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Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II)

Authorized Users Only
2009
Authors
Todorović, Tamara
Rychlewska, Urszula
Warżajtis, Beata
Radanović, Dušanka D.
Filipović, Nenad R.
Pajic, Ivana A.
Sladić, Dušan
Anđelković, Katarina K.
Article (Published version)
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Abstract
The bimetallic [Ni-2(H(2)L2)(2)](ClO4)(4) (1), [Ni-2(HL2)(H(2)L2)](ClO4)(3) (2) and [Zn-2(H(2)L2)(2)](BF4)(4) (3) complexes (H(2)L2 = N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide) were synthesized and characterized. The structure of complexes (1) and (2) was established by X-ray analysis. NMR spectroscopy was used for the characterization of complex (3). The complexes (1) and (2) were obtained from the same synthetic reaction and two crystal types of these complexes have been isolated during the fractional crystallization process. In complex (1) each Ni(II) ion is coordinated with two NNO donor atom sets from two H(2)L2 ligands forming an octahedral geometry. Similarly, in complex (2) the octahedral geometry of each Ni(II) ion is attained by coordination of two NNO donor atom sets, one from the neutral and the other from the monoanionic form of the ligand. The antimicrobial activity of the ligand and complexes is also presented. (C) 2009 Elsevier Ltd. All rights reserve...d.

Keywords:
Malonic acid dihydrazide derivative / Ni(II) and Zn(II) complexes / X-ray analysis / Antimicrobial activity
Source:
Polyhedron, 2009, 28, 12, 2397-2402
Publisher:
  • Pergamon-Elsevier Science Ltd, Oxford
Funding / projects:
  • Interakcije prirodnih proizvoda i njihovih analoga sa proteinima i nukleinskim kiselinama (RS-142026)

DOI: 10.1016/j.poly.2009.05.002

ISSN: 0277-5387

WoS: 000268994200014

Scopus: 2-s2.0-67650333161
[ Google Scholar ]
24
23
URI
https://cherry.chem.bg.ac.rs/handle/123456789/1007
Collections
  • Publikacije
Institution/Community
Hemijski fakultet
TY  - JOUR
AU  - Todorović, Tamara
AU  - Rychlewska, Urszula
AU  - Warżajtis, Beata
AU  - Radanović, Dušanka D.
AU  - Filipović, Nenad R.
AU  - Pajic, Ivana A.
AU  - Sladić, Dušan
AU  - Anđelković, Katarina K.
PY  - 2009
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1007
AB  - The bimetallic [Ni-2(H(2)L2)(2)](ClO4)(4) (1), [Ni-2(HL2)(H(2)L2)](ClO4)(3) (2) and [Zn-2(H(2)L2)(2)](BF4)(4) (3) complexes (H(2)L2 = N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide) were synthesized and characterized. The structure of complexes (1) and (2) was established by X-ray analysis. NMR spectroscopy was used for the characterization of complex (3). The complexes (1) and (2) were obtained from the same synthetic reaction and two crystal types of these complexes have been isolated during the fractional crystallization process. In complex (1) each Ni(II) ion is coordinated with two NNO donor atom sets from two H(2)L2 ligands forming an octahedral geometry. Similarly, in complex (2) the octahedral geometry of each Ni(II) ion is attained by coordination of two NNO donor atom sets, one from the neutral and the other from the monoanionic form of the ligand. The antimicrobial activity of the ligand and complexes is also presented. (C) 2009 Elsevier Ltd. All rights reserved.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Polyhedron
T1  - Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II)
VL  - 28
IS  - 12
SP  - 2397
EP  - 2402
DO  - 10.1016/j.poly.2009.05.002
UR  - Kon_2007
ER  - 
@article{
author = "Todorović, Tamara and Rychlewska, Urszula and Warżajtis, Beata and Radanović, Dušanka D. and Filipović, Nenad R. and Pajic, Ivana A. and Sladić, Dušan and Anđelković, Katarina K.",
year = "2009",
abstract = "The bimetallic [Ni-2(H(2)L2)(2)](ClO4)(4) (1), [Ni-2(HL2)(H(2)L2)](ClO4)(3) (2) and [Zn-2(H(2)L2)(2)](BF4)(4) (3) complexes (H(2)L2 = N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide) were synthesized and characterized. The structure of complexes (1) and (2) was established by X-ray analysis. NMR spectroscopy was used for the characterization of complex (3). The complexes (1) and (2) were obtained from the same synthetic reaction and two crystal types of these complexes have been isolated during the fractional crystallization process. In complex (1) each Ni(II) ion is coordinated with two NNO donor atom sets from two H(2)L2 ligands forming an octahedral geometry. Similarly, in complex (2) the octahedral geometry of each Ni(II) ion is attained by coordination of two NNO donor atom sets, one from the neutral and the other from the monoanionic form of the ligand. The antimicrobial activity of the ligand and complexes is also presented. (C) 2009 Elsevier Ltd. All rights reserved.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Polyhedron",
title = "Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II)",
volume = "28",
number = "12",
pages = "2397-2402",
doi = "10.1016/j.poly.2009.05.002",
url = "Kon_2007"
}
Todorović, T., Rychlewska, U., Warżajtis, B., Radanović, D. D., Filipović, N. R., Pajic, I. A., Sladić, D.,& Anđelković, K. K.. (2009). Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II). in Polyhedron
Pergamon-Elsevier Science Ltd, Oxford., 28(12), 2397-2402.
https://doi.org/10.1016/j.poly.2009.05.002
Kon_2007
Todorović T, Rychlewska U, Warżajtis B, Radanović DD, Filipović NR, Pajic IA, Sladić D, Anđelković KK. Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II). in Polyhedron. 2009;28(12):2397-2402.
doi:10.1016/j.poly.2009.05.002
Kon_2007 .
Todorović, Tamara, Rychlewska, Urszula, Warżajtis, Beata, Radanović, Dušanka D., Filipović, Nenad R., Pajic, Ivana A., Sladić, Dušan, Anđelković, Katarina K., "Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II)" in Polyhedron, 28, no. 12 (2009):2397-2402,
https://doi.org/10.1016/j.poly.2009.05.002 .,
Kon_2007 .

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