Centre for International Cooperation Mobility (ICM)

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Centre for International Cooperation Mobility (ICM)

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Publications

Supplementary data for article: Mehmeti, E.; Stanković, D. M.; Chaiyo, S.; Zavasnik, J.; Žagar, K.; Kalcher, K. Wiring of Glucose Oxidase with Graphene Nanoribbons: An Electrochemical Third Generation Glucose Biosensor. Microchimica Acta 2017, 184 (4), 1127–1134. https://doi.org/10.1007/s00604-017-2115-5

Mehmeti, Eda; Stanković, Dalibor; Chaiyo, Sudkate; Zavašnik, Janez; Žagar, Kristina; Kalcher, Kurt

(Springer Wien, Wien, 2017)

TY  - DATA
AU  - Mehmeti, Eda
AU  - Stanković, Dalibor
AU  - Chaiyo, Sudkate
AU  - Zavašnik, Janez
AU  - Žagar, Kristina
AU  - Kalcher, Kurt
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3104
PB  - Springer Wien, Wien
T2  - Microchimica Acta
T1  - Supplementary data for article:           Mehmeti, E.; Stanković, D. M.; Chaiyo, S.; Zavasnik, J.; Žagar, K.; Kalcher, K. Wiring of Glucose Oxidase with Graphene Nanoribbons: An Electrochemical Third Generation Glucose Biosensor. Microchimica Acta 2017, 184 (4), 1127–1134. https://doi.org/10.1007/s00604-017-2115-5
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3104
ER  - 
@misc{
author = "Mehmeti, Eda and Stanković, Dalibor and Chaiyo, Sudkate and Zavašnik, Janez and Žagar, Kristina and Kalcher, Kurt",
year = "2017",
publisher = "Springer Wien, Wien",
journal = "Microchimica Acta",
title = "Supplementary data for article:           Mehmeti, E.; Stanković, D. M.; Chaiyo, S.; Zavasnik, J.; Žagar, K.; Kalcher, K. Wiring of Glucose Oxidase with Graphene Nanoribbons: An Electrochemical Third Generation Glucose Biosensor. Microchimica Acta 2017, 184 (4), 1127–1134. https://doi.org/10.1007/s00604-017-2115-5",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3104"
}
Mehmeti, E., Stanković, D., Chaiyo, S., Zavašnik, J., Žagar, K.,& Kalcher, K.. (2017). Supplementary data for article:           Mehmeti, E.; Stanković, D. M.; Chaiyo, S.; Zavasnik, J.; Žagar, K.; Kalcher, K. Wiring of Glucose Oxidase with Graphene Nanoribbons: An Electrochemical Third Generation Glucose Biosensor. Microchimica Acta 2017, 184 (4), 1127–1134. https://doi.org/10.1007/s00604-017-2115-5. in Microchimica Acta
Springer Wien, Wien..
https://hdl.handle.net/21.15107/rcub_cherry_3104
Mehmeti E, Stanković D, Chaiyo S, Zavašnik J, Žagar K, Kalcher K. Supplementary data for article:           Mehmeti, E.; Stanković, D. M.; Chaiyo, S.; Zavasnik, J.; Žagar, K.; Kalcher, K. Wiring of Glucose Oxidase with Graphene Nanoribbons: An Electrochemical Third Generation Glucose Biosensor. Microchimica Acta 2017, 184 (4), 1127–1134. https://doi.org/10.1007/s00604-017-2115-5. in Microchimica Acta. 2017;.
https://hdl.handle.net/21.15107/rcub_cherry_3104 .
Mehmeti, Eda, Stanković, Dalibor, Chaiyo, Sudkate, Zavašnik, Janez, Žagar, Kristina, Kalcher, Kurt, "Supplementary data for article:           Mehmeti, E.; Stanković, D. M.; Chaiyo, S.; Zavasnik, J.; Žagar, K.; Kalcher, K. Wiring of Glucose Oxidase with Graphene Nanoribbons: An Electrochemical Third Generation Glucose Biosensor. Microchimica Acta 2017, 184 (4), 1127–1134. https://doi.org/10.1007/s00604-017-2115-5" in Microchimica Acta (2017),
https://hdl.handle.net/21.15107/rcub_cherry_3104 .

