Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade)

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Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200175 (Institute of Technical Sciences of SASA, Belgrade) (en)
Ministarstvo prosvete, nauke i tehnološkog razvoja Republike Srbije, Ugovor br. 451-03-68/2020-14/200175 (Institut tehničkih nauka SANU, Beograd) (sr_RS)
Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 451-03-68/2020-14/200175 (Институт техничких наука САНУ, Београд) (sr)
Authors

Publications

Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals

Dinić, Ivana; Vuković, Marina; Rabanal, Maria Eugenia; Milošević, Milica; Bukumira, Marta; Tomić, Nina; Tomić, Miloš; Mančić, Lidija; Ignjatović, Nenad

(MDPI, 2024)

TY  - JOUR
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Rabanal, Maria Eugenia
AU  - Milošević, Milica
AU  - Bukumira, Marta
AU  - Tomić, Nina
AU  - Tomić, Miloš
AU  - Mančić, Lidija
AU  - Ignjatović, Nenad
PY  - 2024
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6477
AB  - Y0.8−xGdxF3:Yb/Er mesocrystals with a biocompatible surface and diverse morphological characteristics were successfully synthesized using chitosan-assisted solvothermal processing. Their structural properties, studied using X-ray powder diffraction, Fourier transform infrared spectroscopy, scanning and transmission electron microscopy and energy dispersive X-ray analysis, were further correlated with the up-conversion emission (λexc = 976 nm) recorded in function of temperature. Based on the change in the visible green emissions originating from the thermally coupled 2H11/2 and 4S3/2 levels of Er3+, the corresponding LIR was acquired in the physiologically relevant range of temperatures (25–50 °C). The detected absolute sensitivity of about 0.0042 °C−1, along with the low cytotoxicity toward both normal human lung fibroblasts (MRC-5) and cancerous lung epithelial (A549) cells, indicate a potential for use in temperature sensing in biomedicine. Additionally, their enhanced internalization in cells, without suppression of cell viability, enabled in vitro labeling of cancer and healthy cells upon 976 nm laser irradiation.
PB  - MDPI
T2  - Journal of Functional Biomaterials
T1  - Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals
VL  - 15
IS  - 1
SP  - 6
DO  - 10.3390/jfb15010006
ER  - 
@article{
author = "Dinić, Ivana and Vuković, Marina and Rabanal, Maria Eugenia and Milošević, Milica and Bukumira, Marta and Tomić, Nina and Tomić, Miloš and Mančić, Lidija and Ignjatović, Nenad",
year = "2024",
abstract = "Y0.8−xGdxF3:Yb/Er mesocrystals with a biocompatible surface and diverse morphological characteristics were successfully synthesized using chitosan-assisted solvothermal processing. Their structural properties, studied using X-ray powder diffraction, Fourier transform infrared spectroscopy, scanning and transmission electron microscopy and energy dispersive X-ray analysis, were further correlated with the up-conversion emission (λexc = 976 nm) recorded in function of temperature. Based on the change in the visible green emissions originating from the thermally coupled 2H11/2 and 4S3/2 levels of Er3+, the corresponding LIR was acquired in the physiologically relevant range of temperatures (25–50 °C). The detected absolute sensitivity of about 0.0042 °C−1, along with the low cytotoxicity toward both normal human lung fibroblasts (MRC-5) and cancerous lung epithelial (A549) cells, indicate a potential for use in temperature sensing in biomedicine. Additionally, their enhanced internalization in cells, without suppression of cell viability, enabled in vitro labeling of cancer and healthy cells upon 976 nm laser irradiation.",
publisher = "MDPI",
journal = "Journal of Functional Biomaterials",
title = "Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals",
volume = "15",
number = "1",
pages = "6",
doi = "10.3390/jfb15010006"
}
Dinić, I., Vuković, M., Rabanal, M. E., Milošević, M., Bukumira, M., Tomić, N., Tomić, M., Mančić, L.,& Ignjatović, N.. (2024). Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals. in Journal of Functional Biomaterials
MDPI., 15(1), 6.
https://doi.org/10.3390/jfb15010006
Dinić I, Vuković M, Rabanal ME, Milošević M, Bukumira M, Tomić N, Tomić M, Mančić L, Ignjatović N. Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals. in Journal of Functional Biomaterials. 2024;15(1):6.
doi:10.3390/jfb15010006 .
Dinić, Ivana, Vuković, Marina, Rabanal, Maria Eugenia, Milošević, Milica, Bukumira, Marta, Tomić, Nina, Tomić, Miloš, Mančić, Lidija, Ignjatović, Nenad, "Temperature Sensing Properties of Biocompatible Yb/Er-Doped GdF3 and YF3 Mesocrystals" in Journal of Functional Biomaterials, 15, no. 1 (2024):6,
https://doi.org/10.3390/jfb15010006 . .

Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles

Stamenković, Tijana; Radmilović, Nadežda; Dinić, Ivana; Vuković, Marina; Barudžija, Tanja; Čebela, Maria; Lojpur, Vesna

(Belgrade : Institut za multidisciplinarna istraživanja, 2023)

TY  - CONF
AU  - Stamenković, Tijana
AU  - Radmilović, Nadežda
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Barudžija, Tanja
AU  - Čebela, Maria
AU  - Lojpur, Vesna
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6067
AB  - In this investigation, samples of SrGd2O4 doped with different Yb3+ (2, 4, 6 at.%) ions and constant Ho3+ (1 at.%) and Bi3+ (2 at.%) concentrations were prepared. The sol-gel method with glycine as a fuel and citric acid as a chelator was chosen for sample preparation. All samples were heated in the furnace for 1.5 h at 500 °C and then thermally treated for 2.5 h at 1000 °C. The pure orthorhombic lattice of SrGd2O4, space group Pnma, was revealed by X-ray diffraction (XRD) (JCPDS Card No.:01-072-6387). Transmission electron microscopy (TEM) discovered agglomerated clusters of spherical particles measuring around 150 nm in size. Including Bi3+ ions into the structure influenced the morphology of the sample showing fine packing of pyramidal-shaped nanoparticles. The uniform distribution of constitutive elements in the samples was confirmed by energy dispersive spectroscopy (EDS). Up-conversion emission properties were evaluated from photoluminescent emission spectra and intensity dependence on excitation power after excitation at 976 nm. Dominant green (550 nm), red (671 nm), and infrared (758 nm) 5F4, 5S2 → 5I8, 5F5 → 5I8, 5F4, 5S2 → 5I7 transition emissions, respectively, are detected in all samples. The sample co-doped with Bi3+ showed the most intense photoluminescent emission.
PB  - Belgrade : Institut za multidisciplinarna istraživanja
C3  - Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
T1  - Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles
UR  - https://hdl.handle.net/21.15107/rcub_dais_14663
ER  - 
@conference{
author = "Stamenković, Tijana and Radmilović, Nadežda and Dinić, Ivana and Vuković, Marina and Barudžija, Tanja and Čebela, Maria and Lojpur, Vesna",
year = "2023",
abstract = "In this investigation, samples of SrGd2O4 doped with different Yb3+ (2, 4, 6 at.%) ions and constant Ho3+ (1 at.%) and Bi3+ (2 at.%) concentrations were prepared. The sol-gel method with glycine as a fuel and citric acid as a chelator was chosen for sample preparation. All samples were heated in the furnace for 1.5 h at 500 °C and then thermally treated for 2.5 h at 1000 °C. The pure orthorhombic lattice of SrGd2O4, space group Pnma, was revealed by X-ray diffraction (XRD) (JCPDS Card No.:01-072-6387). Transmission electron microscopy (TEM) discovered agglomerated clusters of spherical particles measuring around 150 nm in size. Including Bi3+ ions into the structure influenced the morphology of the sample showing fine packing of pyramidal-shaped nanoparticles. The uniform distribution of constitutive elements in the samples was confirmed by energy dispersive spectroscopy (EDS). Up-conversion emission properties were evaluated from photoluminescent emission spectra and intensity dependence on excitation power after excitation at 976 nm. Dominant green (550 nm), red (671 nm), and infrared (758 nm) 5F4, 5S2 → 5I8, 5F5 → 5I8, 5F4, 5S2 → 5I7 transition emissions, respectively, are detected in all samples. The sample co-doped with Bi3+ showed the most intense photoluminescent emission.",
publisher = "Belgrade : Institut za multidisciplinarna istraživanja",
journal = "Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia",
title = "Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles",
url = "https://hdl.handle.net/21.15107/rcub_dais_14663"
}
Stamenković, T., Radmilović, N., Dinić, I., Vuković, M., Barudžija, T., Čebela, M.,& Lojpur, V.. (2023). Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
Belgrade : Institut za multidisciplinarna istraživanja..
https://hdl.handle.net/21.15107/rcub_dais_14663
Stamenković T, Radmilović N, Dinić I, Vuković M, Barudžija T, Čebela M, Lojpur V. Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia. 2023;.
https://hdl.handle.net/21.15107/rcub_dais_14663 .
Stamenković, Tijana, Radmilović, Nadežda, Dinić, Ivana, Vuković, Marina, Barudžija, Tanja, Čebela, Maria, Lojpur, Vesna, "Enhancement of up-conversion luminescent characteristics of Yb3+/Ho3+ co-doped Bi3+ based SrGd2O4 nanoparticles" in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia (2023),
https://hdl.handle.net/21.15107/rcub_dais_14663 .

Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus

Stamenković, Tijana; Ranđelović, Marjan; Čebela, Maria; Vuković, Marina; Dinić, Ivana; Mančić, Lidija; Lojpur, Vesna

(Belgrade : Institut za multidisciplinarna istraživanja, 2023)

TY  - CONF
AU  - Stamenković, Tijana
AU  - Ranđelović, Marjan
AU  - Čebela, Maria
AU  - Vuković, Marina
AU  - Dinić, Ivana
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6066
AB  - The aim of this research was to investigate for the first-time photocatalytic degradation of methylene blue over SrGd2O4 powders co-doped with constant Er3+ (0.5 at.%) and different Yb3+ (1, 2.5 and 5 at.%) concentrations. Samples were successfully prepared via sol-gel assisted combustion method. They exhibit photoluminescence properties which are manifested as red emission at 661 nm (4F9/2 → 4I15/2) and two green emissions at 551 and 523 nm (4S3/2 → 4I15/2 and 2H11/2 → 4I15/2). X-ray Powder Diffraction pattern proved that all samples crystallize as a pure orthorhombic phase. Scanning electron microscopy was used for morphology characterization and it revealed the existence of porous agglomerated round-shaped particles. Energy dispersive X-ray spectroscopy showed the presence of dopant ions and even distribution of all constituting elements. To calculate the energy band gap, UV-VIS diffuse reflectance spectroscopy was performed and a value of 4.3 eV was obtained, as well as the four additional values from the bands at lower energies. Photocatalytic degradation of methylene blue was monitored using UV-VIS absorption spectroscopy. Obtained results were promising since after 4 h of exposure to the simulating Sun irradiation, more than 50% of the starting dye concentration was mineralized.
PB  - Belgrade : Institut za multidisciplinarna istraživanja
C3  - Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
T1  - Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus
UR  - https://hdl.handle.net/21.15107/rcub_dais_14662
ER  - 
@conference{
author = "Stamenković, Tijana and Ranđelović, Marjan and Čebela, Maria and Vuković, Marina and Dinić, Ivana and Mančić, Lidija and Lojpur, Vesna",
year = "2023",
abstract = "The aim of this research was to investigate for the first-time photocatalytic degradation of methylene blue over SrGd2O4 powders co-doped with constant Er3+ (0.5 at.%) and different Yb3+ (1, 2.5 and 5 at.%) concentrations. Samples were successfully prepared via sol-gel assisted combustion method. They exhibit photoluminescence properties which are manifested as red emission at 661 nm (4F9/2 → 4I15/2) and two green emissions at 551 and 523 nm (4S3/2 → 4I15/2 and 2H11/2 → 4I15/2). X-ray Powder Diffraction pattern proved that all samples crystallize as a pure orthorhombic phase. Scanning electron microscopy was used for morphology characterization and it revealed the existence of porous agglomerated round-shaped particles. Energy dispersive X-ray spectroscopy showed the presence of dopant ions and even distribution of all constituting elements. To calculate the energy band gap, UV-VIS diffuse reflectance spectroscopy was performed and a value of 4.3 eV was obtained, as well as the four additional values from the bands at lower energies. Photocatalytic degradation of methylene blue was monitored using UV-VIS absorption spectroscopy. Obtained results were promising since after 4 h of exposure to the simulating Sun irradiation, more than 50% of the starting dye concentration was mineralized.",
publisher = "Belgrade : Institut za multidisciplinarna istraživanja",
journal = "Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia",
title = "Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus",
url = "https://hdl.handle.net/21.15107/rcub_dais_14662"
}
Stamenković, T., Ranđelović, M., Čebela, M., Vuković, M., Dinić, I., Mančić, L.,& Lojpur, V.. (2023). Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia
Belgrade : Institut za multidisciplinarna istraživanja..
https://hdl.handle.net/21.15107/rcub_dais_14662
Stamenković T, Ranđelović M, Čebela M, Vuković M, Dinić I, Mančić L, Lojpur V. Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus. in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia. 2023;.
https://hdl.handle.net/21.15107/rcub_dais_14662 .
Stamenković, Tijana, Ranđelović, Marjan, Čebela, Maria, Vuković, Marina, Dinić, Ivana, Mančić, Lidija, Lojpur, Vesna, "Characterization and photocatalytic activity of newly synthesized Er and Yb doped SrGd2O4 nanophosphorus" in Programme and the Book of Abstracts / 7th Conference of The Serbian Society for Ceramic Materials, 7CSCS-2023, June 14-16, 2023 Belgrade, Serbia (2023),
https://hdl.handle.net/21.15107/rcub_dais_14662 .

Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase

Stamenković, Tijana; Dinić, Ivana; Vuković, Marina; Radmilović, Nadežda; Barudžija, Tanja; Tomić, Miloš; Mančić, Lidija; Lojpur, Vesna

(Elsevier, 2023)

TY  - JOUR
AU  - Stamenković, Tijana
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Radmilović, Nadežda
AU  - Barudžija, Tanja
AU  - Tomić, Miloš
AU  - Mančić, Lidija
AU  - Lojpur, Vesna
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6087
AB  - In this investigation, samples of strontium-gadolinium-oxide (SrGd2O4) doped with different Yb3+ (2, 4 and 6 at%) and constant Ho3+ (1 at%) contents and co-doped with Bi3+ (2 at%) were prepared using the glycine-assisted sol–gel method. The pure orthorhombic SrGd2O4 phase, space group Pnma, was revealed using X-ray diffraction in all samples. Transmission electron microscopy discovered agglomerated clusters of spherical particles measuring approximately 150 nm in size. The inclusion of Bi3+ ions into the structure influenced the morphology since the formation of larger grains was observed, with sizes reaching up to ∼1.7 μm. The uniform distribution of all constitutive elements was confirmed by energy-dispersive X-ray spectroscopy. In all samples, up-conversion emission spectra revealed two dominant green (540 and 550 nm), red (671 nm), and infrared (758 nm) emission lines, due to the 5F4,5S2→5I8, 5F5→5I8, and 5F4,5S2 → 5I7 transitions, respectively. The sample co-doped with Bi3+ showed the most intense photoluminescent emissions, shorter luminescence decay, and the highest quantum yield. Additionally, a significant decrease in the energy band gap value was detected using diffuse reflectance spectroscopy for this sample. Methylene blue was used as a test pollutant to investigate its photocatalytic efficiency under simulated sunlight irradiation. The results show that Bi3+ co-doping deteriorates the photocatalytic efficiency of the SrGd2O4:Yb3+/Ho3+ phase by reducing hydroxyl radical formation.
PB  - Elsevier
T2  - Ceramics International
T1  - Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase
VL  - 49
IS  - 23
SP  - 37758
EP  - 37767
DO  - 10.1016/j.ceramint.2023.09.103
UR  - https://hdl.handle.net/21.15107/rcub_dais_15138
ER  - 
@article{
author = "Stamenković, Tijana and Dinić, Ivana and Vuković, Marina and Radmilović, Nadežda and Barudžija, Tanja and Tomić, Miloš and Mančić, Lidija and Lojpur, Vesna",
year = "2023",
abstract = "In this investigation, samples of strontium-gadolinium-oxide (SrGd2O4) doped with different Yb3+ (2, 4 and 6 at%) and constant Ho3+ (1 at%) contents and co-doped with Bi3+ (2 at%) were prepared using the glycine-assisted sol–gel method. The pure orthorhombic SrGd2O4 phase, space group Pnma, was revealed using X-ray diffraction in all samples. Transmission electron microscopy discovered agglomerated clusters of spherical particles measuring approximately 150 nm in size. The inclusion of Bi3+ ions into the structure influenced the morphology since the formation of larger grains was observed, with sizes reaching up to ∼1.7 μm. The uniform distribution of all constitutive elements was confirmed by energy-dispersive X-ray spectroscopy. In all samples, up-conversion emission spectra revealed two dominant green (540 and 550 nm), red (671 nm), and infrared (758 nm) emission lines, due to the 5F4,5S2→5I8, 5F5→5I8, and 5F4,5S2 → 5I7 transitions, respectively. The sample co-doped with Bi3+ showed the most intense photoluminescent emissions, shorter luminescence decay, and the highest quantum yield. Additionally, a significant decrease in the energy band gap value was detected using diffuse reflectance spectroscopy for this sample. Methylene blue was used as a test pollutant to investigate its photocatalytic efficiency under simulated sunlight irradiation. The results show that Bi3+ co-doping deteriorates the photocatalytic efficiency of the SrGd2O4:Yb3+/Ho3+ phase by reducing hydroxyl radical formation.",
publisher = "Elsevier",
journal = "Ceramics International",
title = "Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase",
volume = "49",
number = "23",
pages = "37758-37767",
doi = "10.1016/j.ceramint.2023.09.103",
url = "https://hdl.handle.net/21.15107/rcub_dais_15138"
}
Stamenković, T., Dinić, I., Vuković, M., Radmilović, N., Barudžija, T., Tomić, M., Mančić, L.,& Lojpur, V.. (2023). Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase. in Ceramics International
Elsevier., 49(23), 37758-37767.
https://doi.org/10.1016/j.ceramint.2023.09.103
https://hdl.handle.net/21.15107/rcub_dais_15138
Stamenković T, Dinić I, Vuković M, Radmilović N, Barudžija T, Tomić M, Mančić L, Lojpur V. Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase. in Ceramics International. 2023;49(23):37758-37767.
doi:10.1016/j.ceramint.2023.09.103
https://hdl.handle.net/21.15107/rcub_dais_15138 .
Stamenković, Tijana, Dinić, Ivana, Vuković, Marina, Radmilović, Nadežda, Barudžija, Tanja, Tomić, Miloš, Mančić, Lidija, Lojpur, Vesna, "Effect of Bi3+co-doping on the up-converting and photocatalytic properties of SrGd2O4:Yb3+/Ho3+ phase" in Ceramics International, 49, no. 23 (2023):37758-37767,
https://doi.org/10.1016/j.ceramint.2023.09.103 .,
https://hdl.handle.net/21.15107/rcub_dais_15138 .

Synthesis and Biological Properties of Alanine-Grafted Hydroxyapatite Nanoparticles

Dorm, Bruna Carolina; Rosas Costa Iemma, Mônica; Domingos Neto, Benedito; Lopes Francisco, Rauany Cristina; Dinić, Ivana; Ignjatović, Nenad; Marković, Smilja; Vuković, Marina; Škapin, Srečo; Trovatti, Eliane; Mančić, Lidija

(MDPI, 2023)

TY  - JOUR
AU  - Dorm, Bruna Carolina
AU  - Rosas Costa Iemma, Mônica
AU  - Domingos Neto, Benedito
AU  - Lopes Francisco, Rauany Cristina
AU  - Dinić, Ivana
AU  - Ignjatović, Nenad
AU  - Marković, Smilja
AU  - Vuković, Marina
AU  - Škapin, Srečo
AU  - Trovatti, Eliane
AU  - Mančić, Lidija
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5814
AB  - Hydroxyapatite attracts great attention as hard tissues implant material for bones and teeth. Its application in reconstructive medicine depends on its biocompatibility, which is in a function of composition and surface properties. The insertion of a protein element in the composition of implants can improve the cell adhesion and the osseointegration. Having this in mind, the proposal of this work was to develop L-alanine-grafted hydroxyapatite nanoparticles and to study their biocompatibility. Two L-alanine sources and three grafting methods were used for hydroxyapatite surface functionalization. The efficiency of grafting was determined based on X-ray powder diffraction, Fourier-transform infrared spectroscopy, thermal analyses, and field-emission scanning electron microscopy. The results indicated the formation of hydroxyapatite with 8–25 wt% of organic content, depending on the grafting method. Protein adsorption, cell adhesion, and viability studies were carried out to evaluate biological properties of grafted materials. The viability of MG-63 human osteoblastic cells following 24 h incubation with the alanine-grafted hydroxyapatite samples is well preserved, being in all cases above the viability of cells incubated with hydroxyapatite. The alanine-grafted hydroxyapatite prepared in situ and by simple mixture showed higher protein adsorption and cell adhesion, respectively, indicating their potential toward use in regenerative medicine.
PB  - MDPI
T2  - Life
T1  - Synthesis and Biological Properties of Alanine-Grafted Hydroxyapatite Nanoparticles
VL  - 13
IS  - 1
SP  - 116
DO  - 10.3390/life13010116
ER  - 
@article{
author = "Dorm, Bruna Carolina and Rosas Costa Iemma, Mônica and Domingos Neto, Benedito and Lopes Francisco, Rauany Cristina and Dinić, Ivana and Ignjatović, Nenad and Marković, Smilja and Vuković, Marina and Škapin, Srečo and Trovatti, Eliane and Mančić, Lidija",
year = "2023",
abstract = "Hydroxyapatite attracts great attention as hard tissues implant material for bones and teeth. Its application in reconstructive medicine depends on its biocompatibility, which is in a function of composition and surface properties. The insertion of a protein element in the composition of implants can improve the cell adhesion and the osseointegration. Having this in mind, the proposal of this work was to develop L-alanine-grafted hydroxyapatite nanoparticles and to study their biocompatibility. Two L-alanine sources and three grafting methods were used for hydroxyapatite surface functionalization. The efficiency of grafting was determined based on X-ray powder diffraction, Fourier-transform infrared spectroscopy, thermal analyses, and field-emission scanning electron microscopy. The results indicated the formation of hydroxyapatite with 8–25 wt% of organic content, depending on the grafting method. Protein adsorption, cell adhesion, and viability studies were carried out to evaluate biological properties of grafted materials. The viability of MG-63 human osteoblastic cells following 24 h incubation with the alanine-grafted hydroxyapatite samples is well preserved, being in all cases above the viability of cells incubated with hydroxyapatite. The alanine-grafted hydroxyapatite prepared in situ and by simple mixture showed higher protein adsorption and cell adhesion, respectively, indicating their potential toward use in regenerative medicine.",
publisher = "MDPI",
journal = "Life",
title = "Synthesis and Biological Properties of Alanine-Grafted Hydroxyapatite Nanoparticles",
volume = "13",
number = "1",
pages = "116",
doi = "10.3390/life13010116"
}
Dorm, B. C., Rosas Costa Iemma, M., Domingos Neto, B., Lopes Francisco, R. C., Dinić, I., Ignjatović, N., Marković, S., Vuković, M., Škapin, S., Trovatti, E.,& Mančić, L.. (2023). Synthesis and Biological Properties of Alanine-Grafted Hydroxyapatite Nanoparticles. in Life
MDPI., 13(1), 116.
https://doi.org/10.3390/life13010116
Dorm BC, Rosas Costa Iemma M, Domingos Neto B, Lopes Francisco RC, Dinić I, Ignjatović N, Marković S, Vuković M, Škapin S, Trovatti E, Mančić L. Synthesis and Biological Properties of Alanine-Grafted Hydroxyapatite Nanoparticles. in Life. 2023;13(1):116.
doi:10.3390/life13010116 .
Dorm, Bruna Carolina, Rosas Costa Iemma, Mônica, Domingos Neto, Benedito, Lopes Francisco, Rauany Cristina, Dinić, Ivana, Ignjatović, Nenad, Marković, Smilja, Vuković, Marina, Škapin, Srečo, Trovatti, Eliane, Mančić, Lidija, "Synthesis and Biological Properties of Alanine-Grafted Hydroxyapatite Nanoparticles" in Life, 13, no. 1 (2023):116,
https://doi.org/10.3390/life13010116 . .
3
2

One-Step Synthesis of Biocompatible NaY0.65Gd0.15F4:Yb,Er Upconverting Nanoparticles for In Vitro Cell Imaging

Tomić, Nina; Vuković, Marina; Bukumira, Marta; Rabasović, Mihailo; Mančić, Lidija

(Belgrade : Serbian Ceramic Society, 2023)

TY  - CONF
AU  - Tomić, Nina
AU  - Vuković, Marina
AU  - Bukumira, Marta
AU  - Rabasović, Mihailo
AU  - Mančić, Lidija
PY  - 2023
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/6068
AB  - There is a great technological interest in synthesis of lanthanide doped upconverting nanoparticles (UCNPs) with controlled crystal phase, morphology and intense luminescence properties suitable for biomedical use. A conventional approach for synthesis of such particles comprises decomposition of organometallic compounds in an oxygen-free environment, followed either with a ligand exchange, or biocompatible layer coating. Biocompatible NaY0.65Gd0.15F4:Yb,Er nanoparticles used in this study were synthesized through chitosan assisted one-pot hydrothermal synthesis and were characterized by X-ray powder diffraction (XRPD), Fourier-transform infrared (FTIR) spectroscopy, scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM/EDS) and photoluminescence measurement (PL). Due to the presence of the amino groups at their surface, excellent biocompatibility and notably low cytotoxicity against MRC-5 cells (line of normal human fibroblasts) and A549 cells (human lung cancer cells) were detected using MTT assay. Furthermore, upon 980 nm laser irradiation, particles were successfully used in vitro for labeling of both, MRC-5 and A549 cells.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023
T1  - One-Step Synthesis of Biocompatible NaY0.65Gd0.15F4:Yb,Er Upconverting Nanoparticles for In Vitro Cell Imaging
SP  - 70
EP  - 70
UR  - https://hdl.handle.net/21.15107/rcub_dais_15155
ER  - 
@conference{
author = "Tomić, Nina and Vuković, Marina and Bukumira, Marta and Rabasović, Mihailo and Mančić, Lidija",
year = "2023",
abstract = "There is a great technological interest in synthesis of lanthanide doped upconverting nanoparticles (UCNPs) with controlled crystal phase, morphology and intense luminescence properties suitable for biomedical use. A conventional approach for synthesis of such particles comprises decomposition of organometallic compounds in an oxygen-free environment, followed either with a ligand exchange, or biocompatible layer coating. Biocompatible NaY0.65Gd0.15F4:Yb,Er nanoparticles used in this study were synthesized through chitosan assisted one-pot hydrothermal synthesis and were characterized by X-ray powder diffraction (XRPD), Fourier-transform infrared (FTIR) spectroscopy, scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM/EDS) and photoluminescence measurement (PL). Due to the presence of the amino groups at their surface, excellent biocompatibility and notably low cytotoxicity against MRC-5 cells (line of normal human fibroblasts) and A549 cells (human lung cancer cells) were detected using MTT assay. Furthermore, upon 980 nm laser irradiation, particles were successfully used in vitro for labeling of both, MRC-5 and A549 cells.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023",
title = "One-Step Synthesis of Biocompatible NaY0.65Gd0.15F4:Yb,Er Upconverting Nanoparticles for In Vitro Cell Imaging",
pages = "70-70",
url = "https://hdl.handle.net/21.15107/rcub_dais_15155"
}
Tomić, N., Vuković, M., Bukumira, M., Rabasović, M.,& Mančić, L.. (2023). One-Step Synthesis of Biocompatible NaY0.65Gd0.15F4:Yb,Er Upconverting Nanoparticles for In Vitro Cell Imaging. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023
Belgrade : Serbian Ceramic Society., 70-70.
https://hdl.handle.net/21.15107/rcub_dais_15155
Tomić N, Vuković M, Bukumira M, Rabasović M, Mančić L. One-Step Synthesis of Biocompatible NaY0.65Gd0.15F4:Yb,Er Upconverting Nanoparticles for In Vitro Cell Imaging. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023. 2023;:70-70.
https://hdl.handle.net/21.15107/rcub_dais_15155 .
Tomić, Nina, Vuković, Marina, Bukumira, Marta, Rabasović, Mihailo, Mančić, Lidija, "One-Step Synthesis of Biocompatible NaY0.65Gd0.15F4:Yb,Er Upconverting Nanoparticles for In Vitro Cell Imaging" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application XI New Frontiers in Multifunctional Material Science and Processing, Serbian Academy of Sciences and Art Serbia, Belgrade,18-20.September 2023 (2023):70-70,
https://hdl.handle.net/21.15107/rcub_dais_15155 .

The Effects of BSA-Stabilized Selenium Nanoparticles and Sodium Selenite Supplementation on the Structure, Oxidative Stress Parameters and Selenium Redox Biology in Rat Placenta

Manojlović-Stojanoski, Milica; Borković-Mitić, Slavica; Nestorović, Nataša; Ristić, Nataša; Trifunović, Svetlana; Stevanović, Magdalena; Filipović, Nenad; Stojsavljević, Aleksandar; Pavlović, Slađan Z.

