National Science Foundation [CAREER CHE-1254360]

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National Science Foundation [CAREER CHE-1254360]

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Publications

Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction

Cinderella, Andrew P.; Vulović, Bojan; Watson, Donald A.

(Amer Chemical Soc, Washington, 2017)

TY  - JOUR
AU  - Cinderella, Andrew P.
AU  - Vulović, Bojan
AU  - Watson, Donald A.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2475
AB  - We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles. This palladium-catalyzed process provides direct access to alkyl silanes. The delicate balance of steric and electronic parameters of the employed DrewPhos ligand is paramount to suppressing isomerization and promoting efficient and selective cross-coupling.
PB  - Amer Chemical Soc, Washington
T2  - Journal of the American Chemical Society
T1  - Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction
VL  - 139
IS  - 23
SP  - 7741
EP  - 7744
DO  - 10.1021/jacs.7b04364
ER  - 
@article{
author = "Cinderella, Andrew P. and Vulović, Bojan and Watson, Donald A.",
year = "2017",
abstract = "We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles. This palladium-catalyzed process provides direct access to alkyl silanes. The delicate balance of steric and electronic parameters of the employed DrewPhos ligand is paramount to suppressing isomerization and promoting efficient and selective cross-coupling.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of the American Chemical Society",
title = "Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction",
volume = "139",
number = "23",
pages = "7741-7744",
doi = "10.1021/jacs.7b04364"
}
Cinderella, A. P., Vulović, B.,& Watson, D. A.. (2017). Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. in Journal of the American Chemical Society
Amer Chemical Soc, Washington., 139(23), 7741-7744.
https://doi.org/10.1021/jacs.7b04364
Cinderella AP, Vulović B, Watson DA. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. in Journal of the American Chemical Society. 2017;139(23):7741-7744.
doi:10.1021/jacs.7b04364 .
Cinderella, Andrew P., Vulović, Bojan, Watson, Donald A., "Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction" in Journal of the American Chemical Society, 139, no. 23 (2017):7741-7744,
https://doi.org/10.1021/jacs.7b04364 . .
6
83
49
68
71

Heck-Like Reactions Involving Heteroatomic Electrophiles

Vulović, Bojan; Watson, Donald A.

(Wiley-V C H Verlag Gmbh, Weinheim, 2017)

TY  - JOUR
AU  - Vulović, Bojan
AU  - Watson, Donald A.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2525
AB  - Since the discovery of the Heck reaction in the early seventies, the reaction has become a powerful tool in synthetic organic chemistry. By employing heteroatomic instead of traditional carbon electrophiles, the Heck reaction shows an intriguing flexibility. These hetereoatomic Heck reactions reinvigorate the area, by offering new routes to highly useful synthetic precursors and structural motifs present in biologically active compounds. This microreview focuses on early developments leading to the heteroatomic-Heck reactions (silyl-Heck, boryl-Heck and intramolecular aza-Heck), current state of the emerging area, as well as that of a few related processes.
PB  - Wiley-V C H Verlag Gmbh, Weinheim
T2  - European Journal of Organic Chemistry
T1  - Heck-Like Reactions Involving Heteroatomic Electrophiles
IS  - 34
SP  - 4996
EP  - 5009
DO  - 10.1002/ejoc.201700485
ER  - 
@article{
author = "Vulović, Bojan and Watson, Donald A.",
year = "2017",
abstract = "Since the discovery of the Heck reaction in the early seventies, the reaction has become a powerful tool in synthetic organic chemistry. By employing heteroatomic instead of traditional carbon electrophiles, the Heck reaction shows an intriguing flexibility. These hetereoatomic Heck reactions reinvigorate the area, by offering new routes to highly useful synthetic precursors and structural motifs present in biologically active compounds. This microreview focuses on early developments leading to the heteroatomic-Heck reactions (silyl-Heck, boryl-Heck and intramolecular aza-Heck), current state of the emerging area, as well as that of a few related processes.",
publisher = "Wiley-V C H Verlag Gmbh, Weinheim",
journal = "European Journal of Organic Chemistry",
title = "Heck-Like Reactions Involving Heteroatomic Electrophiles",
number = "34",
pages = "4996-5009",
doi = "10.1002/ejoc.201700485"
}
Vulović, B.,& Watson, D. A.. (2017). Heck-Like Reactions Involving Heteroatomic Electrophiles. in European Journal of Organic Chemistry
Wiley-V C H Verlag Gmbh, Weinheim.(34), 4996-5009.
https://doi.org/10.1002/ejoc.201700485
Vulović B, Watson DA. Heck-Like Reactions Involving Heteroatomic Electrophiles. in European Journal of Organic Chemistry. 2017;(34):4996-5009.
doi:10.1002/ejoc.201700485 .
Vulović, Bojan, Watson, Donald A., "Heck-Like Reactions Involving Heteroatomic Electrophiles" in European Journal of Organic Chemistry, no. 34 (2017):4996-5009,
https://doi.org/10.1002/ejoc.201700485 . .
1
37
26
36
33

Supplementary data for article: Cinderella, A. P.; Vulovic, B.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. Journal of the American Chemical Society 2017, 139 (23), 7741–7744. https://doi.org/10.1021/jacs.7b04364

Cinderella, Andrew P.; Vulović, Bojan; Watson, Donald A.

(Amer Chemical Soc, Washington, 2017)

TY  - DATA
AU  - Cinderella, Andrew P.
AU  - Vulović, Bojan
AU  - Watson, Donald A.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3099
PB  - Amer Chemical Soc, Washington
T2  - Journal of the American Chemical Society
T1  - Supplementary data for article:           Cinderella, A. P.; Vulovic, B.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. Journal of the American Chemical Society 2017, 139 (23), 7741–7744. https://doi.org/10.1021/jacs.7b04364
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3099
ER  - 
@misc{
author = "Cinderella, Andrew P. and Vulović, Bojan and Watson, Donald A.",
year = "2017",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of the American Chemical Society",
title = "Supplementary data for article:           Cinderella, A. P.; Vulovic, B.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. Journal of the American Chemical Society 2017, 139 (23), 7741–7744. https://doi.org/10.1021/jacs.7b04364",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3099"
}
Cinderella, A. P., Vulović, B.,& Watson, D. A.. (2017). Supplementary data for article:           Cinderella, A. P.; Vulovic, B.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. Journal of the American Chemical Society 2017, 139 (23), 7741–7744. https://doi.org/10.1021/jacs.7b04364. in Journal of the American Chemical Society
Amer Chemical Soc, Washington..
https://hdl.handle.net/21.15107/rcub_cherry_3099
Cinderella AP, Vulović B, Watson DA. Supplementary data for article:           Cinderella, A. P.; Vulovic, B.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. Journal of the American Chemical Society 2017, 139 (23), 7741–7744. https://doi.org/10.1021/jacs.7b04364. in Journal of the American Chemical Society. 2017;.
https://hdl.handle.net/21.15107/rcub_cherry_3099 .
Cinderella, Andrew P., Vulović, Bojan, Watson, Donald A., "Supplementary data for article:           Cinderella, A. P.; Vulovic, B.; Watson, D. A. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. Journal of the American Chemical Society 2017, 139 (23), 7741–7744. https://doi.org/10.1021/jacs.7b04364" in Journal of the American Chemical Society (2017),
https://hdl.handle.net/21.15107/rcub_cherry_3099 .