Diagnostics and Optimization of Plasma Sources Important for Applications

Link to this page

info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/171034/RS//

Diagnostics and Optimization of Plasma Sources Important for Applications (en)
Дијагностика и оптимизација извора плазме значајних за примене (sr)
Dijagnostika i optimizacija izvora plazme značajnih za primene (sr_RS)
Authors

Publications

Plasma assisted degradation of pharmaceutics in water: propranolol hydrochloride as a model compound

Savić, Slađana D.; Kovačević, Vesna V.; Obradović, Bratislav M.; Dojčinović, BIljana P.; Roglić, Goran

(Belgrade : University of Belgrade - Faculty of Chemistry, 2020)

TY  - CONF
AU  - Savić, Slađana D.
AU  - Kovačević, Vesna V.
AU  - Obradović, Bratislav M.
AU  - Dojčinović, BIljana P.
AU  - Roglić, Goran
PY  - 2020
UR  - http://chem.bg.ac.rs/pz/news1.py?q=2506&l=0
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5926
AB  - Propranolol hydrochloride (PRO, Fig. 1), beta-blocker, is poorly degradable in wastewater treatment plants. Because of its wide use, it could pose a threat to aquatic organisms and water users. [1]
The non-thermal plasma reactor (Fig. 2) is tested for degradation of propranolol hydrochloride solution (100 ppm), using different gases under the same electrical conditions (35 W of power dissipated in plasma). 
The concentration of PRO in samples was quantified using HPLC-DAD (213 nm), with acetonitrile and water (70/30 V/V) as eluents. The retention time of PRO was 5.100 min.
The most successful propranolol hydrochloride degradation was achieved using Ar with O2 (80/20 V/V), applying 35 W of power dissipated in plasma, almost 80 % in the 1stcycle of treatment (Fig. 3). The best results with air are slightly over 80 % but in the 10th cycle of plasma reactor treatment.
The presence of N2 in the air decreases the availability of reactive oxygen species, as shown in [2].
This non-thermal plasma is successful at the degradation of organic pollutants in water, such as propranolol hydrochloride, under given conditions.
The level of propranolol hydrochloride degradation can be increased modifying the composition of feed gas, with best results using Ar with O2.
PB  - Belgrade : University of Belgrade - Faculty of Chemistry
C3  - Japan-Serbia Environmental Exchange Symposium, February 21, 2020, Belgrade
T1  - Plasma assisted degradation of pharmaceutics in water: propranolol hydrochloride as a model compound
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5926
ER  - 
@conference{
author = "Savić, Slađana D. and Kovačević, Vesna V. and Obradović, Bratislav M. and Dojčinović, BIljana P. and Roglić, Goran",
year = "2020",
abstract = "Propranolol hydrochloride (PRO, Fig. 1), beta-blocker, is poorly degradable in wastewater treatment plants. Because of its wide use, it could pose a threat to aquatic organisms and water users. [1]
The non-thermal plasma reactor (Fig. 2) is tested for degradation of propranolol hydrochloride solution (100 ppm), using different gases under the same electrical conditions (35 W of power dissipated in plasma). 
The concentration of PRO in samples was quantified using HPLC-DAD (213 nm), with acetonitrile and water (70/30 V/V) as eluents. The retention time of PRO was 5.100 min.
The most successful propranolol hydrochloride degradation was achieved using Ar with O2 (80/20 V/V), applying 35 W of power dissipated in plasma, almost 80 % in the 1stcycle of treatment (Fig. 3). The best results with air are slightly over 80 % but in the 10th cycle of plasma reactor treatment.
The presence of N2 in the air decreases the availability of reactive oxygen species, as shown in [2].
This non-thermal plasma is successful at the degradation of organic pollutants in water, such as propranolol hydrochloride, under given conditions.
The level of propranolol hydrochloride degradation can be increased modifying the composition of feed gas, with best results using Ar with O2.",
publisher = "Belgrade : University of Belgrade - Faculty of Chemistry",
journal = "Japan-Serbia Environmental Exchange Symposium, February 21, 2020, Belgrade",
title = "Plasma assisted degradation of pharmaceutics in water: propranolol hydrochloride as a model compound",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5926"
}
Savić, S. D., Kovačević, V. V., Obradović, B. M., Dojčinović, B. P.,& Roglić, G.. (2020). Plasma assisted degradation of pharmaceutics in water: propranolol hydrochloride as a model compound. in Japan-Serbia Environmental Exchange Symposium, February 21, 2020, Belgrade
Belgrade : University of Belgrade - Faculty of Chemistry..
https://hdl.handle.net/21.15107/rcub_cherry_5926
Savić SD, Kovačević VV, Obradović BM, Dojčinović BP, Roglić G. Plasma assisted degradation of pharmaceutics in water: propranolol hydrochloride as a model compound. in Japan-Serbia Environmental Exchange Symposium, February 21, 2020, Belgrade. 2020;.
https://hdl.handle.net/21.15107/rcub_cherry_5926 .
Savić, Slađana D., Kovačević, Vesna V., Obradović, Bratislav M., Dojčinović, BIljana P., Roglić, Goran, "Plasma assisted degradation of pharmaceutics in water: propranolol hydrochloride as a model compound" in Japan-Serbia Environmental Exchange Symposium, February 21, 2020, Belgrade (2020),
https://hdl.handle.net/21.15107/rcub_cherry_5926 .

Optical evidence of magnetic field-induced ferrofluid aggregation: Comparison of cobalt ferrite, magnetite, and magnesium ferrite

Lakić, Mladen; Anđelković, Ljubica; Šuljagić, Marija; Vulić, Predrag J.; Perić, Marko; Iskrenović, Predrag; Krstić, Ivan; Kuraica, Milorad M.; Nikolić, Aleksandar S.

(Elsevier, 2019)