Wiring of glucose oxidase with graphene nanoribbons: an electrochemical third generation glucose biosensor

Mehmeti, Eda; Stanković, Dalibor; Chaiyo, Sudkate; Zavašnik, Janez; Zagar, Kristina; Kalcher, Kurt

(Springer Wien, Wien, 2017)

TY  - JOUR
AU  - Mehmeti, Eda
AU  - Stanković, Dalibor
AU  - Chaiyo, Sudkate
AU  - Zavašnik, Janez
AU  - Zagar, Kristina
AU  - Kalcher, Kurt
PY  - 2017
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2438
AB  - A reagentless third generation electrochemical glucose biosensor was fabricated based on wiring the template enzyme glucose oxidase (GOx) with graphene nanoribbons (GN) in order to create direct electron transfer between the co-factor (flavin adenine dinucleotide, FAD) and the electrode. The strategy involved: (i) isolation of the apo-enzyme by separating it from its co-enzyme; (ii) preparation of graphene nanoribbons (GN) by oxidative unzipping of multi-walled carbon nanotubes; (iii) adsorptive immobilization of GNs on the surface of a screen printed carbon electrode (SPCE); (iv) covalent attachment of FAD to the nanoribbons; (v) recombination of the apo-enzyme with the covalently bound FAD to the holoenzyme; and (vi) stabilization of the bio-layer with a thin membrane of Nafion. The biosensor (referred to as GN/FAD/apo-GOx/Nafion/SPCE) is operated at a potential of +0.475 V vs Ag/AgCl/{3 M KCl} in flow-injection mode with an oxygen-free phosphate buffer (pH 7.5) acting as a carrier. The signals are linearly proportional to the concentration of glucose in the range from 50 to 2000 mgai...L-1 with a detection limit of 20 mgai...L-1. The repeatability (10 measurements, at 1000 mgai...L-1 glucose) is +/- 1.4% and the reproducibility (5 sensors, 1000 mgai...L-1 glucose) is +/- 1.8%. The biosensor was applied to the determination of glucose in human serum.
PB  - Springer Wien, Wien
T2  - Microchimica Acta
T1  - Wiring of glucose oxidase with graphene nanoribbons: an electrochemical third generation glucose biosensor
VL  - 184
IS  - 4
SP  - 1127
EP  - 1134
DO  - 10.1007/s00604-017-2115-5
ER  - 
@article{
author = "Mehmeti, Eda and Stanković, Dalibor and Chaiyo, Sudkate and Zavašnik, Janez and Zagar, Kristina and Kalcher, Kurt",
year = "2017",
abstract = "A reagentless third generation electrochemical glucose biosensor was fabricated based on wiring the template enzyme glucose oxidase (GOx) with graphene nanoribbons (GN) in order to create direct electron transfer between the co-factor (flavin adenine dinucleotide, FAD) and the electrode. The strategy involved: (i) isolation of the apo-enzyme by separating it from its co-enzyme; (ii) preparation of graphene nanoribbons (GN) by oxidative unzipping of multi-walled carbon nanotubes; (iii) adsorptive immobilization of GNs on the surface of a screen printed carbon electrode (SPCE); (iv) covalent attachment of FAD to the nanoribbons; (v) recombination of the apo-enzyme with the covalently bound FAD to the holoenzyme; and (vi) stabilization of the bio-layer with a thin membrane of Nafion. The biosensor (referred to as GN/FAD/apo-GOx/Nafion/SPCE) is operated at a potential of +0.475 V vs Ag/AgCl/{3 M KCl} in flow-injection mode with an oxygen-free phosphate buffer (pH 7.5) acting as a carrier. The signals are linearly proportional to the concentration of glucose in the range from 50 to 2000 mgai...L-1 with a detection limit of 20 mgai...L-1. The repeatability (10 measurements, at 1000 mgai...L-1 glucose) is +/- 1.4% and the reproducibility (5 sensors, 1000 mgai...L-1 glucose) is +/- 1.8%. The biosensor was applied to the determination of glucose in human serum.",
publisher = "Springer Wien, Wien",
journal = "Microchimica Acta",
title = "Wiring of glucose oxidase with graphene nanoribbons: an electrochemical third generation glucose biosensor",
volume = "184",
number = "4",
pages = "1127-1134",
doi = "10.1007/s00604-017-2115-5"
}
Mehmeti, E., Stanković, D., Chaiyo, S., Zavašnik, J., Zagar, K.,& Kalcher, K.. (2017). Wiring of glucose oxidase with graphene nanoribbons: an electrochemical third generation glucose biosensor. in Microchimica Acta
Springer Wien, Wien., 184(4), 1127-1134.
https://doi.org/10.1007/s00604-017-2115-5
Mehmeti E, Stanković D, Chaiyo S, Zavašnik J, Zagar K, Kalcher K. Wiring of glucose oxidase with graphene nanoribbons: an electrochemical third generation glucose biosensor. in Microchimica Acta. 2017;184(4):1127-1134.
doi:10.1007/s00604-017-2115-5 .
Mehmeti, Eda, Stanković, Dalibor, Chaiyo, Sudkate, Zavašnik, Janez, Zagar, Kristina, Kalcher, Kurt, "Wiring of glucose oxidase with graphene nanoribbons: an electrochemical third generation glucose biosensor" in Microchimica Acta, 184, no. 4 (2017):1127-1134,
https://doi.org/10.1007/s00604-017-2115-5 . .
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Manganese dioxide-modified carbon paste electrode for voltammetric determination of riboflavin