(MDPI, 2022)

TY  - JOUR
AU  - Manojlović-Stojanoski, Milica
AU  - Borković-Mitić, Slavica
AU  - Nestorović, Nataša
AU  - Ristić, Nataša
AU  - Trifunović, Svetlana
AU  - Stevanović, Magdalena
AU  - Filipović, Nenad
AU  - Stojsavljević, Aleksandar
AU  - Pavlović, Slađan Z.
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5681
AB  - The chemical element selenium (Se) is a nonmetal that is in trace amounts indispensable for normal cellular functioning. During pregnancy, a low Se status can increase the risk of oxidative stress. However, elevated concentrations of Se in the body can also cause oxidative stress. This study aimed to compare the effects of BSA-stabilized Se nanoparticles (SeNPs, Se0) (BSA-bovine serum albumin) and inorganic sodium selenite (NaSe, Se+4) supplementation on the histological structure of the placenta, oxidative stress parameters and the total placental Se concentration of Wistar rats during pregnancy. Pregnant females were randomized into four groups: (i) intact controls; (ii) controls that were dosed by daily oral gavage with 8.6% bovine serum albumin (BSA) and 0.125 M vit C; (iii) the SeNP group that was administered 0.5 mg of SeNPs stabilized with 8.6% BSA and 0.125 M vit C/kg bw/day by oral gavage dosing; (iv) the NaSe group, gavage dosed with 0.5 mg Na2SeO3/kg bw/day. The treatment of pregnant females started on gestational day one, lasted until day 20, and on day 21 of gestation, the fetuses with the placenta were removed from the uterus. Our findings show that the mode of action of equivalent concentrations of Se in SeNPs and NaSe depended on its redox state and chemical structure. Administration of SeNPs (Se0) increased fetal lethality and induced changes in the antioxidative defense parameters in the placenta. The accumulation of Se in the placenta was highest in SeNP-treated animals. All obtained data indicate an increased bioavailability of Se in its organic nano form and Se0 redox state in comparison to its inorganic sodium selenite form and Se+4 redox state.
PB  - MDPI
T2  - International Journal of Molecular Sciences
T1  - The Effects of BSA-Stabilized Selenium Nanoparticles and Sodium Selenite Supplementation on the Structure, Oxidative Stress Parameters and Selenium Redox Biology in Rat Placenta
VL  - 23
IS  - 21
SP  - 13068
DO  - 10.3390/ijms232113068
ER  - 
@article{
author = "Manojlović-Stojanoski, Milica and Borković-Mitić, Slavica and Nestorović, Nataša and Ristić, Nataša and Trifunović, Svetlana and Stevanović, Magdalena and Filipović, Nenad and Stojsavljević, Aleksandar and Pavlović, Slađan Z.",
year = "2022",
abstract = "The chemical element selenium (Se) is a nonmetal that is in trace amounts indispensable for normal cellular functioning. During pregnancy, a low Se status can increase the risk of oxidative stress. However, elevated concentrations of Se in the body can also cause oxidative stress. This study aimed to compare the effects of BSA-stabilized Se nanoparticles (SeNPs, Se0) (BSA-bovine serum albumin) and inorganic sodium selenite (NaSe, Se+4) supplementation on the histological structure of the placenta, oxidative stress parameters and the total placental Se concentration of Wistar rats during pregnancy. Pregnant females were randomized into four groups: (i) intact controls; (ii) controls that were dosed by daily oral gavage with 8.6% bovine serum albumin (BSA) and 0.125 M vit C; (iii) the SeNP group that was administered 0.5 mg of SeNPs stabilized with 8.6% BSA and 0.125 M vit C/kg bw/day by oral gavage dosing; (iv) the NaSe group, gavage dosed with 0.5 mg Na2SeO3/kg bw/day. The treatment of pregnant females started on gestational day one, lasted until day 20, and on day 21 of gestation, the fetuses with the placenta were removed from the uterus. Our findings show that the mode of action of equivalent concentrations of Se in SeNPs and NaSe depended on its redox state and chemical structure. Administration of SeNPs (Se0) increased fetal lethality and induced changes in the antioxidative defense parameters in the placenta. The accumulation of Se in the placenta was highest in SeNP-treated animals. All obtained data indicate an increased bioavailability of Se in its organic nano form and Se0 redox state in comparison to its inorganic sodium selenite form and Se+4 redox state.",
publisher = "MDPI",
journal = "International Journal of Molecular Sciences",
title = "The Effects of BSA-Stabilized Selenium Nanoparticles and Sodium Selenite Supplementation on the Structure, Oxidative Stress Parameters and Selenium Redox Biology in Rat Placenta",
volume = "23",
number = "21",
pages = "13068",
doi = "10.3390/ijms232113068"
}
Manojlović-Stojanoski, M., Borković-Mitić, S., Nestorović, N., Ristić, N., Trifunović, S., Stevanović, M., Filipović, N., Stojsavljević, A.,& Pavlović, S. Z.. (2022). The Effects of BSA-Stabilized Selenium Nanoparticles and Sodium Selenite Supplementation on the Structure, Oxidative Stress Parameters and Selenium Redox Biology in Rat Placenta. in International Journal of Molecular Sciences
MDPI., 23(21), 13068.
https://doi.org/10.3390/ijms232113068
Manojlović-Stojanoski M, Borković-Mitić S, Nestorović N, Ristić N, Trifunović S, Stevanović M, Filipović N, Stojsavljević A, Pavlović SZ. The Effects of BSA-Stabilized Selenium Nanoparticles and Sodium Selenite Supplementation on the Structure, Oxidative Stress Parameters and Selenium Redox Biology in Rat Placenta. in International Journal of Molecular Sciences. 2022;23(21):13068.
doi:10.3390/ijms232113068 .
Manojlović-Stojanoski, Milica, Borković-Mitić, Slavica, Nestorović, Nataša, Ristić, Nataša, Trifunović, Svetlana, Stevanović, Magdalena, Filipović, Nenad, Stojsavljević, Aleksandar, Pavlović, Slađan Z., "The Effects of BSA-Stabilized Selenium Nanoparticles and Sodium Selenite Supplementation on the Structure, Oxidative Stress Parameters and Selenium Redox Biology in Rat Placenta" in International Journal of Molecular Sciences, 23, no. 21 (2022):13068,
https://doi.org/10.3390/ijms232113068 . .
3
3
2

Supplementary material for: Manojlović-Stojanoski, M., Borković-Mitić, S., Nestorović, N., Ristić, N., Trifunović, S., Stevanović, M., Filipović, N., Stojsavljević, A., & Pavlović, S. (2022). The Effects of BSA-Stabilized Selenium Nanoparticles and Sodium Selenite Supplementation on the Structure, Oxidative Stress Parameters and Selenium Redox Biology in Rat Placenta. International Journal of Molecular Sciences, 23(21), 13068. https://doi.org/10.3390/ijms232113068

Manojlović-Stojanoski, Milica; Borković-Mitić, Slavica; Nestorović, Nataša; Ristić, Nataša; Trifunović, Svetlana; Stevanović, Magdalena; Filipović, Nenad; Stojsavljević, Aleksandar; Pavlović, Slađan Z.

(MDPI, 2022)

TY  - DATA
AU  - Manojlović-Stojanoski, Milica
AU  - Borković-Mitić, Slavica
AU  - Nestorović, Nataša
AU  - Ristić, Nataša
AU  - Trifunović, Svetlana
AU  - Stevanović, Magdalena
AU  - Filipović, Nenad
AU  - Stojsavljević, Aleksandar
AU  - Pavlović, Slađan Z.
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5705
AB  - The chemical element selenium (Se) is a nonmetal that is in trace amounts indispensable for normal cellular functioning. During pregnancy, a low Se status can increase the risk of oxidative stress. However, elevated concentrations of Se in the body can also cause oxidative stress. This study aimed to compare the effects of BSA-stabilized Se nanoparticles (SeNPs, Se0) (BSA-bovine serum albumin) and inorganic sodium selenite (NaSe, Se+4) supplementation on the histological structure of the placenta, oxidative stress parameters and the total placental Se concentration of Wistar rats during pregnancy. Pregnant females were randomized into four groups: (i) intact controls; (ii) controls that were dosed by daily oral gavage with 8.6% bovine serum albumin (BSA) and 0.125 M vit C; (iii) the SeNP group that was administered 0.5 mg of SeNPs stabilized with 8.6% BSA and 0.125 M vit C/kg bw/day by oral gavage dosing; (iv) the NaSe group, gavage dosed with 0.5 mg Na2SeO3/kg bw/day. The treatment of pregnant females started on gestational day one, lasted until day 20, and on day 21 of gestation, the fetuses with the placenta were removed from the uterus. Our findings show that the mode of action of equivalent concentrations of Se in SeNPs and NaSe depended on its redox state and chemical structure. Administration of SeNPs (Se0) increased fetal lethality and induced changes in the antioxidative defense parameters in the placenta. The accumulation of Se in the placenta was highest in SeNP-treated animals. All obtained data indicate an increased bioavailability of Se in its organic nano form and Se0 redox state in comparison to its inorganic sodium selenite form and Se+4 redox state.
PB  - MDPI
T2  - International Journal of Molecular Sciences
T1  - Supplementary material for: Manojlović-Stojanoski, M., Borković-Mitić, S., Nestorović, N., Ristić, N., Trifunović, S., Stevanović, M., Filipović, N., Stojsavljević, A., & Pavlović, S. (2022). The Effects of BSA-Stabilized Selenium Nanoparticles and Sodium Selenite Supplementation on the Structure, Oxidative Stress Parameters and Selenium Redox Biology in Rat Placenta. International Journal of Molecular Sciences, 23(21), 13068. https://doi.org/10.3390/ijms232113068
VL  - 23
IS  - 21
SP  - 13068
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5705
ER  - 
@misc{
author = "Manojlović-Stojanoski, Milica and Borković-Mitić, Slavica and Nestorović, Nataša and Ristić, Nataša and Trifunović, Svetlana and Stevanović, Magdalena and Filipović, Nenad and Stojsavljević, Aleksandar and Pavlović, Slađan Z.",
year = "2022",
abstract = "The chemical element selenium (Se) is a nonmetal that is in trace amounts indispensable for normal cellular functioning. During pregnancy, a low Se status can increase the risk of oxidative stress. However, elevated concentrations of Se in the body can also cause oxidative stress. This study aimed to compare the effects of BSA-stabilized Se nanoparticles (SeNPs, Se0) (BSA-bovine serum albumin) and inorganic sodium selenite (NaSe, Se+4) supplementation on the histological structure of the placenta, oxidative stress parameters and the total placental Se concentration of Wistar rats during pregnancy. Pregnant females were randomized into four groups: (i) intact controls; (ii) controls that were dosed by daily oral gavage with 8.6% bovine serum albumin (BSA) and 0.125 M vit C; (iii) the SeNP group that was administered 0.5 mg of SeNPs stabilized with 8.6% BSA and 0.125 M vit C/kg bw/day by oral gavage dosing; (iv) the NaSe group, gavage dosed with 0.5 mg Na2SeO3/kg bw/day. The treatment of pregnant females started on gestational day one, lasted until day 20, and on day 21 of gestation, the fetuses with the placenta were removed from the uterus. Our findings show that the mode of action of equivalent concentrations of Se in SeNPs and NaSe depended on its redox state and chemical structure. Administration of SeNPs (Se0) increased fetal lethality and induced changes in the antioxidative defense parameters in the placenta. The accumulation of Se in the placenta was highest in SeNP-treated animals. All obtained data indicate an increased bioavailability of Se in its organic nano form and Se0 redox state in comparison to its inorganic sodium selenite form and Se+4 redox state.",
publisher = "MDPI",
journal = "International Journal of Molecular Sciences",
title = "Supplementary material for: Manojlović-Stojanoski, M., Borković-Mitić, S., Nestorović, N., Ristić, N., Trifunović, S., Stevanović, M., Filipović, N., Stojsavljević, A., & Pavlović, S. (2022). The Effects of BSA-Stabilized Selenium Nanoparticles and Sodium Selenite Supplementation on the Structure, Oxidative Stress Parameters and Selenium Redox Biology in Rat Placenta. International Journal of Molecular Sciences, 23(21), 13068. https://doi.org/10.3390/ijms232113068",
volume = "23",
number = "21",
pages = "13068",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5705"
}
Manojlović-Stojanoski, M., Borković-Mitić, S., Nestorović, N., Ristić, N., Trifunović, S., Stevanović, M., Filipović, N., Stojsavljević, A.,& Pavlović, S. Z.. (2022). Supplementary material for: Manojlović-Stojanoski, M., Borković-Mitić, S., Nestorović, N., Ristić, N., Trifunović, S., Stevanović, M., Filipović, N., Stojsavljević, A., & Pavlović, S. (2022). The Effects of BSA-Stabilized Selenium Nanoparticles and Sodium Selenite Supplementation on the Structure, Oxidative Stress Parameters and Selenium Redox Biology in Rat Placenta. International Journal of Molecular Sciences, 23(21), 13068. https://doi.org/10.3390/ijms232113068. in International Journal of Molecular Sciences
MDPI., 23(21), 13068.
https://hdl.handle.net/21.15107/rcub_cherry_5705
Manojlović-Stojanoski M, Borković-Mitić S, Nestorović N, Ristić N, Trifunović S, Stevanović M, Filipović N, Stojsavljević A, Pavlović SZ. Supplementary material for: Manojlović-Stojanoski, M., Borković-Mitić, S., Nestorović, N., Ristić, N., Trifunović, S., Stevanović, M., Filipović, N., Stojsavljević, A., & Pavlović, S. (2022). The Effects of BSA-Stabilized Selenium Nanoparticles and Sodium Selenite Supplementation on the Structure, Oxidative Stress Parameters and Selenium Redox Biology in Rat Placenta. International Journal of Molecular Sciences, 23(21), 13068. https://doi.org/10.3390/ijms232113068. in International Journal of Molecular Sciences. 2022;23(21):13068.
https://hdl.handle.net/21.15107/rcub_cherry_5705 .
Manojlović-Stojanoski, Milica, Borković-Mitić, Slavica, Nestorović, Nataša, Ristić, Nataša, Trifunović, Svetlana, Stevanović, Magdalena, Filipović, Nenad, Stojsavljević, Aleksandar, Pavlović, Slađan Z., "Supplementary material for: Manojlović-Stojanoski, M., Borković-Mitić, S., Nestorović, N., Ristić, N., Trifunović, S., Stevanović, M., Filipović, N., Stojsavljević, A., & Pavlović, S. (2022). The Effects of BSA-Stabilized Selenium Nanoparticles and Sodium Selenite Supplementation on the Structure, Oxidative Stress Parameters and Selenium Redox Biology in Rat Placenta. International Journal of Molecular Sciences, 23(21), 13068. https://doi.org/10.3390/ijms232113068" in International Journal of Molecular Sciences, 23, no. 21 (2022):13068,
https://hdl.handle.net/21.15107/rcub_cherry_5705 .
3

