NIH [NSF CHE0421224, CHE0840401, CHE1229234, CHE1048367, NIH S10 OD016267-01, S10 RR026962-01, P20GM104316, P30GM110758]

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NIH [NSF CHE0421224, CHE0840401, CHE1229234, CHE1048367, NIH S10 OD016267-01, S10 RR026962-01, P20GM104316, P30GM110758]

Authors

Publications

Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction

Cinderella, Andrew P.; Vulović, Bojan; Watson, Donald A.

(Amer Chemical Soc, Washington, 2017) 

TY  - JOUR
AU  - Cinderella, Andrew P.
AU  - Vulović, Bojan
AU  - Watson, Donald A.
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2475
AB  - We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles. This palladium-catalyzed process provides direct access to alkyl silanes. The delicate balance of steric and electronic parameters of the employed DrewPhos ligand is paramount to suppressing isomerization and promoting efficient and selective cross-coupling.
PB  - Amer Chemical Soc, Washington
T2  - Journal of the American Chemical Society
T1  - Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction
VL  - 139
IS  - 23
SP  - 7741
EP  - 7744
DO  - 10.1021/jacs.7b04364
ER  - 
@article{
author = "Cinderella, Andrew P. and Vulović, Bojan and Watson, Donald A.",
year = "2017",
abstract = "We report the first example of a silyl-Negishi reaction between secondary zinc organometallics and silicon electrophiles. This palladium-catalyzed process provides direct access to alkyl silanes. The delicate balance of steric and electronic parameters of the employed DrewPhos ligand is paramount to suppressing isomerization and promoting efficient and selective cross-coupling.",
publisher = "Amer Chemical Soc, Washington",
journal = "Journal of the American Chemical Society",
title = "Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction",
volume = "139",
number = "23",
pages = "7741-7744",
doi = "10.1021/jacs.7b04364"
}
Cinderella, A. P., Vulović, B.,& Watson, D. A.. (2017). Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. in Journal of the American Chemical Society
Amer Chemical Soc, Washington., 139(23), 7741-7744.
https://doi.org/10.1021/jacs.7b04364
Cinderella AP, Vulović B, Watson DA. Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction. in Journal of the American Chemical Society. 2017;139(23):7741-7744.
doi:10.1021/jacs.7b04364 .
Cinderella, Andrew P., Vulović, Bojan, Watson, Donald A., "Palladium-Catalyzed Cross-Coupling of Silyl Electrophiles with Alkylzinc Halides: A Silyl-Negishi Reaction" in Journal of the American Chemical Society, 139, no. 23 (2017):7741-7744,
https://doi.org/10.1021/jacs.7b04364 . .
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