TY  - JOUR
AU  - Barać, Nemanja
AU  - Škrivanj, Sandra B.
AU  - Mutić, Jelena
AU  - Manojlović, Dragan D.
AU  - Bukumirić, Zoran
AU  - Živojinović, Dragana
AU  - Petrović, Rada
AU  - Ćorac, Aleksandar
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2370
AB  - Improved understanding of the relationships between heavy metals fractionation in agricultural soils and biological uptake could be obtained by analysing samples of biota in parallel with sequential extraction of their grown media. The overall goals of this study were to identify the characteristics of metal fractions and their bioavailability to maize and potato plants in the agricultural land of the Ibar River in southern Serbia and northern Kosovo. The concentrations of Pb, Zn, Cd, Ni, Cr and Cu in soil and vegetable samples were determined by the ICP-OES method. Pb/Zn production and industrial waste disposal significantly increased the pseudo-total concentrations of heavy metals in the soil together with their mobile and potentially bioavailable amounts. The Pb concentrations in the vegetable samples were generally above the EU maximum permitted concentrations in foodstuffs. However, the concentrations of Zn, Ni, Cr and Cu in the vegetables were below the critical levels. The results of the present study indicated that the intensive industrial production of Pb/Zn over the years and permanent pollution were responsible for the environmental contamination by heavy metals in the study area, particularly by Pb and Zn. The quantity of the mobile and potentially bioavailable heavy metals in the studied soils threatens the quality of Zea mays L. and Solanum tuberosum L. crops, with a real risk that these elements could enter the food chain.
PB  - Springer, Dordrecht
T2  - Water Air and Soil Pollution
T1  - Heavy Metals Fractionation in Agricultural Soils of Pb/Zn Mining Region and Their Transfer to Selected Vegetables
VL  - 227
IS  - 12
DO  - 10.1007/s11270-016-3177-4
ER  - 

@article{
author = "Barać, Nemanja and Škrivanj, Sandra B. and Mutić, Jelena and Manojlović, Dragan D. and Bukumirić, Zoran and Živojinović, Dragana and Petrović, Rada and Ćorac, Aleksandar",
year = "2016",
abstract = "Improved understanding of the relationships between heavy metals fractionation in agricultural soils and biological uptake could be obtained by analysing samples of biota in parallel with sequential extraction of their grown media. The overall goals of this study were to identify the characteristics of metal fractions and their bioavailability to maize and potato plants in the agricultural land of the Ibar River in southern Serbia and northern Kosovo. The concentrations of Pb, Zn, Cd, Ni, Cr and Cu in soil and vegetable samples were determined by the ICP-OES method. Pb/Zn production and industrial waste disposal significantly increased the pseudo-total concentrations of heavy metals in the soil together with their mobile and potentially bioavailable amounts. The Pb concentrations in the vegetable samples were generally above the EU maximum permitted concentrations in foodstuffs. However, the concentrations of Zn, Ni, Cr and Cu in the vegetables were below the critical levels. The results of the present study indicated that the intensive industrial production of Pb/Zn over the years and permanent pollution were responsible for the environmental contamination by heavy metals in the study area, particularly by Pb and Zn. The quantity of the mobile and potentially bioavailable heavy metals in the studied soils threatens the quality of Zea mays L. and Solanum tuberosum L. crops, with a real risk that these elements could enter the food chain.",
publisher = "Springer, Dordrecht",
journal = "Water Air and Soil Pollution",
title = "Heavy Metals Fractionation in Agricultural Soils of Pb/Zn Mining Region and Their Transfer to Selected Vegetables",
volume = "227",
number = "12",
doi = "10.1007/s11270-016-3177-4"
}

Barać, N., Škrivanj, S. B., Mutić, J., Manojlović, D. D., Bukumirić, Z., Živojinović, D., Petrović, R.,& Ćorac, A.. (2016). Heavy Metals Fractionation in Agricultural Soils of Pb/Zn Mining Region and Their Transfer to Selected Vegetables. in Water Air and Soil Pollution
Springer, Dordrecht., 227(12).
https://doi.org/10.1007/s11270-016-3177-4

Barać N, Škrivanj SB, Mutić J, Manojlović DD, Bukumirić Z, Živojinović D, Petrović R, Ćorac A. Heavy Metals Fractionation in Agricultural Soils of Pb/Zn Mining Region and Their Transfer to Selected Vegetables. in Water Air and Soil Pollution. 2016;227(12).
doi:10.1007/s11270-016-3177-4 .

Barać, Nemanja, Škrivanj, Sandra B., Mutić, Jelena, Manojlović, Dragan D., Bukumirić, Zoran, Živojinović, Dragana, Petrović, Rada, Ćorac, Aleksandar, "Heavy Metals Fractionation in Agricultural Soils of Pb/Zn Mining Region and Their Transfer to Selected Vegetables" in Water Air and Soil Pollution, 227, no. 12 (2016),
https://doi.org/10.1007/s11270-016-3177-4 . .