Optically active SrGd2O4 phase: Yb3+/Ho3+ and Yb3+/Tm3+ co-doping

Stamenković, Tijana; Lojpur, Vesna; Radmilović, Nadežda; Vuković, Marina; Dinić, Ivana; Mančić, Lidija

(Belgrade : Serbian Ceramic Society, 2022)

TY  - CONF
AU  - Stamenković, Tijana
AU  - Lojpur, Vesna
AU  - Radmilović, Nadežda
AU  - Vuković, Marina
AU  - Dinić, Ivana
AU  - Mančić, Lidija
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5745
AB  - Optically active materials have a wide range of applications. The phenomenon of light conversion includes two main types: up-conversion, which is the ability of convertion lower energy photons into the ones with the higher energy, and down-conversion, which is vice versa. Orthorhorhombic SrGd2O4 doped with rare earth elements is established to have promising optical characteristics, but rarely explored until nowadays as up-converting material. Due to the phonon energy of around 475 cm-1, which is lower than in many other compounds commonly used hosts, this one has a great perspective as an optically active material. Here, for the first time two combinations of rare earth dopant ions, Yb3+/Ho3+ and Yb3+/Tm3+, with different mutual ratios were chosen as pairs for inducing up-conversion. Sol-gel assisted combustion synthesis, which comprises citric acid as chelator and glycine as fuel, was used to obtain powdered samples that are subsequently thermally treated for 3.5 h at 1100°C. X-ray powder diffraction analysis (XRPD) was performed to determine crystal structure. Morphology characteristics were observed by scanning and transmission electron microscopy (SEM/TEM). Photoluminescent up-converting properties were measured in function of laser power (976 nm) in order to define optimal doping concentration and upconversion mechanism.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.
T1  - Optically active SrGd2O4 phase: Yb3+/Ho3+ and Yb3+/Tm3+ co-doping
SP  - 76
EP  - 77
UR  - https://hdl.handle.net/21.15107/rcub_dais_13629
ER  - 
@conference{
author = "Stamenković, Tijana and Lojpur, Vesna and Radmilović, Nadežda and Vuković, Marina and Dinić, Ivana and Mančić, Lidija",
year = "2022",
abstract = "Optically active materials have a wide range of applications. The phenomenon of light conversion includes two main types: up-conversion, which is the ability of convertion lower energy photons into the ones with the higher energy, and down-conversion, which is vice versa. Orthorhorhombic SrGd2O4 doped with rare earth elements is established to have promising optical characteristics, but rarely explored until nowadays as up-converting material. Due to the phonon energy of around 475 cm-1, which is lower than in many other compounds commonly used hosts, this one has a great perspective as an optically active material. Here, for the first time two combinations of rare earth dopant ions, Yb3+/Ho3+ and Yb3+/Tm3+, with different mutual ratios were chosen as pairs for inducing up-conversion. Sol-gel assisted combustion synthesis, which comprises citric acid as chelator and glycine as fuel, was used to obtain powdered samples that are subsequently thermally treated for 3.5 h at 1100°C. X-ray powder diffraction analysis (XRPD) was performed to determine crystal structure. Morphology characteristics were observed by scanning and transmission electron microscopy (SEM/TEM). Photoluminescent up-converting properties were measured in function of laser power (976 nm) in order to define optimal doping concentration and upconversion mechanism.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.",
title = "Optically active SrGd2O4 phase: Yb3+/Ho3+ and Yb3+/Tm3+ co-doping",
pages = "76-77",
url = "https://hdl.handle.net/21.15107/rcub_dais_13629"
}
Stamenković, T., Lojpur, V., Radmilović, N., Vuković, M., Dinić, I.,& Mančić, L.. (2022). Optically active SrGd2O4 phase: Yb3+/Ho3+ and Yb3+/Tm3+ co-doping. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.
Belgrade : Serbian Ceramic Society., 76-77.
https://hdl.handle.net/21.15107/rcub_dais_13629
Stamenković T, Lojpur V, Radmilović N, Vuković M, Dinić I, Mančić L. Optically active SrGd2O4 phase: Yb3+/Ho3+ and Yb3+/Tm3+ co-doping. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.. 2022;:76-77.
https://hdl.handle.net/21.15107/rcub_dais_13629 .
Stamenković, Tijana, Lojpur, Vesna, Radmilović, Nadežda, Vuković, Marina, Dinić, Ivana, Mančić, Lidija, "Optically active SrGd2O4 phase: Yb3+/Ho3+ and Yb3+/Tm3+ co-doping" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022. (2022):76-77,
https://hdl.handle.net/21.15107/rcub_dais_13629 .

Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles

Dinić, Ivana; Stamenković, Tijana; Radmilović, Nadežda; Vuković, Marina; Rabasović, Mihailo; Lojpur, Vesna; Mančić, Lidija

(Belgrade : Serbian Ceramic Society, 2022)

TY  - CONF
AU  - Dinić, Ivana
AU  - Stamenković, Tijana
AU  - Radmilović, Nadežda
AU  - Vuković, Marina
AU  - Rabasović, Mihailo
AU  - Lojpur, Vesna
AU  - Mančić, Lidija
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5837
AB  - Up-conversion properties of SrGd2O4 nanoparticles co-doped with different Yb3+ and constant Er3+ ions were successfully prepared via sol- gel assisted combustion. Rietveld refinement and scanning/transmission electron microscopy with corresponding energydispersive X-ray spectroscopy revealed that obtained powders are composed of agglomerated nanoparticles with orthorhombic (Pnma) structure that have a uniform distribution of all constituting elements. Photoluminescence measurements implied intensification of the upconversion (UC) emission in the visible part of spectrum with the increase of Yb3+ content, which is followed by a significant change in the green to red ratio. Two-photon UC processes are established as a result of Er3+ f-f electronic transitions: green emission at 523 and 551 nm (2H11/2, 4S3/2 → 4I15/2) as well as a red emission at 661 nm (4F9/2 → 4I15/2). The highest value of absolute quantum efficiency (0.055%) is determined for SrGd2O4 nanoparticles doped with 0.5 at% of Er3+ and co-doped with 5 at% of Yb3+ (λexc=976 nm, power density 200W/cm2).
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.
T1  - Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles
SP  - 59
EP  - 59
UR  - https://hdl.handle.net/21.15107/rcub_dais_13621
ER  - 
@conference{
author = "Dinić, Ivana and Stamenković, Tijana and Radmilović, Nadežda and Vuković, Marina and Rabasović, Mihailo and Lojpur, Vesna and Mančić, Lidija",
year = "2022",
abstract = "Up-conversion properties of SrGd2O4 nanoparticles co-doped with different Yb3+ and constant Er3+ ions were successfully prepared via sol- gel assisted combustion. Rietveld refinement and scanning/transmission electron microscopy with corresponding energydispersive X-ray spectroscopy revealed that obtained powders are composed of agglomerated nanoparticles with orthorhombic (Pnma) structure that have a uniform distribution of all constituting elements. Photoluminescence measurements implied intensification of the upconversion (UC) emission in the visible part of spectrum with the increase of Yb3+ content, which is followed by a significant change in the green to red ratio. Two-photon UC processes are established as a result of Er3+ f-f electronic transitions: green emission at 523 and 551 nm (2H11/2, 4S3/2 → 4I15/2) as well as a red emission at 661 nm (4F9/2 → 4I15/2). The highest value of absolute quantum efficiency (0.055%) is determined for SrGd2O4 nanoparticles doped with 0.5 at% of Er3+ and co-doped with 5 at% of Yb3+ (λexc=976 nm, power density 200W/cm2).",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.",
title = "Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles",
pages = "59-59",
url = "https://hdl.handle.net/21.15107/rcub_dais_13621"
}
Dinić, I., Stamenković, T., Radmilović, N., Vuković, M., Rabasović, M., Lojpur, V.,& Mančić, L.. (2022). Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.
Belgrade : Serbian Ceramic Society., 59-59.
https://hdl.handle.net/21.15107/rcub_dais_13621
Dinić I, Stamenković T, Radmilović N, Vuković M, Rabasović M, Lojpur V, Mančić L. Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.. 2022;:59-59.
https://hdl.handle.net/21.15107/rcub_dais_13621 .
Dinić, Ivana, Stamenković, Tijana, Radmilović, Nadežda, Vuković, Marina, Rabasović, Mihailo, Lojpur, Vesna, Mančić, Lidija, "Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022. (2022):59-59,
https://hdl.handle.net/21.15107/rcub_dais_13621 .

The low-temperature sonochemical synthesis of up-converting β NaYF4: Yb,Er mesocrystals

Vuković, Marina; Dinić, Ivana; Jardim, Paola; Marković, Smilja; Veselinović, Ljiljana M.; Nikolić, Marko G.; Mančić, Lidija

(Elsevier, 2022)

TY  - JOUR
AU  - Vuković, Marina
AU  - Dinić, Ivana
AU  - Jardim, Paola
AU  - Marković, Smilja
AU  - Veselinović, Ljiljana M.
AU  - Nikolić, Marko G.
AU  - Mančić, Lidija
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4894
AB  - In this paper, we report the mild sonochemical synthesis of hexagonal (β) NaYF4:Yb,Er mesocrystals at
low temperature of 40 °C. The nucleation and transformation of crystal structures is investigated in
the course of time, and it is shown that the pure β phase is obtained after 2 h of pulsed sonication.
The crystallization of orthorhombic YF3:Yb,Er and cubic (α) NaYF4:Yb,Er precedes the appearance of a
thermodynamically stable β NaYF4:Yb,Er phase. Based on the evolution of the nanoparticle morphology,
it is concluded that the transition from a to β phase is consistent with the dissolution-recrystallization
process, while the final shape of mesocrystals is a consequence of the oriented attachment growth in
the newly formed b phase nanocrystallites along two planes. The structural properties of all compounds
are analyzed and correlated with their thermal and optical characteristics. The pump power dependence
of green and red emissions confirms that only two-photon process is involved in up-conversion, which is
superior in β phase mesocrystals.
PB  - Elsevier
T2  - Advanced Powder Technology
T1  - The low-temperature sonochemical synthesis of up-converting β NaYF4: Yb,Er mesocrystals
VL  - 33
IS  - 2
SP  - 103403
DO  - 10.1016/j.apt.2021.103403
ER  - 
@article{
author = "Vuković, Marina and Dinić, Ivana and Jardim, Paola and Marković, Smilja and Veselinović, Ljiljana M. and Nikolić, Marko G. and Mančić, Lidija",
year = "2022",
abstract = "In this paper, we report the mild sonochemical synthesis of hexagonal (β) NaYF4:Yb,Er mesocrystals at
low temperature of 40 °C. The nucleation and transformation of crystal structures is investigated in
the course of time, and it is shown that the pure β phase is obtained after 2 h of pulsed sonication.
The crystallization of orthorhombic YF3:Yb,Er and cubic (α) NaYF4:Yb,Er precedes the appearance of a
thermodynamically stable β NaYF4:Yb,Er phase. Based on the evolution of the nanoparticle morphology,
it is concluded that the transition from a to β phase is consistent with the dissolution-recrystallization
process, while the final shape of mesocrystals is a consequence of the oriented attachment growth in
the newly formed b phase nanocrystallites along two planes. The structural properties of all compounds
are analyzed and correlated with their thermal and optical characteristics. The pump power dependence
of green and red emissions confirms that only two-photon process is involved in up-conversion, which is
superior in β phase mesocrystals.",
publisher = "Elsevier",
journal = "Advanced Powder Technology",
title = "The low-temperature sonochemical synthesis of up-converting β NaYF4: Yb,Er mesocrystals",
volume = "33",
number = "2",
pages = "103403",
doi = "10.1016/j.apt.2021.103403"
}
Vuković, M., Dinić, I., Jardim, P., Marković, S., Veselinović, L. M., Nikolić, M. G.,& Mančić, L.. (2022). The low-temperature sonochemical synthesis of up-converting β NaYF4: Yb,Er mesocrystals. in Advanced Powder Technology
Elsevier., 33(2), 103403.
https://doi.org/10.1016/j.apt.2021.103403
Vuković M, Dinić I, Jardim P, Marković S, Veselinović LM, Nikolić MG, Mančić L. The low-temperature sonochemical synthesis of up-converting β NaYF4: Yb,Er mesocrystals. in Advanced Powder Technology. 2022;33(2):103403.
doi:10.1016/j.apt.2021.103403 .
Vuković, Marina, Dinić, Ivana, Jardim, Paola, Marković, Smilja, Veselinović, Ljiljana M., Nikolić, Marko G., Mančić, Lidija, "The low-temperature sonochemical synthesis of up-converting β NaYF4: Yb,Er mesocrystals" in Advanced Powder Technology, 33, no. 2 (2022):103403,
https://doi.org/10.1016/j.apt.2021.103403 . .
6
7
2

The low-temperature sonochemical synthesis of up-converting β NaYF4:Yb,Er mesocrystals

Vuković, Marina; Dinić, Ivana; Jardim, Paula; Marković, Smilja; Veselinović, Ljiljana M.; Nikolić, Marko G.; Mančić, Lidija

(Elsevier BV, 2022)

