All Publications

Link to this page

Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea

Milićević, Tijana; Herceg Romanić, Snježana; Popović, Aleksandar; Mustać, Bosiljka; Đinović-Stojanović, Jasna; Jovanović, Gordana; Relić, Dubravka

(Elsevier, 2022)

TY  - JOUR
AU  - Milićević, Tijana
AU  - Herceg Romanić, Snježana
AU  - Popović, Aleksandar
AU  - Mustać, Bosiljka
AU  - Đinović-Stojanović, Jasna
AU  - Jovanović, Gordana
AU  - Relić, Dubravka
PY  - 2022
UR  - https://www.sciencedirect.com/science/article/pii/S0045653521025406
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4664
AB  - Benefits and risks of the fish consumption should be assessed to balance the ingestion of healthy omega-3 fatty acids and adverse chemicals. Persistent organic pollutants-POPs (organochlorine pesticides-OCPs and polychlorinated biphenyls-PCB), macro- and micro-elements and fatty acid contents were determined in six fish species from the Adriatic Sea to assess health risks for consumers (worst-case scenario, diseases development risks and benefit-risk). 16 element, 24 POPs and 14 fatty acid contents were determined in six pelagic species which can be used in human diet. Element concentrations were determined by inductively coupled plasma mass spectrometry (ICP-MS), POPs by high-resolution gas chromatography and fatty acid content by gas–liquid chromatography. Diet based on chub mackerel and round sardinella showed lower daily intake (DI) of POPs and highest DI of essential omega-3 fatty acids than other investigated species. Lower ingestion of toxic elements can be observed by consuming anchovy and round sardinella. Based on POP concentrations, there was not observed non-carcinogenic (HI) nor carcinogenic (CR) risks for consumers. Based on element concentrations, there was low HI (0.1 ≥ HI ≥ 1), while the maximum HIs and outlier values (horse mackerel and anchovy samples) implied the presence of HI (HI > 1). The most significant contributor to total non-carcinogenic and carcinogenic risks was inorganic arsenic (inorganic As). Acceptable CR for consumers was assessed, but maximum CR for consumers of horse mackerel and anchovy (CR ≥ 1 × 10–6) showed adverse effects on human health. There were low HIs for developing cardiovascular, nervous, and reproductive diseases, and maximum HIs were higher than 1. Acceptable (1 × 10−4≥CR ≥ 1 × 10−6) risks were observed for developing cancer of nervous system and reproductive organs. Among investigated fish samples, those with higher ƩBR (benefit-risks) and BR for arsenic (As) than median value have a higher risk than benefits in the human diet.
PB  - Elsevier
T2  - Chemosphere
T1  - Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea
VL  - 287
SP  - 132068
DO  - 10.1016/j.chemosphere.2021.132068
ER  - 
@article{
author = "Milićević, Tijana and Herceg Romanić, Snježana and Popović, Aleksandar and Mustać, Bosiljka and Đinović-Stojanović, Jasna and Jovanović, Gordana and Relić, Dubravka",
year = "2022",
abstract = "Benefits and risks of the fish consumption should be assessed to balance the ingestion of healthy omega-3 fatty acids and adverse chemicals. Persistent organic pollutants-POPs (organochlorine pesticides-OCPs and polychlorinated biphenyls-PCB), macro- and micro-elements and fatty acid contents were determined in six fish species from the Adriatic Sea to assess health risks for consumers (worst-case scenario, diseases development risks and benefit-risk). 16 element, 24 POPs and 14 fatty acid contents were determined in six pelagic species which can be used in human diet. Element concentrations were determined by inductively coupled plasma mass spectrometry (ICP-MS), POPs by high-resolution gas chromatography and fatty acid content by gas–liquid chromatography. Diet based on chub mackerel and round sardinella showed lower daily intake (DI) of POPs and highest DI of essential omega-3 fatty acids than other investigated species. Lower ingestion of toxic elements can be observed by consuming anchovy and round sardinella. Based on POP concentrations, there was not observed non-carcinogenic (HI) nor carcinogenic (CR) risks for consumers. Based on element concentrations, there was low HI (0.1 ≥ HI ≥ 1), while the maximum HIs and outlier values (horse mackerel and anchovy samples) implied the presence of HI (HI > 1). The most significant contributor to total non-carcinogenic and carcinogenic risks was inorganic arsenic (inorganic As). Acceptable CR for consumers was assessed, but maximum CR for consumers of horse mackerel and anchovy (CR ≥ 1 × 10–6) showed adverse effects on human health. There were low HIs for developing cardiovascular, nervous, and reproductive diseases, and maximum HIs were higher than 1. Acceptable (1 × 10−4≥CR ≥ 1 × 10−6) risks were observed for developing cancer of nervous system and reproductive organs. Among investigated fish samples, those with higher ƩBR (benefit-risks) and BR for arsenic (As) than median value have a higher risk than benefits in the human diet.",
publisher = "Elsevier",
journal = "Chemosphere",
title = "Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea",
volume = "287",
pages = "132068",
doi = "10.1016/j.chemosphere.2021.132068"
}
Milićević, T., Herceg Romanić, S., Popović, A., Mustać, B., Đinović-Stojanović, J., Jovanović, G.,& Relić, D.. (2022). Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea. in Chemosphere
Elsevier., 287, 132068.
https://doi.org/10.1016/j.chemosphere.2021.132068
Milićević T, Herceg Romanić S, Popović A, Mustać B, Đinović-Stojanović J, Jovanović G, Relić D. Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea. in Chemosphere. 2022;287:132068.
doi:10.1016/j.chemosphere.2021.132068 .
Milićević, Tijana, Herceg Romanić, Snježana, Popović, Aleksandar, Mustać, Bosiljka, Đinović-Stojanović, Jasna, Jovanović, Gordana, Relić, Dubravka, "Human health risks and benefits assessment based on OCPs, PCBs, toxic elements and fatty acids in the pelagic fish species from the Adriatic Sea" in Chemosphere, 287 (2022):132068,
https://doi.org/10.1016/j.chemosphere.2021.132068 . .

Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.

Milićević, Tijana; Herceg Romanić, Snježana; Popović, Aleksandar; Mustać, Bosiljka; Đinović-Stojanović, Jasna; Jovanović, Gordana; Relić, Dubravka

(Elsevier, 2022)

TY  - DATA
AU  - Milićević, Tijana
AU  - Herceg Romanić, Snježana
AU  - Popović, Aleksandar
AU  - Mustać, Bosiljka
AU  - Đinović-Stojanović, Jasna
AU  - Jovanović, Gordana
AU  - Relić, Dubravka
PY  - 2022
UR  - https://www.sciencedirect.com/science/article/pii/S0045653521025406
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4665
PB  - Elsevier
T2  - Chemosphere
T1  - Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.
ER  - 
@misc{
author = "Milićević, Tijana and Herceg Romanić, Snježana and Popović, Aleksandar and Mustać, Bosiljka and Đinović-Stojanović, Jasna and Jovanović, Gordana and Relić, Dubravka",
year = "2022",
publisher = "Elsevier",
journal = "Chemosphere",
title = "Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068."
}
Milićević, T., Herceg Romanić, S., Popović, A., Mustać, B., Đinović-Stojanović, J., Jovanović, G.,& Relić, D.. (2022). Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.. in Chemosphere
Elsevier..
Milićević T, Herceg Romanić S, Popović A, Mustać B, Đinović-Stojanović J, Jovanović G, Relić D. Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068.. in Chemosphere. 2022;..
Milićević, Tijana, Herceg Romanić, Snježana, Popović, Aleksandar, Mustać, Bosiljka, Đinović-Stojanović, Jasna, Jovanović, Gordana, Relić, Dubravka, "Supplementary data for the article: Milićević, T.; Romanić, S. H.; Popović, A.; Mustać, B.; Đinović-Stojanović, J.; Jovanović, G.; Relić, D. Human Health Risks and Benefits Assessment Based on OCPs, PCBs, Toxic Elements and Fatty Acids in the Pelagic Fish Species from the Adriatic Sea. Chemosphere 2022, 287, 132068. https://doi.org/10.1016/j.chemosphere.2021.132068." in Chemosphere (2022).

Izolovanje i karakterizacija triterpena cikloartanskog tipa iz biljke Euphorbia palustris

Lekić, Stefan

(2021)

TY  - THES
AU  - Lekić, Stefan
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4732
AB  - Biljna vrsta Euphorbia palustris pripada rodu Euphorbia iz familije Euphorbiaceae. U
oviru ovog završnog rada iz biljne vrste E. palustris izolovan je, a potom i okarakterisan
triterpen cikloartanskog tipa. Izolovanje i ispitivanje biloške aktivnosti
triterpena iz lateksa navedene biljne vrste može doprineti primeni ovih jedinjena u
medicinske svrhe. Pokazalo se da mnogi diterpeni i triterpeni izolovani iz lateksa
biljnih vrsta Euphorbia pokazaju značajne biloške aktivnosti, kao što su antivirusne,
anti-HIV, antibakterijske, antitumorne itd.
T1  - Izolovanje i karakterizacija triterpena
cikloartanskog tipa iz biljke Euphorbia palustris
SP  - 1
EP  - 20
ER  - 
@misc{
author = "Lekić, Stefan",
year = "2021",
abstract = "Biljna vrsta Euphorbia palustris pripada rodu Euphorbia iz familije Euphorbiaceae. U
oviru ovog završnog rada iz biljne vrste E. palustris izolovan je, a potom i okarakterisan
triterpen cikloartanskog tipa. Izolovanje i ispitivanje biloške aktivnosti
triterpena iz lateksa navedene biljne vrste može doprineti primeni ovih jedinjena u
medicinske svrhe. Pokazalo se da mnogi diterpeni i triterpeni izolovani iz lateksa
biljnih vrsta Euphorbia pokazaju značajne biloške aktivnosti, kao što su antivirusne,
anti-HIV, antibakterijske, antitumorne itd.",
title = "Izolovanje i karakterizacija triterpena
cikloartanskog tipa iz biljke Euphorbia palustris",
pages = "1-20"
}
Lekić, S.. (2021). Izolovanje i karakterizacija triterpena
cikloartanskog tipa iz biljke Euphorbia palustris. , 1-20.
Lekić S. Izolovanje i karakterizacija triterpena
cikloartanskog tipa iz biljke Euphorbia palustris. 2021;:1-20..
Lekić, Stefan, "Izolovanje i karakterizacija triterpena
cikloartanskog tipa iz biljke Euphorbia palustris" (2021):1-20.

Razvoj GC MS metoda zasnovanih na mikroekstrakciji na pakovanom sorbentu u određivanju analoga nervnih otrova za potrebe terenskih analiza

Ćorović, Senad

(2021)

TY  - THES
AU  - Ćorović, Senad
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4731
AB  - Cilj ovog rada je određivanje analoga nervnih otrova u svrhe terenskih analiza zbog čega je
potrebno optimizovati GC MS uslove. U radu su upotrebljena organofosforna jedinjenja, odnosno,
dialkil alkilfosfon ati koji pripadaju 2B klasi jedinjenja pr ema OPCW klasifikaciji. Za terenske
analize je bitno vreme koje protekne od momenta uzorkovanja do momenta analize. Između ostalog,
zbog toga je razvijena mikroekstrakcija na pakovanom sorbentu (MEPS), kao nova metoda koja
omogućava precizno i efikasno uzo rkovanje na terenu sa mogućnošću ručnog injektovanja u GC
MS sistem. U ovom radu je praćeno vreme starenja uzorka na MEPS nosaču od momenta
uzorkovanja do momenta analize do dvadeset prvog dana. Na taj način je ustanovljeno da se ova
tehnika može koristiti za uzorkovanje analoga nervnih otrova u organskim matriksima. Zbog velike
stabilnosti MEPS tehnika se uspešno može koristiti za analize na terenu, ali i za slanje MEPS igle sa
nosačem klasičnim laboratorijama na hemijsku analizu.
T1  - Razvoj GC MS metoda zasnovanih na mikroekstrakciji na pakovanom sorbentu u određivanju analoga nervnih otrova za potrebe terenskih analiza
SP  - 7
EP  - 40
ER  - 
@misc{
author = "Ćorović, Senad",
year = "2021",
abstract = "Cilj ovog rada je određivanje analoga nervnih otrova u svrhe terenskih analiza zbog čega je
potrebno optimizovati GC MS uslove. U radu su upotrebljena organofosforna jedinjenja, odnosno,
dialkil alkilfosfon ati koji pripadaju 2B klasi jedinjenja pr ema OPCW klasifikaciji. Za terenske
analize je bitno vreme koje protekne od momenta uzorkovanja do momenta analize. Između ostalog,
zbog toga je razvijena mikroekstrakcija na pakovanom sorbentu (MEPS), kao nova metoda koja
omogućava precizno i efikasno uzo rkovanje na terenu sa mogućnošću ručnog injektovanja u GC
MS sistem. U ovom radu je praćeno vreme starenja uzorka na MEPS nosaču od momenta
uzorkovanja do momenta analize do dvadeset prvog dana. Na taj način je ustanovljeno da se ova
tehnika može koristiti za uzorkovanje analoga nervnih otrova u organskim matriksima. Zbog velike
stabilnosti MEPS tehnika se uspešno može koristiti za analize na terenu, ali i za slanje MEPS igle sa
nosačem klasičnim laboratorijama na hemijsku analizu.",
title = "Razvoj GC MS metoda zasnovanih na mikroekstrakciji na pakovanom sorbentu u određivanju analoga nervnih otrova za potrebe terenskih analiza",
pages = "7-40"
}
Ćorović, S.. (2021). Razvoj GC MS metoda zasnovanih na mikroekstrakciji na pakovanom sorbentu u određivanju analoga nervnih otrova za potrebe terenskih analiza. , 7-40.
Ćorović S. Razvoj GC MS metoda zasnovanih na mikroekstrakciji na pakovanom sorbentu u određivanju analoga nervnih otrova za potrebe terenskih analiza. 2021;:7-40..
Ćorović, Senad, "Razvoj GC MS metoda zasnovanih na mikroekstrakciji na pakovanom sorbentu u određivanju analoga nervnih otrova za potrebe terenskih analiza" (2021):7-40.