Mehmeti, Eda; Stanković, Dalibor; Chaiyo, Sudkate; Šovrc, Ľubomír; Kalcher, Kurt

(Springer Wien, Wien, 2016)

TY  - JOUR
AU  - Mehmeti, Eda
AU  - Stanković, Dalibor
AU  - Chaiyo, Sudkate
AU  - Šovrc, Ľubomír
AU  - Kalcher, Kurt
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1926
AB  - A carbon paste electrode bulk was modified with MnO2 and investigated for use as an electrochemical sensor for riboflavin (vitamin B-2) using differential pulse voltammetry (DPV). Riboflavin displays a well expressed oxidation peak at -0.15 V (versus Ag/AgCl) in solutions with a pH value of 2. Effects of pH value, pulse amplitude and pulse time were optimized by employing DPV. The signals obtained are linearly related to the concentrations of riboflavin in the range from 0.02 to 9 mu M. Other features include a 15 nM detection limit, and good reproducibility (+/- 3 %) and repeatability (+/- 2 %). Interferences by common compounds were tested, and the method was successfully applied to the determination of riboflavin in pharmaceutical formulations where is gave recoveries in the range from 95 to 97 %.
PB  - Springer Wien, Wien
T2  - Microchimica Acta
T1  - Manganese dioxide-modified carbon paste electrode for voltammetric determination of riboflavin
VL  - 183
IS  - 5
SP  - 1619
EP  - 1624
DO  - 10.1007/s00604-016-1789-4
ER  - 
@article{
author = "Mehmeti, Eda and Stanković, Dalibor and Chaiyo, Sudkate and Šovrc, Ľubomír and Kalcher, Kurt",
year = "2016",
abstract = "A carbon paste electrode bulk was modified with MnO2 and investigated for use as an electrochemical sensor for riboflavin (vitamin B-2) using differential pulse voltammetry (DPV). Riboflavin displays a well expressed oxidation peak at -0.15 V (versus Ag/AgCl) in solutions with a pH value of 2. Effects of pH value, pulse amplitude and pulse time were optimized by employing DPV. The signals obtained are linearly related to the concentrations of riboflavin in the range from 0.02 to 9 mu M. Other features include a 15 nM detection limit, and good reproducibility (+/- 3 %) and repeatability (+/- 2 %). Interferences by common compounds were tested, and the method was successfully applied to the determination of riboflavin in pharmaceutical formulations where is gave recoveries in the range from 95 to 97 %.",
publisher = "Springer Wien, Wien",
journal = "Microchimica Acta",
title = "Manganese dioxide-modified carbon paste electrode for voltammetric determination of riboflavin",
volume = "183",
number = "5",
pages = "1619-1624",
doi = "10.1007/s00604-016-1789-4"
}
Mehmeti, E., Stanković, D., Chaiyo, S., Šovrc, Ľ.,& Kalcher, K.. (2016). Manganese dioxide-modified carbon paste electrode for voltammetric determination of riboflavin. in Microchimica Acta
Springer Wien, Wien., 183(5), 1619-1624.
https://doi.org/10.1007/s00604-016-1789-4
Mehmeti E, Stanković D, Chaiyo S, Šovrc Ľ, Kalcher K. Manganese dioxide-modified carbon paste electrode for voltammetric determination of riboflavin. in Microchimica Acta. 2016;183(5):1619-1624.
doi:10.1007/s00604-016-1789-4 .
Mehmeti, Eda, Stanković, Dalibor, Chaiyo, Sudkate, Šovrc, Ľubomír, Kalcher, Kurt, "Manganese dioxide-modified carbon paste electrode for voltammetric determination of riboflavin" in Microchimica Acta, 183, no. 5 (2016):1619-1624,
https://doi.org/10.1007/s00604-016-1789-4 . .
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Determination of nitrite in tap water: A comparative study between cerium, titanium and selenium dioxide doped reduced graphene oxide modified glassy carbon electrodes

