Aristotle University of Thessaloniki

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Aristotle University of Thessaloniki

Authors

Publications

Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA

Zianna, Ariadni; Šumar-Ristović, Maja; Psomas, George; Hatzidimitriou, Antonis; Coutouli-Argyropoulou, Evdoxia; Lalia-Kantouri, Maria

(Taylor & Francis Ltd, Abingdon, 2015) 

TY  - JOUR
AU  - Zianna, Ariadni
AU  - Šumar-Ristović, Maja
AU  - Psomas, George
AU  - Hatzidimitriou, Antonis
AU  - Coutouli-Argyropoulou, Evdoxia
AU  - Lalia-Kantouri, Maria
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2004
AB  - Five Cd( II) complexes with the anion of 5- NO2- salicylaldehydeH ( 5- NO2- saloH) in the absence or presence of the alpha-diimine 1,10- phenanthroline ( phen), 2,2'- dipyridylamine ( dpamH), 2,2'- dipyridine ( bipy), or 2,9- dimethyl- 1,10- phenanthroline ( neoc) were synthesized and characterized as [Cd(5- NO2- salo)(2)(CH3OH)(2)] (1), [Cd(5-NO2- salo)(2)( phen)] center dot 2CH3OH center dot H2O (2), [Cd(5- NO2- salo) 2( dpam.)] (3), [Cd-3(5-NO2- salo)(6)(bipy)(2)] (4), and [ Cd(5-NO2-salo)(neoc)(NO3)](2) (5). Based on spectroscopic results ( IR, UV, NMR), elemental analysis and conductivity measurements an octahedral geometry around cadmium metal ion is suggested, with the 5- NO2- salicylaldehyde ligand having different coordination modes. The structures determined by X-ray crystallography verified neutral mononuclear 1-3 and trinuclear 4. Simultaneous TG/DTG-DTA technique was used to analyze the thermal behavior of 1, 2, and 3. The complexes bind tightly to calf-thymus DNA mainly by intercalation, as concluded by DNA viscosity measurements and exhibit significant displacement of EB from the EB- DNA complex.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA
VL  - 68
IS  - 24
SP  - 4444
EP  - 4463
DO  - 10.1080/00958972.2015.1101075
ER  - 
@article{
author = "Zianna, Ariadni and Šumar-Ristović, Maja and Psomas, George and Hatzidimitriou, Antonis and Coutouli-Argyropoulou, Evdoxia and Lalia-Kantouri, Maria",
year = "2015",
abstract = "Five Cd( II) complexes with the anion of 5- NO2- salicylaldehydeH ( 5- NO2- saloH) in the absence or presence of the alpha-diimine 1,10- phenanthroline ( phen), 2,2'- dipyridylamine ( dpamH), 2,2'- dipyridine ( bipy), or 2,9- dimethyl- 1,10- phenanthroline ( neoc) were synthesized and characterized as [Cd(5- NO2- salo)(2)(CH3OH)(2)] (1), [Cd(5-NO2- salo)(2)( phen)] center dot 2CH3OH center dot H2O (2), [Cd(5- NO2- salo) 2( dpam.)] (3), [Cd-3(5-NO2- salo)(6)(bipy)(2)] (4), and [ Cd(5-NO2-salo)(neoc)(NO3)](2) (5). Based on spectroscopic results ( IR, UV, NMR), elemental analysis and conductivity measurements an octahedral geometry around cadmium metal ion is suggested, with the 5- NO2- salicylaldehyde ligand having different coordination modes. The structures determined by X-ray crystallography verified neutral mononuclear 1-3 and trinuclear 4. Simultaneous TG/DTG-DTA technique was used to analyze the thermal behavior of 1, 2, and 3. The complexes bind tightly to calf-thymus DNA mainly by intercalation, as concluded by DNA viscosity measurements and exhibit significant displacement of EB from the EB- DNA complex.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA",
volume = "68",
number = "24",
pages = "4444-4463",
doi = "10.1080/00958972.2015.1101075"
}
Zianna, A., Šumar-Ristović, M., Psomas, G., Hatzidimitriou, A., Coutouli-Argyropoulou, E.,& Lalia-Kantouri, M.. (2015). Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 68(24), 4444-4463.
https://doi.org/10.1080/00958972.2015.1101075
Zianna A, Šumar-Ristović M, Psomas G, Hatzidimitriou A, Coutouli-Argyropoulou E, Lalia-Kantouri M. Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA. in Journal of Coordination Chemistry. 2015;68(24):4444-4463.
doi:10.1080/00958972.2015.1101075 .
Zianna, Ariadni, Šumar-Ristović, Maja, Psomas, George, Hatzidimitriou, Antonis, Coutouli-Argyropoulou, Evdoxia, Lalia-Kantouri, Maria, "Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA" in Journal of Coordination Chemistry, 68, no. 24 (2015):4444-4463,
https://doi.org/10.1080/00958972.2015.1101075 . .
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Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA

Zianna, Ariadni; Šumar-Ristović, Maja; Psomas, George; Hatzidimitriou, Antonis; Coutouli-Argyropoulou, Evdoxia; Lalia-Kantouri, Maria

(Taylor & Francis Ltd, Abingdon, 2015) 

TY  - JOUR
AU  - Zianna, Ariadni
AU  - Šumar-Ristović, Maja
AU  - Psomas, George
AU  - Hatzidimitriou, Antonis
AU  - Coutouli-Argyropoulou, Evdoxia
AU  - Lalia-Kantouri, Maria
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3350
AB  - Five Cd( II) complexes with the anion of 5- NO2- salicylaldehydeH ( 5- NO2- saloH) in the absence or presence of the alpha-diimine 1,10- phenanthroline ( phen), 2,2'- dipyridylamine ( dpamH), 2,2'- dipyridine ( bipy), or 2,9- dimethyl- 1,10- phenanthroline ( neoc) were synthesized and characterized as [Cd(5- NO2- salo)(2)(CH3OH)(2)] (1), [Cd(5-NO2- salo)(2)( phen)] center dot 2CH3OH center dot H2O (2), [Cd(5- NO2- salo) 2( dpam.)] (3), [Cd-3(5-NO2- salo)(6)(bipy)(2)] (4), and [ Cd(5-NO2-salo)(neoc)(NO3)](2) (5). Based on spectroscopic results ( IR, UV, NMR), elemental analysis and conductivity measurements an octahedral geometry around cadmium metal ion is suggested, with the 5- NO2- salicylaldehyde ligand having different coordination modes. The structures determined by X-ray crystallography verified neutral mononuclear 1-3 and trinuclear 4. Simultaneous TG/DTG-DTA technique was used to analyze the thermal behavior of 1, 2, and 3. The complexes bind tightly to calf-thymus DNA mainly by intercalation, as concluded by DNA viscosity measurements and exhibit significant displacement of EB from the EB- DNA complex.
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA
VL  - 68
IS  - 24
SP  - 4444
EP  - 4463
DO  - 10.1080/00958972.2015.1101075
ER  - 
@article{
author = "Zianna, Ariadni and Šumar-Ristović, Maja and Psomas, George and Hatzidimitriou, Antonis and Coutouli-Argyropoulou, Evdoxia and Lalia-Kantouri, Maria",
year = "2015",
abstract = "Five Cd( II) complexes with the anion of 5- NO2- salicylaldehydeH ( 5- NO2- saloH) in the absence or presence of the alpha-diimine 1,10- phenanthroline ( phen), 2,2'- dipyridylamine ( dpamH), 2,2'- dipyridine ( bipy), or 2,9- dimethyl- 1,10- phenanthroline ( neoc) were synthesized and characterized as [Cd(5- NO2- salo)(2)(CH3OH)(2)] (1), [Cd(5-NO2- salo)(2)( phen)] center dot 2CH3OH center dot H2O (2), [Cd(5- NO2- salo) 2( dpam.)] (3), [Cd-3(5-NO2- salo)(6)(bipy)(2)] (4), and [ Cd(5-NO2-salo)(neoc)(NO3)](2) (5). Based on spectroscopic results ( IR, UV, NMR), elemental analysis and conductivity measurements an octahedral geometry around cadmium metal ion is suggested, with the 5- NO2- salicylaldehyde ligand having different coordination modes. The structures determined by X-ray crystallography verified neutral mononuclear 1-3 and trinuclear 4. Simultaneous TG/DTG-DTA technique was used to analyze the thermal behavior of 1, 2, and 3. The complexes bind tightly to calf-thymus DNA mainly by intercalation, as concluded by DNA viscosity measurements and exhibit significant displacement of EB from the EB- DNA complex.",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA",
volume = "68",
number = "24",
pages = "4444-4463",
doi = "10.1080/00958972.2015.1101075"
}
Zianna, A., Šumar-Ristović, M., Psomas, G., Hatzidimitriou, A., Coutouli-Argyropoulou, E.,& Lalia-Kantouri, M.. (2015). Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon., 68(24), 4444-4463.
https://doi.org/10.1080/00958972.2015.1101075
Zianna A, Šumar-Ristović M, Psomas G, Hatzidimitriou A, Coutouli-Argyropoulou E, Lalia-Kantouri M. Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA. in Journal of Coordination Chemistry. 2015;68(24):4444-4463.
doi:10.1080/00958972.2015.1101075 .
Zianna, Ariadni, Šumar-Ristović, Maja, Psomas, George, Hatzidimitriou, Antonis, Coutouli-Argyropoulou, Evdoxia, Lalia-Kantouri, Maria, "Cadmium(II) complexes of 5-nitro-salicylaldehyde and -diimines: synthesis, structure and interaction with calf-thymus DNA" in Journal of Coordination Chemistry, 68, no. 24 (2015):4444-4463,
https://doi.org/10.1080/00958972.2015.1101075 . .
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12
18
18