TY  - JOUR
AU  - Lakić, Mladen
AU  - Anđelković, Ljubica
AU  - Šuljagić, Marija
AU  - Vulić, Predrag J.
AU  - Perić, Marko
AU  - Iskrenović, Predrag
AU  - Krstić, Ivan
AU  - Kuraica, Milorad M.
AU  - Nikolić, Aleksandar S.
PY  - 2019
AB  - Light-transmitting measurements of white light and a consequentially chosen laser beam of 655 nm propagating through citrate- and oleate-coated CoFe 2 O 4 , FeFe 2 O 4 and MgFe 2 O 4 nanoparticles under the influence of an external magnetic field were presented. New experimental settings were developed for the optical study of ferrites’ behavior in ferrofluid with the applied magnetic field strength within the 30–400 mT range. A magnetic field-induced change of light transmittance occurred and a precipitation of all studied samples was obtained. Optical investigations of ferrofluid suspensions revealed that, contrary to the linear aggregates of colloidal CoFe 2 O 4 and FeFe 2 O 4 , spheroidal aggregates were formed in the case of MgFe 2 O 4 . In all three cases, the surface modification resulted in decreased dipole–dipole interactions between ferrite cores, and thus, less precipitates were noticed. All oleate-coated nanoparticles have demonstrated weaker magnetic responses compared to the citrate-encapsulated samples. The aggregation of nanoparticles potentially increases cytotoxicity. Regarding non-linear clustering of MgFe 2 O 4 suspensions, it can be concluded that its excretion from the organism may likely be easier and faster when used in diagnosis and/or therapy. Therefore, more attention should be paid to the lowly toxic MgFe 2 O 4 regarding its medical application.
PB  - Elsevier
T2  - Optical Materials
T1  - Optical evidence of magnetic field-induced ferrofluid aggregation: Comparison of cobalt ferrite, magnetite, and magnesium ferrite
VL  - 91
SP  - 279
EP  - 285
DO  - 10.1016/j.optmat.2019.03.031
ER  - 
@article{
author = "Lakić, Mladen and Anđelković, Ljubica and Šuljagić, Marija and Vulić, Predrag J. and Perić, Marko and Iskrenović, Predrag and Krstić, Ivan and Kuraica, Milorad M. and Nikolić, Aleksandar S.",
year = "2019",
abstract = "Light-transmitting measurements of white light and a consequentially chosen laser beam of 655 nm propagating through citrate- and oleate-coated CoFe 2 O 4 , FeFe 2 O 4 and MgFe 2 O 4 nanoparticles under the influence of an external magnetic field were presented. New experimental settings were developed for the optical study of ferrites’ behavior in ferrofluid with the applied magnetic field strength within the 30–400 mT range. A magnetic field-induced change of light transmittance occurred and a precipitation of all studied samples was obtained. Optical investigations of ferrofluid suspensions revealed that, contrary to the linear aggregates of colloidal CoFe 2 O 4 and FeFe 2 O 4 , spheroidal aggregates were formed in the case of MgFe 2 O 4 . In all three cases, the surface modification resulted in decreased dipole–dipole interactions between ferrite cores, and thus, less precipitates were noticed. All oleate-coated nanoparticles have demonstrated weaker magnetic responses compared to the citrate-encapsulated samples. The aggregation of nanoparticles potentially increases cytotoxicity. Regarding non-linear clustering of MgFe 2 O 4 suspensions, it can be concluded that its excretion from the organism may likely be easier and faster when used in diagnosis and/or therapy. Therefore, more attention should be paid to the lowly toxic MgFe 2 O 4 regarding its medical application.",
publisher = "Elsevier",
journal = "Optical Materials",
title = "Optical evidence of magnetic field-induced ferrofluid aggregation: Comparison of cobalt ferrite, magnetite, and magnesium ferrite",
volume = "91",
pages = "279-285",
doi = "10.1016/j.optmat.2019.03.031"
}
Lakić, M., Anđelković, L., Šuljagić, M., Vulić, P. J., Perić, M., Iskrenović, P., Krstić, I., Kuraica, M. M.,& Nikolić, A. S.. (2019). Optical evidence of magnetic field-induced ferrofluid aggregation: Comparison of cobalt ferrite, magnetite, and magnesium ferrite. in Optical Materials
Elsevier., 91, 279-285.
https://doi.org/10.1016/j.optmat.2019.03.031
Lakić M, Anđelković L, Šuljagić M, Vulić PJ, Perić M, Iskrenović P, Krstić I, Kuraica MM, Nikolić AS. Optical evidence of magnetic field-induced ferrofluid aggregation: Comparison of cobalt ferrite, magnetite, and magnesium ferrite. in Optical Materials. 2019;91:279-285.
doi:10.1016/j.optmat.2019.03.031 .
Lakić, Mladen, Anđelković, Ljubica, Šuljagić, Marija, Vulić, Predrag J., Perić, Marko, Iskrenović, Predrag, Krstić, Ivan, Kuraica, Milorad M., Nikolić, Aleksandar S., "Optical evidence of magnetic field-induced ferrofluid aggregation: Comparison of cobalt ferrite, magnetite, and magnesium ferrite" in Optical Materials, 91 (2019):279-285,
https://doi.org/10.1016/j.optmat.2019.03.031 . .
8
7
7
7

Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres

Savić, Slađana D.; Kovačević, Vesna V.; Obradović, Bratislav; Roglić, Goran

(Belgrade : Serbian Chemical Society, 2019)

TY  - CONF
AU  - Savić, Slađana D.
AU  - Kovačević, Vesna V.
AU  - Obradović, Bratislav
AU  - Roglić, Goran
PY  - 2019
UR  - http://www.kmhem.net/kmhem_fin/wp-content/uploads/2019/01/7th_CYCS_Program_FINAL.pdf
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5923
AB  - Chemical properties of distilled water treated by non-thermal plasma reactor were studied. Hydrogen-peroxide production, pH value and conductivity in distilled water were measured after plasma-treatment in air, argon and argon-oxygen mixture as working gases. Water falling film dielectric barrier discharge (DBD) reactor 1 was used for water treatment. Direct contact of water film with plasma in this reactor enables efficient transfer of reactive species generated in plasma to liquid phase. For optimization of reactive species production frequency and amplitude of the applied voltage were varied. 
Chemical characterization of water treated by DBD generated in different gases shows that hydrogen peroxide production in argon reaches yield of 0.78 g/kWh, while in air it was 0.19 g/kWh. Both measurements were made with 35 W of power dissipated in plasma. Moreover, significant influence of gas atmosphere was observed in measurements of pH value and conductivity which imply that production of ions is about 15 times greater in water treated with plasma generated in air than in argon. Advanced oxidation using this type of non-thermal plasma reactor enables production of active species in situ, while working in ambient conditions.1 Effectiveness of plasma treatment was already confirmed with degradation of some waterborne pharmaceuticals.2 This opens opportunities for new studies of plasma oxidation of pharmaceuticals in aquatic environments.
PB  - Belgrade : Serbian Chemical Society
PB  - Belgrade : Serbian Young Chemists Club
C3  - Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade
T1  - Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres
IS  - 7
SP  - 107
EP  - 107
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5923
ER  - 
@conference{
author = "Savić, Slađana D. and Kovačević, Vesna V. and Obradović, Bratislav and Roglić, Goran",
year = "2019",
abstract = "Chemical properties of distilled water treated by non-thermal plasma reactor were studied. Hydrogen-peroxide production, pH value and conductivity in distilled water were measured after plasma-treatment in air, argon and argon-oxygen mixture as working gases. Water falling film dielectric barrier discharge (DBD) reactor 1 was used for water treatment. Direct contact of water film with plasma in this reactor enables efficient transfer of reactive species generated in plasma to liquid phase. For optimization of reactive species production frequency and amplitude of the applied voltage were varied. 
Chemical characterization of water treated by DBD generated in different gases shows that hydrogen peroxide production in argon reaches yield of 0.78 g/kWh, while in air it was 0.19 g/kWh. Both measurements were made with 35 W of power dissipated in plasma. Moreover, significant influence of gas atmosphere was observed in measurements of pH value and conductivity which imply that production of ions is about 15 times greater in water treated with plasma generated in air than in argon. Advanced oxidation using this type of non-thermal plasma reactor enables production of active species in situ, while working in ambient conditions.1 Effectiveness of plasma treatment was already confirmed with degradation of some waterborne pharmaceuticals.2 This opens opportunities for new studies of plasma oxidation of pharmaceuticals in aquatic environments.",
publisher = "Belgrade : Serbian Chemical Society, Belgrade : Serbian Young Chemists Club",
journal = "Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade",
title = "Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres",
number = "7",
pages = "107-107",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5923"
}
Savić, S. D., Kovačević, V. V., Obradović, B.,& Roglić, G.. (2019). Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres. in Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade
Belgrade : Serbian Chemical Society.(7), 107-107.
https://hdl.handle.net/21.15107/rcub_cherry_5923
Savić SD, Kovačević VV, Obradović B, Roglić G. Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres. in Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade. 2019;(7):107-107.
https://hdl.handle.net/21.15107/rcub_cherry_5923 .
Savić, Slađana D., Kovačević, Vesna V., Obradović, Bratislav, Roglić, Goran, "Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres" in Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade, no. 7 (2019):107-107,
https://hdl.handle.net/21.15107/rcub_cherry_5923 .

Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres

Savić, Slađana D.; Kovačević, Vesna V.; Obradović, Bratislav; Roglić, Goran

(Belgrade : Serbian Chemical Society, 2019)

TY  - CONF
AU  - Savić, Slađana D.
AU  - Kovačević, Vesna V.
AU  - Obradović, Bratislav
AU  - Roglić, Goran
PY  - 2019
UR  - http://www.kmhem.net/kmhem_fin/wp-content/uploads/2019/01/7th_CYCS_Program_FINAL.pdf
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5924
AB  - Chemical properties of distilled water treated by non-thermal plasma reactor were studied. Hydrogen-peroxide production, pH value and conductivity in distilled water were measured after plasma-treatment in air, argon and argon-oxygen mixture as working gases. Water falling film dielectric barrier discharge (DBD) reactor 1 was used for water treatment. Direct contact of water film with plasma in this reactor enables efficient transfer of reactive species generated in plasma to liquid phase. For optimization of reactive species production frequency and amplitude of the applied voltage were varied. Chemical characterization of water treated by DBD generated in different gases shows that hydrogen peroxide production in argon reaches yield of 0.78 g/kWh, while in air it was 0.19 g/kWh. Both measurements were made with 35 W of power dissipated in plasma. Moreover, significant influence of gas atmosphere was observed in measurements of pH value and conductivity which imply that production of ions is about 15 times greater in water treated with plasma generated in air than in argon. Advanced oxidation using this type of non-thermal plasma reactor enables production of active species in situ, while working in ambient conditions.1 Effectiveness of plasma treatment was already confirmed with degradation of some waterborne pharmaceuticals.2 This opens opportunities for new studies of plasma oxidation of pharmaceuticals in aquatic environments.
PB  - Belgrade : Serbian Chemical Society
PB  - Belgrade : Serbian Young Chemists Club
C3  - Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade
T1  - Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5924
ER  - 
@conference{
author = "Savić, Slađana D. and Kovačević, Vesna V. and Obradović, Bratislav and Roglić, Goran",
year = "2019",
abstract = "Chemical properties of distilled water treated by non-thermal plasma reactor were studied. Hydrogen-peroxide production, pH value and conductivity in distilled water were measured after plasma-treatment in air, argon and argon-oxygen mixture as working gases. Water falling film dielectric barrier discharge (DBD) reactor 1 was used for water treatment. Direct contact of water film with plasma in this reactor enables efficient transfer of reactive species generated in plasma to liquid phase. For optimization of reactive species production frequency and amplitude of the applied voltage were varied. Chemical characterization of water treated by DBD generated in different gases shows that hydrogen peroxide production in argon reaches yield of 0.78 g/kWh, while in air it was 0.19 g/kWh. Both measurements were made with 35 W of power dissipated in plasma. Moreover, significant influence of gas atmosphere was observed in measurements of pH value and conductivity which imply that production of ions is about 15 times greater in water treated with plasma generated in air than in argon. Advanced oxidation using this type of non-thermal plasma reactor enables production of active species in situ, while working in ambient conditions.1 Effectiveness of plasma treatment was already confirmed with degradation of some waterborne pharmaceuticals.2 This opens opportunities for new studies of plasma oxidation of pharmaceuticals in aquatic environments.",
publisher = "Belgrade : Serbian Chemical Society, Belgrade : Serbian Young Chemists Club",
journal = "Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade",
title = "Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5924"
}
Savić, S. D., Kovačević, V. V., Obradović, B.,& Roglić, G.. (2019). Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres. in Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade
Belgrade : Serbian Chemical Society..
https://hdl.handle.net/21.15107/rcub_cherry_5924
Savić SD, Kovačević VV, Obradović B, Roglić G. Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres. in Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade. 2019;.
https://hdl.handle.net/21.15107/rcub_cherry_5924 .
Savić, Slađana D., Kovačević, Vesna V., Obradović, Bratislav, Roglić, Goran, "Hydrogen Peroxide Production in Water Treated by Non-Thermal Plasma in Different Atmospheres" in Seventh Conference of the Young Chemists of Serbia: Book of Abstracts, 2nd November 2019, Belgrade (2019),
https://hdl.handle.net/21.15107/rcub_cherry_5924 .

The analysis of 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles under an external magnetic field and their radiolabeling for possible theranostic applications

Perić, Marko; Radović, Magdalena; Mirković, Marija D.; Nikolić, Aleksandar S.; Iskrenović, Predrag; Janković, Drina; Vranješ-Đurić, Sanja

(The Royal Society of Chemistry, 2019)

TY  - JOUR
AU  - Perić, Marko
AU  - Radović, Magdalena
AU  - Mirković, Marija D.
AU  - Nikolić, Aleksandar S.
AU  - Iskrenović, Predrag
AU  - Janković, Drina
AU  - Vranješ-Đurić, Sanja
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2910
AB  - The advances in nanotechnology are directed towards the development of new theranostic agents based on magnetic nanoparticles that can be used for both cancer detection and treatment. In this study, 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles (Fe 3 O 4 -DPD MNPs) were evaluated for their theranostic application using different methods. The magnetic hyperthermia efficiency of the Fe 3 O 4 -DPD MNPs was investigated in saline solution with ionic strengths between 0.05 and 1.0 mol dm −3 . For a better understanding of hyperthermia, the behavior of Fe 3 O 4 -DPD MNPs under a non-alternating magnetic field was studied, and the transparency of the sample was measured. Furthermore, the radiotracer method using the radionuclides 99m Tc and 90 Y was applied as a reliable and powerful method for evaluating the in vivo behavior of a nanoprobe; a high radiolabeling yield (>93%), in vitro and in vivo stability of the radiolabeled nanoparticles and high heating effect were observed, thus paving the way for the possible theranostic applications of Fe 3 O 4 -DPD MNPs.
PB  - The Royal Society of Chemistry
T2  - New Journal of Chemistry
T1  - The analysis of 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles under an external magnetic field and their radiolabeling for possible theranostic applications
VL  - 43
IS  - 15
SP  - 5932
EP  - 5939
DO  - 10.1039/c8nj06478d
ER  - 
@article{
author = "Perić, Marko and Radović, Magdalena and Mirković, Marija D. and Nikolić, Aleksandar S. and Iskrenović, Predrag and Janković, Drina and Vranješ-Đurić, Sanja",
year = "2019",
abstract = "The advances in nanotechnology are directed towards the development of new theranostic agents based on magnetic nanoparticles that can be used for both cancer detection and treatment. In this study, 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles (Fe 3 O 4 -DPD MNPs) were evaluated for their theranostic application using different methods. The magnetic hyperthermia efficiency of the Fe 3 O 4 -DPD MNPs was investigated in saline solution with ionic strengths between 0.05 and 1.0 mol dm −3 . For a better understanding of hyperthermia, the behavior of Fe 3 O 4 -DPD MNPs under a non-alternating magnetic field was studied, and the transparency of the sample was measured. Furthermore, the radiotracer method using the radionuclides 99m Tc and 90 Y was applied as a reliable and powerful method for evaluating the in vivo behavior of a nanoprobe; a high radiolabeling yield (>93%), in vitro and in vivo stability of the radiolabeled nanoparticles and high heating effect were observed, thus paving the way for the possible theranostic applications of Fe 3 O 4 -DPD MNPs.",
publisher = "The Royal Society of Chemistry",
journal = "New Journal of Chemistry",
title = "The analysis of 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles under an external magnetic field and their radiolabeling for possible theranostic applications",
volume = "43",
number = "15",
pages = "5932-5939",
doi = "10.1039/c8nj06478d"
}
Perić, M., Radović, M., Mirković, M. D., Nikolić, A. S., Iskrenović, P., Janković, D.,& Vranješ-Đurić, S.. (2019). The analysis of 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles under an external magnetic field and their radiolabeling for possible theranostic applications. in New Journal of Chemistry
The Royal Society of Chemistry., 43(15), 5932-5939.
https://doi.org/10.1039/c8nj06478d
Perić M, Radović M, Mirković MD, Nikolić AS, Iskrenović P, Janković D, Vranješ-Đurić S. The analysis of 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles under an external magnetic field and their radiolabeling for possible theranostic applications. in New Journal of Chemistry. 2019;43(15):5932-5939.
doi:10.1039/c8nj06478d .
Perić, Marko, Radović, Magdalena, Mirković, Marija D., Nikolić, Aleksandar S., Iskrenović, Predrag, Janković, Drina, Vranješ-Đurić, Sanja, "The analysis of 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles under an external magnetic field and their radiolabeling for possible theranostic applications" in New Journal of Chemistry, 43, no. 15 (2019):5932-5939,
https://doi.org/10.1039/c8nj06478d . .
4
2
3
3