TY  - JOUR
AU  - Vuković, Marina
AU  - Dinić, Ivana
AU  - Jardim, Paula
AU  - Marković, Smilja
AU  - Veselinović, Ljiljana M.
AU  - Nikolić, Marko G.
AU  - Mančić, Lidija
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5119
AB  - In this paper, we report the mild sonochemical synthesis of hexagonal (β) NaYF4:Yb,Er mesocrystals at low temperature of 40 °C. The nucleation and transformation of crystal structures is investigated in the course of time, and it is shown that the pure β phase is obtained after 2 h of pulsed sonication. The crystallization of orthorhombic YF3:Yb,Er and cubic (α) NaYF4:Yb,Er precedes the appearance of a thermodynamically stable β NaYF4:Yb,Er phase. Based on the evolution of the nanoparticle morphology, it is concluded that the transition from α to β phase is consistent with the dissolution-recrystallization process, while the final shape of mesocrystals is a consequence of the oriented attachment growth in the newly formed β phase nanocrystallites along two planes. The structural properties of all compounds are analyzed and correlated with their thermal and optical characteristics. The pump power dependence of green and red emissions confirms that only two-photon process is involved in up-conversion, which is superior in β phase mesocrystals.
PB  - Elsevier BV
T2  - Advanced Powder Technology
T1  - The low-temperature sonochemical synthesis of up-converting β NaYF4:Yb,Er mesocrystals
VL  - 33
IS  - 2
SP  - 103403
DO  - 10.1016/j.apt.2021.103403
ER  - 
@article{
author = "Vuković, Marina and Dinić, Ivana and Jardim, Paula and Marković, Smilja and Veselinović, Ljiljana M. and Nikolić, Marko G. and Mančić, Lidija",
year = "2022",
abstract = "In this paper, we report the mild sonochemical synthesis of hexagonal (β) NaYF4:Yb,Er mesocrystals at low temperature of 40 °C. The nucleation and transformation of crystal structures is investigated in the course of time, and it is shown that the pure β phase is obtained after 2 h of pulsed sonication. The crystallization of orthorhombic YF3:Yb,Er and cubic (α) NaYF4:Yb,Er precedes the appearance of a thermodynamically stable β NaYF4:Yb,Er phase. Based on the evolution of the nanoparticle morphology, it is concluded that the transition from α to β phase is consistent with the dissolution-recrystallization process, while the final shape of mesocrystals is a consequence of the oriented attachment growth in the newly formed β phase nanocrystallites along two planes. The structural properties of all compounds are analyzed and correlated with their thermal and optical characteristics. The pump power dependence of green and red emissions confirms that only two-photon process is involved in up-conversion, which is superior in β phase mesocrystals.",
publisher = "Elsevier BV",
journal = "Advanced Powder Technology",
title = "The low-temperature sonochemical synthesis of up-converting β NaYF4:Yb,Er mesocrystals",
volume = "33",
number = "2",
pages = "103403",
doi = "10.1016/j.apt.2021.103403"
}
Vuković, M., Dinić, I., Jardim, P., Marković, S., Veselinović, L. M., Nikolić, M. G.,& Mančić, L.. (2022). The low-temperature sonochemical synthesis of up-converting β NaYF4:Yb,Er mesocrystals. in Advanced Powder Technology
Elsevier BV., 33(2), 103403.
https://doi.org/10.1016/j.apt.2021.103403
Vuković M, Dinić I, Jardim P, Marković S, Veselinović LM, Nikolić MG, Mančić L. The low-temperature sonochemical synthesis of up-converting β NaYF4:Yb,Er mesocrystals. in Advanced Powder Technology. 2022;33(2):103403.
doi:10.1016/j.apt.2021.103403 .
Vuković, Marina, Dinić, Ivana, Jardim, Paula, Marković, Smilja, Veselinović, Ljiljana M., Nikolić, Marko G., Mančić, Lidija, "The low-temperature sonochemical synthesis of up-converting β NaYF4:Yb,Er mesocrystals" in Advanced Powder Technology, 33, no. 2 (2022):103403,
https://doi.org/10.1016/j.apt.2021.103403 . .
6
6
2

Supplementary information for the article: Vuković, Marina, Dinić, Ivana, Jardim, Paula, Marković, Smilja, Veselinović, Ljiljana, Nikolić, Marko, Mančić, Lidija, "The low-temperature sonochemical synthesis of up-converting β NaYF4:Yb,Er mesocrystals" in Advanced Powder Technology, 33, no. 2 (2022):103403, https://doi.org/10.1016/j.apt.2021.103403

Vuković, Marina; Dinić, Ivana; Jardim, Paula; Marković, Smilja; Veselinović, Ljiljana M.; Nikolić, Marko G.; Mančić, Lidija

(Elsevier BV, 2022)

TY  - DATA
AU  - Vuković, Marina
AU  - Dinić, Ivana
AU  - Jardim, Paula
AU  - Marković, Smilja
AU  - Veselinović, Ljiljana M.
AU  - Nikolić, Marko G.
AU  - Mančić, Lidija
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5120
AB  - Figure S1. XRPD data and refined patterns of the obtained samples; Figure S2. Typical spectrum of FT-IR analysis; Figure S3. XRPD of samples obtained through sonochemical synthesis after DSC analysis; Figure S4: Simulated electron diffraction pattern of β NaYF4:Yb,Er hexagonal [-111] zone axis  compared with experimental SAED; Figure S5: Simulated electron diffraction pattern of β NaYF4:Yb,Er hexagonal [2-10] zone axis  compared with experimental SAED
PB  - Elsevier BV
T2  - Advanced Powder Technology
T1  - Supplementary information for the article: Vuković, Marina, Dinić, Ivana, Jardim, Paula, Marković, Smilja, Veselinović, Ljiljana, Nikolić, Marko, Mančić, Lidija, "The low-temperature sonochemical synthesis of up-converting β NaYF4:Yb,Er mesocrystals" in Advanced Powder Technology, 33, no. 2 (2022):103403, https://doi.org/10.1016/j.apt.2021.103403
VL  - 33
IS  - 2
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5120
ER  - 
@misc{
author = "Vuković, Marina and Dinić, Ivana and Jardim, Paula and Marković, Smilja and Veselinović, Ljiljana M. and Nikolić, Marko G. and Mančić, Lidija",
year = "2022",
abstract = "Figure S1. XRPD data and refined patterns of the obtained samples; Figure S2. Typical spectrum of FT-IR analysis; Figure S3. XRPD of samples obtained through sonochemical synthesis after DSC analysis; Figure S4: Simulated electron diffraction pattern of β NaYF4:Yb,Er hexagonal [-111] zone axis  compared with experimental SAED; Figure S5: Simulated electron diffraction pattern of β NaYF4:Yb,Er hexagonal [2-10] zone axis  compared with experimental SAED",
publisher = "Elsevier BV",
journal = "Advanced Powder Technology",
title = "Supplementary information for the article: Vuković, Marina, Dinić, Ivana, Jardim, Paula, Marković, Smilja, Veselinović, Ljiljana, Nikolić, Marko, Mančić, Lidija, "The low-temperature sonochemical synthesis of up-converting β NaYF4:Yb,Er mesocrystals" in Advanced Powder Technology, 33, no. 2 (2022):103403, https://doi.org/10.1016/j.apt.2021.103403",
volume = "33",
number = "2",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5120"
}
Vuković, M., Dinić, I., Jardim, P., Marković, S., Veselinović, L. M., Nikolić, M. G.,& Mančić, L.. (2022). Supplementary information for the article: Vuković, Marina, Dinić, Ivana, Jardim, Paula, Marković, Smilja, Veselinović, Ljiljana, Nikolić, Marko, Mančić, Lidija, "The low-temperature sonochemical synthesis of up-converting β NaYF4:Yb,Er mesocrystals" in Advanced Powder Technology, 33, no. 2 (2022):103403, https://doi.org/10.1016/j.apt.2021.103403. in Advanced Powder Technology
Elsevier BV., 33(2).
https://hdl.handle.net/21.15107/rcub_cherry_5120
Vuković M, Dinić I, Jardim P, Marković S, Veselinović LM, Nikolić MG, Mančić L. Supplementary information for the article: Vuković, Marina, Dinić, Ivana, Jardim, Paula, Marković, Smilja, Veselinović, Ljiljana, Nikolić, Marko, Mančić, Lidija, "The low-temperature sonochemical synthesis of up-converting β NaYF4:Yb,Er mesocrystals" in Advanced Powder Technology, 33, no. 2 (2022):103403, https://doi.org/10.1016/j.apt.2021.103403. in Advanced Powder Technology. 2022;33(2).
https://hdl.handle.net/21.15107/rcub_cherry_5120 .
Vuković, Marina, Dinić, Ivana, Jardim, Paula, Marković, Smilja, Veselinović, Ljiljana M., Nikolić, Marko G., Mančić, Lidija, "Supplementary information for the article: Vuković, Marina, Dinić, Ivana, Jardim, Paula, Marković, Smilja, Veselinović, Ljiljana, Nikolić, Marko, Mančić, Lidija, "The low-temperature sonochemical synthesis of up-converting β NaYF4:Yb,Er mesocrystals" in Advanced Powder Technology, 33, no. 2 (2022):103403, https://doi.org/10.1016/j.apt.2021.103403" in Advanced Powder Technology, 33, no. 2 (2022),
https://hdl.handle.net/21.15107/rcub_cherry_5120 .

Synthesis of Up-converting β-NaYF4:Yb/Er Nanoparticles by Low-temperature Sonochemical Method

Dinić, Ivana; Vuković, Marina; Jardim, Paula M.; Mančić, Lidija

(Belgrade : Serbian Academy of Sciences and Arts, 2022)

TY  - CONF
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Jardim, Paula M.
AU  - Mančić, Lidija
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5742
AB  - Up-converting nanoparticles (UCNPs) have unique optical properties to convert NIR to VIS light, and therefore are widely used in optoelectronics, forensic, medicine, etc. [1,2]. During the last decade interest in obtaining of the pure hexagonal (β) NaYF4:Yb/Er phase through some environmental friendly method which could be easily scaled-up is permanently present in scientific community. Different synthesis methods, like co-precipitation, thermal decomposition, hydro- and solvo-thermal methods were usually reported like promising ones, but obtaining of the highly efficient (β) phase is usually coupled with harsh processing conditions [3]. This phase is characterized by a higher degree of crystal asymmetry and multisite dopant accommodation which ensures better luminescence response than of cubic (beta) phase. To prevent nucleation of kinetically stable alpha phase, we applied for the first time ultrasound treatment (20 kHz, Vibra Cell VCX750 Sonic) to the simple mixture of the rare earth nitrates and NaF in different solvents (ethanol and water) for 30, 60, 90 and 120 min.
PB  - Belgrade : Serbian Academy of Sciences and Arts
C3  - Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022
T1  - Synthesis of Up-converting β-NaYF4:Yb/Er Nanoparticles by Low-temperature Sonochemical Method
SP  - 190
EP  - 191
UR  - https://hdl.handle.net/21.15107/rcub_dais_13639
ER  - 
@conference{
author = "Dinić, Ivana and Vuković, Marina and Jardim, Paula M. and Mančić, Lidija",
year = "2022",
abstract = "Up-converting nanoparticles (UCNPs) have unique optical properties to convert NIR to VIS light, and therefore are widely used in optoelectronics, forensic, medicine, etc. [1,2]. During the last decade interest in obtaining of the pure hexagonal (β) NaYF4:Yb/Er phase through some environmental friendly method which could be easily scaled-up is permanently present in scientific community. Different synthesis methods, like co-precipitation, thermal decomposition, hydro- and solvo-thermal methods were usually reported like promising ones, but obtaining of the highly efficient (β) phase is usually coupled with harsh processing conditions [3]. This phase is characterized by a higher degree of crystal asymmetry and multisite dopant accommodation which ensures better luminescence response than of cubic (beta) phase. To prevent nucleation of kinetically stable alpha phase, we applied for the first time ultrasound treatment (20 kHz, Vibra Cell VCX750 Sonic) to the simple mixture of the rare earth nitrates and NaF in different solvents (ethanol and water) for 30, 60, 90 and 120 min.",
publisher = "Belgrade : Serbian Academy of Sciences and Arts",
journal = "Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022",
title = "Synthesis of Up-converting β-NaYF4:Yb/Er Nanoparticles by Low-temperature Sonochemical Method",
pages = "190-191",
url = "https://hdl.handle.net/21.15107/rcub_dais_13639"
}
Dinić, I., Vuković, M., Jardim, P. M.,& Mančić, L.. (2022). Synthesis of Up-converting β-NaYF4:Yb/Er Nanoparticles by Low-temperature Sonochemical Method. in Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022
Belgrade : Serbian Academy of Sciences and Arts., 190-191.
https://hdl.handle.net/21.15107/rcub_dais_13639
Dinić I, Vuković M, Jardim PM, Mančić L. Synthesis of Up-converting β-NaYF4:Yb/Er Nanoparticles by Low-temperature Sonochemical Method. in Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022. 2022;:190-191.
https://hdl.handle.net/21.15107/rcub_dais_13639 .
Dinić, Ivana, Vuković, Marina, Jardim, Paula M., Mančić, Lidija, "Synthesis of Up-converting β-NaYF4:Yb/Er Nanoparticles by Low-temperature Sonochemical Method" in Program & Book of Abstracts / Second International Conference ELMINA 2022, Belgrade, Serbia, August 22nd-26th, 2022 (2022):190-191,
https://hdl.handle.net/21.15107/rcub_dais_13639 .

Influence of different synthesis methods on morphological and optical properties of the rare earth doped fluorides

Dinić, Ivana; Vuković, Marina; Rabanal, Maria Eugenia; Mančić, Lidija

(Belgrade : Materials Research Society of Serbia, 2022)

TY  - CONF
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Rabanal, Maria Eugenia
AU  - Mančić, Lidija
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5743
AB  - Over the last few years there has been a great interest in developing the efficient methodologies for the preparation of rare earth doped up-converting nanoparticles (UCNPs), which exhibit emission in visible part of spectra when excited by the near infrared (NIR) radiation. Due to this unique optical property, as well as the high chemical stability they could be used either as security or fluorescent biological labels. Depending on the host crystal structure and choice of the dopant, these could exhibit different luminescence response. In this work we represent the effect which hydro/solvo thermal treatment and simple co-precipitation have on structural, morphological and optical properties of NaYF4:Yb,Er UCNPs. We showed that pure cubic phase crystallizes in monodisperse spherical nanoparticles obtained through hydro/solvothermal synthesis, while co-precipitation and annealing at 500°C for 5 hours leads to the obtaining of agglomerated microparticles with hexagonal phase. Due to the difference in size and morphology of the samples, the different up-conversion mechanisms are established upon the excitation by the infrared light (λ = 978 nm), intensifying green emission (2H11/2,4S3/2 →4I15/2 ) in sample obtained through hydro/solvo thermal synthesis.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022
T1  - Influence of different synthesis methods on morphological and optical properties of the rare earth doped fluorides
SP  - 126
EP  - 126
UR  - https://hdl.handle.net/21.15107/rcub_dais_13595
ER  - 
@conference{
author = "Dinić, Ivana and Vuković, Marina and Rabanal, Maria Eugenia and Mančić, Lidija",
year = "2022",
abstract = "Over the last few years there has been a great interest in developing the efficient methodologies for the preparation of rare earth doped up-converting nanoparticles (UCNPs), which exhibit emission in visible part of spectra when excited by the near infrared (NIR) radiation. Due to this unique optical property, as well as the high chemical stability they could be used either as security or fluorescent biological labels. Depending on the host crystal structure and choice of the dopant, these could exhibit different luminescence response. In this work we represent the effect which hydro/solvo thermal treatment and simple co-precipitation have on structural, morphological and optical properties of NaYF4:Yb,Er UCNPs. We showed that pure cubic phase crystallizes in monodisperse spherical nanoparticles obtained through hydro/solvothermal synthesis, while co-precipitation and annealing at 500°C for 5 hours leads to the obtaining of agglomerated microparticles with hexagonal phase. Due to the difference in size and morphology of the samples, the different up-conversion mechanisms are established upon the excitation by the infrared light (λ = 978 nm), intensifying green emission (2H11/2,4S3/2 →4I15/2 ) in sample obtained through hydro/solvo thermal synthesis.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022",
title = "Influence of different synthesis methods on morphological and optical properties of the rare earth doped fluorides",
pages = "126-126",
url = "https://hdl.handle.net/21.15107/rcub_dais_13595"
}
Dinić, I., Vuković, M., Rabanal, M. E.,& Mančić, L.. (2022). Influence of different synthesis methods on morphological and optical properties of the rare earth doped fluorides. in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022
Belgrade : Materials Research Society of Serbia., 126-126.
https://hdl.handle.net/21.15107/rcub_dais_13595
Dinić I, Vuković M, Rabanal ME, Mančić L. Influence of different synthesis methods on morphological and optical properties of the rare earth doped fluorides. in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022. 2022;:126-126.
https://hdl.handle.net/21.15107/rcub_dais_13595 .
Dinić, Ivana, Vuković, Marina, Rabanal, Maria Eugenia, Mančić, Lidija, "Influence of different synthesis methods on morphological and optical properties of the rare earth doped fluorides" in Program and The Book of abstracts / Twenty-third Annual Conference YUCOMAT 2022 & Twelfth World Round Table Conference on Sintering XII WRTCS 2022, Herceg Novi, Montenegro, August 29 - September 2, 2022 (2022):126-126,
https://hdl.handle.net/21.15107/rcub_dais_13595 .

