TY  - JOUR
AU  - Mitrović, Aleksandra D.
AU  - Wild, Stefan
AU  - Lloret, Vicent
AU  - Fickert, Michael
AU  - Assebban, Mhamed
AU  - Márkus, Bence Gábor
AU  - Simon, Ferenc
AU  - Hauke, Frank
AU  - Abellán, Gonzalo
AU  - Hirsch, Andreas
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4501
AB  - Two-dimensional (2D) black phosphorus (BP) represents one of the most appealing 2D materials due to its electronic, optical, and chemical properties. Many strategies have been pursued to face its environmental instability, covalent functionalization being one of the most promising. However, the extremely low functionalization degrees and the limitations in proving the nature of the covalent functionalization still represent challenges in many of these sheet architectures reported to date. Here we shine light on the structural evolution of 2D-BP upon the addition of electrophilic diazonium salts. We demonstrated the absence of covalent functionalization in both the neutral and the reductive routes, observing in the latter case an unexpected interface conversion of BP to red phosphorus (RP), as characterized by Raman, 31P-MAS NMR, and X-ray photoelectron spectroscopies (XPS). Furthermore, thermogravimetric analysis coupled to gas chromatography and mass spectrometry (TG-GC-MS), as well as electron paramagnetic resonance (EPR) gave insights into the potential underlying radical mechanism, suggesting a Sandmeyer-like reaction.
PB  - Wiley-VCH Verlag
T2  - European Chemical Societies
T1  - Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts
VL  - 27
SP  - 3361
EP  - 3366
DO  - 10.1002/chem.202003584
ER  - 

@article{
author = "Mitrović, Aleksandra D. and Wild, Stefan and Lloret, Vicent and Fickert, Michael and Assebban, Mhamed and Márkus, Bence Gábor and Simon, Ferenc and Hauke, Frank and Abellán, Gonzalo and Hirsch, Andreas",
year = "2021",
abstract = "Two-dimensional (2D) black phosphorus (BP) represents one of the most appealing 2D materials due to its electronic, optical, and chemical properties. Many strategies have been pursued to face its environmental instability, covalent functionalization being one of the most promising. However, the extremely low functionalization degrees and the limitations in proving the nature of the covalent functionalization still represent challenges in many of these sheet architectures reported to date. Here we shine light on the structural evolution of 2D-BP upon the addition of electrophilic diazonium salts. We demonstrated the absence of covalent functionalization in both the neutral and the reductive routes, observing in the latter case an unexpected interface conversion of BP to red phosphorus (RP), as characterized by Raman, 31P-MAS NMR, and X-ray photoelectron spectroscopies (XPS). Furthermore, thermogravimetric analysis coupled to gas chromatography and mass spectrometry (TG-GC-MS), as well as electron paramagnetic resonance (EPR) gave insights into the potential underlying radical mechanism, suggesting a Sandmeyer-like reaction.",
publisher = "Wiley-VCH Verlag",
journal = "European Chemical Societies",
title = "Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts",
volume = "27",
pages = "3361-3366",
doi = "10.1002/chem.202003584"
}

Mitrović, A. D., Wild, S., Lloret, V., Fickert, M., Assebban, M., Márkus, B. G., Simon, F., Hauke, F., Abellán, G.,& Hirsch, A.. (2021). Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. in European Chemical Societies
Wiley-VCH Verlag., 27, 3361-3366.
https://doi.org/10.1002/chem.202003584

Mitrović AD, Wild S, Lloret V, Fickert M, Assebban M, Márkus BG, Simon F, Hauke F, Abellán G, Hirsch A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. in European Chemical Societies. 2021;27:3361-3366.
doi:10.1002/chem.202003584 .

Mitrović, Aleksandra D., Wild, Stefan, Lloret, Vicent, Fickert, Michael, Assebban, Mhamed, Márkus, Bence Gábor, Simon, Ferenc, Hauke, Frank, Abellán, Gonzalo, Hirsch, Andreas, "Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts" in European Chemical Societies, 27 (2021):3361-3366,
https://doi.org/10.1002/chem.202003584 . .

TY  - DATA
AU  - Mitrović, Aleksandra D.
AU  - Wild, Stefan
AU  - Lloret, Vicent
AU  - Fickert, Michael
AU  - Assebban, Mhamed
AU  - Márkus, Bence Gábor
AU  - Simon, Ferenc
AU  - Hauke, Frank
AU  - Abellán, Gonzalo
AU  - Hirsch, Andreas
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4501
PB  - Wiley-VCH Verlag
T2  - European Chemical Societies
T1  - Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4502
ER  - 

@misc{
author = "Mitrović, Aleksandra D. and Wild, Stefan and Lloret, Vicent and Fickert, Michael and Assebban, Mhamed and Márkus, Bence Gábor and Simon, Ferenc and Hauke, Frank and Abellán, Gonzalo and Hirsch, Andreas",
year = "2021",
publisher = "Wiley-VCH Verlag",
journal = "European Chemical Societies",
title = "Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4502"
}

Mitrović, A. D., Wild, S., Lloret, V., Fickert, M., Assebban, M., Márkus, B. G., Simon, F., Hauke, F., Abellán, G.,& Hirsch, A.. (2021). Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584.. in European Chemical Societies
Wiley-VCH Verlag..
https://hdl.handle.net/21.15107/rcub_cherry_4502

Mitrović AD, Wild S, Lloret V, Fickert M, Assebban M, Márkus BG, Simon F, Hauke F, Abellán G, Hirsch A. Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584.. in European Chemical Societies. 2021;.
https://hdl.handle.net/21.15107/rcub_cherry_4502 .

Mitrović, Aleksandra D., Wild, Stefan, Lloret, Vicent, Fickert, Michael, Assebban, Mhamed, Márkus, Bence Gábor, Simon, Ferenc, Hauke, Frank, Abellán, Gonzalo, Hirsch, Andreas, "Supplementary data for the article: Mitrović, A.; Wild, S.; Lloret, V.; Fickert, M.; Assebban, M.; Márkus, B. G.; Simon, F.; Hauke, F.; Abellán, G.; Hirsch, A. Interface Amorphization of Two-Dimensional Black Phosphorus upon Treatment with Diazonium Salts. Chemistry – A European Journal 2021, 27 (10), 3361–3366. https://doi.org/10.1002/chem.202003584." in European Chemical Societies (2021),
https://hdl.handle.net/21.15107/rcub_cherry_4502 .