Automatizacija mikroekstrakcije na pakovanom sorbentu silika gela na CTC PAL GC-MS platformi na primeru dipropil propilfosfonata

Simić, Mihajlo

(2021)

TY  - THES
AU  - Simić, Mihajlo
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4709
AB  - Poslednjih godina se ulažu veliki napori u poboljšanju analitičkih metoda u poboljšanju identifikacije i kvantifikacije organskih jedinjenja u različitim složenim matriksima, pre svega u razblaženim uzorcima malih zapremina. Sve je veća potreba za razvitkom novih analitičkih metoda koje će doprineti istraživanjima na polju uzoraka iz životne sredine. U ovom radu je vršena optimizacija mikroekstrakcije na pakovanom sorbentu u cilju poboljšanja detekcije alkil-fosfonata, analoga hemijskog oružja, u dizelu kao ugljovodoničnom zahtevnom matriksu. Nakon optimizacije mikroekstrakcije urađena je i automatizacija na CTC PAL platformi povezanoj na gasno-hromatografski i maseno-spektrometrijski sistem. Metoda je uspešno automatizovana upotrebom ChemStation i Cycle Editor programa pri čemu je omogućena analiza pojedinačnih, kao i uzastopnih uzoraka korišćenjem sekvence. Zaključeno je da je optimizacijom i automatizacijom metode mikroekstrakcije na pakovanom sorbentu donet korak napred po pitanju zelene analitičke hemije i detekcije hemijskog oružja. Znatno je redukovano vreme pri pripremi i tretiranju uzoraka, smanjeno korišćenje reagenasa i rastvarača, smanjena emisija gasova, tečnih i čvrstih otpadaka, kao i manje potrebne radne snage i energije, sve su faktori koji doprinose upotrebi ove analitičke metode u poređenju sa konvencionalnim tehnikama ekstrakcije. Kombinacija tehnika mikroekstrakcije sa novim ekstraktantima i rastvaračima otvara mogućnosti u poboljšanju postojećih metoda i razvitku novih u cilju redukcije zagađenja životne sredine.
T1  - Automatizacija mikroekstrakcije na pakovanom sorbentu silika gela na CTC PAL GC-MS platformi na primeru dipropil propilfosfonata
SP  - 2
EP  - 27
EP  - 
ER  - 
@misc{
author = "Simić, Mihajlo",
year = "2021",
abstract = "Poslednjih godina se ulažu veliki napori u poboljšanju analitičkih metoda u poboljšanju identifikacije i kvantifikacije organskih jedinjenja u različitim složenim matriksima, pre svega u razblaženim uzorcima malih zapremina. Sve je veća potreba za razvitkom novih analitičkih metoda koje će doprineti istraživanjima na polju uzoraka iz životne sredine. U ovom radu je vršena optimizacija mikroekstrakcije na pakovanom sorbentu u cilju poboljšanja detekcije alkil-fosfonata, analoga hemijskog oružja, u dizelu kao ugljovodoničnom zahtevnom matriksu. Nakon optimizacije mikroekstrakcije urađena je i automatizacija na CTC PAL platformi povezanoj na gasno-hromatografski i maseno-spektrometrijski sistem. Metoda je uspešno automatizovana upotrebom ChemStation i Cycle Editor programa pri čemu je omogućena analiza pojedinačnih, kao i uzastopnih uzoraka korišćenjem sekvence. Zaključeno je da je optimizacijom i automatizacijom metode mikroekstrakcije na pakovanom sorbentu donet korak napred po pitanju zelene analitičke hemije i detekcije hemijskog oružja. Znatno je redukovano vreme pri pripremi i tretiranju uzoraka, smanjeno korišćenje reagenasa i rastvarača, smanjena emisija gasova, tečnih i čvrstih otpadaka, kao i manje potrebne radne snage i energije, sve su faktori koji doprinose upotrebi ove analitičke metode u poređenju sa konvencionalnim tehnikama ekstrakcije. Kombinacija tehnika mikroekstrakcije sa novim ekstraktantima i rastvaračima otvara mogućnosti u poboljšanju postojećih metoda i razvitku novih u cilju redukcije zagađenja životne sredine.",
title = "Automatizacija mikroekstrakcije na pakovanom sorbentu silika gela na CTC PAL GC-MS platformi na primeru dipropil propilfosfonata",
pages = "2-27-"
}
Simić, M.. (2021). Automatizacija mikroekstrakcije na pakovanom sorbentu silika gela na CTC PAL GC-MS platformi na primeru dipropil propilfosfonata. , 2-27.
Simić M. Automatizacija mikroekstrakcije na pakovanom sorbentu silika gela na CTC PAL GC-MS platformi na primeru dipropil propilfosfonata. 2021;:2-27..
Simić, Mihajlo, "Automatizacija mikroekstrakcije na pakovanom sorbentu silika gela na CTC PAL GC-MS platformi na primeru dipropil propilfosfonata" (2021):2-27.

Evaluation of potential human health risks from exposure to volatile organic compounds in contaminated urban groundwater in the Sava river aquifer, Belgrade, Serbia

Bulatović, Sandra; Ilić, Mila V.; Šolević Knudsen, Tatjana; Milić, Jelena; Pucarević, Mira; Jovančićević, Branimir; Vrvić, Miroslav M.

(Springer, 2021)

TY  - JOUR
AU  - Bulatović, Sandra
AU  - Ilić, Mila V.
AU  - Šolević Knudsen, Tatjana
AU  - Milić, Jelena
AU  - Pucarević, Mira
AU  - Jovančićević, Branimir
AU  - Vrvić, Miroslav M.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4753
AB  - The oil pollutant in the Sava River aquifer in the residential area of Belgrade, Serbia was investigated in order to analyze the extent, origin and spatial distribution of the pollution, with the aim to estimate potential human health risks from exposure to the compounds detected. Analytical methods indicated that the dominant compounds in this oil pollutant were gasoline range organic compounds. Benzene, toluene, ethylbenzene and xylenes (BTEX) were identified as compounds of concern and quantified by headspace gas chromatography. The concentrations of benzene measured at all sampling points were higher than the remediation value while the maximum concentrations of BTEX quantified were among the highest concentrations of these compounds reported in the petroleum-contaminated aquifers in the world. The assessment of the human health risks from exposure to BTEX-covered industrial scenario for adult receptors and residential scenario for adult receptors and children. The exposure routes analyzed were dermal contact with and ingestion of contaminated water, considering both cancer and non-cancer effects. The analysis of the lifetime incremental cancer risk indicated the potential for adverse health effects for human exposure at the investigated location, and because of that it was interpreted as an unacceptable risk level or risks of high priority which required immediate consideration for remedial measures at this location. A complete set of mitigation measures was proposed including: groundwater decontamination treatment, installation of filters for tap water, development of the system for monitoring of BTEX in the groundwater and development of the emergency response capacities at this location.
PB  - Springer
T2  - Environmental Geochemistry and Health
T1  - Evaluation of potential human health risks from exposure to volatile organic compounds in contaminated urban groundwater in the Sava river aquifer, Belgrade, Serbia
DO  - 10.1007/s10653-021-01119-2
ER  - 
@article{
author = "Bulatović, Sandra and Ilić, Mila V. and Šolević Knudsen, Tatjana and Milić, Jelena and Pucarević, Mira and Jovančićević, Branimir and Vrvić, Miroslav M.",
year = "2021",
abstract = "The oil pollutant in the Sava River aquifer in the residential area of Belgrade, Serbia was investigated in order to analyze the extent, origin and spatial distribution of the pollution, with the aim to estimate potential human health risks from exposure to the compounds detected. Analytical methods indicated that the dominant compounds in this oil pollutant were gasoline range organic compounds. Benzene, toluene, ethylbenzene and xylenes (BTEX) were identified as compounds of concern and quantified by headspace gas chromatography. The concentrations of benzene measured at all sampling points were higher than the remediation value while the maximum concentrations of BTEX quantified were among the highest concentrations of these compounds reported in the petroleum-contaminated aquifers in the world. The assessment of the human health risks from exposure to BTEX-covered industrial scenario for adult receptors and residential scenario for adult receptors and children. The exposure routes analyzed were dermal contact with and ingestion of contaminated water, considering both cancer and non-cancer effects. The analysis of the lifetime incremental cancer risk indicated the potential for adverse health effects for human exposure at the investigated location, and because of that it was interpreted as an unacceptable risk level or risks of high priority which required immediate consideration for remedial measures at this location. A complete set of mitigation measures was proposed including: groundwater decontamination treatment, installation of filters for tap water, development of the system for monitoring of BTEX in the groundwater and development of the emergency response capacities at this location.",
publisher = "Springer",
journal = "Environmental Geochemistry and Health",
title = "Evaluation of potential human health risks from exposure to volatile organic compounds in contaminated urban groundwater in the Sava river aquifer, Belgrade, Serbia",
doi = "10.1007/s10653-021-01119-2"
}
Bulatović, S., Ilić, M. V., Šolević Knudsen, T., Milić, J., Pucarević, M., Jovančićević, B.,& Vrvić, M. M.. (2021). Evaluation of potential human health risks from exposure to volatile organic compounds in contaminated urban groundwater in the Sava river aquifer, Belgrade, Serbia. in Environmental Geochemistry and Health
Springer..
https://doi.org/10.1007/s10653-021-01119-2
Bulatović S, Ilić MV, Šolević Knudsen T, Milić J, Pucarević M, Jovančićević B, Vrvić MM. Evaluation of potential human health risks from exposure to volatile organic compounds in contaminated urban groundwater in the Sava river aquifer, Belgrade, Serbia. in Environmental Geochemistry and Health. 2021;.
doi:10.1007/s10653-021-01119-2 .
Bulatović, Sandra, Ilić, Mila V., Šolević Knudsen, Tatjana, Milić, Jelena, Pucarević, Mira, Jovančićević, Branimir, Vrvić, Miroslav M., "Evaluation of potential human health risks from exposure to volatile organic compounds in contaminated urban groundwater in the Sava river aquifer, Belgrade, Serbia" in Environmental Geochemistry and Health (2021),
https://doi.org/10.1007/s10653-021-01119-2 . .

Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using Cell-MG hybrid adsorbent

Perendija, Jovana; Veličković, Zlate; Dražević, Ljubinka; Stojiljković, Ivana N.; Milčić, Miloš K.; Milosavljević, Milutin M.; Marinković, Aleksandar; Pavlović, Vladimir B.

(Association for ETRAN Society, 2021)

TY  - JOUR
AU  - Perendija, Jovana
AU  - Veličković, Zlate
AU  - Dražević, Ljubinka
AU  - Stojiljković, Ivana N.
AU  - Milčić, Miloš K.
AU  - Milosavljević, Milutin M.
AU  - Marinković, Aleksandar
AU  - Pavlović, Vladimir B.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4752
AB  - Magnetite (MG) modified cellulose membrane (Cell-MG), obtained by reaction of 3-aminosilane and subsequently with diethylenetriaminepentaacetic acid dianhydride functionalized waste Cell fibers (Cell-NH2 and Cell-DTPA, respectively), and amino-modified diatomite was used for Azoxystrobin and Iprodione removal from water. Cell-MG membrane was structurally and morphologically characterized using FT-IR and FE-SEM techniques. The influences of operational parameters, i.e. pH, contact time, temperature, and the mass of adsorbent on adsorption and kinetics were studied in a batch system. The calculated capacities of 35.32 and 30.16 mg g-1 for Azoxystrobin and Iprodione, respectively, were obtained from non-linear Langmuir model fitting. Weber-Morris model fitting indicates the main contribution of intra-particle diffusion to overall mass transport resistance. Thermodynamic data indicate spontaneous and endothermic adsorption. The reusability of adsorbent and results from wastewater purification showed that Cell-MG could be used as general-purpose adsorbent. The adsorbent/adsorbate surface interaction was considered from the results obtained using density functional theory (DFT) and calculation of molecular electrostatic potential (MEP). Thus, a better understanding of the relation between the adsorption performances and contribution of non-specific and specific interactions to adsorption performances and design of novel adsorbent with improved properties was deduced
PB  - Association for ETRAN Society
T2  - Science of Sintering
T1  - Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using Cell-MG hybrid adsorbent
VL  - 53
IS  - 3
SP  - 355
EP  - 378
DO  - 10.2298/SOS2103355P
ER  - 
@article{
author = "Perendija, Jovana and Veličković, Zlate and Dražević, Ljubinka and Stojiljković, Ivana N. and Milčić, Miloš K. and Milosavljević, Milutin M. and Marinković, Aleksandar and Pavlović, Vladimir B.",
year = "2021",
abstract = "Magnetite (MG) modified cellulose membrane (Cell-MG), obtained by reaction of 3-aminosilane and subsequently with diethylenetriaminepentaacetic acid dianhydride functionalized waste Cell fibers (Cell-NH2 and Cell-DTPA, respectively), and amino-modified diatomite was used for Azoxystrobin and Iprodione removal from water. Cell-MG membrane was structurally and morphologically characterized using FT-IR and FE-SEM techniques. The influences of operational parameters, i.e. pH, contact time, temperature, and the mass of adsorbent on adsorption and kinetics were studied in a batch system. The calculated capacities of 35.32 and 30.16 mg g-1 for Azoxystrobin and Iprodione, respectively, were obtained from non-linear Langmuir model fitting. Weber-Morris model fitting indicates the main contribution of intra-particle diffusion to overall mass transport resistance. Thermodynamic data indicate spontaneous and endothermic adsorption. The reusability of adsorbent and results from wastewater purification showed that Cell-MG could be used as general-purpose adsorbent. The adsorbent/adsorbate surface interaction was considered from the results obtained using density functional theory (DFT) and calculation of molecular electrostatic potential (MEP). Thus, a better understanding of the relation between the adsorption performances and contribution of non-specific and specific interactions to adsorption performances and design of novel adsorbent with improved properties was deduced",
publisher = "Association for ETRAN Society",
journal = "Science of Sintering",
title = "Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using Cell-MG hybrid adsorbent",
volume = "53",
number = "3",
pages = "355-378",
doi = "10.2298/SOS2103355P"
}
Perendija, J., Veličković, Z., Dražević, L., Stojiljković, I. N., Milčić, M. K., Milosavljević, M. M., Marinković, A.,& Pavlović, V. B.. (2021). Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using Cell-MG hybrid adsorbent. in Science of Sintering
Association for ETRAN Society., 53(3), 355-378.
https://doi.org/10.2298/SOS2103355P
Perendija J, Veličković Z, Dražević L, Stojiljković IN, Milčić MK, Milosavljević MM, Marinković A, Pavlović VB. Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using Cell-MG hybrid adsorbent. in Science of Sintering. 2021;53(3):355-378.
doi:10.2298/SOS2103355P .
Perendija, Jovana, Veličković, Zlate, Dražević, Ljubinka, Stojiljković, Ivana N., Milčić, Miloš K., Milosavljević, Milutin M., Marinković, Aleksandar, Pavlović, Vladimir B., "Evaluation of adsorption performance and quantum chemical modeling of pesticides removal using Cell-MG hybrid adsorbent" in Science of Sintering, 53, no. 3 (2021):355-378,
https://doi.org/10.2298/SOS2103355P . .

Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography

Lugonja, Nikoleta; Gorjanović, Stanislava ; Pastor, Ferenc T.; Marinković, Vesna S.; Miličić, Biljana; Vrvić, Miroslav M.; Spasić, Snežana

(Springer Link, 2021)

TY  - JOUR
AU  - Lugonja, Nikoleta
AU  - Gorjanović, Stanislava 
AU  - Pastor, Ferenc T.
AU  - Marinković, Vesna S.
AU  - Miličić, Biljana
AU  - Vrvić, Miroslav M.
AU  - Spasić, Snežana 
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4517
AB  - Antioxidants present in infant food contribute to its nutritive value and provide protection from oxidative damage. Here, a direct current polarographic method, based on a decrease of anodic current from the hydroxoperhydroxo-mercury(II) complex (HPMC) formed at a mercury dropping electrode at its potential of dissolution, was used to determine the total antioxidant capacity (TAC) of infant formulas, human milk collected from mothers of full-term and preterm infants, human milk supplemented with fortifier, and cow milk. TAC of milk samples and infant formula correlated with protein content measured by the Bradford method (Pearson correlation coefficient 0.605, p<0.001), while TAC of human milk correlated with content of free thiol groups measured by the Ellman method (0.779, p<0.001). The results obtained showed that, in contrast to the 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay, HPMC enables specific insight into the quality of infant milk food which reflects the amounts of free thiol groups and protein content. The significant contribution of milk proteins and the most prevalent amino acids, particularly cysteine, arginine, and phenylalanine, to TAC was shown. Thus, the HPMC method might be useful in monitoring the quality of infant formulas and human milk for preterm infants before and after supplementation with fortifier.
PB  - Springer Link
T2  - Food Analytical Methods
T2  - Food Analytical Methods
T1  - Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography
DO  - 10.1007/s12161-021-02030-3
ER  - 
@article{
author = "Lugonja, Nikoleta and Gorjanović, Stanislava  and Pastor, Ferenc T. and Marinković, Vesna S. and Miličić, Biljana and Vrvić, Miroslav M. and Spasić, Snežana ",
year = "2021",
abstract = "Antioxidants present in infant food contribute to its nutritive value and provide protection from oxidative damage. Here, a direct current polarographic method, based on a decrease of anodic current from the hydroxoperhydroxo-mercury(II) complex (HPMC) formed at a mercury dropping electrode at its potential of dissolution, was used to determine the total antioxidant capacity (TAC) of infant formulas, human milk collected from mothers of full-term and preterm infants, human milk supplemented with fortifier, and cow milk. TAC of milk samples and infant formula correlated with protein content measured by the Bradford method (Pearson correlation coefficient 0.605, p<0.001), while TAC of human milk correlated with content of free thiol groups measured by the Ellman method (0.779, p<0.001). The results obtained showed that, in contrast to the 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay, HPMC enables specific insight into the quality of infant milk food which reflects the amounts of free thiol groups and protein content. The significant contribution of milk proteins and the most prevalent amino acids, particularly cysteine, arginine, and phenylalanine, to TAC was shown. Thus, the HPMC method might be useful in monitoring the quality of infant formulas and human milk for preterm infants before and after supplementation with fortifier.",
publisher = "Springer Link",
journal = "Food Analytical Methods, Food Analytical Methods",
title = "Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography",
doi = "10.1007/s12161-021-02030-3"
}
Lugonja, N., Gorjanović, S., Pastor, F. T., Marinković, V. S., Miličić, B., Vrvić, M. M.,& Spasić, S.. (2021). Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography. in Food Analytical Methods
Springer Link..
https://doi.org/10.1007/s12161-021-02030-3
Lugonja N, Gorjanović S, Pastor FT, Marinković VS, Miličić B, Vrvić MM, Spasić S. Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography. in Food Analytical Methods. 2021;.
doi:10.1007/s12161-021-02030-3 .
Lugonja, Nikoleta, Gorjanović, Stanislava , Pastor, Ferenc T., Marinković, Vesna S., Miličić, Biljana, Vrvić, Miroslav M., Spasić, Snežana , "Antioxidant Capacity and Quality of Human Milk and Infant Formula Determined by Direct Current Polarography" in Food Analytical Methods (2021),
https://doi.org/10.1007/s12161-021-02030-3 . .

Study on the assessment of humification processes during biodegradation of heavy residual fuel oil

Avdalović, Jelena; Miletić, Srđan; Božović, Olga; Šolević Knudsen, Tatjana; Stanković, Dalibor; Lugonja, Nikoleta; Spasić, Snežana; Joksimović, Kristina; Dragičević, Igor; Vrvić, Miroslav M.

(Elsevier, 2021)

TY  - JOUR
AU  - Avdalović, Jelena
AU  - Miletić, Srđan
AU  - Božović, Olga
AU  - Šolević Knudsen, Tatjana
AU  - Stanković, Dalibor
AU  - Lugonja, Nikoleta
AU  - Spasić, Snežana
AU  - Joksimović, Kristina
AU  - Dragičević, Igor
AU  - Vrvić, Miroslav M.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4608
AB  - The aim of this study was to investigate the creation of humic substances during biodegradation of heavy residual fuel oil, because there are indications that substances similar to humic substances are generated during biodegradation of polycyclic aromatic hydrocarbons. In the study, which lasted for 110 days, biodegradation of heavy residual fuel oil was carried out in a layer of artificial soil substrate. The initial concentration of the total petroleum hydrocarbon in the prepared artificial soil substrate (biopile) was 23.1 g kg-1 dry weight (d.w.). At the end of the process, the total petroleum hydrocarbons were reduced to 8.1 g kg-1 d.w. in the inoculated biopile, while the content of humic acids increased during bioremediation from 3.15 g kg-1 d.w. to 4.95 g kg-1 d.w. The humic acids extracted from biopile during the biodegradation process were characterized by various chemical techniques (elemental analysis, spectrofluorimetric analysis, electrochemical measurements, and size exclusion chromatography). The results showed that levels of C, H and the H/C ratio decreased as the biodegradation process progressed. This indicated that humic acids aromatization process took place and this was confirmed by the spectrofluorimetric analysis. The increase of oxygen percentage and the O/C ratio in the humic acids after the biodegradation treatment indicated an increase in functional oxygen groups. Additional analyses of humic acids from the inoculated biopile showed that they were transformed during the bioremediation process. They had greater redox and buffering capacities and a larger portion of the fractions had high molecular mass. Also, the humification parameters (the CHAs/CFAs ratio and CHAs/Corg ratio) increased during the biodegradation. This is one of the few studies that describes the generation of humic substances during the biodegradation of oil compounds.
PB  - Elsevier
T2  - Science of the Total Environment
T1  - Study on the assessment of humification processes during biodegradation of heavy residual fuel oil
VL  - 797
SP  - 149099
DO  - 10.1016/j.scitotenv.2021.149099
ER  - 
@article{
author = "Avdalović, Jelena and Miletić, Srđan and Božović, Olga and Šolević Knudsen, Tatjana and Stanković, Dalibor and Lugonja, Nikoleta and Spasić, Snežana and Joksimović, Kristina and Dragičević, Igor and Vrvić, Miroslav M.",
year = "2021",
abstract = "The aim of this study was to investigate the creation of humic substances during biodegradation of heavy residual fuel oil, because there are indications that substances similar to humic substances are generated during biodegradation of polycyclic aromatic hydrocarbons. In the study, which lasted for 110 days, biodegradation of heavy residual fuel oil was carried out in a layer of artificial soil substrate. The initial concentration of the total petroleum hydrocarbon in the prepared artificial soil substrate (biopile) was 23.1 g kg-1 dry weight (d.w.). At the end of the process, the total petroleum hydrocarbons were reduced to 8.1 g kg-1 d.w. in the inoculated biopile, while the content of humic acids increased during bioremediation from 3.15 g kg-1 d.w. to 4.95 g kg-1 d.w. The humic acids extracted from biopile during the biodegradation process were characterized by various chemical techniques (elemental analysis, spectrofluorimetric analysis, electrochemical measurements, and size exclusion chromatography). The results showed that levels of C, H and the H/C ratio decreased as the biodegradation process progressed. This indicated that humic acids aromatization process took place and this was confirmed by the spectrofluorimetric analysis. The increase of oxygen percentage and the O/C ratio in the humic acids after the biodegradation treatment indicated an increase in functional oxygen groups. Additional analyses of humic acids from the inoculated biopile showed that they were transformed during the bioremediation process. They had greater redox and buffering capacities and a larger portion of the fractions had high molecular mass. Also, the humification parameters (the CHAs/CFAs ratio and CHAs/Corg ratio) increased during the biodegradation. This is one of the few studies that describes the generation of humic substances during the biodegradation of oil compounds.",
publisher = "Elsevier",
journal = "Science of the Total Environment",
title = "Study on the assessment of humification processes during biodegradation of heavy residual fuel oil",
volume = "797",
pages = "149099",
doi = "10.1016/j.scitotenv.2021.149099"
}
Avdalović, J., Miletić, S., Božović, O., Šolević Knudsen, T., Stanković, D., Lugonja, N., Spasić, S., Joksimović, K., Dragičević, I.,& Vrvić, M. M.. (2021). Study on the assessment of humification processes during biodegradation of heavy residual fuel oil. in Science of the Total Environment
Elsevier., 797, 149099.
https://doi.org/10.1016/j.scitotenv.2021.149099
Avdalović J, Miletić S, Božović O, Šolević Knudsen T, Stanković D, Lugonja N, Spasić S, Joksimović K, Dragičević I, Vrvić MM. Study on the assessment of humification processes during biodegradation of heavy residual fuel oil. in Science of the Total Environment. 2021;797:149099.
doi:10.1016/j.scitotenv.2021.149099 .
Avdalović, Jelena, Miletić, Srđan, Božović, Olga, Šolević Knudsen, Tatjana, Stanković, Dalibor, Lugonja, Nikoleta, Spasić, Snežana, Joksimović, Kristina, Dragičević, Igor, Vrvić, Miroslav M., "Study on the assessment of humification processes during biodegradation of heavy residual fuel oil" in Science of the Total Environment, 797 (2021):149099,
https://doi.org/10.1016/j.scitotenv.2021.149099 . .

Sekvencijalna ekstrakcija lantana i neodimijuma iz zemljišta

Nikolovski, Zlatko

(2021)

TY  - THES
AU  - Nikolovski, Zlatko
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4352
AB  - Cilj ovog rada jeste primena metode sekvencijalne ekstrakcije i ICP-OES analize metalnih jona radi određivanja koncentracije ekstrahovanih metalnih jona, interakcija sa ekstrakcionim rastvorima i razmatranja pogodnosti nametnutih uslova za ekstrakciju ovih elemenata iz zemljišta. Kasnije se ovim omogućava predviđanje njihovog ponašanja u životnoj sredini. Odabir ovih elemenata je bio takav da imamo jednog tipičnog predstavnika lantanoida, lantana (La), i element koji se pojavljuje u magnetima visokih performansi i optičkim sočivima, neodimijum (Nd).
T1  - Sekvencijalna ekstrakcija lantana i neodimijuma iz zemljišta
SP  - 1
EP  - 36
ER  - 
@mastersthesis{
author = "Nikolovski, Zlatko",
year = "2021",
abstract = "Cilj ovog rada jeste primena metode sekvencijalne ekstrakcije i ICP-OES analize metalnih jona radi određivanja koncentracije ekstrahovanih metalnih jona, interakcija sa ekstrakcionim rastvorima i razmatranja pogodnosti nametnutih uslova za ekstrakciju ovih elemenata iz zemljišta. Kasnije se ovim omogućava predviđanje njihovog ponašanja u životnoj sredini. Odabir ovih elemenata je bio takav da imamo jednog tipičnog predstavnika lantanoida, lantana (La), i element koji se pojavljuje u magnetima visokih performansi i optičkim sočivima, neodimijum (Nd).",
title = "Sekvencijalna ekstrakcija lantana i neodimijuma iz zemljišta",
pages = "1-36"
}
Nikolovski, Z.. (2021). Sekvencijalna ekstrakcija lantana i neodimijuma iz zemljišta. , 1-36.
Nikolovski Z. Sekvencijalna ekstrakcija lantana i neodimijuma iz zemljišta. 2021;:1-36..
Nikolovski, Zlatko, "Sekvencijalna ekstrakcija lantana i neodimijuma iz zemljišta" (2021):1-36.