Hydroxyapatite grafting with alanine amino acid - efficiency of different methods

Vuković, Marina; Dorm, Bruna Carolina; Trovatti, Eliane; Ignjatović, Nenad; Marković, Smilja; Škapin, Srečo; Dinić, Ivana; Mančić, Lidija

(Belgrade : Serbian Ceramic Society, 2022)

TY  - CONF
AU  - Vuković, Marina
AU  - Dorm, Bruna Carolina
AU  - Trovatti, Eliane
AU  - Ignjatović, Nenad
AU  - Marković, Smilja
AU  - Škapin, Srečo
AU  - Dinić, Ivana
AU  - Mančić, Lidija
PY  - 2022
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5744
AB  - Hydroxyapatite (HAp) attracts great attention due to application in reconstructive medicine for hard tissues, mostly bones and teeth, where it is declared to be highly biocompatible material. Its grafting with amino acids further increases biocompatibility and has crucial importance for acceptance of body implants. In this work different methods of grafting were investigated: simple mixing, thermal treatment induction and in situ synthesis/grafting reactions. Two amino acid precursors were separately tested in grafting procedures: pure alanine and alanine methyl ester hydrochloride. The efficiency of grafting was determined based on X-ray powder diffraction (XRPD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and thermal analyses (DSC, TG/DTA) of obtained powders, while complementary UV-VIS spectroscopy of supernatants was additionally performed for quantitative determination of non-grafted nitrogen using ninhydrin standardized procedure.
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.
T1  - Hydroxyapatite grafting with alanine amino acid - efficiency of different methods
SP  - 58
EP  - 59
UR  - https://hdl.handle.net/21.15107/rcub_dais_13630
ER  - 
@conference{
author = "Vuković, Marina and Dorm, Bruna Carolina and Trovatti, Eliane and Ignjatović, Nenad and Marković, Smilja and Škapin, Srečo and Dinić, Ivana and Mančić, Lidija",
year = "2022",
abstract = "Hydroxyapatite (HAp) attracts great attention due to application in reconstructive medicine for hard tissues, mostly bones and teeth, where it is declared to be highly biocompatible material. Its grafting with amino acids further increases biocompatibility and has crucial importance for acceptance of body implants. In this work different methods of grafting were investigated: simple mixing, thermal treatment induction and in situ synthesis/grafting reactions. Two amino acid precursors were separately tested in grafting procedures: pure alanine and alanine methyl ester hydrochloride. The efficiency of grafting was determined based on X-ray powder diffraction (XRPD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and thermal analyses (DSC, TG/DTA) of obtained powders, while complementary UV-VIS spectroscopy of supernatants was additionally performed for quantitative determination of non-grafted nitrogen using ninhydrin standardized procedure.",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.",
title = "Hydroxyapatite grafting with alanine amino acid - efficiency of different methods",
pages = "58-59",
url = "https://hdl.handle.net/21.15107/rcub_dais_13630"
}
Vuković, M., Dorm, B. C., Trovatti, E., Ignjatović, N., Marković, S., Škapin, S., Dinić, I.,& Mančić, L.. (2022). Hydroxyapatite grafting with alanine amino acid - efficiency of different methods. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.
Belgrade : Serbian Ceramic Society., 58-59.
https://hdl.handle.net/21.15107/rcub_dais_13630
Vuković M, Dorm BC, Trovatti E, Ignjatović N, Marković S, Škapin S, Dinić I, Mančić L. Hydroxyapatite grafting with alanine amino acid - efficiency of different methods. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.. 2022;:58-59.
https://hdl.handle.net/21.15107/rcub_dais_13630 .
Vuković, Marina, Dorm, Bruna Carolina, Trovatti, Eliane, Ignjatović, Nenad, Marković, Smilja, Škapin, Srečo, Dinić, Ivana, Mančić, Lidija, "Hydroxyapatite grafting with alanine amino acid - efficiency of different methods" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022. (2022):58-59,
https://hdl.handle.net/21.15107/rcub_dais_13630 .

Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction

Filipović, Suzana; Obradović, Nina; Anđelković, Ljubica; Olćan, Dragan; Petrović, Jovana P.; Mirković, Marija D..; Pavlović, Vladimir B.; Jeremić, Dejan; Vlahović, Branislav; Đorđević, Antonije

(ETRAN Society, 2021)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Anđelković, Ljubica
AU  - Olćan, Dragan
AU  - Petrović, Jovana P.
AU  - Mirković, Marija D..
AU  - Pavlović, Vladimir B.
AU  - Jeremić, Dejan
AU  - Vlahović, Branislav
AU  - Đorđević, Antonije
PY  - 2021
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4511
AB  - Solid-state reaction between BaTiO3and Fe2O3was used to produce a multiferroic heterostructure composite. Commercial BaTiO3and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300°C for 6 h. Sintering at 1300 °C for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3with Fe2O3resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature. © 2021 Authors. Published by association for ETRAN Society.
PB  - ETRAN Society
T2  - Science of Sintering
T2  - Science of Sintering
T1  - Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction
VL  - 53
IS  - 1
SP  - 1
EP  - 8
DO  - 10.2298/SOS2101001F
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Anđelković, Ljubica and Olćan, Dragan and Petrović, Jovana P. and Mirković, Marija D.. and Pavlović, Vladimir B. and Jeremić, Dejan and Vlahović, Branislav and Đorđević, Antonije",
year = "2021",
abstract = "Solid-state reaction between BaTiO3and Fe2O3was used to produce a multiferroic heterostructure composite. Commercial BaTiO3and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300°C for 6 h. Sintering at 1300 °C for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3with Fe2O3resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature. © 2021 Authors. Published by association for ETRAN Society.",
publisher = "ETRAN Society",
journal = "Science of Sintering, Science of Sintering",
title = "Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction",
volume = "53",
number = "1",
pages = "1-8",
doi = "10.2298/SOS2101001F"
}
Filipović, S., Obradović, N., Anđelković, L., Olćan, D., Petrović, J. P., Mirković, M. D.., Pavlović, V. B., Jeremić, D., Vlahović, B.,& Đorđević, A.. (2021). Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction. in Science of Sintering
ETRAN Society., 53(1), 1-8.
https://doi.org/10.2298/SOS2101001F
Filipović S, Obradović N, Anđelković L, Olćan D, Petrović JP, Mirković MD, Pavlović VB, Jeremić D, Vlahović B, Đorđević A. Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction. in Science of Sintering. 2021;53(1):1-8.
doi:10.2298/SOS2101001F .
Filipović, Suzana, Obradović, Nina, Anđelković, Ljubica, Olćan, Dragan, Petrović, Jovana P., Mirković, Marija D.., Pavlović, Vladimir B., Jeremić, Dejan, Vlahović, Branislav, Đorđević, Antonije, "Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction" in Science of Sintering, 53, no. 1 (2021):1-8,
https://doi.org/10.2298/SOS2101001F . .
2
1
4
2

Sonochemical synthesis of optically active fluorides

Vuković, Marina; Dinić, Ivana; Jardim, Paula M.; Marković, Smilja; Veselinović, Ljiljana M.; Nikolić, Marko G.; Mančić, Lidija

(Belgrade : Institute of Technical Sciences of SASA, 2021)

TY  - CONF
AU  - Vuković, Marina
AU  - Dinić, Ivana
AU  - Jardim, Paula M.
AU  - Marković, Smilja
AU  - Veselinović, Ljiljana M.
AU  - Nikolić, Marko G.
AU  - Mančić, Lidija
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5213
AB  - Up-conversion is the optical property of materials which have ability to convert low energy photons (usually from infrared spectrum) into higher energy photons (from visible spectrum). Such compounds, usually lanthanide doped oxides or fluorides, have many applications in photoluminescence science and technology today. Currently, (β) NaYF4:Yb,Er polymorph is considered to be the most efficient up-converting material. Its synthesis usually includes the usage of toxic solvents, long-term heating, high pressures, controlled gas atmosphere, etc. The aim of this work was to utilize rarely applied sonochemical synthesis for the stabilization of (β) NaYF4:Yb,Er phase under mild and environmental friendly conditions. For this purpose, we performed ultrasonic treatment of common nitrate precursors and sodium fluorine for a different time. The obtained powders were analyzed in order to determine their phase composition and thermal stability, morphology, dopants distribution, particles surface purity and luminescent characteristics. Owing to this, the chemical and crystal phase transformations that occurred  in specified periods of synthesis time are explained in detail. Moreover, it was shown that obtaining of uniformly doped (β) NaYF4:Yb,Er mosocrystalline particles is possible after 2h of sonication.
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
T1  - Sonochemical synthesis of optically active fluorides
SP  - 33
EP  - 33
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5213
ER  - 
@conference{
author = "Vuković, Marina and Dinić, Ivana and Jardim, Paula M. and Marković, Smilja and Veselinović, Ljiljana M. and Nikolić, Marko G. and Mančić, Lidija",
year = "2021",
abstract = "Up-conversion is the optical property of materials which have ability to convert low energy photons (usually from infrared spectrum) into higher energy photons (from visible spectrum). Such compounds, usually lanthanide doped oxides or fluorides, have many applications in photoluminescence science and technology today. Currently, (β) NaYF4:Yb,Er polymorph is considered to be the most efficient up-converting material. Its synthesis usually includes the usage of toxic solvents, long-term heating, high pressures, controlled gas atmosphere, etc. The aim of this work was to utilize rarely applied sonochemical synthesis for the stabilization of (β) NaYF4:Yb,Er phase under mild and environmental friendly conditions. For this purpose, we performed ultrasonic treatment of common nitrate precursors and sodium fluorine for a different time. The obtained powders were analyzed in order to determine their phase composition and thermal stability, morphology, dopants distribution, particles surface purity and luminescent characteristics. Owing to this, the chemical and crystal phase transformations that occurred  in specified periods of synthesis time are explained in detail. Moreover, it was shown that obtaining of uniformly doped (β) NaYF4:Yb,Er mosocrystalline particles is possible after 2h of sonication.",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021",
title = "Sonochemical synthesis of optically active fluorides",
pages = "33-33",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5213"
}
Vuković, M., Dinić, I., Jardim, P. M., Marković, S., Veselinović, L. M., Nikolić, M. G.,& Mančić, L.. (2021). Sonochemical synthesis of optically active fluorides. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
Belgrade : Institute of Technical Sciences of SASA., 33-33.
https://hdl.handle.net/21.15107/rcub_cherry_5213
Vuković M, Dinić I, Jardim PM, Marković S, Veselinović LM, Nikolić MG, Mančić L. Sonochemical synthesis of optically active fluorides. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021. 2021;:33-33.
https://hdl.handle.net/21.15107/rcub_cherry_5213 .
Vuković, Marina, Dinić, Ivana, Jardim, Paula M., Marković, Smilja, Veselinović, Ljiljana M., Nikolić, Marko G., Mančić, Lidija, "Sonochemical synthesis of optically active fluorides" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 (2021):33-33,
https://hdl.handle.net/21.15107/rcub_cherry_5213 .

Sonochemical synthesis of up-converting β-NaYF4: Yb, Er nanoparticles

Dinić, Ivana; Vuković, Marina; Jardim, Paula M.; Nikolić, Marko G.; Mančić, Lidija

(Belgrade : Materials Research Society of Serbia, 2021)

TY  - CONF
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Jardim, Paula M.
AU  - Nikolić, Marko G.
AU  - Mančić, Lidija
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5214
AB  - Up-converting nanoparticles (UCNPs) with unique ability to convert NIR to VIS light (anti-Stokes process) have a wide application in optoelectronics, forensic, security labeling and biomedicine. Over the past few years different methods (like co-precipitation, thermal decomposition, hydro/solvothermal synthesis, etc.) are used for synthesis of β-NaYF4: Yb/Er phase, mainly from toxic organic precursors. In this work we explore conditions for stabilization of β-NaYF4: Yb/Er phase in nanoparticles applying sonochemistry synthesis of common inorganic precursor. The XRPD analysis showed that pure β phase is possible to obtained after 120 min of ultrasonification, while for shorter processing time (30-90min), cubic α-NaYF4: Yb/Er or orthorhombic YF3 : Yb,Er phase were founded too. The SEM and TEM analysis reveal presence of elongated nanoparticles self-assembled in spindles long up to 500 nm. Evolution of particle morphological and particle composition are analysed and correlated further with intensity of green emission (2H11/2,4S3/2→4I15/2) intensity measured under excitation of 978 nm.
PB  - Belgrade : Materials Research Society of Serbia
C3  - Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021
T1  - Sonochemical synthesis of up-converting β-NaYF4: Yb, Er nanoparticles
SP  - 103
EP  - 103
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5214
ER  - 
@conference{
author = "Dinić, Ivana and Vuković, Marina and Jardim, Paula M. and Nikolić, Marko G. and Mančić, Lidija",
year = "2021",
abstract = "Up-converting nanoparticles (UCNPs) with unique ability to convert NIR to VIS light (anti-Stokes process) have a wide application in optoelectronics, forensic, security labeling and biomedicine. Over the past few years different methods (like co-precipitation, thermal decomposition, hydro/solvothermal synthesis, etc.) are used for synthesis of β-NaYF4: Yb/Er phase, mainly from toxic organic precursors. In this work we explore conditions for stabilization of β-NaYF4: Yb/Er phase in nanoparticles applying sonochemistry synthesis of common inorganic precursor. The XRPD analysis showed that pure β phase is possible to obtained after 120 min of ultrasonification, while for shorter processing time (30-90min), cubic α-NaYF4: Yb/Er or orthorhombic YF3 : Yb,Er phase were founded too. The SEM and TEM analysis reveal presence of elongated nanoparticles self-assembled in spindles long up to 500 nm. Evolution of particle morphological and particle composition are analysed and correlated further with intensity of green emission (2H11/2,4S3/2→4I15/2) intensity measured under excitation of 978 nm.",
publisher = "Belgrade : Materials Research Society of Serbia",
journal = "Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021",
title = "Sonochemical synthesis of up-converting β-NaYF4: Yb, Er nanoparticles",
pages = "103-103",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5214"
}
Dinić, I., Vuković, M., Jardim, P. M., Nikolić, M. G.,& Mančić, L.. (2021). Sonochemical synthesis of up-converting β-NaYF4: Yb, Er nanoparticles. in Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021
Belgrade : Materials Research Society of Serbia., 103-103.
https://hdl.handle.net/21.15107/rcub_cherry_5214
Dinić I, Vuković M, Jardim PM, Nikolić MG, Mančić L. Sonochemical synthesis of up-converting β-NaYF4: Yb, Er nanoparticles. in Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021. 2021;:103-103.
https://hdl.handle.net/21.15107/rcub_cherry_5214 .
Dinić, Ivana, Vuković, Marina, Jardim, Paula M., Nikolić, Marko G., Mančić, Lidija, "Sonochemical synthesis of up-converting β-NaYF4: Yb, Er nanoparticles" in Programme and the Book of abstracts / Twenty-second Annual Conference YUCOMAT 2021 Herceg Novi, Montenegro, August 30 - September 3, 2021 (2021):103-103,
https://hdl.handle.net/21.15107/rcub_cherry_5214 .