TY  - JOUR
AU  - Barać, Nemanja
AU  - Škrivanj, Sandra B.
AU  - Bukumirić, Zoran
AU  - Živojinović, Dragana
AU  - Manojlović, Dragan D.
AU  - Barać, Milan
AU  - Petrović, Rada
AU  - Ćorac, Aleksandar
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1929
AB  - This work investigates the influence of a high-magnitude flood event on heavy elements (HEs) pollution and mobility in the agricultural soils along Ibar River in Southern Serbia and Northern Kosovo. The study area was one of the most important Pb/Zn industrial regions in Europe. Soil samples (n = 50) collected before and after the floods in May 2014 were subjected to the sequential extraction procedure proposed by the Community Bureau of Reference (BCR). The results indicated that the floods significantly increased not only the pseudo total concentrations of HEs in the soil but also their mobile and potentially bioavailable amounts. Moreover, higher concentrations (both pseudo total and potentially bioavailable) were found in the agricultural soils closer to the industrial hotspots. Principal component analysis and hierarchical cluster analysis successfully grouped the analyzed elements according to their anthropogenic or natural origin. The floods significantly increased the potential ecological risk of HEs associated with Pb/Zn industrial activities in the study area. The potential ecological risk of Cd after the floods was highest and should be of special concern.
PB  - Springer Heidelberg, Heidelberg
T2  - Environmental Science and Pollution Research
T1  - Distribution and mobility of heavy elements in floodplain agricultural soils along the Ibar River (Southern Serbia and Northern Kosovo). Chemometric investigation of pollutant sources and ecological risk assessment
VL  - 23
IS  - 9
SP  - 9000
EP  - 9011
DO  - 10.1007/s11356-016-6142-2
ER  - 

@article{
author = "Barać, Nemanja and Škrivanj, Sandra B. and Bukumirić, Zoran and Živojinović, Dragana and Manojlović, Dragan D. and Barać, Milan and Petrović, Rada and Ćorac, Aleksandar",
year = "2016",
abstract = "This work investigates the influence of a high-magnitude flood event on heavy elements (HEs) pollution and mobility in the agricultural soils along Ibar River in Southern Serbia and Northern Kosovo. The study area was one of the most important Pb/Zn industrial regions in Europe. Soil samples (n = 50) collected before and after the floods in May 2014 were subjected to the sequential extraction procedure proposed by the Community Bureau of Reference (BCR). The results indicated that the floods significantly increased not only the pseudo total concentrations of HEs in the soil but also their mobile and potentially bioavailable amounts. Moreover, higher concentrations (both pseudo total and potentially bioavailable) were found in the agricultural soils closer to the industrial hotspots. Principal component analysis and hierarchical cluster analysis successfully grouped the analyzed elements according to their anthropogenic or natural origin. The floods significantly increased the potential ecological risk of HEs associated with Pb/Zn industrial activities in the study area. The potential ecological risk of Cd after the floods was highest and should be of special concern.",
publisher = "Springer Heidelberg, Heidelberg",
journal = "Environmental Science and Pollution Research",
title = "Distribution and mobility of heavy elements in floodplain agricultural soils along the Ibar River (Southern Serbia and Northern Kosovo). Chemometric investigation of pollutant sources and ecological risk assessment",
volume = "23",
number = "9",
pages = "9000-9011",
doi = "10.1007/s11356-016-6142-2"
}

Barać, N., Škrivanj, S. B., Bukumirić, Z., Živojinović, D., Manojlović, D. D., Barać, M., Petrović, R.,& Ćorac, A.. (2016). Distribution and mobility of heavy elements in floodplain agricultural soils along the Ibar River (Southern Serbia and Northern Kosovo). Chemometric investigation of pollutant sources and ecological risk assessment. in Environmental Science and Pollution Research
Springer Heidelberg, Heidelberg., 23(9), 9000-9011.
https://doi.org/10.1007/s11356-016-6142-2

Barać N, Škrivanj SB, Bukumirić Z, Živojinović D, Manojlović DD, Barać M, Petrović R, Ćorac A. Distribution and mobility of heavy elements in floodplain agricultural soils along the Ibar River (Southern Serbia and Northern Kosovo). Chemometric investigation of pollutant sources and ecological risk assessment. in Environmental Science and Pollution Research. 2016;23(9):9000-9011.
doi:10.1007/s11356-016-6142-2 .

Barać, Nemanja, Škrivanj, Sandra B., Bukumirić, Zoran, Živojinović, Dragana, Manojlović, Dragan D., Barać, Milan, Petrović, Rada, Ćorac, Aleksandar, "Distribution and mobility of heavy elements in floodplain agricultural soils along the Ibar River (Southern Serbia and Northern Kosovo). Chemometric investigation of pollutant sources and ecological risk assessment" in Environmental Science and Pollution Research, 23, no. 9 (2016):9000-9011,
https://doi.org/10.1007/s11356-016-6142-2 . .