Overview of Erasmus+ NETCHEM project: ICT networking for overcoming technical and social barriers in instrumental analytical chemistry education

Maletić, Snežana; Ivančev-Tumbas, Ivana; Brossas, Annie; Antonijević, Milan; Čáslavský, Josef; Jovančićević, Branimir; Matović, Zoran; Kongoli, Renata; MajlindaVasjari; Petrović, Maja; Andrejić, Nenad; Popov, Saša; Vesović, Nataša Ljubojević; Tabet, Jean-Claude; Warnet, Anna; Darko Anđelković; Gajica, Gordana; Anđelković, Tatjana

(Springer, 2021)

TY  - JOUR
AU  - Maletić, Snežana
AU  - Ivančev-Tumbas, Ivana
AU  - Brossas, Annie
AU  - Antonijević, Milan
AU  - Čáslavský, Josef
AU  - Jovančićević, Branimir
AU  - Matović, Zoran
AU  - Kongoli, Renata
AU  - MajlindaVasjari
AU  - Petrović, Maja
AU  - Andrejić, Nenad
AU  - Popov, Saša
AU  - Vesović, Nataša Ljubojević
AU  - Tabet, Jean-Claude
AU  - Warnet, Anna
AU  - Darko Anđelković
AU  - Gajica, Gordana
AU  - Anđelković, Tatjana
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4435
AB  - The paper briefly presents goals, activities, challenges, and outcomes of the NETCHEM project (http://www.netchem.ac.rs/) that was co-funded by the Erasmus+ Program of European Union (573885-EPP-1-2016-1-RS-EPPKA2- CBHE-JP). The project has been started in October 2016 and with extension lasted until April 2020. Western Balkan region has been targeted by upgrading capacities for education and research in environmental and food analysis in cooperation with partners from France, the UK, and Czech Republic. NETCHEM platform providing Web Accessed Remote Instrumental Analytical Laboratories (WARIAL) network, Database service and Open education system was created in order to improve the cooperation, educational, and research capacities of Higher Education Institutions involved, but also targeting whether audience not only from academic domain but from industry as well. The NETCHEM platform is free for access to public; thus, the external users to NETCHEM consortium can not only see its content but also actively participate, enter Database and WARIAL network, and upload their own educational/research material.
PB  - Springer
T2  - Environmental Science and Pollution Research
T2  - Environmental Science and Pollution ResearchEnviron Sci Pollut Res
T1  - Overview of Erasmus+ NETCHEM project: ICT networking for overcoming technical and social barriers in instrumental analytical chemistry education
VL  - 28
IS  - 2
SP  - 2479
EP  - 2483
DO  - 10.1007/s11356-020-11506-4
ER  - 
@article{
author = "Maletić, Snežana and Ivančev-Tumbas, Ivana and Brossas, Annie and Antonijević, Milan and Čáslavský, Josef and Jovančićević, Branimir and Matović, Zoran and Kongoli, Renata and MajlindaVasjari and Petrović, Maja and Andrejić, Nenad and Popov, Saša and Vesović, Nataša Ljubojević and Tabet, Jean-Claude and Warnet, Anna and Darko Anđelković and Gajica, Gordana and Anđelković, Tatjana",
year = "2021",
abstract = "The paper briefly presents goals, activities, challenges, and outcomes of the NETCHEM project (http://www.netchem.ac.rs/) that was co-funded by the Erasmus+ Program of European Union (573885-EPP-1-2016-1-RS-EPPKA2- CBHE-JP). The project has been started in October 2016 and with extension lasted until April 2020. Western Balkan region has been targeted by upgrading capacities for education and research in environmental and food analysis in cooperation with partners from France, the UK, and Czech Republic. NETCHEM platform providing Web Accessed Remote Instrumental Analytical Laboratories (WARIAL) network, Database service and Open education system was created in order to improve the cooperation, educational, and research capacities of Higher Education Institutions involved, but also targeting whether audience not only from academic domain but from industry as well. The NETCHEM platform is free for access to public; thus, the external users to NETCHEM consortium can not only see its content but also actively participate, enter Database and WARIAL network, and upload their own educational/research material.",
publisher = "Springer",
journal = "Environmental Science and Pollution Research, Environmental Science and Pollution ResearchEnviron Sci Pollut Res",
title = "Overview of Erasmus+ NETCHEM project: ICT networking for overcoming technical and social barriers in instrumental analytical chemistry education",
volume = "28",
number = "2",
pages = "2479-2483",
doi = "10.1007/s11356-020-11506-4"
}
Maletić, S., Ivančev-Tumbas, I., Brossas, A., Antonijević, M., Čáslavský, J., Jovančićević, B., Matović, Z., Kongoli, R., MajlindaVasjari, Petrović, M., Andrejić, N., Popov, S., Vesović, N. L., Tabet, J., Warnet, A., Darko Anđelković, Gajica, G.,& Anđelković, T.. (2021). Overview of Erasmus+ NETCHEM project: ICT networking for overcoming technical and social barriers in instrumental analytical chemistry education. in Environmental Science and Pollution Research
Springer., 28(2), 2479-2483.
https://doi.org/10.1007/s11356-020-11506-4
Maletić S, Ivančev-Tumbas I, Brossas A, Antonijević M, Čáslavský J, Jovančićević B, Matović Z, Kongoli R, MajlindaVasjari, Petrović M, Andrejić N, Popov S, Vesović NL, Tabet J, Warnet A, Darko Anđelković, Gajica G, Anđelković T. Overview of Erasmus+ NETCHEM project: ICT networking for overcoming technical and social barriers in instrumental analytical chemistry education. in Environmental Science and Pollution Research. 2021;28(2):2479-2483.
doi:10.1007/s11356-020-11506-4 .
Maletić, Snežana, Ivančev-Tumbas, Ivana, Brossas, Annie, Antonijević, Milan, Čáslavský, Josef, Jovančićević, Branimir, Matović, Zoran, Kongoli, Renata, MajlindaVasjari, Petrović, Maja, Andrejić, Nenad, Popov, Saša, Vesović, Nataša Ljubojević, Tabet, Jean-Claude, Warnet, Anna, Darko Anđelković, Gajica, Gordana, Anđelković, Tatjana, "Overview of Erasmus+ NETCHEM project: ICT networking for overcoming technical and social barriers in instrumental analytical chemistry education" in Environmental Science and Pollution Research, 28, no. 2 (2021):2479-2483,
https://doi.org/10.1007/s11356-020-11506-4 . .
1

Određivanje i karakterizacija aromatičnih karotenoidnih derivata β-karotena u sedimentima iz Valjevsko-mioničkog basena

Vukićević, Emilija

(2021)

TY  - THES
AU  - Vukićević, Emilija
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4560
AB  - U ovom radu su analizirani ugljovodonici sedimentnih stena iz Valjevsko-mioničkog basena u cilju određivanja i karakterizacije aromatičnih karotenoidnih ugljovodonika koji vode poreklo od β-karotena. Prethodna ispitivanja pokazala su da ovi uzorci sadrže nezrelu organsku supstancu pretežno algalnog porekla, taloženu u anoksičnim uslovima. Pored toga, utvrđeno je prisustvo raznih bornih minerala, pre svega probertita i sirlezita, kao i slojeva uljnih škriljaca. Poznato je da probertit (NaCaB5O7(OH)4 x 3H2O) nastaje u relativno plitkom jezeru, evaporitnim naslagama i uslovima aridne klime. To znači da preovladava isparavanje vode i koncentrovanje soli u zatvorenoj jezerskoj sredini, što dovodi do formiranja plitkog, slanog jezera.
Zonu mineralizacije, odnosno ležište minerala probertita na dubinskom intervalu od 365 m do 412 m karakteriše povišen salinitet, što je uslovilo da u zasićenoj raspodeli ugljovodonika β-karotan bude najzastupljenije jedinjenje. Sedimente iz podine i povlate ovog ležišta karakteriše drugačija raspodela biomarkera.
Fokus ovog rada bio je na uzorcima kod kojih je β-karotan obilan. Cilj je bio da se odrede dominantni putevi transformacije β-karotena, koji proizvodi nastaju tim transformacijama kao i uslovi pod kojima su se te promene odigrale. Identifikovani karotenoidi predstavljaju indikatore određenih uslova sedimentacije.
Zaključeno je da je povlata ležišta probertita relativno siromašna karotenoidima, što može biti posledica mešanja sa slatkom vodom gde se salinitet sredine smanjivao. Aromatični karotenoidi pronađeni u ležištu probertita u saglasnosti su sa hiperslanim, anoksičnim uslovima sedimentacije, što potvrđuje i raspodela zasićenih ugljovodonika. Sedimenti iz podine ležišta taloženi su u slanoj ali ne i hiperslanoj sredini, dok su sedimenti iz povlate ležišta formirani u uslovima pozitivnijeg redoks potencijala u odnosu na samo ležište.
T1  - Određivanje i karakterizacija aromatičnih karotenoidnih derivata β-karotena u sedimentima iz Valjevsko-mioničkog basena
SP  - 1
EP  - 25
ER  - 
@mastersthesis{
author = "Vukićević, Emilija",
year = "2021",
abstract = "U ovom radu su analizirani ugljovodonici sedimentnih stena iz Valjevsko-mioničkog basena u cilju određivanja i karakterizacije aromatičnih karotenoidnih ugljovodonika koji vode poreklo od β-karotena. Prethodna ispitivanja pokazala su da ovi uzorci sadrže nezrelu organsku supstancu pretežno algalnog porekla, taloženu u anoksičnim uslovima. Pored toga, utvrđeno je prisustvo raznih bornih minerala, pre svega probertita i sirlezita, kao i slojeva uljnih škriljaca. Poznato je da probertit (NaCaB5O7(OH)4 x 3H2O) nastaje u relativno plitkom jezeru, evaporitnim naslagama i uslovima aridne klime. To znači da preovladava isparavanje vode i koncentrovanje soli u zatvorenoj jezerskoj sredini, što dovodi do formiranja plitkog, slanog jezera.
Zonu mineralizacije, odnosno ležište minerala probertita na dubinskom intervalu od 365 m do 412 m karakteriše povišen salinitet, što je uslovilo da u zasićenoj raspodeli ugljovodonika β-karotan bude najzastupljenije jedinjenje. Sedimente iz podine i povlate ovog ležišta karakteriše drugačija raspodela biomarkera.
Fokus ovog rada bio je na uzorcima kod kojih je β-karotan obilan. Cilj je bio da se odrede dominantni putevi transformacije β-karotena, koji proizvodi nastaju tim transformacijama kao i uslovi pod kojima su se te promene odigrale. Identifikovani karotenoidi predstavljaju indikatore određenih uslova sedimentacije.
Zaključeno je da je povlata ležišta probertita relativno siromašna karotenoidima, što može biti posledica mešanja sa slatkom vodom gde se salinitet sredine smanjivao. Aromatični karotenoidi pronađeni u ležištu probertita u saglasnosti su sa hiperslanim, anoksičnim uslovima sedimentacije, što potvrđuje i raspodela zasićenih ugljovodonika. Sedimenti iz podine ležišta taloženi su u slanoj ali ne i hiperslanoj sredini, dok su sedimenti iz povlate ležišta formirani u uslovima pozitivnijeg redoks potencijala u odnosu na samo ležište.",
title = "Određivanje i karakterizacija aromatičnih karotenoidnih derivata β-karotena u sedimentima iz Valjevsko-mioničkog basena",
pages = "1-25"
}
Vukićević, E.. (2021). Određivanje i karakterizacija aromatičnih karotenoidnih derivata β-karotena u sedimentima iz Valjevsko-mioničkog basena. , 1-25.
Vukićević E. Određivanje i karakterizacija aromatičnih karotenoidnih derivata β-karotena u sedimentima iz Valjevsko-mioničkog basena. 2021;:1-25..
Vukićević, Emilija, "Određivanje i karakterizacija aromatičnih karotenoidnih derivata β-karotena u sedimentima iz Valjevsko-mioničkog basena" (2021):1-25.

Polycyclic aromatic hydrocarbons and their relationship to maturity and paleoenvironmental settings in lacustrine sediments of the Neogene Toplica Basin, Serbia

Burazer, Nikola; Šajnović, Aleksandra M.; Kašanin-Grubin, Milica; Radisavljević, Marija; Jovančićević, Branimir

(Springer, 2021)