Stanković, Dalibor; Mehmeti, Eda; Zavašnik, Janez; Kalcher, Kurt

(Elsevier Science Sa, Lausanne, 2016)

TY  - JOUR
AU  - Stanković, Dalibor
AU  - Mehmeti, Eda
AU  - Zavašnik, Janez
AU  - Kalcher, Kurt
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2298
AB  - In this work, a comparative study between three different novel synthesized materials, cerium, titanium and selenium dioxide doped reduced graphene oxide, was done toward detection of nitrite in tap water. It was found that best response and analytical performance were achieved with acerium dioxide reduced graphene oxide modified glassy carbon electrode. The materials were synthesized and characterized with transmission electron microscopy (TEM), electrochemical impedance spectroscopy and UV-vis spectroscopy. The prepared electrode has a wide linear range from 0.7 to 385 mu M witha detection of 0.18 mu M using amperometric detection. Various parameters were optimized and the sensor was successfully applied for the nitrite ion quantification in tap water samples. Inclusion of different dopants in the graphene structure for novel materials to modify solid electrodes was found to enhance the catalytic effect toward nitrite detection. (C) 2016 Elsevier B.V. All Rights reserved.
PB  - Elsevier Science Sa, Lausanne
T2  - Sensors and Actuators B: Chemical
T1  - Determination of nitrite in tap water: A comparative study between cerium, titanium and selenium dioxide doped reduced graphene oxide modified glassy carbon electrodes
VL  - 236
SP  - 311
EP  - 317
DO  - 10.1016/j.snb.2016.06.018
ER  - 
@article{
author = "Stanković, Dalibor and Mehmeti, Eda and Zavašnik, Janez and Kalcher, Kurt",
year = "2016",
abstract = "In this work, a comparative study between three different novel synthesized materials, cerium, titanium and selenium dioxide doped reduced graphene oxide, was done toward detection of nitrite in tap water. It was found that best response and analytical performance were achieved with acerium dioxide reduced graphene oxide modified glassy carbon electrode. The materials were synthesized and characterized with transmission electron microscopy (TEM), electrochemical impedance spectroscopy and UV-vis spectroscopy. The prepared electrode has a wide linear range from 0.7 to 385 mu M witha detection of 0.18 mu M using amperometric detection. Various parameters were optimized and the sensor was successfully applied for the nitrite ion quantification in tap water samples. Inclusion of different dopants in the graphene structure for novel materials to modify solid electrodes was found to enhance the catalytic effect toward nitrite detection. (C) 2016 Elsevier B.V. All Rights reserved.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Sensors and Actuators B: Chemical",
title = "Determination of nitrite in tap water: A comparative study between cerium, titanium and selenium dioxide doped reduced graphene oxide modified glassy carbon electrodes",
volume = "236",
pages = "311-317",
doi = "10.1016/j.snb.2016.06.018"
}
Stanković, D., Mehmeti, E., Zavašnik, J.,& Kalcher, K.. (2016). Determination of nitrite in tap water: A comparative study between cerium, titanium and selenium dioxide doped reduced graphene oxide modified glassy carbon electrodes. in Sensors and Actuators B: Chemical
Elsevier Science Sa, Lausanne., 236, 311-317.
https://doi.org/10.1016/j.snb.2016.06.018
Stanković D, Mehmeti E, Zavašnik J, Kalcher K. Determination of nitrite in tap water: A comparative study between cerium, titanium and selenium dioxide doped reduced graphene oxide modified glassy carbon electrodes. in Sensors and Actuators B: Chemical. 2016;236:311-317.
doi:10.1016/j.snb.2016.06.018 .
Stanković, Dalibor, Mehmeti, Eda, Zavašnik, Janez, Kalcher, Kurt, "Determination of nitrite in tap water: A comparative study between cerium, titanium and selenium dioxide doped reduced graphene oxide modified glassy carbon electrodes" in Sensors and Actuators B: Chemical, 236 (2016):311-317,
https://doi.org/10.1016/j.snb.2016.06.018 . .
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