of Nanocomposite Catalysts

Kamberović, Željko; Sokic, Miroslav; Matkovic, Vladislav; Anđić, Zoran; Korać, Marija; Nikolić, Vesna

(Editura Stiintifica Fmr, Bucharest, 2012)

TY  - JOUR
AU  - Kamberović, Željko
AU  - Sokic, Miroslav
AU  - Matkovic, Vladislav
AU  - Anđić, Zoran
AU  - Korać, Marija
AU  - Nikolić, Vesna
PY  - 2012
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1269
AB  - Catalysts based on nickel, as active component, exhibit suitable properties in various heterogeneous catalysis processes; however, they quickly deactivate due to deposits formation during exploitation and sintering at elevated temperatures. Considering that catalysts with several catalytic components possess enhanced catalytic properties, in present study the influence of temperature, time and additives (PdCl2, FeCl2 and CuCl2) on the reduction degree of nickel(II)-chloride by hydrogen have been investigated. The objectives of the study were selection of an appropriate catalytic activity modifier and development of a new synthesis method for nanocomposite catalysts production, which are characterized by enhanced properties compared to the commercial Ni/Al2O3 catalysts. Obtained experimental results clearly indicate that the best effect was achieved with addition of 0.1 wt. % PdCl2, whereby NiCl2, reduction degree was 58.16% at 653 K and Pd significantly increased the reduction rate. According to the obtained results., new technological synthesis method of nanocomposite Ni-Pd/Al2O3 catalysis was proposed, where Ni and Pd. as catalytically active components, are homogeneously dispersed in monolithic Al2O3 based ceramic foam.
PB  - Editura Stiintifica Fmr, Bucharest
T2  - Metalurgia International
T1  - Effects of Additives on Nickel (Ii)-Chloride Hydrogen Reduction for Production of Nanocomposite Catalysts
VL  - 17
IS  - 5
SP  - 37
EP  - 41
UR  - https://hdl.handle.net/21.15107/rcub_cherry_1269
ER  - 
@article{
author = "Kamberović, Željko and Sokic, Miroslav and Matkovic, Vladislav and Anđić, Zoran and Korać, Marija and Nikolić, Vesna",
year = "2012",
abstract = "Catalysts based on nickel, as active component, exhibit suitable properties in various heterogeneous catalysis processes; however, they quickly deactivate due to deposits formation during exploitation and sintering at elevated temperatures. Considering that catalysts with several catalytic components possess enhanced catalytic properties, in present study the influence of temperature, time and additives (PdCl2, FeCl2 and CuCl2) on the reduction degree of nickel(II)-chloride by hydrogen have been investigated. The objectives of the study were selection of an appropriate catalytic activity modifier and development of a new synthesis method for nanocomposite catalysts production, which are characterized by enhanced properties compared to the commercial Ni/Al2O3 catalysts. Obtained experimental results clearly indicate that the best effect was achieved with addition of 0.1 wt. % PdCl2, whereby NiCl2, reduction degree was 58.16% at 653 K and Pd significantly increased the reduction rate. According to the obtained results., new technological synthesis method of nanocomposite Ni-Pd/Al2O3 catalysis was proposed, where Ni and Pd. as catalytically active components, are homogeneously dispersed in monolithic Al2O3 based ceramic foam.",
publisher = "Editura Stiintifica Fmr, Bucharest",
journal = "Metalurgia International",
title = "Effects of Additives on Nickel (Ii)-Chloride Hydrogen Reduction for Production of Nanocomposite Catalysts",
volume = "17",
number = "5",
pages = "37-41",
url = "https://hdl.handle.net/21.15107/rcub_cherry_1269"
}
Kamberović, Ž., Sokic, M., Matkovic, V., Anđić, Z., Korać, M.,& Nikolić, V.. (2012). Effects of Additives on Nickel (Ii)-Chloride Hydrogen Reduction for Production of Nanocomposite Catalysts. in Metalurgia International
Editura Stiintifica Fmr, Bucharest., 17(5), 37-41.
https://hdl.handle.net/21.15107/rcub_cherry_1269
Kamberović Ž, Sokic M, Matkovic V, Anđić Z, Korać M, Nikolić V. Effects of Additives on Nickel (Ii)-Chloride Hydrogen Reduction for Production of Nanocomposite Catalysts. in Metalurgia International. 2012;17(5):37-41.
https://hdl.handle.net/21.15107/rcub_cherry_1269 .
Kamberović, Željko, Sokic, Miroslav, Matkovic, Vladislav, Anđić, Zoran, Korać, Marija, Nikolić, Vesna, "Effects of Additives on Nickel (Ii)-Chloride Hydrogen Reduction for Production of Nanocomposite Catalysts" in Metalurgia International, 17, no. 5 (2012):37-41,
https://hdl.handle.net/21.15107/rcub_cherry_1269 .
1
2