The analysis of 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles under an external magnetic field and their radiolabeling for possible theranostic applications

Perić, Marko; Radović, Magdalena; Mirković, Marija D.; Nikolić, Aleksandar S.; Iskrenović, Predrag; Janković, Drina; Vranješ-Đurić, Sanja

(The Royal Society of Chemistry, 2019)

TY  - JOUR
AU  - Perić, Marko
AU  - Radović, Magdalena
AU  - Mirković, Marija D.
AU  - Nikolić, Aleksandar S.
AU  - Iskrenović, Predrag
AU  - Janković, Drina
AU  - Vranješ-Đurić, Sanja
PY  - 2019
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2911
AB  - The advances in nanotechnology are directed towards the development of new theranostic agents based on magnetic nanoparticles that can be used for both cancer detection and treatment. In this study, 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles (Fe 3 O 4 -DPD MNPs) were evaluated for their theranostic application using different methods. The magnetic hyperthermia efficiency of the Fe 3 O 4 -DPD MNPs was investigated in saline solution with ionic strengths between 0.05 and 1.0 mol dm −3 . For a better understanding of hyperthermia, the behavior of Fe 3 O 4 -DPD MNPs under a non-alternating magnetic field was studied, and the transparency of the sample was measured. Furthermore, the radiotracer method using the radionuclides 99m Tc and 90 Y was applied as a reliable and powerful method for evaluating the in vivo behavior of a nanoprobe; a high radiolabeling yield (>93%), in vitro and in vivo stability of the radiolabeled nanoparticles and high heating effect were observed, thus paving the way for the possible theranostic applications of Fe 3 O 4 -DPD MNPs.
PB  - The Royal Society of Chemistry
T2  - New Journal of Chemistry
T1  - The analysis of 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles under an external magnetic field and their radiolabeling for possible theranostic applications
VL  - 43
IS  - 15
SP  - 5932
EP  - 5939
DO  - 10.1039/c8nj06478d
ER  - 
@article{
author = "Perić, Marko and Radović, Magdalena and Mirković, Marija D. and Nikolić, Aleksandar S. and Iskrenović, Predrag and Janković, Drina and Vranješ-Đurić, Sanja",
year = "2019",
abstract = "The advances in nanotechnology are directed towards the development of new theranostic agents based on magnetic nanoparticles that can be used for both cancer detection and treatment. In this study, 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles (Fe 3 O 4 -DPD MNPs) were evaluated for their theranostic application using different methods. The magnetic hyperthermia efficiency of the Fe 3 O 4 -DPD MNPs was investigated in saline solution with ionic strengths between 0.05 and 1.0 mol dm −3 . For a better understanding of hyperthermia, the behavior of Fe 3 O 4 -DPD MNPs under a non-alternating magnetic field was studied, and the transparency of the sample was measured. Furthermore, the radiotracer method using the radionuclides 99m Tc and 90 Y was applied as a reliable and powerful method for evaluating the in vivo behavior of a nanoprobe; a high radiolabeling yield (>93%), in vitro and in vivo stability of the radiolabeled nanoparticles and high heating effect were observed, thus paving the way for the possible theranostic applications of Fe 3 O 4 -DPD MNPs.",
publisher = "The Royal Society of Chemistry",
journal = "New Journal of Chemistry",
title = "The analysis of 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles under an external magnetic field and their radiolabeling for possible theranostic applications",
volume = "43",
number = "15",
pages = "5932-5939",
doi = "10.1039/c8nj06478d"
}
Perić, M., Radović, M., Mirković, M. D., Nikolić, A. S., Iskrenović, P., Janković, D.,& Vranješ-Đurić, S.. (2019). The analysis of 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles under an external magnetic field and their radiolabeling for possible theranostic applications. in New Journal of Chemistry
The Royal Society of Chemistry., 43(15), 5932-5939.
https://doi.org/10.1039/c8nj06478d
Perić M, Radović M, Mirković MD, Nikolić AS, Iskrenović P, Janković D, Vranješ-Đurić S. The analysis of 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles under an external magnetic field and their radiolabeling for possible theranostic applications. in New Journal of Chemistry. 2019;43(15):5932-5939.
doi:10.1039/c8nj06478d .
Perić, Marko, Radović, Magdalena, Mirković, Marija D., Nikolić, Aleksandar S., Iskrenović, Predrag, Janković, Drina, Vranješ-Đurić, Sanja, "The analysis of 2,3-dicarboxypropane-1,1-diphosphonic acid-coated magnetite nanoparticles under an external magnetic field and their radiolabeling for possible theranostic applications" in New Journal of Chemistry, 43, no. 15 (2019):5932-5939,
https://doi.org/10.1039/c8nj06478d . .
4
2
3
3

Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment

Krupež, Jelena; Kovačević, Vesna V.; Jović, Milica; Roglić, Goran; Natić, Maja; Kuraica, Milorad M.; Obradović, Bratislav M.; Dojčinović, Biljana P.

(Iop Publishing Ltd, Bristol, 2018)