TY  - JOUR
AU  - Burazer, Nikola
AU  - Šajnović, Aleksandra M.
AU  - Kašanin-Grubin, Milica
AU  - Radisavljević, Marija
AU  - Jovančićević, Branimir
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4563
AB  - The study investigated the influence of maturity, biomass type, and depositional settings on the distribution and relative abundance of polycyclic aromatic hydrocarbons (PAHs) for lacustrine sediments collected from depths up to 1000 m of Prebreza and Čučale stratigraphic units (the northwest part of the Toplica Basin). A recently proposed benzo[ghi]perylene/(perylene + benzo[ghi]perylene) parameter, along with commonly used Phenanthrene Alkylation Index and benzo[e]pyrene/(perylene + benzo[e]pyrene) indices, pointed out differences in maturity levels between stratigraphic units by displaying a positive linear relationship with vitrinite reflectance. However, in several immature Prebreza sediments, a substantial presence of algae and/or anoxic, mesosaline/hypersaline conditions were suitable for forming β-substituted methylphenanthrenes and 6-ring benzo[ghi]perylene. Generally, high molecular weight unsubstituted PAHs (HMWPAHs), particularly perylene, predominated Prebreza sediments. Anoxic conditions appeared to be decisive for accumulating and preserving the perylene carbon skeleton in studied stratigraphic units. Besides, more intense volcanism in the Čučale unit favored combustion processes, which prompted the accumulation of low molecular weight unsubstituted PAHs (LMWPAHs), especially phenanthrene. A general prevalence of retene over cadalene in Prebreza sediments, in which alginite and liptodetrinite predominated, implied algae as retene precursor. Selective degradation of retene or hindered demethylation of 9-methylphenanthrene under anoxic and more saline environmental settings had occurred notably in the Prebreza unit, which led to the formation of 1-methylphenanthrene and/or pimanthrene (1,7-dimethylphenanthrene). Čučale sediments with substantial amounts of vitrinite macerals or saturated diterpenoids had a predominant simonellite derived from conifers. Non-degraded and well-preserved Pinaceae conifers predominated in Prebreza sediments deposited under semi-arid climatic conditions, whereas mixed degraded/non-degraded conifers characterized Čučale sediments deposited in a wide range of climatic conditions, from semi-arid to semi-humid. © 2021, The Author(s), under exclusive licence to Springer Nature B.V.
PB  - Springer
T2  - Journal of Paleolimnology
T1  - Polycyclic aromatic hydrocarbons and their relationship to maturity and paleoenvironmental settings in lacustrine sediments of the Neogene Toplica Basin, Serbia
VL  - 66
IS  - 3
SP  - 187
EP  - 205
DO  - 10.1007/s10933-021-00199-5
ER  - 
@article{
author = "Burazer, Nikola and Šajnović, Aleksandra M. and Kašanin-Grubin, Milica and Radisavljević, Marija and Jovančićević, Branimir",
year = "2021",
abstract = "The study investigated the influence of maturity, biomass type, and depositional settings on the distribution and relative abundance of polycyclic aromatic hydrocarbons (PAHs) for lacustrine sediments collected from depths up to 1000 m of Prebreza and Čučale stratigraphic units (the northwest part of the Toplica Basin). A recently proposed benzo[ghi]perylene/(perylene + benzo[ghi]perylene) parameter, along with commonly used Phenanthrene Alkylation Index and benzo[e]pyrene/(perylene + benzo[e]pyrene) indices, pointed out differences in maturity levels between stratigraphic units by displaying a positive linear relationship with vitrinite reflectance. However, in several immature Prebreza sediments, a substantial presence of algae and/or anoxic, mesosaline/hypersaline conditions were suitable for forming β-substituted methylphenanthrenes and 6-ring benzo[ghi]perylene. Generally, high molecular weight unsubstituted PAHs (HMWPAHs), particularly perylene, predominated Prebreza sediments. Anoxic conditions appeared to be decisive for accumulating and preserving the perylene carbon skeleton in studied stratigraphic units. Besides, more intense volcanism in the Čučale unit favored combustion processes, which prompted the accumulation of low molecular weight unsubstituted PAHs (LMWPAHs), especially phenanthrene. A general prevalence of retene over cadalene in Prebreza sediments, in which alginite and liptodetrinite predominated, implied algae as retene precursor. Selective degradation of retene or hindered demethylation of 9-methylphenanthrene under anoxic and more saline environmental settings had occurred notably in the Prebreza unit, which led to the formation of 1-methylphenanthrene and/or pimanthrene (1,7-dimethylphenanthrene). Čučale sediments with substantial amounts of vitrinite macerals or saturated diterpenoids had a predominant simonellite derived from conifers. Non-degraded and well-preserved Pinaceae conifers predominated in Prebreza sediments deposited under semi-arid climatic conditions, whereas mixed degraded/non-degraded conifers characterized Čučale sediments deposited in a wide range of climatic conditions, from semi-arid to semi-humid. © 2021, The Author(s), under exclusive licence to Springer Nature B.V.",
publisher = "Springer",
journal = "Journal of Paleolimnology",
title = "Polycyclic aromatic hydrocarbons and their relationship to maturity and paleoenvironmental settings in lacustrine sediments of the Neogene Toplica Basin, Serbia",
volume = "66",
number = "3",
pages = "187-205",
doi = "10.1007/s10933-021-00199-5"
}
Burazer, N., Šajnović, A. M., Kašanin-Grubin, M., Radisavljević, M.,& Jovančićević, B.. (2021). Polycyclic aromatic hydrocarbons and their relationship to maturity and paleoenvironmental settings in lacustrine sediments of the Neogene Toplica Basin, Serbia. in Journal of Paleolimnology
Springer., 66(3), 187-205.
https://doi.org/10.1007/s10933-021-00199-5
Burazer N, Šajnović AM, Kašanin-Grubin M, Radisavljević M, Jovančićević B. Polycyclic aromatic hydrocarbons and their relationship to maturity and paleoenvironmental settings in lacustrine sediments of the Neogene Toplica Basin, Serbia. in Journal of Paleolimnology. 2021;66(3):187-205.
doi:10.1007/s10933-021-00199-5 .
Burazer, Nikola, Šajnović, Aleksandra M., Kašanin-Grubin, Milica, Radisavljević, Marija, Jovančićević, Branimir, "Polycyclic aromatic hydrocarbons and their relationship to maturity and paleoenvironmental settings in lacustrine sediments of the Neogene Toplica Basin, Serbia" in Journal of Paleolimnology, 66, no. 3 (2021):187-205,
https://doi.org/10.1007/s10933-021-00199-5 . .

Supplementary data for the article: Burazer, N.; Šajnović, A.; Kašanin-Grubin, M.; Radisavljević, M.; Jovančićević, B. Polycyclic Aromatic Hydrocarbons and Their Relationship to Maturity and Paleoenvironmental Settings in Lacustrine Sediments of the Neogene Toplica Basin, Serbia. Journal of Paleolimnology 2021, 66 (3), 187–205. https://doi.org/10.1007/s10933-021-00199-5.

Burazer, Nikola; Šajnović, Aleksandra M.; Kašanin-Grubin, Milica; Radisavljević, Marija; Jovančićević, Branimir

(Springer, 2021)

TY  - DATA
AU  - Burazer, Nikola
AU  - Šajnović, Aleksandra M.
AU  - Kašanin-Grubin, Milica
AU  - Radisavljević, Marija
AU  - Jovančićević, Branimir 
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4564
PB  - Springer
T2  - Journal of Paleolimnology
T1  - Supplementary data for the article: Burazer, N.; Šajnović, A.; Kašanin-Grubin, M.; Radisavljević, M.; Jovančićević, B. Polycyclic Aromatic Hydrocarbons and Their Relationship to Maturity and Paleoenvironmental Settings in Lacustrine Sediments of the Neogene Toplica Basin, Serbia. Journal of Paleolimnology 2021, 66 (3), 187–205. https://doi.org/10.1007/s10933-021-00199-5.
ER  - 
@misc{
author = "Burazer, Nikola and Šajnović, Aleksandra M. and Kašanin-Grubin, Milica and Radisavljević, Marija and Jovančićević, Branimir ",
year = "2021",
publisher = "Springer",
journal = "Journal of Paleolimnology",
title = "Supplementary data for the article: Burazer, N.; Šajnović, A.; Kašanin-Grubin, M.; Radisavljević, M.; Jovančićević, B. Polycyclic Aromatic Hydrocarbons and Their Relationship to Maturity and Paleoenvironmental Settings in Lacustrine Sediments of the Neogene Toplica Basin, Serbia. Journal of Paleolimnology 2021, 66 (3), 187–205. https://doi.org/10.1007/s10933-021-00199-5."
}
Burazer, N., Šajnović, A. M., Kašanin-Grubin, M., Radisavljević, M.,& Jovančićević, B.. (2021). Supplementary data for the article: Burazer, N.; Šajnović, A.; Kašanin-Grubin, M.; Radisavljević, M.; Jovančićević, B. Polycyclic Aromatic Hydrocarbons and Their Relationship to Maturity and Paleoenvironmental Settings in Lacustrine Sediments of the Neogene Toplica Basin, Serbia. Journal of Paleolimnology 2021, 66 (3), 187–205. https://doi.org/10.1007/s10933-021-00199-5.. in Journal of Paleolimnology
Springer..
Burazer N, Šajnović AM, Kašanin-Grubin M, Radisavljević M, Jovančićević B. Supplementary data for the article: Burazer, N.; Šajnović, A.; Kašanin-Grubin, M.; Radisavljević, M.; Jovančićević, B. Polycyclic Aromatic Hydrocarbons and Their Relationship to Maturity and Paleoenvironmental Settings in Lacustrine Sediments of the Neogene Toplica Basin, Serbia. Journal of Paleolimnology 2021, 66 (3), 187–205. https://doi.org/10.1007/s10933-021-00199-5.. in Journal of Paleolimnology. 2021;..
Burazer, Nikola, Šajnović, Aleksandra M., Kašanin-Grubin, Milica, Radisavljević, Marija, Jovančićević, Branimir , "Supplementary data for the article: Burazer, N.; Šajnović, A.; Kašanin-Grubin, M.; Radisavljević, M.; Jovančićević, B. Polycyclic Aromatic Hydrocarbons and Their Relationship to Maturity and Paleoenvironmental Settings in Lacustrine Sediments of the Neogene Toplica Basin, Serbia. Journal of Paleolimnology 2021, 66 (3), 187–205. https://doi.org/10.1007/s10933-021-00199-5." in Journal of Paleolimnology (2021).

The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods

Šuljagić, Marija; Vulić, Predrag; Jeremić, Dejan; Pavlović, Vladimir B.; Filipović, Suzana; Kilanski, Lukasz; Lewinska, Sabina; Slawska-Waniewska, Anna; Milenković, Milica R.; Nikolić, Aleksandar S.; Anđelković, Ljubica

(Elsevier, 2021)

TY  - JOUR
AU  - Šuljagić, Marija
AU  - Vulić, Predrag
AU  - Jeremić, Dejan
AU  - Pavlović, Vladimir B.
AU  - Filipović, Suzana
AU  - Kilanski, Lukasz
AU  - Lewinska, Sabina
AU  - Slawska-Waniewska, Anna
AU  - Milenković, Milica R.
AU  - Nikolić, Aleksandar S.
AU  - Anđelković, Ljubica
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4271
AB  - To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.
PB  - Elsevier
T2  - Materials Research Bulletin
T1  - The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods
VL  - 134
SP  - 111117
DO  - 10.1016/j.materresbull.2020.111117
ER  - 
@article{
author = "Šuljagić, Marija and Vulić, Predrag and Jeremić, Dejan and Pavlović, Vladimir B. and Filipović, Suzana and Kilanski, Lukasz and Lewinska, Sabina and Slawska-Waniewska, Anna and Milenković, Milica R. and Nikolić, Aleksandar S. and Anđelković, Ljubica",
year = "2021",
abstract = "To investigate the magnetic behavior of starch-coated cobalt ferrites, well-established synthetic methods, i.e., coprecipitation, mechanochemical, ultrasonically assisted coprecipitation, microemulsion, and microwave-assisted hydrothermal syntheses were chosen for their preparation. The obtained materials had pure single-phase spinel structures. Scanning and transmission electron microscopy analyses revealed that the morphology of the samples is not uniform, and particle aggregation is a dominant process. Fourier transform infrared spectra and thermogravimetric analysis confirmed the presence of starch in all–coated samples. The unusually higher saturation magnetization of starch-coated samples than their as-prepared analogs, obtained by coprecipitation, ultrasonically assisted coprecipitation, and microwave-assisted hydrothermal methods, might be explained by the Ostwald ripening mechanism induced by the coating process. A decrease in magnetization was noticed for the starch-functionalized nanomaterials synthesized by mechanochemical and microemulsion methods, in comparison to their as-prepared analogs, i.e., the size distribution of such nanoparticles is narrow, and the average diameter of the grains is near critical for the Ostwald ripening process.",
publisher = "Elsevier",
journal = "Materials Research Bulletin",
title = "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods",
volume = "134",
pages = "111117",
doi = "10.1016/j.materresbull.2020.111117"
}
Šuljagić, M., Vulić, P., Jeremić, D., Pavlović, V. B., Filipović, S., Kilanski, L., Lewinska, S., Slawska-Waniewska, A., Milenković, M. R., Nikolić, A. S.,& Anđelković, L.. (2021). The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods. in Materials Research Bulletin
Elsevier., 134, 111117.
https://doi.org/10.1016/j.materresbull.2020.111117
Šuljagić M, Vulić P, Jeremić D, Pavlović VB, Filipović S, Kilanski L, Lewinska S, Slawska-Waniewska A, Milenković MR, Nikolić AS, Anđelković L. The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods. in Materials Research Bulletin. 2021;134:111117.
doi:10.1016/j.materresbull.2020.111117 .
Šuljagić, Marija, Vulić, Predrag, Jeremić, Dejan, Pavlović, Vladimir B., Filipović, Suzana, Kilanski, Lukasz, Lewinska, Sabina, Slawska-Waniewska, Anna, Milenković, Milica R., Nikolić, Aleksandar S., Anđelković, Ljubica, "The influence of the starch coating on the magnetic properties of nanosized cobalt ferrites obtained by different synthetic methods" in Materials Research Bulletin, 134 (2021):111117,
https://doi.org/10.1016/j.materresbull.2020.111117 . .
3
2

Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction

Filipović, Suzana; Obradović, Nina; Anđelković, Ljubica; Olćan, Dragan; Petrović, Jovana P.; Mirković, Marija; Pavlović, Vladimir B.; Jeremić, Dejan; Vlahović, Branislav; Đorđević, Antonije

(ETRAN Society, 2021)

TY  - JOUR
AU  - Filipović, Suzana
AU  - Obradović, Nina
AU  - Anđelković, Ljubica
AU  - Olćan, Dragan
AU  - Petrović, Jovana P.
AU  - Mirković, Marija
AU  - Pavlović, Vladimir B.
AU  - Jeremić, Dejan
AU  - Vlahović, Branislav
AU  - Đorđević, Antonije
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4511
AB  - Solid-state reaction between BaTiO3and Fe2O3was used to produce a multiferroic heterostructure composite. Commercial BaTiO3and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300°C for 6 h. Sintering at 1300 °C for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3with Fe2O3resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature. © 2021 Authors. Published by association for ETRAN Society.
PB  - ETRAN Society
T2  - Science of Sintering
T2  - Science of Sintering
T1  - Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction
VL  - 53
IS  - 1
SP  - 1
EP  - 8
DO  - 10.2298/SOS2101001F
ER  - 
@article{
author = "Filipović, Suzana and Obradović, Nina and Anđelković, Ljubica and Olćan, Dragan and Petrović, Jovana P. and Mirković, Marija and Pavlović, Vladimir B. and Jeremić, Dejan and Vlahović, Branislav and Đorđević, Antonije",
year = "2021",
abstract = "Solid-state reaction between BaTiO3and Fe2O3was used to produce a multiferroic heterostructure composite. Commercial BaTiO3and Fe(NO3)3•9H2O were suspended in ethanol for 30 minutes in an ultrasound bath. The prepared mixture was thermally processed at 300°C for 6 h. Sintering at 1300 °C for 1 h resulted in a mixture of different phases, BaTiO3, BaFe12O19and Ba12Ti28Fe15O84, which were confirmed by x-ray powder diffraction. A dense microstructure with a small volume fraction of closed porosity was indicated by the scanning electron microscopy, while a homogeneous distribution of Fe ions over BaTiO3phase was visible from energy dispersive spectroscopy mapping. Doping of BaTiO3with Fe2O3resulted in formation of magnetic hexaferrite phases, as confirmed by dielectric measurements that showed a broadened maximum of the permittivity measured as a function of temperature. © 2021 Authors. Published by association for ETRAN Society.",
publisher = "ETRAN Society",
journal = "Science of Sintering, Science of Sintering",
title = "Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction",
volume = "53",
number = "1",
pages = "1-8",
doi = "10.2298/SOS2101001F"
}
Filipović, S., Obradović, N., Anđelković, L., Olćan, D., Petrović, J. P., Mirković, M., Pavlović, V. B., Jeremić, D., Vlahović, B.,& Đorđević, A.. (2021). Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction. in Science of Sintering
ETRAN Society., 53(1), 1-8.
https://doi.org/10.2298/SOS2101001F
Filipović S, Obradović N, Anđelković L, Olćan D, Petrović JP, Mirković M, Pavlović VB, Jeremić D, Vlahović B, Đorđević A. Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction. in Science of Sintering. 2021;53(1):1-8.
doi:10.2298/SOS2101001F .
Filipović, Suzana, Obradović, Nina, Anđelković, Ljubica, Olćan, Dragan, Petrović, Jovana P., Mirković, Marija, Pavlović, Vladimir B., Jeremić, Dejan, Vlahović, Branislav, Đorđević, Antonije, "Multiferroic heterostructure BaTiO3/ε-Fe2O3composite obtained by in situ reaction" in Science of Sintering, 53, no. 1 (2021):1-8,
https://doi.org/10.2298/SOS2101001F . .