TY  - JOUR
AU  - Barać, Nemanja
AU  - Škrivanj, Sandra B.
AU  - Bukumirić, Zoran
AU  - Barać, Milan
AU  - Manojlović, Dragan D.
AU  - Petrović, Rada
AU  - Ćorac, Aleksandar
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2043
AB  - This article reports the results of a study focused on the presence and bioavailability of arsenic in agricultural soil in the mining and industrial regions of northern Kosovo and southern Serbia, as well as uptake and bioaccumulation of arsenic in two commonly cultivated plant species (Zea mays L. and Solanum tuberosum L.). This area was one of the most important mining districts in Europe. The collected soil samples were subjected to a modified BCR three-step sequential extraction procedure in order to investigate the chemical partitioning of arsenic in the soils. The general distribution of arsenic in various fractions was: exchangeable  lt  reducible  lt  oxidizable fractions. Highest concentrations of total arsenic in soil were found close to industrial facilities and tailing ponds. In addition, fluvisols were significantly more enriched with arsenic than soils at a distance from the river flows. The edible parts of the plant specimen showed different As contents, suggesting that these plant species have different propensities for the uptake and bioaccumulation of arsenic from soil.
PB  - Taylor & Francis Inc, Philadelphia
T2  - Soil and Sediment Contamination
T1  - Arsenic in Agricultural Soils of a Historically Mined and Industrial Region of Southern Serbia and Northern Kosovo: Bioavailability and Uptake by Plants Species Zea mays L. and Solanum tuberosum L.
VL  - 24
IS  - 6
SP  - 656
EP  - 674
DO  - 10.1080/15320383.2015.997868
ER  - 

@article{
author = "Barać, Nemanja and Škrivanj, Sandra B. and Bukumirić, Zoran and Barać, Milan and Manojlović, Dragan D. and Petrović, Rada and Ćorac, Aleksandar",
year = "2015",
abstract = "This article reports the results of a study focused on the presence and bioavailability of arsenic in agricultural soil in the mining and industrial regions of northern Kosovo and southern Serbia, as well as uptake and bioaccumulation of arsenic in two commonly cultivated plant species (Zea mays L. and Solanum tuberosum L.). This area was one of the most important mining districts in Europe. The collected soil samples were subjected to a modified BCR three-step sequential extraction procedure in order to investigate the chemical partitioning of arsenic in the soils. The general distribution of arsenic in various fractions was: exchangeable  lt  reducible  lt  oxidizable fractions. Highest concentrations of total arsenic in soil were found close to industrial facilities and tailing ponds. In addition, fluvisols were significantly more enriched with arsenic than soils at a distance from the river flows. The edible parts of the plant specimen showed different As contents, suggesting that these plant species have different propensities for the uptake and bioaccumulation of arsenic from soil.",
publisher = "Taylor & Francis Inc, Philadelphia",
journal = "Soil and Sediment Contamination",
title = "Arsenic in Agricultural Soils of a Historically Mined and Industrial Region of Southern Serbia and Northern Kosovo: Bioavailability and Uptake by Plants Species Zea mays L. and Solanum tuberosum L.",
volume = "24",
number = "6",
pages = "656-674",
doi = "10.1080/15320383.2015.997868"
}

Barać, N., Škrivanj, S. B., Bukumirić, Z., Barać, M., Manojlović, D. D., Petrović, R.,& Ćorac, A.. (2015). Arsenic in Agricultural Soils of a Historically Mined and Industrial Region of Southern Serbia and Northern Kosovo: Bioavailability and Uptake by Plants Species Zea mays L. and Solanum tuberosum L.. in Soil and Sediment Contamination
Taylor & Francis Inc, Philadelphia., 24(6), 656-674.
https://doi.org/10.1080/15320383.2015.997868

Barać N, Škrivanj SB, Bukumirić Z, Barać M, Manojlović DD, Petrović R, Ćorac A. Arsenic in Agricultural Soils of a Historically Mined and Industrial Region of Southern Serbia and Northern Kosovo: Bioavailability and Uptake by Plants Species Zea mays L. and Solanum tuberosum L.. in Soil and Sediment Contamination. 2015;24(6):656-674.
doi:10.1080/15320383.2015.997868 .

Barać, Nemanja, Škrivanj, Sandra B., Bukumirić, Zoran, Barać, Milan, Manojlović, Dragan D., Petrović, Rada, Ćorac, Aleksandar, "Arsenic in Agricultural Soils of a Historically Mined and Industrial Region of Southern Serbia and Northern Kosovo: Bioavailability and Uptake by Plants Species Zea mays L. and Solanum tuberosum L." in Soil and Sediment Contamination, 24, no. 6 (2015):656-674,
https://doi.org/10.1080/15320383.2015.997868 . .