TY  - JOUR
AU  - Krupež, Jelena
AU  - Kovačević, Vesna V.
AU  - Jović, Milica
AU  - Roglić, Goran
AU  - Natić, Maja
AU  - Kuraica, Milorad M.
AU  - Obradović, Bratislav M.
AU  - Dojčinović, Biljana P.
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2126
AB  - Nicotine degradation efficiency in water solutions was studied using a water falling film dielectric barrier discharge (DBD) reactor. Two different treatments were applied: direct treatment, the recirculation of the solution through a DBD reactor, and indirect treatment, the bubbling of the gas from the DBD through the porous filter into the solution. In a separate experiment, samples spiked with nicotine in double distilled water (ddH(2)O) and tap water were studied and compared after both treatments. Furthermore, the effects of the homogeneous catalysts, namely, Fe2+ and H2O2, were tested in the direct treatment. Nicotine degradation efficiency was determined using high-performance liquid chromatography. A degradation efficiency of 90% was achieved after the direct treatment catalyzed with Fe2+. In order to analyze the biodegradability, mineralization level, and toxicity of the obtained solutions, after all degradation procedures the values of the following parameters were determined: total organic carbon, chemical oxygen demand, biochemical oxygen demand, and the Artemia salina toxicity test. The results showed that an increase in biodegradability was obtained, after all treatments. A partial nicotine mineralization was achieved and the mortality of the A. salina organism decreased in the treated samples, all of which indicating the effective removal of nicotine and the creation of less toxic solutions. Nicotine degradation products were identified using ultrahigh-performance liquid chromatography coupled with a linear ion trap Orbitrap hybrid mass spectrometer and a simple mechanism for oxidative degradation of nicotine in non-thermal plasma systems is proposed.
PB  - Iop Publishing Ltd, Bristol
T2  - Journal of Physics. D: Applied Physics
T1  - Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment
VL  - 51
IS  - 17
DO  - 10.1088/1361-6463/aab632
ER  - 
@article{
author = "Krupež, Jelena and Kovačević, Vesna V. and Jović, Milica and Roglić, Goran and Natić, Maja and Kuraica, Milorad M. and Obradović, Bratislav M. and Dojčinović, Biljana P.",
year = "2018",
abstract = "Nicotine degradation efficiency in water solutions was studied using a water falling film dielectric barrier discharge (DBD) reactor. Two different treatments were applied: direct treatment, the recirculation of the solution through a DBD reactor, and indirect treatment, the bubbling of the gas from the DBD through the porous filter into the solution. In a separate experiment, samples spiked with nicotine in double distilled water (ddH(2)O) and tap water were studied and compared after both treatments. Furthermore, the effects of the homogeneous catalysts, namely, Fe2+ and H2O2, were tested in the direct treatment. Nicotine degradation efficiency was determined using high-performance liquid chromatography. A degradation efficiency of 90% was achieved after the direct treatment catalyzed with Fe2+. In order to analyze the biodegradability, mineralization level, and toxicity of the obtained solutions, after all degradation procedures the values of the following parameters were determined: total organic carbon, chemical oxygen demand, biochemical oxygen demand, and the Artemia salina toxicity test. The results showed that an increase in biodegradability was obtained, after all treatments. A partial nicotine mineralization was achieved and the mortality of the A. salina organism decreased in the treated samples, all of which indicating the effective removal of nicotine and the creation of less toxic solutions. Nicotine degradation products were identified using ultrahigh-performance liquid chromatography coupled with a linear ion trap Orbitrap hybrid mass spectrometer and a simple mechanism for oxidative degradation of nicotine in non-thermal plasma systems is proposed.",
publisher = "Iop Publishing Ltd, Bristol",
journal = "Journal of Physics. D: Applied Physics",
title = "Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment",
volume = "51",
number = "17",
doi = "10.1088/1361-6463/aab632"
}
Krupež, J., Kovačević, V. V., Jović, M., Roglić, G., Natić, M., Kuraica, M. M., Obradović, B. M.,& Dojčinović, B. P.. (2018). Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment. in Journal of Physics. D: Applied Physics
Iop Publishing Ltd, Bristol., 51(17).
https://doi.org/10.1088/1361-6463/aab632
Krupež J, Kovačević VV, Jović M, Roglić G, Natić M, Kuraica MM, Obradović BM, Dojčinović BP. Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment. in Journal of Physics. D: Applied Physics. 2018;51(17).
doi:10.1088/1361-6463/aab632 .
Krupež, Jelena, Kovačević, Vesna V., Jović, Milica, Roglić, Goran, Natić, Maja, Kuraica, Milorad M., Obradović, Bratislav M., Dojčinović, Biljana P., "Degradation of nicotine in water solutions using a water falling film DBD plasma reactor: direct and indirect treatment" in Journal of Physics. D: Applied Physics, 51, no. 17 (2018),
https://doi.org/10.1088/1361-6463/aab632 . .
19
10
18
16

External magnetic field influence on magnetite and cobalt-ferrite nano-particles in ferrofluid

Kuraica, Milorad M.; Iskrenović, Predrag; Perić, Marko; Krstić, Ivan; Nikolić, Aleksandar S.

(Springer International Publishing Ag, Cham, 2018)

TY  - JOUR
AU  - Kuraica, Milorad M.
AU  - Iskrenović, Predrag
AU  - Perić, Marko
AU  - Krstić, Ivan
AU  - Nikolić, Aleksandar S.
PY  - 2018
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2146
AB  - Using simple optical measurements, the selective spectral behavior of suspended nano-particles of magnetite (Fe3O4) and cobalt-ferrite (CoFe2O4) coated with starch, was observed through switching on/off of external magnetic field. The field strength was varied in the interval 30-300 mT. In these transient regimes, the unexpected and unusually large changes of transmitted light occur. An explanation is suggested, within the model based on ordering of magnetic moments of nano-particles along the lines of magnetic field into magnetic chains and organization of magnetic chains into spatial structure-a quasi-lattice. This fact indicates the possibility of more efficient local heating of nano-particles in the fast changing magnetic field; for instance when taking magnetic nano-particles for therapeutic purposes.
PB  - Springer International Publishing Ag, Cham
T2  - Chemical Papers = Chemicke Zvesti
T1  - External magnetic field influence on magnetite and cobalt-ferrite nano-particles in ferrofluid
VL  - 72
IS  - 6
SP  - 1535
EP  - 1542
DO  - 10.1007/s11696-017-0380-8
ER  - 
@article{
author = "Kuraica, Milorad M. and Iskrenović, Predrag and Perić, Marko and Krstić, Ivan and Nikolić, Aleksandar S.",
year = "2018",
abstract = "Using simple optical measurements, the selective spectral behavior of suspended nano-particles of magnetite (Fe3O4) and cobalt-ferrite (CoFe2O4) coated with starch, was observed through switching on/off of external magnetic field. The field strength was varied in the interval 30-300 mT. In these transient regimes, the unexpected and unusually large changes of transmitted light occur. An explanation is suggested, within the model based on ordering of magnetic moments of nano-particles along the lines of magnetic field into magnetic chains and organization of magnetic chains into spatial structure-a quasi-lattice. This fact indicates the possibility of more efficient local heating of nano-particles in the fast changing magnetic field; for instance when taking magnetic nano-particles for therapeutic purposes.",
publisher = "Springer International Publishing Ag, Cham",
journal = "Chemical Papers = Chemicke Zvesti",
title = "External magnetic field influence on magnetite and cobalt-ferrite nano-particles in ferrofluid",
volume = "72",
number = "6",
pages = "1535-1542",
doi = "10.1007/s11696-017-0380-8"
}
Kuraica, M. M., Iskrenović, P., Perić, M., Krstić, I.,& Nikolić, A. S.. (2018). External magnetic field influence on magnetite and cobalt-ferrite nano-particles in ferrofluid. in Chemical Papers = Chemicke Zvesti
Springer International Publishing Ag, Cham., 72(6), 1535-1542.
https://doi.org/10.1007/s11696-017-0380-8
Kuraica MM, Iskrenović P, Perić M, Krstić I, Nikolić AS. External magnetic field influence on magnetite and cobalt-ferrite nano-particles in ferrofluid. in Chemical Papers = Chemicke Zvesti. 2018;72(6):1535-1542.
doi:10.1007/s11696-017-0380-8 .
Kuraica, Milorad M., Iskrenović, Predrag, Perić, Marko, Krstić, Ivan, Nikolić, Aleksandar S., "External magnetic field influence on magnetite and cobalt-ferrite nano-particles in ferrofluid" in Chemical Papers = Chemicke Zvesti, 72, no. 6 (2018):1535-1542,
https://doi.org/10.1007/s11696-017-0380-8 . .
10
6
8
8

Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres

Kovačević, Vesna V.; Dojčinović, Biljana P.; Jović, Milica; Roglić, Goran; Obradović, Bratislav M.; Kuraica, Milorad M.