Assessing the potential of para-donor and para-acceptor substituted 5-benzylidenebarbituric acid derivatives as push–pull electronic systems: Experimental and quantum chemical study

Stojiljković, Ivana N.; Rančić, Milica; Marinković, Aleksandar; Cvijetić, Ilija; Milčić, Miloš K.

(Elsevier, 2021)

TY  - JOUR
AU  - Stojiljković, Ivana N.
AU  - Rančić, Milica
AU  - Marinković, Aleksandar
AU  - Cvijetić, Ilija
AU  - Milčić, Miloš K.
PY  - 2021
UR  - https://www.sciencedirect.com/science/article/pii/S1386142521001529
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4420
AB  - Electronic interactions in donor-π-linker-acceptor systems with barbituric acid as an electron acceptor and possible electron donor were investigated to screen promising candidates with a push–pull character based on experimental and quantum chemical studies. The tautomeric properties of 5-benzylidenebarbituric acid derivatives were studied with NMR spectra, spectrophotometric determination of the pKa values, and quantum chemical calculations. Linear solvation energy relationships (LSER) and linear free energy relationships (LFER) were applied to the spectral data - UV frequencies and 13C NMR chemical shifts. The experimental studies of the nature of the ground and excited state of investigated compounds were successfully interpreted using a computational chemistry approach including ab initio MP2 geometry optimization and time-dependent DFT calculations of excited states. Quantification of the push–pull character of barbituric acid derivatives was performed by the 13CNMR chemical shift differences, Mayer π bond order analysis, hole-electron distribution analysis, and calculations of intramolecular charge transfer (ICT) indices. The results obtained show, that when coupled with a strong electron-donor, barbituric acid can act as the electron-acceptor in push–pull systems, and when coupled with a strong electron-acceptor, barbituric acid can act as the weak electron-donor.
PB  - Elsevier
T2  - Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
T2  - Spectrochimica Acta Part A: Molecular and Biomolecular SpectroscopySpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
T1  - Assessing the potential of para-donor and para-acceptor substituted 5-benzylidenebarbituric acid derivatives as push–pull electronic systems: Experimental and quantum chemical study
VL  - 253
SP  - 119576
DO  - 10.1016/j.saa.2021.119576
ER  - 
@article{
author = "Stojiljković, Ivana N. and Rančić, Milica and Marinković, Aleksandar and Cvijetić, Ilija and Milčić, Miloš K.",
year = "2021",
abstract = "Electronic interactions in donor-π-linker-acceptor systems with barbituric acid as an electron acceptor and possible electron donor were investigated to screen promising candidates with a push–pull character based on experimental and quantum chemical studies. The tautomeric properties of 5-benzylidenebarbituric acid derivatives were studied with NMR spectra, spectrophotometric determination of the pKa values, and quantum chemical calculations. Linear solvation energy relationships (LSER) and linear free energy relationships (LFER) were applied to the spectral data - UV frequencies and 13C NMR chemical shifts. The experimental studies of the nature of the ground and excited state of investigated compounds were successfully interpreted using a computational chemistry approach including ab initio MP2 geometry optimization and time-dependent DFT calculations of excited states. Quantification of the push–pull character of barbituric acid derivatives was performed by the 13CNMR chemical shift differences, Mayer π bond order analysis, hole-electron distribution analysis, and calculations of intramolecular charge transfer (ICT) indices. The results obtained show, that when coupled with a strong electron-donor, barbituric acid can act as the electron-acceptor in push–pull systems, and when coupled with a strong electron-acceptor, barbituric acid can act as the weak electron-donor.",
publisher = "Elsevier",
journal = "Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Spectrochimica Acta Part A: Molecular and Biomolecular SpectroscopySpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy",
title = "Assessing the potential of para-donor and para-acceptor substituted 5-benzylidenebarbituric acid derivatives as push–pull electronic systems: Experimental and quantum chemical study",
volume = "253",
pages = "119576",
doi = "10.1016/j.saa.2021.119576"
}
Stojiljković, I. N., Rančić, M., Marinković, A., Cvijetić, I.,& Milčić, M. K.. (2021). Assessing the potential of para-donor and para-acceptor substituted 5-benzylidenebarbituric acid derivatives as push–pull electronic systems: Experimental and quantum chemical study. in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Elsevier., 253, 119576.
https://doi.org/10.1016/j.saa.2021.119576
Stojiljković IN, Rančić M, Marinković A, Cvijetić I, Milčić MK. Assessing the potential of para-donor and para-acceptor substituted 5-benzylidenebarbituric acid derivatives as push–pull electronic systems: Experimental and quantum chemical study. in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2021;253:119576.
doi:10.1016/j.saa.2021.119576 .
Stojiljković, Ivana N., Rančić, Milica, Marinković, Aleksandar, Cvijetić, Ilija, Milčić, Miloš K., "Assessing the potential of para-donor and para-acceptor substituted 5-benzylidenebarbituric acid derivatives as push–pull electronic systems: Experimental and quantum chemical study" in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 253 (2021):119576,
https://doi.org/10.1016/j.saa.2021.119576 . .

Supplementary data for the article: Stojiljković, I. N.; Rančić, M. P.; Marinković, A. D.; Cvijetić, I. N.; Milčić, M. K. Assessing the Potential of Para-Donor and Para-Acceptor Substituted 5-Benzylidenebarbituric Acid Derivatives as Push–Pull Electronic Systems: Experimental and Quantum Chemical Study. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2021, 253, 119576. https://doi.org/10.1016/j.saa.2021.119576.

Stojiljković, Ivana N.; Rančić, Milica; Marinković, Aleksandar; Cvijetić, Ilija; Milčić, Miloš K.

(Elsevier, 2021)

TY  - DATA
AU  - Stojiljković, Ivana N.
AU  - Rančić, Milica
AU  - Marinković, Aleksandar
AU  - Cvijetić, Ilija
AU  - Milčić, Miloš K.
PY  - 2021
UR  - https://www.sciencedirect.com/science/article/pii/S1386142521001529
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4421
PB  - Elsevier
T2  - Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
T2  - Spectrochimica Acta Part A: Molecular and Biomolecular SpectroscopySpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
T1  - Supplementary data for the article: Stojiljković, I. N.; Rančić, M. P.; Marinković, A. D.; Cvijetić, I. N.; Milčić, M. K. Assessing the Potential of Para-Donor and Para-Acceptor Substituted 5-Benzylidenebarbituric Acid Derivatives as Push–Pull Electronic Systems: Experimental and Quantum Chemical Study. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2021, 253, 119576. https://doi.org/10.1016/j.saa.2021.119576.
ER  - 
@misc{
author = "Stojiljković, Ivana N. and Rančić, Milica and Marinković, Aleksandar and Cvijetić, Ilija and Milčić, Miloš K.",
year = "2021",
publisher = "Elsevier",
journal = "Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Spectrochimica Acta Part A: Molecular and Biomolecular SpectroscopySpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy",
title = "Supplementary data for the article: Stojiljković, I. N.; Rančić, M. P.; Marinković, A. D.; Cvijetić, I. N.; Milčić, M. K. Assessing the Potential of Para-Donor and Para-Acceptor Substituted 5-Benzylidenebarbituric Acid Derivatives as Push–Pull Electronic Systems: Experimental and Quantum Chemical Study. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2021, 253, 119576. https://doi.org/10.1016/j.saa.2021.119576."
}
Stojiljković, I. N., Rančić, M., Marinković, A., Cvijetić, I.,& Milčić, M. K.. (2021). Supplementary data for the article: Stojiljković, I. N.; Rančić, M. P.; Marinković, A. D.; Cvijetić, I. N.; Milčić, M. K. Assessing the Potential of Para-Donor and Para-Acceptor Substituted 5-Benzylidenebarbituric Acid Derivatives as Push–Pull Electronic Systems: Experimental and Quantum Chemical Study. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2021, 253, 119576. https://doi.org/10.1016/j.saa.2021.119576.. in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Elsevier..
Stojiljković IN, Rančić M, Marinković A, Cvijetić I, Milčić MK. Supplementary data for the article: Stojiljković, I. N.; Rančić, M. P.; Marinković, A. D.; Cvijetić, I. N.; Milčić, M. K. Assessing the Potential of Para-Donor and Para-Acceptor Substituted 5-Benzylidenebarbituric Acid Derivatives as Push–Pull Electronic Systems: Experimental and Quantum Chemical Study. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2021, 253, 119576. https://doi.org/10.1016/j.saa.2021.119576.. in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2021;..
Stojiljković, Ivana N., Rančić, Milica, Marinković, Aleksandar, Cvijetić, Ilija, Milčić, Miloš K., "Supplementary data for the article: Stojiljković, I. N.; Rančić, M. P.; Marinković, A. D.; Cvijetić, I. N.; Milčić, M. K. Assessing the Potential of Para-Donor and Para-Acceptor Substituted 5-Benzylidenebarbituric Acid Derivatives as Push–Pull Electronic Systems: Experimental and Quantum Chemical Study. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2021, 253, 119576. https://doi.org/10.1016/j.saa.2021.119576." in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy (2021).

Synthesis and Characterization of Azido Esters as Green Energetic Plasticizers

Nešić, Jovica; Cvijetić, Ilija; Bogdanov, Jovica; Marinković, Aleksandar

(Wiley, 2021)

TY  - JOUR
AU  - Nešić, Jovica
AU  - Cvijetić, Ilija
AU  - Bogdanov, Jovica
AU  - Marinković, Aleksandar
PY  - 2021
UR  - https://onlinelibrary.wiley.com/doi/abs/10.1002/prep.202100105
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4612
AB  - Three azido-esters based green energetic plasticizers were synthesized from their chlorides including DEGBAA (diethyleneglycol bis(azidoacetate)), DPGBAA (dipropyleneglycol bis(azidoacetate)) and HETTAA (hexanetriol tris(azidoacetate)). The syntheses were carried out in a two-step process: the first step was esterification of glycol or triol using chloroacetyl chloride, and the second step was substitution of chloracetate with sodium azide that yields corresponding azido derivatives. The parameters of synthesis such as molar ratio of hydroxyl and acyl groups, and amount and type of solvent (dimethyl sulfoxide and dimethyl formamide) were optimized to achieve maximal conversion and purity of the products. The obtained products were characterized by elemental analysis, nuclear magnetic resonance (NMR), and infrared vibrational spectroscopy (IR). Thermal and rheological properties were determined using DSC and Modular Compact Rheometer. Condensed phase heat of formation and several properties important for high-energy materials were predicted from quantum chemical calculations using CBS-4M method. Detonation and combustion performance of energetic compounds were calculated with the thermochemical computer code EXPLO5V06.05. using the predicted heats of formation and experimentally determined densities as input. The energetic and physical properties of the synthesized compounds were compared to the literature data for common plasticizers.
PB  - Wiley
T2  - Propellants, Explosives, Pyrotechnics
T1  - Synthesis and Characterization of Azido Esters as Green Energetic Plasticizers
DO  - 10.1002/prep.202100105
ER  - 
@article{
author = "Nešić, Jovica and Cvijetić, Ilija and Bogdanov, Jovica and Marinković, Aleksandar",
year = "2021",
abstract = "Three azido-esters based green energetic plasticizers were synthesized from their chlorides including DEGBAA (diethyleneglycol bis(azidoacetate)), DPGBAA (dipropyleneglycol bis(azidoacetate)) and HETTAA (hexanetriol tris(azidoacetate)). The syntheses were carried out in a two-step process: the first step was esterification of glycol or triol using chloroacetyl chloride, and the second step was substitution of chloracetate with sodium azide that yields corresponding azido derivatives. The parameters of synthesis such as molar ratio of hydroxyl and acyl groups, and amount and type of solvent (dimethyl sulfoxide and dimethyl formamide) were optimized to achieve maximal conversion and purity of the products. The obtained products were characterized by elemental analysis, nuclear magnetic resonance (NMR), and infrared vibrational spectroscopy (IR). Thermal and rheological properties were determined using DSC and Modular Compact Rheometer. Condensed phase heat of formation and several properties important for high-energy materials were predicted from quantum chemical calculations using CBS-4M method. Detonation and combustion performance of energetic compounds were calculated with the thermochemical computer code EXPLO5V06.05. using the predicted heats of formation and experimentally determined densities as input. The energetic and physical properties of the synthesized compounds were compared to the literature data for common plasticizers.",
publisher = "Wiley",
journal = "Propellants, Explosives, Pyrotechnics",
title = "Synthesis and Characterization of Azido Esters as Green Energetic Plasticizers",
doi = "10.1002/prep.202100105"
}
Nešić, J., Cvijetić, I., Bogdanov, J.,& Marinković, A.. (2021). Synthesis and Characterization of Azido Esters as Green Energetic Plasticizers. in Propellants, Explosives, Pyrotechnics
Wiley..
https://doi.org/10.1002/prep.202100105
Nešić J, Cvijetić I, Bogdanov J, Marinković A. Synthesis and Characterization of Azido Esters as Green Energetic Plasticizers. in Propellants, Explosives, Pyrotechnics. 2021;.
doi:10.1002/prep.202100105 .
Nešić, Jovica, Cvijetić, Ilija, Bogdanov, Jovica, Marinković, Aleksandar, "Synthesis and Characterization of Azido Esters as Green Energetic Plasticizers" in Propellants, Explosives, Pyrotechnics (2021),
https://doi.org/10.1002/prep.202100105 . .

Supplementary data for the article: Nešić, J.; Cvijetić, I. N.; Bogdanov, J.; Marinković, A. Synthesis and Characterization of Azido Esters as Green Energetic Plasticizers. Propellants, Explosives, Pyrotechnics n/a (n/a). https://doi.org/10.1002/prep.202100105.