Influence of solvothermal synthesis parameters on NaY0.65Gd0.15F4:Yb0.18Er0.02 UCNPs structural, morphological and optical characteristics

Dinić, Ivana; Vuković, Marina; Nikolić, Marko G.; Mančić, Lidija

(Belgrade : Serbian Ceramic Society, 2021)

TY  - CONF
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Nikolić, Marko G.
AU  - Mančić, Lidija
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5215
AB  - Monosized Up-Converting NanoParticles (UCNPs) with biocompatible surface and unique optical properties attract a great interest as new cell markers or drug delivery systems. The uppermost UC efficiency of β-NaYF4:Yb/Er phase is due to its hexagonal P63/m space group arrangement which could accommodate higher concentration of dopants at shorter distance. Stabilization of this phase in nanoparticles is usually achieved through thermal decomposition of organic precursors in the presence of solvents with a high boiling point. Here, for the same purpose, we used gadolinium co-doping during chitosan assisted solvothermal processing of inorganic precursor salts. Precursor concentration, solvent type, and synthesis time were varied in order to determine their influence on the β-NaY0.65Gd0.15F4:Yb0.18Er0.02 phase crystallization. The XRPD analysis showed that lower surplus of fluoride ions during synthesis leads to formation of Y0.65Gd0.15F4:Yb0.18Er0.02 orthorhombic phase, while the increase of fluoride content or prolongation of the processing time enhances formation α- NaY0.65Gd0.15F4:Yb0.18Er0.18 phase. Along with it, the changes of UCNPs morphology from spindle to spherical shape is detected. All samples emit intense green emission due to the (2H11/2, 4S3/2) → 4I15/2 electronic transitions, after been excited with infrared light (λ=978 nm).
PB  - Belgrade : Serbian Ceramic Society
C3  - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
T1  - Influence of solvothermal synthesis parameters on NaY0.65Gd0.15F4:Yb0.18Er0.02 UCNPs structural, morphological and optical characteristics
SP  - 34
EP  - 35
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5215
ER  - 
@conference{
author = "Dinić, Ivana and Vuković, Marina and Nikolić, Marko G. and Mančić, Lidija",
year = "2021",
abstract = "Monosized Up-Converting NanoParticles (UCNPs) with biocompatible surface and unique optical properties attract a great interest as new cell markers or drug delivery systems. The uppermost UC efficiency of β-NaYF4:Yb/Er phase is due to its hexagonal P63/m space group arrangement which could accommodate higher concentration of dopants at shorter distance. Stabilization of this phase in nanoparticles is usually achieved through thermal decomposition of organic precursors in the presence of solvents with a high boiling point. Here, for the same purpose, we used gadolinium co-doping during chitosan assisted solvothermal processing of inorganic precursor salts. Precursor concentration, solvent type, and synthesis time were varied in order to determine their influence on the β-NaY0.65Gd0.15F4:Yb0.18Er0.02 phase crystallization. The XRPD analysis showed that lower surplus of fluoride ions during synthesis leads to formation of Y0.65Gd0.15F4:Yb0.18Er0.02 orthorhombic phase, while the increase of fluoride content or prolongation of the processing time enhances formation α- NaY0.65Gd0.15F4:Yb0.18Er0.18 phase. Along with it, the changes of UCNPs morphology from spindle to spherical shape is detected. All samples emit intense green emission due to the (2H11/2, 4S3/2) → 4I15/2 electronic transitions, after been excited with infrared light (λ=978 nm).",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021",
title = "Influence of solvothermal synthesis parameters on NaY0.65Gd0.15F4:Yb0.18Er0.02 UCNPs structural, morphological and optical characteristics",
pages = "34-35",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5215"
}
Dinić, I., Vuković, M., Nikolić, M. G.,& Mančić, L.. (2021). Influence of solvothermal synthesis parameters on NaY0.65Gd0.15F4:Yb0.18Er0.02 UCNPs structural, morphological and optical characteristics. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021
Belgrade : Serbian Ceramic Society., 34-35.
https://hdl.handle.net/21.15107/rcub_cherry_5215
Dinić I, Vuković M, Nikolić MG, Mančić L. Influence of solvothermal synthesis parameters on NaY0.65Gd0.15F4:Yb0.18Er0.02 UCNPs structural, morphological and optical characteristics. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021. 2021;:34-35.
https://hdl.handle.net/21.15107/rcub_cherry_5215 .
Dinić, Ivana, Vuković, Marina, Nikolić, Marko G., Mančić, Lidija, "Influence of solvothermal synthesis parameters on NaY0.65Gd0.15F4:Yb0.18Er0.02 UCNPs structural, morphological and optical characteristics" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application IX : New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 20-21. September 2021 (2021):34-35,
https://hdl.handle.net/21.15107/rcub_cherry_5215 .

Solvothermal synthesis of NaGdYF4:Yb,Er UCNPs with different structual, morphological and optical properties

Dinić, Ivana; Vuković, Marina; Nikolić, Marko G.; Mančić, Lidija

(Novi Sad : Faculty of Technology, 2021)

TY  - CONF
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Nikolić, Marko G.
AU  - Mančić, Lidija
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5216
AB  - Up-Converting NanoParticles (UCNPs) with biocompatible surface and unique optical properties, low phonon energy (350 cm-1) and high chemical stability attract a great interest as potential biomarkers or drug delivery systems. The hydro/solvo thermal method, as one of the most economical method which do not include the use of toxic precursors, was applied here for the synthesis of NaY0.65Gd0.15F4:Yb,Er nanoparticles at 200oC. Chitosan is used as surfactant and structural directing agent. In addition, different processing parameters (precursor concentration, solvent type, and synthesis time) were applied to investigate their influence on the structural, morphological, and optical properties of UCNP. The XRD analysis showed that with a smaller surplus of fluoride ions the formation of Y0.65Gd0.15F4:Yb,Er orthorhombic phase occurs, while the increase of fluoride content or reaction time leads to NaY0.65Gd0.15F4:Yb,Er cubic phase formation. Along with it, the changes of UCNPs morphology from spindle to spherical shape is detected. All samples emit intense green emission due to the (2H11/2, 4S3/2) → 4I15/2 electronic transitions, after been excited with infrared light (λ=978 nm).
PB  - Novi Sad : Faculty of Technology
C3  - Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad
T1  - Solvothermal synthesis of NaGdYF4:Yb,Er UCNPs with different structual, morphological and optical properties
SP  - 121
EP  - 121
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5216
ER  - 
@conference{
author = "Dinić, Ivana and Vuković, Marina and Nikolić, Marko G. and Mančić, Lidija",
year = "2021",
abstract = "Up-Converting NanoParticles (UCNPs) with biocompatible surface and unique optical properties, low phonon energy (350 cm-1) and high chemical stability attract a great interest as potential biomarkers or drug delivery systems. The hydro/solvo thermal method, as one of the most economical method which do not include the use of toxic precursors, was applied here for the synthesis of NaY0.65Gd0.15F4:Yb,Er nanoparticles at 200oC. Chitosan is used as surfactant and structural directing agent. In addition, different processing parameters (precursor concentration, solvent type, and synthesis time) were applied to investigate their influence on the structural, morphological, and optical properties of UCNP. The XRD analysis showed that with a smaller surplus of fluoride ions the formation of Y0.65Gd0.15F4:Yb,Er orthorhombic phase occurs, while the increase of fluoride content or reaction time leads to NaY0.65Gd0.15F4:Yb,Er cubic phase formation. Along with it, the changes of UCNPs morphology from spindle to spherical shape is detected. All samples emit intense green emission due to the (2H11/2, 4S3/2) → 4I15/2 electronic transitions, after been excited with infrared light (λ=978 nm).",
publisher = "Novi Sad : Faculty of Technology",
journal = "Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad",
title = "Solvothermal synthesis of NaGdYF4:Yb,Er UCNPs with different structual, morphological and optical properties",
pages = "121-121",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5216"
}
Dinić, I., Vuković, M., Nikolić, M. G.,& Mančić, L.. (2021). Solvothermal synthesis of NaGdYF4:Yb,Er UCNPs with different structual, morphological and optical properties. in Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad
Novi Sad : Faculty of Technology., 121-121.
https://hdl.handle.net/21.15107/rcub_cherry_5216
Dinić I, Vuković M, Nikolić MG, Mančić L. Solvothermal synthesis of NaGdYF4:Yb,Er UCNPs with different structual, morphological and optical properties. in Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad. 2021;:121-121.
https://hdl.handle.net/21.15107/rcub_cherry_5216 .
Dinić, Ivana, Vuković, Marina, Nikolić, Marko G., Mančić, Lidija, "Solvothermal synthesis of NaGdYF4:Yb,Er UCNPs with different structual, morphological and optical properties" in Programme and book of abstracts / 14th ECerS Conference for Young Scientists in Ceramics (CYSC-2021), October 20-23, 2021, Novi Sad (2021):121-121,
https://hdl.handle.net/21.15107/rcub_cherry_5216 .

Effect of processing parameters on NaGdYF4:Yb,Er UCNPs structural, morphological and optical properties

Dinić, Ivana; Vuković, Marina; Nikolić, Marko G.; Mančić, Lidija

(Belgrade : Institute of Technical Sciences of SASA, 2021)

TY  - CONF
AU  - Dinić, Ivana
AU  - Vuković, Marina
AU  - Nikolić, Marko G.
AU  - Mančić, Lidija
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/5217
AB  - Synthesis of monosized and spherical Up-Converting NanoParticles (UCNPs) with biocompatible surface are of a great interest because of their potential application in biomedicine as biomarkers or drug delivery systems. Among different synthesis routes reported in the literature, a hydro/solvo thermal method is consider to be most potential one for scaling-up due fact that is simple and economically cost-effective. In this work the synthesis of NaY0.65Gd0.15F4:Yb,Er UCNPs were performed through chitosan assistant solvothermal synthesis at 200oC. Variation of precursors concentration, type of solvent and synthesis time were performed in order to explore their influence on the structural, morphological and optical properties of the UCNPs. The XRD analysis showed that with a smaller surplus of fluoride ions the formation of Y0.65Gd0.15F4:Yb,Er orthorhombic phase occurs, while the increase of fluoride content or reaction time leads to NaY0.65Gd0.15F4:Yb,Er cubic phase formation. Along with it, the changes of UCNPs morphology from spindle to spherical shape is detected. All samples emitintense green emission due to the (2H11/2, 4S3/2) → 4I15/2electronic transitions, after been excited with infrared light (λ=978 nm).
PB  - Belgrade : Institute of Technical Sciences of SASA
C3  - Program and the Book of abstracts / Nineteenth Young Researchers' Conference Materials Science and Engineering, December 1-3, 2021, Belgrade, Serbia
T1  - Effect of processing parameters on NaGdYF4:Yb,Er UCNPs structural, morphological and optical properties
SP  - 29
EP  - 29
UR  - https://hdl.handle.net/21.15107/rcub_cherry_5217
ER  - 
@conference{
author = "Dinić, Ivana and Vuković, Marina and Nikolić, Marko G. and Mančić, Lidija",
year = "2021",
abstract = "Synthesis of monosized and spherical Up-Converting NanoParticles (UCNPs) with biocompatible surface are of a great interest because of their potential application in biomedicine as biomarkers or drug delivery systems. Among different synthesis routes reported in the literature, a hydro/solvo thermal method is consider to be most potential one for scaling-up due fact that is simple and economically cost-effective. In this work the synthesis of NaY0.65Gd0.15F4:Yb,Er UCNPs were performed through chitosan assistant solvothermal synthesis at 200oC. Variation of precursors concentration, type of solvent and synthesis time were performed in order to explore their influence on the structural, morphological and optical properties of the UCNPs. The XRD analysis showed that with a smaller surplus of fluoride ions the formation of Y0.65Gd0.15F4:Yb,Er orthorhombic phase occurs, while the increase of fluoride content or reaction time leads to NaY0.65Gd0.15F4:Yb,Er cubic phase formation. Along with it, the changes of UCNPs morphology from spindle to spherical shape is detected. All samples emitintense green emission due to the (2H11/2, 4S3/2) → 4I15/2electronic transitions, after been excited with infrared light (λ=978 nm).",
publisher = "Belgrade : Institute of Technical Sciences of SASA",
journal = "Program and the Book of abstracts / Nineteenth Young Researchers' Conference Materials Science and Engineering, December 1-3, 2021, Belgrade, Serbia",
title = "Effect of processing parameters on NaGdYF4:Yb,Er UCNPs structural, morphological and optical properties",
pages = "29-29",
url = "https://hdl.handle.net/21.15107/rcub_cherry_5217"
}
Dinić, I., Vuković, M., Nikolić, M. G.,& Mančić, L.. (2021). Effect of processing parameters on NaGdYF4:Yb,Er UCNPs structural, morphological and optical properties. in Program and the Book of abstracts / Nineteenth Young Researchers' Conference Materials Science and Engineering, December 1-3, 2021, Belgrade, Serbia
Belgrade : Institute of Technical Sciences of SASA., 29-29.
https://hdl.handle.net/21.15107/rcub_cherry_5217
Dinić I, Vuković M, Nikolić MG, Mančić L. Effect of processing parameters on NaGdYF4:Yb,Er UCNPs structural, morphological and optical properties. in Program and the Book of abstracts / Nineteenth Young Researchers' Conference Materials Science and Engineering, December 1-3, 2021, Belgrade, Serbia. 2021;:29-29.
https://hdl.handle.net/21.15107/rcub_cherry_5217 .
Dinić, Ivana, Vuković, Marina, Nikolić, Marko G., Mančić, Lidija, "Effect of processing parameters on NaGdYF4:Yb,Er UCNPs structural, morphological and optical properties" in Program and the Book of abstracts / Nineteenth Young Researchers' Conference Materials Science and Engineering, December 1-3, 2021, Belgrade, Serbia (2021):29-29,
https://hdl.handle.net/21.15107/rcub_cherry_5217 .