(Iop Publishing Ltd, Bristol, 2017)

TY  - JOUR
AU  - Kovačević, Vesna V.
AU  - Dojčinović, Biljana P.
AU  - Jović, Milica
AU  - Roglić, Goran
AU  - Obradović, Bratislav M.
AU  - Kuraica, Milorad M.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2440
AB  - The formation of hydroxyl radical and long-living chemical species (H2O2, O-3, NO3- and NO2-) generated in the liquid phase of a water falling film dielectric barrier discharge in dependence on the gas atmosphere (air, nitrogen, oxygen, argon and helium) was studied. The chemical molecular probe dimethyl sulfoxide was employed for quantification of. OH, and the influence of hydroxyl radical scavenging on formation of reactive oxygen and nitrogen species was investigated. In addition to liquid analysis, plasma diagnostics was applied to indicate possible reaction pathways of plasma-liquid interaction. The highest. OH production rate of 1.19 x 10 (5) mol l (1) s (1) was found when water was treated in oxygen, with a yield of 2.75 x 10(-2) molecules of. OH per 100 eV. Formation of hydrogen peroxide in air, nitrogen and argon discharges is determined by recombination reaction of hydroxyl radicals, reaching the highest yield of about 0.7 g kWh(-1) when distilled water was treated in argon discharge. Ozone formation was dominant in oxygen and air discharges. Strong acidification along with formation of reactive nitrogen species was detected in water treated in air and nitrogen discharges.
PB  - Iop Publishing Ltd, Bristol
T2  - Journal of Physics. D: Applied Physics
T1  - Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres
VL  - 50
IS  - 15
DO  - 10.1088/1361-6463/aa5fde
ER  - 
@article{
author = "Kovačević, Vesna V. and Dojčinović, Biljana P. and Jović, Milica and Roglić, Goran and Obradović, Bratislav M. and Kuraica, Milorad M.",
year = "2017",
abstract = "The formation of hydroxyl radical and long-living chemical species (H2O2, O-3, NO3- and NO2-) generated in the liquid phase of a water falling film dielectric barrier discharge in dependence on the gas atmosphere (air, nitrogen, oxygen, argon and helium) was studied. The chemical molecular probe dimethyl sulfoxide was employed for quantification of. OH, and the influence of hydroxyl radical scavenging on formation of reactive oxygen and nitrogen species was investigated. In addition to liquid analysis, plasma diagnostics was applied to indicate possible reaction pathways of plasma-liquid interaction. The highest. OH production rate of 1.19 x 10 (5) mol l (1) s (1) was found when water was treated in oxygen, with a yield of 2.75 x 10(-2) molecules of. OH per 100 eV. Formation of hydrogen peroxide in air, nitrogen and argon discharges is determined by recombination reaction of hydroxyl radicals, reaching the highest yield of about 0.7 g kWh(-1) when distilled water was treated in argon discharge. Ozone formation was dominant in oxygen and air discharges. Strong acidification along with formation of reactive nitrogen species was detected in water treated in air and nitrogen discharges.",
publisher = "Iop Publishing Ltd, Bristol",
journal = "Journal of Physics. D: Applied Physics",
title = "Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres",
volume = "50",
number = "15",
doi = "10.1088/1361-6463/aa5fde"
}
Kovačević, V. V., Dojčinović, B. P., Jović, M., Roglić, G., Obradović, B. M.,& Kuraica, M. M.. (2017). Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres. in Journal of Physics. D: Applied Physics
Iop Publishing Ltd, Bristol., 50(15).
https://doi.org/10.1088/1361-6463/aa5fde
Kovačević VV, Dojčinović BP, Jović M, Roglić G, Obradović BM, Kuraica MM. Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres. in Journal of Physics. D: Applied Physics. 2017;50(15).
doi:10.1088/1361-6463/aa5fde .
Kovačević, Vesna V., Dojčinović, Biljana P., Jović, Milica, Roglić, Goran, Obradović, Bratislav M., Kuraica, Milorad M., "Measurement of reactive species generated by dielectric barrier discharge in direct contact with water in different atmospheres" in Journal of Physics. D: Applied Physics, 50, no. 15 (2017),
https://doi.org/10.1088/1361-6463/aa5fde . .
3
146
88
139
130

Application of non-thermal plasma reactor for degradation and detoxification of high concentrations of dye Reactive Black 5 in water

Dojčinović, Biljana P.; Obradović, Bratislav M.; Kuraica, Milorad M.; Pergal, Marija V.; Dolic, Slobodan D.; Indic, Dejan R.; Tosti, Tomislav; Manojlović, Dragan D.

(Serbian Chemical Soc, Belgrade, 2016)

TY  - JOUR
AU  - Dojčinović, Biljana P.
AU  - Obradović, Bratislav M.
AU  - Kuraica, Milorad M.
AU  - Pergal, Marija V.
AU  - Dolic, Slobodan D.
AU  - Indic, Dejan R.
AU  - Tosti, Tomislav
AU  - Manojlović, Dragan D.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2296
AB  - Degradation and detoxification efficiency of high concentrations of commercially available reactive textile dye Reactive Black 5 solution (40, 80, 200, 500, 1000 mg L-1), were studied. Advanced oxidation processes in water falling film based on dielectric barrier discharge in a non-thermal plasma reactor were used. For the first time, this reactor was used for the treatment of high concentrations of organic pollutants such as reactive textile dye Reactive Black 5 in water. Solution of the dye was plasma treated in a thin aqueous solution film that was constantly regenerated. The reactor works as a continuous flow reactor and the electrical discharge itself takes place at the gas-liquid interphase. The dye solution was recirculated through the reactor with an applied energy density of 0-374 kJ L-1. Decolorization efficiency (%) was monitored by UV-Vis spectrophotometry. Samples were taken after every recirculation (similar to 22 kJ L-1) and decolorization percentage was measured after 5 min and 24 h post plasma treatment. The efficiency of degradation (i.e., mineralization) and possible degradation products were also monitored by determination of the chemical oxygen demand (COD) and by ion chromatography (IC). Initial toxicity and toxicity of the solutions after the treatment were studied using Artemia salina test organisms. Efficiency of decolorization decreased with the increase of the dye concentration. Complete decolorization, high mineralization and non-toxicity of the solution ( lt 10 %) were acomplished after plasma treatment using energy density of 242 kJ L-1, while the initial concentrations of Reactive Black 5 were 40 and 80 mg L-1.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Application of non-thermal plasma reactor for degradation and detoxification of high concentrations of dye Reactive Black 5 in water
VL  - 81
IS  - 7
SP  - 829
EP  - 845
DO  - 10.2298/JSC160105030D
ER  - 
@article{
author = "Dojčinović, Biljana P. and Obradović, Bratislav M. and Kuraica, Milorad M. and Pergal, Marija V. and Dolic, Slobodan D. and Indic, Dejan R. and Tosti, Tomislav and Manojlović, Dragan D.",
year = "2016",
abstract = "Degradation and detoxification efficiency of high concentrations of commercially available reactive textile dye Reactive Black 5 solution (40, 80, 200, 500, 1000 mg L-1), were studied. Advanced oxidation processes in water falling film based on dielectric barrier discharge in a non-thermal plasma reactor were used. For the first time, this reactor was used for the treatment of high concentrations of organic pollutants such as reactive textile dye Reactive Black 5 in water. Solution of the dye was plasma treated in a thin aqueous solution film that was constantly regenerated. The reactor works as a continuous flow reactor and the electrical discharge itself takes place at the gas-liquid interphase. The dye solution was recirculated through the reactor with an applied energy density of 0-374 kJ L-1. Decolorization efficiency (%) was monitored by UV-Vis spectrophotometry. Samples were taken after every recirculation (similar to 22 kJ L-1) and decolorization percentage was measured after 5 min and 24 h post plasma treatment. The efficiency of degradation (i.e., mineralization) and possible degradation products were also monitored by determination of the chemical oxygen demand (COD) and by ion chromatography (IC). Initial toxicity and toxicity of the solutions after the treatment were studied using Artemia salina test organisms. Efficiency of decolorization decreased with the increase of the dye concentration. Complete decolorization, high mineralization and non-toxicity of the solution ( lt 10 %) were acomplished after plasma treatment using energy density of 242 kJ L-1, while the initial concentrations of Reactive Black 5 were 40 and 80 mg L-1.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Application of non-thermal plasma reactor for degradation and detoxification of high concentrations of dye Reactive Black 5 in water",
volume = "81",
number = "7",
pages = "829-845",
doi = "10.2298/JSC160105030D"
}
Dojčinović, B. P., Obradović, B. M., Kuraica, M. M., Pergal, M. V., Dolic, S. D., Indic, D. R., Tosti, T.,& Manojlović, D. D.. (2016). Application of non-thermal plasma reactor for degradation and detoxification of high concentrations of dye Reactive Black 5 in water. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 81(7), 829-845.
https://doi.org/10.2298/JSC160105030D
Dojčinović BP, Obradović BM, Kuraica MM, Pergal MV, Dolic SD, Indic DR, Tosti T, Manojlović DD. Application of non-thermal plasma reactor for degradation and detoxification of high concentrations of dye Reactive Black 5 in water. in Journal of the Serbian Chemical Society. 2016;81(7):829-845.
doi:10.2298/JSC160105030D .
Dojčinović, Biljana P., Obradović, Bratislav M., Kuraica, Milorad M., Pergal, Marija V., Dolic, Slobodan D., Indic, Dejan R., Tosti, Tomislav, Manojlović, Dragan D., "Application of non-thermal plasma reactor for degradation and detoxification of high concentrations of dye Reactive Black 5 in water" in Journal of the Serbian Chemical Society, 81, no. 7 (2016):829-845,
https://doi.org/10.2298/JSC160105030D . .
9
10
12
8