Nešić, Jovica; Cvijetić, Ilija; Bogdanov, Jovica; Marinković, Aleksandar

(Wiley, 2021)

TY  - DATA
AU  - Nešić, Jovica
AU  - Cvijetić, Ilija
AU  - Bogdanov, Jovica
AU  - Marinković, Aleksandar
PY  - 2021
UR  - https://onlinelibrary.wiley.com/doi/abs/10.1002/prep.202100105
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4613
PB  - Wiley
T2  - Propellants, Explosives, Pyrotechnics
T1  - Supplementary data for the article: Nešić, J.; Cvijetić, I. N.; Bogdanov, J.; Marinković, A. Synthesis and Characterization of Azido Esters as Green Energetic Plasticizers. Propellants, Explosives, Pyrotechnics n/a (n/a). https://doi.org/10.1002/prep.202100105.
ER  - 
@misc{
author = "Nešić, Jovica and Cvijetić, Ilija and Bogdanov, Jovica and Marinković, Aleksandar",
year = "2021",
publisher = "Wiley",
journal = "Propellants, Explosives, Pyrotechnics",
title = "Supplementary data for the article: Nešić, J.; Cvijetić, I. N.; Bogdanov, J.; Marinković, A. Synthesis and Characterization of Azido Esters as Green Energetic Plasticizers. Propellants, Explosives, Pyrotechnics n/a (n/a). https://doi.org/10.1002/prep.202100105."
}
Nešić, J., Cvijetić, I., Bogdanov, J.,& Marinković, A.. (2021). Supplementary data for the article: Nešić, J.; Cvijetić, I. N.; Bogdanov, J.; Marinković, A. Synthesis and Characterization of Azido Esters as Green Energetic Plasticizers. Propellants, Explosives, Pyrotechnics n/a (n/a). https://doi.org/10.1002/prep.202100105.. in Propellants, Explosives, Pyrotechnics
Wiley..
Nešić J, Cvijetić I, Bogdanov J, Marinković A. Supplementary data for the article: Nešić, J.; Cvijetić, I. N.; Bogdanov, J.; Marinković, A. Synthesis and Characterization of Azido Esters as Green Energetic Plasticizers. Propellants, Explosives, Pyrotechnics n/a (n/a). https://doi.org/10.1002/prep.202100105.. in Propellants, Explosives, Pyrotechnics. 2021;..
Nešić, Jovica, Cvijetić, Ilija, Bogdanov, Jovica, Marinković, Aleksandar, "Supplementary data for the article: Nešić, J.; Cvijetić, I. N.; Bogdanov, J.; Marinković, A. Synthesis and Characterization of Azido Esters as Green Energetic Plasticizers. Propellants, Explosives, Pyrotechnics n/a (n/a). https://doi.org/10.1002/prep.202100105." in Propellants, Explosives, Pyrotechnics (2021).

Interaction, binding capacity and anticancer properties of N,N′-bis(acetylacetone)-propylenediimine-copper(II) on colorectal cancer cell line Caco-2

Stevanović, Nikola R.; Apostolović, Danijela; Milčić, Miloš K.; Lolić, Aleksandar; Hage, Marianne van; Ćirković-Veličković, Tanja; Baošić, Rada

(2021)

TY  - JOUR
AU  - Stevanović, Nikola R.
AU  - Apostolović, Danijela
AU  - Milčić, Miloš K.
AU  - Lolić, Aleksandar
AU  - Hage, Marianne van
AU  - Ćirković-Veličković, Tanja
AU  - Baošić, Rada
PY  - 2021
UR  - https://pubs.rsc.org/en/content/articlelanding/2021/nj/d1nj00040c
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4399
AB  - Different Schiff base complexes have biological activities that make them suitable for drug design. The biological properties of tetradentate Schiff base copper(II) complexed with N,N′-bis(acetylacetone)propylenediimine have been studied. The cytotoxic activity towards Caco-2 cells were determined by MTT, Anexin V and PI apoptosis assays. N,N′-bis(acetylacetone)propylenediimine-copper(II) showed the anti-cancer and anti-proliferative properties by inducing apoptosis in Caco-2 cells. A comparison of the cytotoxic activity of this compound with cisplatin shows that it is more effective on the colorectal cancer cell line Caco-2. The binding capacity and interaction of N,N′-bis(acetylacetone)propylenediimine-copper(II) with HSA were systemically investigated by in vitro fluorescence spectroscopy, CD spectroscopy, and in silico molecular docking study. Furthermore, in vitro and in silico interaction studies indicated that the complex binds to HSA through a static quenching mechanism without changes in protein conformation. The calculated number of binding sites was in line with molecular docking studies. The obtained Ka value suggests that the compound can be released from the protein in target cells. The tetradentate Schiff base copper(II) complex exhibited in vitro biological activities against cancer epithelial cells, which depend on the molecular structure of the complex, causing apoptosis, and the complex can bind to the protein drug carrier in circulation to the target tissue.
T2  - New Journal of Chemistry
T1  - Interaction, binding capacity and anticancer properties of N,N′-bis(acetylacetone)-propylenediimine-copper(II) on colorectal cancer cell line Caco-2
VL  - 45
IS  - 14
SP  - 6231
EP  - 6237
DO  - 10.1039/D1NJ00040C
ER  - 
@article{
author = "Stevanović, Nikola R. and Apostolović, Danijela and Milčić, Miloš K. and Lolić, Aleksandar and Hage, Marianne van and Ćirković-Veličković, Tanja and Baošić, Rada",
year = "2021",
abstract = "Different Schiff base complexes have biological activities that make them suitable for drug design. The biological properties of tetradentate Schiff base copper(II) complexed with N,N′-bis(acetylacetone)propylenediimine have been studied. The cytotoxic activity towards Caco-2 cells were determined by MTT, Anexin V and PI apoptosis assays. N,N′-bis(acetylacetone)propylenediimine-copper(II) showed the anti-cancer and anti-proliferative properties by inducing apoptosis in Caco-2 cells. A comparison of the cytotoxic activity of this compound with cisplatin shows that it is more effective on the colorectal cancer cell line Caco-2. The binding capacity and interaction of N,N′-bis(acetylacetone)propylenediimine-copper(II) with HSA were systemically investigated by in vitro fluorescence spectroscopy, CD spectroscopy, and in silico molecular docking study. Furthermore, in vitro and in silico interaction studies indicated that the complex binds to HSA through a static quenching mechanism without changes in protein conformation. The calculated number of binding sites was in line with molecular docking studies. The obtained Ka value suggests that the compound can be released from the protein in target cells. The tetradentate Schiff base copper(II) complex exhibited in vitro biological activities against cancer epithelial cells, which depend on the molecular structure of the complex, causing apoptosis, and the complex can bind to the protein drug carrier in circulation to the target tissue.",
journal = "New Journal of Chemistry",
title = "Interaction, binding capacity and anticancer properties of N,N′-bis(acetylacetone)-propylenediimine-copper(II) on colorectal cancer cell line Caco-2",
volume = "45",
number = "14",
pages = "6231-6237",
doi = "10.1039/D1NJ00040C"
}
Stevanović, N. R., Apostolović, D., Milčić, M. K., Lolić, A., Hage, M. v., Ćirković-Veličković, T.,& Baošić, R.. (2021). Interaction, binding capacity and anticancer properties of N,N′-bis(acetylacetone)-propylenediimine-copper(II) on colorectal cancer cell line Caco-2. in New Journal of Chemistry, 45(14), 6231-6237.
https://doi.org/10.1039/D1NJ00040C
Stevanović NR, Apostolović D, Milčić MK, Lolić A, Hage MV, Ćirković-Veličković T, Baošić R. Interaction, binding capacity and anticancer properties of N,N′-bis(acetylacetone)-propylenediimine-copper(II) on colorectal cancer cell line Caco-2. in New Journal of Chemistry. 2021;45(14):6231-6237.
doi:10.1039/D1NJ00040C .
Stevanović, Nikola R., Apostolović, Danijela, Milčić, Miloš K., Lolić, Aleksandar, Hage, Marianne van, Ćirković-Veličković, Tanja, Baošić, Rada, "Interaction, binding capacity and anticancer properties of N,N′-bis(acetylacetone)-propylenediimine-copper(II) on colorectal cancer cell line Caco-2" in New Journal of Chemistry, 45, no. 14 (2021):6231-6237,
https://doi.org/10.1039/D1NJ00040C . .

Supplementary data for the article: Stevanović, N.; Apostolović, D.; Milčić, M.; Lolić, A.; Hage, M. van; Veličković, T. Ć.; Baošić, R. Interaction, Binding Capacity and Anticancer Properties of N,N′-Bis(Acetylacetone)-Propylenediimine-Copper(II) on Colorectal Cancer Cell Line Caco-2. New J. Chem. 2021, 45 (14), 6231–6237. https://doi.org/10.1039/D1NJ00040C.

Stevanović, Nikola R.; Apostolović, Danijela; Milčić, Miloš K.; Lolić, Aleksandar; Hage, Marianne van; Ćirković-Veličković, Tanja; Baošić, Rada

(2021)

TY  - DATA
AU  - Stevanović, Nikola R.
AU  - Apostolović, Danijela
AU  - Milčić, Miloš K.
AU  - Lolić, Aleksandar
AU  - Hage, Marianne van
AU  - Ćirković-Veličković, Tanja
AU  - Baošić, Rada
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4400
T2  - New Journal of Chemistry
T1  - Supplementary data for the article: Stevanović, N.; Apostolović, D.; Milčić, M.; Lolić, A.; Hage, M. van; Veličković, T. Ć.; Baošić, R. Interaction, Binding Capacity and Anticancer Properties of N,N′-Bis(Acetylacetone)-Propylenediimine-Copper(II) on Colorectal Cancer Cell Line Caco-2. New J. Chem. 2021, 45 (14), 6231–6237. https://doi.org/10.1039/D1NJ00040C.
ER  - 
@misc{
author = "Stevanović, Nikola R. and Apostolović, Danijela and Milčić, Miloš K. and Lolić, Aleksandar and Hage, Marianne van and Ćirković-Veličković, Tanja and Baošić, Rada",
year = "2021",
journal = "New Journal of Chemistry",
title = "Supplementary data for the article: Stevanović, N.; Apostolović, D.; Milčić, M.; Lolić, A.; Hage, M. van; Veličković, T. Ć.; Baošić, R. Interaction, Binding Capacity and Anticancer Properties of N,N′-Bis(Acetylacetone)-Propylenediimine-Copper(II) on Colorectal Cancer Cell Line Caco-2. New J. Chem. 2021, 45 (14), 6231–6237. https://doi.org/10.1039/D1NJ00040C."
}
Stevanović, N. R., Apostolović, D., Milčić, M. K., Lolić, A., Hage, M. v., Ćirković-Veličković, T.,& Baošić, R.. (2021). Supplementary data for the article: Stevanović, N.; Apostolović, D.; Milčić, M.; Lolić, A.; Hage, M. van; Veličković, T. Ć.; Baošić, R. Interaction, Binding Capacity and Anticancer Properties of N,N′-Bis(Acetylacetone)-Propylenediimine-Copper(II) on Colorectal Cancer Cell Line Caco-2. New J. Chem. 2021, 45 (14), 6231–6237. https://doi.org/10.1039/D1NJ00040C.. in New Journal of Chemistry.
Stevanović NR, Apostolović D, Milčić MK, Lolić A, Hage MV, Ćirković-Veličković T, Baošić R. Supplementary data for the article: Stevanović, N.; Apostolović, D.; Milčić, M.; Lolić, A.; Hage, M. van; Veličković, T. Ć.; Baošić, R. Interaction, Binding Capacity and Anticancer Properties of N,N′-Bis(Acetylacetone)-Propylenediimine-Copper(II) on Colorectal Cancer Cell Line Caco-2. New J. Chem. 2021, 45 (14), 6231–6237. https://doi.org/10.1039/D1NJ00040C.. in New Journal of Chemistry. 2021;..
Stevanović, Nikola R., Apostolović, Danijela, Milčić, Miloš K., Lolić, Aleksandar, Hage, Marianne van, Ćirković-Veličković, Tanja, Baošić, Rada, "Supplementary data for the article: Stevanović, N.; Apostolović, D.; Milčić, M.; Lolić, A.; Hage, M. van; Veličković, T. Ć.; Baošić, R. Interaction, Binding Capacity and Anticancer Properties of N,N′-Bis(Acetylacetone)-Propylenediimine-Copper(II) on Colorectal Cancer Cell Line Caco-2. New J. Chem. 2021, 45 (14), 6231–6237. https://doi.org/10.1039/D1NJ00040C." in New Journal of Chemistry (2021).

Synthesis, physicochemical characterization, and TD–DFT calculations of monothiocarbohydrazone derivatives

Mrđan, Gorana S.; Vastag, Gyöngyi Gy.; Škorić, Dušan Đ.; Radanović, Mirjana M.; Verbić, Tatjana; Milčić, Miloš K.; Stojiljković, Ivana N.; Marković, Olivera S.; Matijević, Borko M.