2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior

Ristić, Predrag; Filipović, Nenad R.; Blagojević, Vladimir A.; Ćirković, Jovana; Barta Holló, Berta; Đokić, Veljko R.; Donnard, Morgan; Gulea, Mihaela; Marjanović, Ivana; Klisurić, Olivera R.; Todorović, Tamara

(Royal Society of Chemistry, 2021)

TY  - JOUR
AU  - Ristić, Predrag
AU  - Filipović, Nenad R.
AU  - Blagojević, Vladimir A.
AU  - Ćirković, Jovana
AU  - Barta Holló, Berta
AU  - Đokić, Veljko R.
AU  - Donnard, Morgan
AU  - Gulea, Mihaela
AU  - Marjanović, Ivana
AU  - Klisurić, Olivera R.
AU  - Todorović, Tamara
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4831
AB  - Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞(1), {[Ag(L1)2]ClO4}∞(2), {[Ag(L2)2]NO3·H2O}∞(3) and {[Ag(L2)2]ClO4}∞(4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds1and2are two-dimensional, while3and4are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in1and2have ansqltopology, while3and4exhibit adiatopology. Thermal analysis shows that3loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound4, which can be correlated to its largest lattice volume.
PB  - Royal Society of Chemistry
T2  - CrystEngComm
T1  - 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior
VL  - 23
IS  - 27
SP  - 4799
EP  - 4815
DO  - 10.1039/d1ce00394a
ER  - 
@article{
author = "Ristić, Predrag and Filipović, Nenad R. and Blagojević, Vladimir A. and Ćirković, Jovana and Barta Holló, Berta and Đokić, Veljko R. and Donnard, Morgan and Gulea, Mihaela and Marjanović, Ivana and Klisurić, Olivera R. and Todorović, Tamara",
year = "2021",
abstract = "Four silver-based coordination polymers, {[Ag(L1)2]NO3}∞(1), {[Ag(L1)2]ClO4}∞(2), {[Ag(L2)2]NO3·H2O}∞(3) and {[Ag(L2)2]ClO4}∞(4), were synthesized using the thiomorpholine-4-carbonitrile (L1) and piperazine-1,4-dicarbonitrile (L2) ligands. Compounds1and2are two-dimensional, while3and4are three-dimensional. L1 and L2 are 1,4-bis-monodentate ligands in all compounds, while Ag(i) ions are four-coordinated in a slightly distorted tetrahedral geometry. Topological analysis in standard representations suggests that underlying nets in1and2have ansqltopology, while3and4exhibit adiatopology. Thermal analysis shows that3loses crystalline water at room temperature, while other compounds show good thermal stability. All compounds show good photocatalytic activity for photocatalytic degradation of the mordant blue 9 dye, with reaction rates in the range 0.029 to 0.061 min−1. The best result was obtained for compound4, which can be correlated to its largest lattice volume.",
publisher = "Royal Society of Chemistry",
journal = "CrystEngComm",
title = "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior",
volume = "23",
number = "27",
pages = "4799-4815",
doi = "10.1039/d1ce00394a"
}
Ristić, P., Filipović, N. R., Blagojević, V. A., Ćirković, J., Barta Holló, B., Đokić, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisurić, O. R.,& Todorović, T.. (2021). 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in CrystEngComm
Royal Society of Chemistry., 23(27), 4799-4815.
https://doi.org/10.1039/d1ce00394a
Ristić P, Filipović NR, Blagojević VA, Ćirković J, Barta Holló B, Đokić VR, Donnard M, Gulea M, Marjanović I, Klisurić OR, Todorović T. 2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior. in CrystEngComm. 2021;23(27):4799-4815.
doi:10.1039/d1ce00394a .
Ristić, Predrag, Filipović, Nenad R., Blagojević, Vladimir A., Ćirković, Jovana, Barta Holló, Berta, Đokić, Veljko R., Donnard, Morgan, Gulea, Mihaela, Marjanović, Ivana, Klisurić, Olivera R., Todorović, Tamara, "2D and 3D silver-based coordination polymers with thiomorpholine-4-carbonitrile and piperazine-1,4-dicarbonitrile: structure, intermolecular interactions, photocatalysis, and thermal behavior" in CrystEngComm, 23, no. 27 (2021):4799-4815,
https://doi.org/10.1039/d1ce00394a . .
3
8
7
4

Supplementary data for the article: Ristić, P.; Filipović, N.; Blagojević, V.; Ćirković, J.; Holló, B. B.; Đokić, V. R.; Donnard, M.; Gulea, M.; Marjanović, I.; Klisurić, O. R.; Todorović, T. R. 2D and 3D Silver-Based Coordination Polymers with Thiomorpholine-4-Carbonitrile and Piperazine-1,4-Dicarbonitrile: Structure, Intermolecular Interactions, Photocatalysis, and Thermal Behavior. CrystEngComm 2021, 23 (27), 4799–4815. https://doi.org/10.1039/D1CE00394A.

Ristić, Predrag; Filipović, Nenad R.; Blagojević, Vladimir A.; Ćirković, Jovana; Barta Holló, Berta; Đokić, Veljko R.; Donnard, Morgan; Gulea, Mihaela; Marjanović, Ivana; Klisurić, Olivera R.; Todorović, Tamara

(Royal Society of Chemistry, 2021)

TY  - DATA
AU  - Ristić, Predrag
AU  - Filipović, Nenad R.
AU  - Blagojević, Vladimir A.
AU  - Ćirković, Jovana
AU  - Barta Holló, Berta
AU  - Đokić, Veljko R.
AU  - Donnard, Morgan
AU  - Gulea, Mihaela
AU  - Marjanović, Ivana
AU  - Klisurić, Olivera R.
AU  - Todorović, Tamara
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4832
PB  - Royal Society of Chemistry
T2  - CrystEngComm
T1  - Supplementary data for the article: Ristić, P.; Filipović, N.; Blagojević, V.; Ćirković, J.; Holló, B. B.; Đokić, V. R.; Donnard, M.; Gulea, M.; Marjanović, I.; Klisurić, O. R.; Todorović, T. R. 2D and 3D Silver-Based Coordination Polymers with Thiomorpholine-4-Carbonitrile and Piperazine-1,4-Dicarbonitrile: Structure, Intermolecular Interactions, Photocatalysis, and Thermal Behavior. CrystEngComm 2021, 23 (27), 4799–4815. https://doi.org/10.1039/D1CE00394A.
UR  - https://hdl.handle.net/21.15107/rcub_cherry_4832
ER  - 
@misc{
author = "Ristić, Predrag and Filipović, Nenad R. and Blagojević, Vladimir A. and Ćirković, Jovana and Barta Holló, Berta and Đokić, Veljko R. and Donnard, Morgan and Gulea, Mihaela and Marjanović, Ivana and Klisurić, Olivera R. and Todorović, Tamara",
year = "2021",
publisher = "Royal Society of Chemistry",
journal = "CrystEngComm",
title = "Supplementary data for the article: Ristić, P.; Filipović, N.; Blagojević, V.; Ćirković, J.; Holló, B. B.; Đokić, V. R.; Donnard, M.; Gulea, M.; Marjanović, I.; Klisurić, O. R.; Todorović, T. R. 2D and 3D Silver-Based Coordination Polymers with Thiomorpholine-4-Carbonitrile and Piperazine-1,4-Dicarbonitrile: Structure, Intermolecular Interactions, Photocatalysis, and Thermal Behavior. CrystEngComm 2021, 23 (27), 4799–4815. https://doi.org/10.1039/D1CE00394A.",
url = "https://hdl.handle.net/21.15107/rcub_cherry_4832"
}
Ristić, P., Filipović, N. R., Blagojević, V. A., Ćirković, J., Barta Holló, B., Đokić, V. R., Donnard, M., Gulea, M., Marjanović, I., Klisurić, O. R.,& Todorović, T.. (2021). Supplementary data for the article: Ristić, P.; Filipović, N.; Blagojević, V.; Ćirković, J.; Holló, B. B.; Đokić, V. R.; Donnard, M.; Gulea, M.; Marjanović, I.; Klisurić, O. R.; Todorović, T. R. 2D and 3D Silver-Based Coordination Polymers with Thiomorpholine-4-Carbonitrile and Piperazine-1,4-Dicarbonitrile: Structure, Intermolecular Interactions, Photocatalysis, and Thermal Behavior. CrystEngComm 2021, 23 (27), 4799–4815. https://doi.org/10.1039/D1CE00394A.. in CrystEngComm
Royal Society of Chemistry..
https://hdl.handle.net/21.15107/rcub_cherry_4832
Ristić P, Filipović NR, Blagojević VA, Ćirković J, Barta Holló B, Đokić VR, Donnard M, Gulea M, Marjanović I, Klisurić OR, Todorović T. Supplementary data for the article: Ristić, P.; Filipović, N.; Blagojević, V.; Ćirković, J.; Holló, B. B.; Đokić, V. R.; Donnard, M.; Gulea, M.; Marjanović, I.; Klisurić, O. R.; Todorović, T. R. 2D and 3D Silver-Based Coordination Polymers with Thiomorpholine-4-Carbonitrile and Piperazine-1,4-Dicarbonitrile: Structure, Intermolecular Interactions, Photocatalysis, and Thermal Behavior. CrystEngComm 2021, 23 (27), 4799–4815. https://doi.org/10.1039/D1CE00394A.. in CrystEngComm. 2021;.
https://hdl.handle.net/21.15107/rcub_cherry_4832 .
Ristić, Predrag, Filipović, Nenad R., Blagojević, Vladimir A., Ćirković, Jovana, Barta Holló, Berta, Đokić, Veljko R., Donnard, Morgan, Gulea, Mihaela, Marjanović, Ivana, Klisurić, Olivera R., Todorović, Tamara, "Supplementary data for the article: Ristić, P.; Filipović, N.; Blagojević, V.; Ćirković, J.; Holló, B. B.; Đokić, V. R.; Donnard, M.; Gulea, M.; Marjanović, I.; Klisurić, O. R.; Todorović, T. R. 2D and 3D Silver-Based Coordination Polymers with Thiomorpholine-4-Carbonitrile and Piperazine-1,4-Dicarbonitrile: Structure, Intermolecular Interactions, Photocatalysis, and Thermal Behavior. CrystEngComm 2021, 23 (27), 4799–4815. https://doi.org/10.1039/D1CE00394A." in CrystEngComm (2021),
https://hdl.handle.net/21.15107/rcub_cherry_4832 .

Structure and properties of nanocrystalline tetragonal BaTiO3 prepared by combustion solid state synthesis

Filipović, S.; Anđelković, Ljubica; Jeremić, Dejan; Vulić, P.; Nikolić, A. S.; Marković, S.; Paunović, V.; Lević, Steva M.; Pavlović, Vladimir B.

(Association for ETRAN Society, 2020)

TY  - JOUR
AU  - Filipović, S.
AU  - Anđelković, Ljubica
AU  - Jeremić, Dejan
AU  - Vulić, P.
AU  - Nikolić, A. S.
AU  - Marković, S.
AU  - Paunović, V.
AU  - Lević, Steva M.
AU  - Pavlović, Vladimir B.
PY  - 2020
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/4301
AB  - Barium titanate (BaTiO3) attracts high scientific and technological attention due to good dielectric and electromechanical properties. Although BaTiO3 is one of the most frequently investigated ferroelectric materials, the need for finding new and/or improved synthesis methods of this material still exists. In this paper, a novel, mild synthesis route for producing tetragonal BaTiO3 from barium nitrate and Ti-oxalate precursor is presented. Morphology of the prepared and subsequently sintered BaTiO3 was determined by SEM. Particle size distribution of the as prepared powder was monitored by the laser diffraction. The phase composition, structure and lattice dynamics were investigated by XRD and Raman spectroscopy. Finally, dielectric parameters were determined in the temperature range from 30 to 180ºC, and within a variety of frequencies. Curie temperature was detected at 130ºC.
PB  - Association for ETRAN Society
T2  - Science of Sintering
T1  - Structure and properties of nanocrystalline tetragonal BaTiO3 prepared by combustion solid state synthesis
VL  - 52
IS  - 3
SP  - 257
EP  - 268
DO  - 10.2298/SOS2003257F
ER  - 
@article{
author = "Filipović, S. and Anđelković, Ljubica and Jeremić, Dejan and Vulić, P. and Nikolić, A. S. and Marković, S. and Paunović, V. and Lević, Steva M. and Pavlović, Vladimir B.",
year = "2020",
abstract = "Barium titanate (BaTiO3) attracts high scientific and technological attention due to good dielectric and electromechanical properties. Although BaTiO3 is one of the most frequently investigated ferroelectric materials, the need for finding new and/or improved synthesis methods of this material still exists. In this paper, a novel, mild synthesis route for producing tetragonal BaTiO3 from barium nitrate and Ti-oxalate precursor is presented. Morphology of the prepared and subsequently sintered BaTiO3 was determined by SEM. Particle size distribution of the as prepared powder was monitored by the laser diffraction. The phase composition, structure and lattice dynamics were investigated by XRD and Raman spectroscopy. Finally, dielectric parameters were determined in the temperature range from 30 to 180ºC, and within a variety of frequencies. Curie temperature was detected at 130ºC.",
publisher = "Association for ETRAN Society",
journal = "Science of Sintering",
title = "Structure and properties of nanocrystalline tetragonal BaTiO3 prepared by combustion solid state synthesis",
volume = "52",
number = "3",
pages = "257-268",
doi = "10.2298/SOS2003257F"
}
Filipović, S., Anđelković, L., Jeremić, D., Vulić, P., Nikolić, A. S., Marković, S., Paunović, V., Lević, S. M.,& Pavlović, V. B.. (2020). Structure and properties of nanocrystalline tetragonal BaTiO3 prepared by combustion solid state synthesis. in Science of Sintering
Association for ETRAN Society., 52(3), 257-268.
https://doi.org/10.2298/SOS2003257F
Filipović S, Anđelković L, Jeremić D, Vulić P, Nikolić AS, Marković S, Paunović V, Lević SM, Pavlović VB. Structure and properties of nanocrystalline tetragonal BaTiO3 prepared by combustion solid state synthesis. in Science of Sintering. 2020;52(3):257-268.
doi:10.2298/SOS2003257F .
Filipović, S., Anđelković, Ljubica, Jeremić, Dejan, Vulić, P., Nikolić, A. S., Marković, S., Paunović, V., Lević, Steva M., Pavlović, Vladimir B., "Structure and properties of nanocrystalline tetragonal BaTiO3 prepared by combustion solid state synthesis" in Science of Sintering, 52, no. 3 (2020):257-268,
https://doi.org/10.2298/SOS2003257F . .
4
1
5
4