Application of Water Falling Film Dbd for Degradation of Nicotine in Water Solutions

Kovačević, Vesna V.; Dojčinović, Biljana P.; Krupež, Jelena; Jović, Mihajlo D.; Natić, Maja; Sretenovic, G. B.; Manojlović, Dragan D.; Obradović, Bratislav M.; Kuraica, Milorad M.

(Masarykova Univ, Brno, 2016)

TY  - CONF
AU  - Kovačević, Vesna V.
AU  - Dojčinović, Biljana P.
AU  - Krupež, Jelena
AU  - Jović, Mihajlo D.
AU  - Natić, Maja
AU  - Sretenovic, G. B.
AU  - Manojlović, Dragan D.
AU  - Obradović, Bratislav M.
AU  - Kuraica, Milorad M.
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2394
AB  - In this paper we present plasma-based degradation of nicotine in water solutions. Water falling film dielectric barrier discharge (DBD) was used as plasma source operating in air at atmospheric pressure. Solutions containing 50 ppm and 300 ppm of nicotine in distilled or tape water were treated directly and indirectly by plasma. Influence of homogeneous catalysts Fe2+ and H2O2 was also tested. Artemia Salina organisms were used for toxicity tests of treated solutions. Degradation efficiency was the highest in direct plasma treatment of nicotine with Fe2+ as a catalyst and in this case the toxicity test showed the lowest mortality.
PB  - Masarykova Univ, Brno
T1  - Application of Water Falling Film Dbd for Degradation of Nicotine in Water Solutions
SP  - 420
EP  - 423
UR  - https://hdl.handle.net/21.15107/rcub_cherry_2394
ER  - 
@conference{
author = "Kovačević, Vesna V. and Dojčinović, Biljana P. and Krupež, Jelena and Jović, Mihajlo D. and Natić, Maja and Sretenovic, G. B. and Manojlović, Dragan D. and Obradović, Bratislav M. and Kuraica, Milorad M.",
year = "2016",
abstract = "In this paper we present plasma-based degradation of nicotine in water solutions. Water falling film dielectric barrier discharge (DBD) was used as plasma source operating in air at atmospheric pressure. Solutions containing 50 ppm and 300 ppm of nicotine in distilled or tape water were treated directly and indirectly by plasma. Influence of homogeneous catalysts Fe2+ and H2O2 was also tested. Artemia Salina organisms were used for toxicity tests of treated solutions. Degradation efficiency was the highest in direct plasma treatment of nicotine with Fe2+ as a catalyst and in this case the toxicity test showed the lowest mortality.",
publisher = "Masarykova Univ, Brno",
title = "Application of Water Falling Film Dbd for Degradation of Nicotine in Water Solutions",
pages = "420-423",
url = "https://hdl.handle.net/21.15107/rcub_cherry_2394"
}
Kovačević, V. V., Dojčinović, B. P., Krupež, J., Jović, M. D., Natić, M., Sretenovic, G. B., Manojlović, D. D., Obradović, B. M.,& Kuraica, M. M.. (2016). Application of Water Falling Film Dbd for Degradation of Nicotine in Water Solutions. 
Masarykova Univ, Brno., 420-423.
https://hdl.handle.net/21.15107/rcub_cherry_2394
Kovačević VV, Dojčinović BP, Krupež J, Jović MD, Natić M, Sretenovic GB, Manojlović DD, Obradović BM, Kuraica MM. Application of Water Falling Film Dbd for Degradation of Nicotine in Water Solutions. 2016;:420-423.
https://hdl.handle.net/21.15107/rcub_cherry_2394 .
Kovačević, Vesna V., Dojčinović, Biljana P., Krupež, Jelena, Jović, Mihajlo D., Natić, Maja, Sretenovic, G. B., Manojlović, Dragan D., Obradović, Bratislav M., Kuraica, Milorad M., "Application of Water Falling Film Dbd for Degradation of Nicotine in Water Solutions" (2016):420-423,
https://hdl.handle.net/21.15107/rcub_cherry_2394 .

Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen

Marković, Marijana; Jović, Milica; Stanković, Dalibor; Kovačević, Vesna V.; Roglić, Goran; Gojgić-Cvijović, Gordana D.; Manojlović, Dragan D.

(Elsevier Science Bv, Amsterdam, 2015)