(Springer Nature, 2021)

TY  - JOUR
AU  - Mrđan, Gorana S.
AU  - Vastag, Gyöngyi Gy.
AU  - Škorić, Dušan Đ.
AU  - Radanović, Mirjana M.
AU  - Verbić, Tatjana
AU  - Milčić, Miloš K.
AU  - Stojiljković, Ivana N.
AU  - Marković, Olivera S.
AU  - Matijević, Borko M.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4453
AB  - Derivatives of thiocarbohydrazone studied so far have shown great biological activity such as antioxidant, antimicrobial, and anticancer. Most of these compounds are bis-substituted derivatives, while monothiocarbohydrazones are much less investigated. Еighteen monothiocarbohydrazones were synthesized and subjected to physicochemical characterization in order to facilitate the examination of their potential biological activity and application in future studies. The structure of synthesized derivatives was confirmed with NMR and FT–IR spectroscopy, and with elemental analysis. For one of the compounds, single-crystal X-ray diffraction analysis was performed. Specific and non-specific molecular interactions were interpreted by LSER principles, using Catalan’s model. For additional information about the dominance and influence of the interactions presented, correlations with Hansen’s solubility parameters were calculated. Influence of the type and position of the substituent on absorption maxima was determined with LFER (linear free-energy relationship) principles, using Hammett’s equation. Acidity constants of the synthesized compounds were theoretically calculated and experimentally determined. Moreover, the excitation of a molecule by a photon of UV–Vis light was interpreted by time-dependent density functional theory (TD–DFT) calculations of UV absorption bands, and intramolecular charge transfer (ICT) was quantified by calculations of the charge transfer distances (DCT). © 2021, The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature.
PB  - Springer Nature
T2  - Structural Chemistry
T2  - Structural Chemistry
T2  - Structural Chemistry
T1  - Synthesis, physicochemical characterization, and TD–DFT calculations of monothiocarbohydrazone derivatives
VL  - 32
IS  - 3
SP  - 1231
EP  - 1245
DO  - 10.1007/s11224-020-01700-y
ER  - 
@article{
author = "Mrđan, Gorana S. and Vastag, Gyöngyi Gy. and Škorić, Dušan Đ. and Radanović, Mirjana M. and Verbić, Tatjana and Milčić, Miloš K. and Stojiljković, Ivana N. and Marković, Olivera S. and Matijević, Borko M.",
year = "2021",
abstract = "Derivatives of thiocarbohydrazone studied so far have shown great biological activity such as antioxidant, antimicrobial, and anticancer. Most of these compounds are bis-substituted derivatives, while monothiocarbohydrazones are much less investigated. Еighteen monothiocarbohydrazones were synthesized and subjected to physicochemical characterization in order to facilitate the examination of their potential biological activity and application in future studies. The structure of synthesized derivatives was confirmed with NMR and FT–IR spectroscopy, and with elemental analysis. For one of the compounds, single-crystal X-ray diffraction analysis was performed. Specific and non-specific molecular interactions were interpreted by LSER principles, using Catalan’s model. For additional information about the dominance and influence of the interactions presented, correlations with Hansen’s solubility parameters were calculated. Influence of the type and position of the substituent on absorption maxima was determined with LFER (linear free-energy relationship) principles, using Hammett’s equation. Acidity constants of the synthesized compounds were theoretically calculated and experimentally determined. Moreover, the excitation of a molecule by a photon of UV–Vis light was interpreted by time-dependent density functional theory (TD–DFT) calculations of UV absorption bands, and intramolecular charge transfer (ICT) was quantified by calculations of the charge transfer distances (DCT). © 2021, The Author(s), under exclusive licence to Springer Science+Business Media, LLC part of Springer Nature.",
publisher = "Springer Nature",
journal = "Structural Chemistry, Structural Chemistry, Structural Chemistry",
title = "Synthesis, physicochemical characterization, and TD–DFT calculations of monothiocarbohydrazone derivatives",
volume = "32",
number = "3",
pages = "1231-1245",
doi = "10.1007/s11224-020-01700-y"
}
Mrđan, G. S., Vastag, G. Gy., Škorić, D. Đ., Radanović, M. M., Verbić, T., Milčić, M. K., Stojiljković, I. N., Marković, O. S.,& Matijević, B. M.. (2021). Synthesis, physicochemical characterization, and TD–DFT calculations of monothiocarbohydrazone derivatives. in Structural Chemistry
Springer Nature., 32(3), 1231-1245.
https://doi.org/10.1007/s11224-020-01700-y
Mrđan GS, Vastag GG, Škorić DĐ, Radanović MM, Verbić T, Milčić MK, Stojiljković IN, Marković OS, Matijević BM. Synthesis, physicochemical characterization, and TD–DFT calculations of monothiocarbohydrazone derivatives. in Structural Chemistry. 2021;32(3):1231-1245.
doi:10.1007/s11224-020-01700-y .
Mrđan, Gorana S., Vastag, Gyöngyi Gy., Škorić, Dušan Đ., Radanović, Mirjana M., Verbić, Tatjana, Milčić, Miloš K., Stojiljković, Ivana N., Marković, Olivera S., Matijević, Borko M., "Synthesis, physicochemical characterization, and TD–DFT calculations of monothiocarbohydrazone derivatives" in Structural Chemistry, 32, no. 3 (2021):1231-1245,
https://doi.org/10.1007/s11224-020-01700-y . .

Supplementary data for the article: Mrđan, G. S.; Vastag, G. G.; Škorić, D. Đ.; Radanović, M. M.; Verbić, T. Ž.; Milčić, M. K.; Stojiljković, I. N.; Marković, O. S.; Matijević, B. M. Synthesis, Physicochemical Characterization, and TD–DFT Calculations of Monothiocarbohydrazone Derivatives. Structural Chemistry 2021, 32 (3), 1231–1245. https://doi.org/10.1007/s11224-020-01700-y.

Mrđan, Gorana S.; Vastag, Gyöngyi Gy.; Škorić, Dušan Đ.; Radanović, Mirjana M.; Verbić, Tatjana; Milčić, Miloš K.; Stojiljković, Ivana N.; Marković, Olivera S.; Matijević, Borko M.

(Springer Nature, 2021)

TY  - DATA
AU  - Mrđan, Gorana S.
AU  - Vastag, Gyöngyi Gy.
AU  - Škorić, Dušan Đ.
AU  - Radanović, Mirjana M.
AU  - Verbić, Tatjana
AU  - Milčić, Miloš K.
AU  - Stojiljković, Ivana N.
AU  - Marković, Olivera S.
AU  - Matijević, Borko M.
PY  - 2021
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4454
PB  - Springer Nature
T2  - Structural Chemistry
T1  - Supplementary data for the article: Mrđan, G. S.; Vastag, G. G.; Škorić, D. Đ.; Radanović, M. M.; Verbić, T. Ž.; Milčić, M. K.; Stojiljković, I. N.; Marković, O. S.; Matijević, B. M. Synthesis, Physicochemical Characterization, and TD–DFT Calculations of Monothiocarbohydrazone Derivatives. Structural Chemistry 2021, 32 (3), 1231–1245. https://doi.org/10.1007/s11224-020-01700-y.
ER  - 
@misc{
author = "Mrđan, Gorana S. and Vastag, Gyöngyi Gy. and Škorić, Dušan Đ. and Radanović, Mirjana M. and Verbić, Tatjana and Milčić, Miloš K. and Stojiljković, Ivana N. and Marković, Olivera S. and Matijević, Borko M.",
year = "2021",
publisher = "Springer Nature",
journal = "Structural Chemistry",
title = "Supplementary data for the article: Mrđan, G. S.; Vastag, G. G.; Škorić, D. Đ.; Radanović, M. M.; Verbić, T. Ž.; Milčić, M. K.; Stojiljković, I. N.; Marković, O. S.; Matijević, B. M. Synthesis, Physicochemical Characterization, and TD–DFT Calculations of Monothiocarbohydrazone Derivatives. Structural Chemistry 2021, 32 (3), 1231–1245. https://doi.org/10.1007/s11224-020-01700-y."
}
Mrđan, G. S., Vastag, G. Gy., Škorić, D. Đ., Radanović, M. M., Verbić, T., Milčić, M. K., Stojiljković, I. N., Marković, O. S.,& Matijević, B. M.. (2021). Supplementary data for the article: Mrđan, G. S.; Vastag, G. G.; Škorić, D. Đ.; Radanović, M. M.; Verbić, T. Ž.; Milčić, M. K.; Stojiljković, I. N.; Marković, O. S.; Matijević, B. M. Synthesis, Physicochemical Characterization, and TD–DFT Calculations of Monothiocarbohydrazone Derivatives. Structural Chemistry 2021, 32 (3), 1231–1245. https://doi.org/10.1007/s11224-020-01700-y.. in Structural Chemistry
Springer Nature..
Mrđan GS, Vastag GG, Škorić DĐ, Radanović MM, Verbić T, Milčić MK, Stojiljković IN, Marković OS, Matijević BM. Supplementary data for the article: Mrđan, G. S.; Vastag, G. G.; Škorić, D. Đ.; Radanović, M. M.; Verbić, T. Ž.; Milčić, M. K.; Stojiljković, I. N.; Marković, O. S.; Matijević, B. M. Synthesis, Physicochemical Characterization, and TD–DFT Calculations of Monothiocarbohydrazone Derivatives. Structural Chemistry 2021, 32 (3), 1231–1245. https://doi.org/10.1007/s11224-020-01700-y.. in Structural Chemistry. 2021;..
Mrđan, Gorana S., Vastag, Gyöngyi Gy., Škorić, Dušan Đ., Radanović, Mirjana M., Verbić, Tatjana, Milčić, Miloš K., Stojiljković, Ivana N., Marković, Olivera S., Matijević, Borko M., "Supplementary data for the article: Mrđan, G. S.; Vastag, G. G.; Škorić, D. Đ.; Radanović, M. M.; Verbić, T. Ž.; Milčić, M. K.; Stojiljković, I. N.; Marković, O. S.; Matijević, B. M. Synthesis, Physicochemical Characterization, and TD–DFT Calculations of Monothiocarbohydrazone Derivatives. Structural Chemistry 2021, 32 (3), 1231–1245. https://doi.org/10.1007/s11224-020-01700-y." in Structural Chemistry (2021).

Antipsychotic clozapine binding to alpha-2-macroglobulin protects interacting partners against oxidation and preserves the anti-proteinase activity of the protein

Šunderić, Miloš; Vasović, Tamara; Milčić, Miloš K.; Miljević, Čedo; Nedić, Olgica; Nikolić, Milan ; Gligorijević, Nikola

(Elsevier, 2021)

TY  - JOUR
AU  - Šunderić, Miloš
AU  - Vasović, Tamara
AU  - Milčić, Miloš K.
AU  - Miljević, Čedo
AU  - Nedić, Olgica
AU  - Nikolić, Milan 
AU  - Gligorijević, Nikola
PY  - 2021
UR  - https://www.sciencedirect.com/science/article/pii/S0141813021009284
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/4538
AB  - In this study, the interaction between clozapine, an atypical antipsychotic drug, and alpha-2-macroglobulin (α2M), a multipurpose anti-proteinase, was investigated under simulated (patho) physiological conditions using multiple spectroscopic techniques and molecular modeling. It was found that α2M binds clozapine with a moderate affinity (the binding constant of 0.9 × 105 M−1 at 37 °C). The preferable binding site for both clozapine's atropisomers was revealed to be a large pocket at the interface of C and D monomer subunits of the protein. Hydrogen bonds and the hydrophobic effect were proposed as dominant forces in complex formation. The binding of clozapine did not induce significant conformational change of the protein, as confirmed by virtually unaltered α2M secondary structure and anti-proteinase activity. However, both clozapine and α2M shielded each other from the deleterious influence of strong oxidants: sodium hypochlorite and 2,2′-azobis-2-methyl-propanimidamide dihydrochloride (AAPH). Moreover, clozapine in a concentration range that is usually targeted in the plasma during patients' treatment effectively protected the anti-proteinase activity of α2M under AAPH-induced free radical overproduction. Our results suggest that the cooperation between α2M and clozapine may be a path by which these two molecules synergistically protect neural tissue against injury caused by disturbed proteostasis or oxidative stress.
PB  - Elsevier
T2  - International Journal of Biological Macromolecules
T1  - Antipsychotic clozapine binding to alpha-2-macroglobulin protects interacting partners against oxidation and preserves the anti-proteinase activity of the protein
VL  - 183
SP  - 502
EP  - 512
DO  - 10.1016/j.ijbiomac.2021.04.155
ER  - 
@article{
author = "Šunderić, Miloš and Vasović, Tamara and Milčić, Miloš K. and Miljević, Čedo and Nedić, Olgica and Nikolić, Milan  and Gligorijević, Nikola",
year = "2021",
abstract = "In this study, the interaction between clozapine, an atypical antipsychotic drug, and alpha-2-macroglobulin (α2M), a multipurpose anti-proteinase, was investigated under simulated (patho) physiological conditions using multiple spectroscopic techniques and molecular modeling. It was found that α2M binds clozapine with a moderate affinity (the binding constant of 0.9 × 105 M−1 at 37 °C). The preferable binding site for both clozapine's atropisomers was revealed to be a large pocket at the interface of C and D monomer subunits of the protein. Hydrogen bonds and the hydrophobic effect were proposed as dominant forces in complex formation. The binding of clozapine did not induce significant conformational change of the protein, as confirmed by virtually unaltered α2M secondary structure and anti-proteinase activity. However, both clozapine and α2M shielded each other from the deleterious influence of strong oxidants: sodium hypochlorite and 2,2′-azobis-2-methyl-propanimidamide dihydrochloride (AAPH). Moreover, clozapine in a concentration range that is usually targeted in the plasma during patients' treatment effectively protected the anti-proteinase activity of α2M under AAPH-induced free radical overproduction. Our results suggest that the cooperation between α2M and clozapine may be a path by which these two molecules synergistically protect neural tissue against injury caused by disturbed proteostasis or oxidative stress.",
publisher = "Elsevier",
journal = "International Journal of Biological Macromolecules",
title = "Antipsychotic clozapine binding to alpha-2-macroglobulin protects interacting partners against oxidation and preserves the anti-proteinase activity of the protein",
volume = "183",
pages = "502-512",
doi = "10.1016/j.ijbiomac.2021.04.155"
}
Šunderić, M., Vasović, T., Milčić, M. K., Miljević, Č., Nedić, O., Nikolić, M.,& Gligorijević, N.. (2021). Antipsychotic clozapine binding to alpha-2-macroglobulin protects interacting partners against oxidation and preserves the anti-proteinase activity of the protein. in International Journal of Biological Macromolecules
Elsevier., 183, 502-512.
https://doi.org/10.1016/j.ijbiomac.2021.04.155
Šunderić M, Vasović T, Milčić MK, Miljević Č, Nedić O, Nikolić M, Gligorijević N. Antipsychotic clozapine binding to alpha-2-macroglobulin protects interacting partners against oxidation and preserves the anti-proteinase activity of the protein. in International Journal of Biological Macromolecules. 2021;183:502-512.
doi:10.1016/j.ijbiomac.2021.04.155 .
Šunderić, Miloš, Vasović, Tamara, Milčić, Miloš K., Miljević, Čedo, Nedić, Olgica, Nikolić, Milan , Gligorijević, Nikola, "Antipsychotic clozapine binding to alpha-2-macroglobulin protects interacting partners against oxidation and preserves the anti-proteinase activity of the protein" in International Journal of Biological Macromolecules, 183 (2021):502-512,
https://doi.org/10.1016/j.ijbiomac.2021.04.155 . .
2