Supplementary data for article: Zianna, A.; Sumar Ristovic, M.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Nitro-Salicylaldehyde and α -Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA. Journal of Coordination Chemistry 2015, 68 (24), 4444–4463. https://doi.org/10.1080/00958972.2015.1101075

Zianna, Ariadni; Šumar-Ristović, Maja; Psomas, George; Hatzidimitriou, Antonis; Coutouli-Argyropoulou, Evdoxia; Lalia-Kantouri, Maria

(Taylor & Francis Ltd, Abingdon, 2015) 

TY  - DATA
AU  - Zianna, Ariadni
AU  - Šumar-Ristović, Maja
AU  - Psomas, George
AU  - Hatzidimitriou, Antonis
AU  - Coutouli-Argyropoulou, Evdoxia
AU  - Lalia-Kantouri, Maria
PY  - 2015
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3351
PB  - Taylor & Francis Ltd, Abingdon
T2  - Journal of Coordination Chemistry
T1  - Supplementary data for article: Zianna, A.; Sumar Ristovic, M.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Nitro-Salicylaldehyde and α -Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA. Journal of Coordination Chemistry 2015, 68 (24), 4444–4463. https://doi.org/10.1080/00958972.2015.1101075
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3351
ER  - 
@misc{
author = "Zianna, Ariadni and Šumar-Ristović, Maja and Psomas, George and Hatzidimitriou, Antonis and Coutouli-Argyropoulou, Evdoxia and Lalia-Kantouri, Maria",
year = "2015",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Journal of Coordination Chemistry",
title = "Supplementary data for article: Zianna, A.; Sumar Ristovic, M.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Nitro-Salicylaldehyde and α -Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA. Journal of Coordination Chemistry 2015, 68 (24), 4444–4463. https://doi.org/10.1080/00958972.2015.1101075",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3351"
}
Zianna, A., Šumar-Ristović, M., Psomas, G., Hatzidimitriou, A., Coutouli-Argyropoulou, E.,& Lalia-Kantouri, M.. (2015). Supplementary data for article: Zianna, A.; Sumar Ristovic, M.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Nitro-Salicylaldehyde and α -Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA. Journal of Coordination Chemistry 2015, 68 (24), 4444–4463. https://doi.org/10.1080/00958972.2015.1101075. in Journal of Coordination Chemistry
Taylor & Francis Ltd, Abingdon..
https://hdl.handle.net/21.15107/rcub_cherry_3351
Zianna A, Šumar-Ristović M, Psomas G, Hatzidimitriou A, Coutouli-Argyropoulou E, Lalia-Kantouri M. Supplementary data for article: Zianna, A.; Sumar Ristovic, M.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Nitro-Salicylaldehyde and α -Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA. Journal of Coordination Chemistry 2015, 68 (24), 4444–4463. https://doi.org/10.1080/00958972.2015.1101075. in Journal of Coordination Chemistry. 2015;.
https://hdl.handle.net/21.15107/rcub_cherry_3351 .
Zianna, Ariadni, Šumar-Ristović, Maja, Psomas, George, Hatzidimitriou, Antonis, Coutouli-Argyropoulou, Evdoxia, Lalia-Kantouri, Maria, "Supplementary data for article: Zianna, A.; Sumar Ristovic, M.; Psomas, G.; Hatzidimitriou, A.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Cadmium(II) Complexes of 5-Nitro-Salicylaldehyde and α -Diimines: Synthesis, Structure and Interaction with Calf-Thymus DNA. Journal of Coordination Chemistry 2015, 68 (24), 4444–4463. https://doi.org/10.1080/00958972.2015.1101075" in Journal of Coordination Chemistry (2015),
https://hdl.handle.net/21.15107/rcub_cherry_3351 .