TY  - JOUR
AU  - Marković, Marijana
AU  - Jović, Milica
AU  - Stanković, Dalibor
AU  - Kovačević, Vesna V.
AU  - Roglić, Goran
AU  - Gojgić-Cvijović, Gordana D.
AU  - Manojlović, Dragan D.
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1898
AB  - Pharmaceutical compounds have been detected frequently in surface and ground water. Advanced Oxidation Processes (AOPs) were reported as very efficient for removal of various organic compounds. Nevertheless, due to incomplete degradation, toxic intermediates can induce more severe effects than the parent compound. Therefore, toxicity studies are necessary for the evaluation of possible uses of AOPs. In this study the effectiveness and capacity for environmental application of three different AOPs were estimated. They were applied and evaluated for removal of ibuprofen from water solutions. Therefore, two treatments were performed in a non-thermal plasma reactor with dielectric barrier discharge with and without a homogenous catalyst (Fe2+). The third treatment was the Fenton reaction. The degradation rate of ibuprofen was measured by HPLC-DAD and the main degradation products were identified using LC-MS TOF. Twelve degradation products were identified, and there were differences according to the various treatments applied. Toxicity effects were determined with two bioassays: Vibrio fischeri and Artemia salina. The efficiency of AOPs was demonstrated for all treatments, where after 15 min degradation percentage was over 80% accompanied by opening of the aromatic ring. In the treatment with homogenous catalyst degradation reached 99%. V. fischeri toxicity test has shown greater sensitivity to ibuprofen solution after the Fenton treatment in comparison to A. salina. (C) 2014 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Science of the Total Environment
T1  - Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen
VL  - 505
SP  - 1148
EP  - 1155
DO  - 10.1016/j.scitotenv.2014.11.017
ER  - 
@article{
author = "Marković, Marijana and Jović, Milica and Stanković, Dalibor and Kovačević, Vesna V. and Roglić, Goran and Gojgić-Cvijović, Gordana D. and Manojlović, Dragan D.",
year = "2015",
abstract = "Pharmaceutical compounds have been detected frequently in surface and ground water. Advanced Oxidation Processes (AOPs) were reported as very efficient for removal of various organic compounds. Nevertheless, due to incomplete degradation, toxic intermediates can induce more severe effects than the parent compound. Therefore, toxicity studies are necessary for the evaluation of possible uses of AOPs. In this study the effectiveness and capacity for environmental application of three different AOPs were estimated. They were applied and evaluated for removal of ibuprofen from water solutions. Therefore, two treatments were performed in a non-thermal plasma reactor with dielectric barrier discharge with and without a homogenous catalyst (Fe2+). The third treatment was the Fenton reaction. The degradation rate of ibuprofen was measured by HPLC-DAD and the main degradation products were identified using LC-MS TOF. Twelve degradation products were identified, and there were differences according to the various treatments applied. Toxicity effects were determined with two bioassays: Vibrio fischeri and Artemia salina. The efficiency of AOPs was demonstrated for all treatments, where after 15 min degradation percentage was over 80% accompanied by opening of the aromatic ring. In the treatment with homogenous catalyst degradation reached 99%. V. fischeri toxicity test has shown greater sensitivity to ibuprofen solution after the Fenton treatment in comparison to A. salina. (C) 2014 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Science of the Total Environment",
title = "Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen",
volume = "505",
pages = "1148-1155",
doi = "10.1016/j.scitotenv.2014.11.017"
}
Marković, M., Jović, M., Stanković, D., Kovačević, V. V., Roglić, G., Gojgić-Cvijović, G. D.,& Manojlović, D. D.. (2015). Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen. in Science of the Total Environment
Elsevier Science Bv, Amsterdam., 505, 1148-1155.
https://doi.org/10.1016/j.scitotenv.2014.11.017
Marković M, Jović M, Stanković D, Kovačević VV, Roglić G, Gojgić-Cvijović GD, Manojlović DD. Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen. in Science of the Total Environment. 2015;505:1148-1155.
doi:10.1016/j.scitotenv.2014.11.017 .
Marković, Marijana, Jović, Milica, Stanković, Dalibor, Kovačević, Vesna V., Roglić, Goran, Gojgić-Cvijović, Gordana D., Manojlović, Dragan D., "Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen" in Science of the Total Environment, 505 (2015):1148-1155,
https://doi.org/10.1016/j.scitotenv.2014.11.017 . .
1
92
61
89
80

Effect of different catalysts on mesotrione degradation in water falling film DBD reactor

Jović, Milica; Dojčinović, Biljana P.; Kovačević, Vesna V.; Obradović, Bratislav M.; Kuraica, Milorad M.; Gašić, Uroš M.; Roglić, Goran

(Elsevier Science Sa, Lausanne, 2014)

TY  - JOUR
AU  - Jović, Milica
AU  - Dojčinović, Biljana P.
AU  - Kovačević, Vesna V.
AU  - Obradović, Bratislav M.
AU  - Kuraica, Milorad M.
AU  - Gašić, Uroš M.
AU  - Roglić, Goran
PY  - 2014
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1790
AB  - In this study the effect of different homogenous catalysts and their dosage on mesotrione degradation in water falling film dielectric barrier discharge (DBD) reactor was investigated. Four catalytic systems Mn2+ /DBD, Co2+/DBD, Fe2+/DBD and H2O2/DBD were examined. In order to find optimal conditions various concentrations of catalysts and specific energy density (SED) values were tested in each system. Mesotrione degradation efficiency was determined by HPLC-DAD and mineralization efficiency by TOC value. Degradation products were identified by UHPLC-Orbitrap-MS and compared after finding out the optimal concentration for each catalytic system. All studied catalytic systems have proved to be successful in improving mesotrione removal, but the highest improvement in degradation efficiency was obtained with catalytic system 5 ppm Fe2+/DBD (by 50% for SED 124 kJ/L) and 10 mM H2O2/DBD for improving mineralization efficiency (by 45% for SED 310 kJ/L). Nine degradation products were identified in catalytic DBD treatments. Main degradation products were: glutaric acid, 2-nitro-4-methylsulfonylbenzaldehyde and 2-nitro-4-methylsulfonylbenzoic acid. H2O2/DBD gave significantly different degradation products than other catalytic systems. Dominant degradation products in other systems were not identified in system with hydrogen peroxide, which supported the fact that the highest mineralization efficiency was achieved with peroxide catalytic system. Global toxicity of samples after degradation in each system was determined using Artemia sauna and they could be considered as "non toxic". (c) 2014 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Sa, Lausanne
T2  - Chemical Engineering Journal
T1  - Effect of different catalysts on mesotrione degradation in water falling film DBD reactor
VL  - 248
SP  - 63
EP  - 70
DO  - 10.1016/j.cej.2014.03.031
ER  - 
@article{
author = "Jović, Milica and Dojčinović, Biljana P. and Kovačević, Vesna V. and Obradović, Bratislav M. and Kuraica, Milorad M. and Gašić, Uroš M. and Roglić, Goran",
year = "2014",
abstract = "In this study the effect of different homogenous catalysts and their dosage on mesotrione degradation in water falling film dielectric barrier discharge (DBD) reactor was investigated. Four catalytic systems Mn2+ /DBD, Co2+/DBD, Fe2+/DBD and H2O2/DBD were examined. In order to find optimal conditions various concentrations of catalysts and specific energy density (SED) values were tested in each system. Mesotrione degradation efficiency was determined by HPLC-DAD and mineralization efficiency by TOC value. Degradation products were identified by UHPLC-Orbitrap-MS and compared after finding out the optimal concentration for each catalytic system. All studied catalytic systems have proved to be successful in improving mesotrione removal, but the highest improvement in degradation efficiency was obtained with catalytic system 5 ppm Fe2+/DBD (by 50% for SED 124 kJ/L) and 10 mM H2O2/DBD for improving mineralization efficiency (by 45% for SED 310 kJ/L). Nine degradation products were identified in catalytic DBD treatments. Main degradation products were: glutaric acid, 2-nitro-4-methylsulfonylbenzaldehyde and 2-nitro-4-methylsulfonylbenzoic acid. H2O2/DBD gave significantly different degradation products than other catalytic systems. Dominant degradation products in other systems were not identified in system with hydrogen peroxide, which supported the fact that the highest mineralization efficiency was achieved with peroxide catalytic system. Global toxicity of samples after degradation in each system was determined using Artemia sauna and they could be considered as "non toxic". (c) 2014 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Chemical Engineering Journal",
title = "Effect of different catalysts on mesotrione degradation in water falling film DBD reactor",
volume = "248",
pages = "63-70",
doi = "10.1016/j.cej.2014.03.031"
}
Jović, M., Dojčinović, B. P., Kovačević, V. V., Obradović, B. M., Kuraica, M. M., Gašić, U. M.,& Roglić, G.. (2014). Effect of different catalysts on mesotrione degradation in water falling film DBD reactor. in Chemical Engineering Journal
Elsevier Science Sa, Lausanne., 248, 63-70.
https://doi.org/10.1016/j.cej.2014.03.031
Jović M, Dojčinović BP, Kovačević VV, Obradović BM, Kuraica MM, Gašić UM, Roglić G. Effect of different catalysts on mesotrione degradation in water falling film DBD reactor. in Chemical Engineering Journal. 2014;248:63-70.
doi:10.1016/j.cej.2014.03.031 .
Jović, Milica, Dojčinović, Biljana P., Kovačević, Vesna V., Obradović, Bratislav M., Kuraica, Milorad M., Gašić, Uroš M., Roglić, Goran, "Effect of different catalysts on mesotrione degradation in water falling film DBD reactor" in Chemical Engineering Journal, 248 (2014):63-70,
https://doi.org/10.1016/j.cej.2014.03.031 . .
38
30
37
35