Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II)
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2009
Authors
Todorović, TamaraRychlewska, Urszula
Warżajtis, Beata
Radanović, Dušanka D.
Filipović, Nenad R.
Pajic, Ivana A.
Sladić, Dušan
Anđelković, Katarina K.
Article (Published version)
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The bimetallic [Ni-2(H(2)L2)(2)](ClO4)(4) (1), [Ni-2(HL2)(H(2)L2)](ClO4)(3) (2) and [Zn-2(H(2)L2)(2)](BF4)(4) (3) complexes (H(2)L2 = N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide) were synthesized and characterized. The structure of complexes (1) and (2) was established by X-ray analysis. NMR spectroscopy was used for the characterization of complex (3). The complexes (1) and (2) were obtained from the same synthetic reaction and two crystal types of these complexes have been isolated during the fractional crystallization process. In complex (1) each Ni(II) ion is coordinated with two NNO donor atom sets from two H(2)L2 ligands forming an octahedral geometry. Similarly, in complex (2) the octahedral geometry of each Ni(II) ion is attained by coordination of two NNO donor atom sets, one from the neutral and the other from the monoanionic form of the ligand. The antimicrobial activity of the ligand and complexes is also presented. (C) 2009 Elsevier Ltd. All rights reserve...d.
Keywords:
Malonic acid dihydrazide derivative / Ni(II) and Zn(II) complexes / X-ray analysis / Antimicrobial activitySource:
Polyhedron, 2009, 28, 12, 2397-2402Publisher:
- Pergamon-Elsevier Science Ltd, Oxford
Funding / projects:
- Interakcije prirodnih proizvoda i njihovih analoga sa proteinima i nukleinskim kiselinama (RS-MESTD-MPN2006-2010-142026)
DOI: 10.1016/j.poly.2009.05.002
ISSN: 0277-5387
WoS: 000268994200014
Scopus: 2-s2.0-67650333161
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Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Todorović, Tamara AU - Rychlewska, Urszula AU - Warżajtis, Beata AU - Radanović, Dušanka D. AU - Filipović, Nenad R. AU - Pajic, Ivana A. AU - Sladić, Dušan AU - Anđelković, Katarina K. PY - 2009 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1007 AB - The bimetallic [Ni-2(H(2)L2)(2)](ClO4)(4) (1), [Ni-2(HL2)(H(2)L2)](ClO4)(3) (2) and [Zn-2(H(2)L2)(2)](BF4)(4) (3) complexes (H(2)L2 = N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide) were synthesized and characterized. The structure of complexes (1) and (2) was established by X-ray analysis. NMR spectroscopy was used for the characterization of complex (3). The complexes (1) and (2) were obtained from the same synthetic reaction and two crystal types of these complexes have been isolated during the fractional crystallization process. In complex (1) each Ni(II) ion is coordinated with two NNO donor atom sets from two H(2)L2 ligands forming an octahedral geometry. Similarly, in complex (2) the octahedral geometry of each Ni(II) ion is attained by coordination of two NNO donor atom sets, one from the neutral and the other from the monoanionic form of the ligand. The antimicrobial activity of the ligand and complexes is also presented. (C) 2009 Elsevier Ltd. All rights reserved. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Polyhedron T1 - Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II) VL - 28 IS - 12 SP - 2397 EP - 2402 DO - 10.1016/j.poly.2009.05.002 ER -
@article{ author = "Todorović, Tamara and Rychlewska, Urszula and Warżajtis, Beata and Radanović, Dušanka D. and Filipović, Nenad R. and Pajic, Ivana A. and Sladić, Dušan and Anđelković, Katarina K.", year = "2009", abstract = "The bimetallic [Ni-2(H(2)L2)(2)](ClO4)(4) (1), [Ni-2(HL2)(H(2)L2)](ClO4)(3) (2) and [Zn-2(H(2)L2)(2)](BF4)(4) (3) complexes (H(2)L2 = N',N'(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide) were synthesized and characterized. The structure of complexes (1) and (2) was established by X-ray analysis. NMR spectroscopy was used for the characterization of complex (3). The complexes (1) and (2) were obtained from the same synthetic reaction and two crystal types of these complexes have been isolated during the fractional crystallization process. In complex (1) each Ni(II) ion is coordinated with two NNO donor atom sets from two H(2)L2 ligands forming an octahedral geometry. Similarly, in complex (2) the octahedral geometry of each Ni(II) ion is attained by coordination of two NNO donor atom sets, one from the neutral and the other from the monoanionic form of the ligand. The antimicrobial activity of the ligand and complexes is also presented. (C) 2009 Elsevier Ltd. All rights reserved.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Polyhedron", title = "Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II)", volume = "28", number = "12", pages = "2397-2402", doi = "10.1016/j.poly.2009.05.002" }
Todorović, T., Rychlewska, U., Warżajtis, B., Radanović, D. D., Filipović, N. R., Pajic, I. A., Sladić, D.,& Anđelković, K. K.. (2009). Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II). in Polyhedron Pergamon-Elsevier Science Ltd, Oxford., 28(12), 2397-2402. https://doi.org/10.1016/j.poly.2009.05.002
Todorović T, Rychlewska U, Warżajtis B, Radanović DD, Filipović NR, Pajic IA, Sladić D, Anđelković KK. Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II). in Polyhedron. 2009;28(12):2397-2402. doi:10.1016/j.poly.2009.05.002 .
Todorović, Tamara, Rychlewska, Urszula, Warżajtis, Beata, Radanović, Dušanka D., Filipović, Nenad R., Pajic, Ivana A., Sladić, Dušan, Anđelković, Katarina K., "Synthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N ',N '(2)-bis[(1E)-1-(2-pyridyl)ethylidene]propanedihydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II)" in Polyhedron, 28, no. 12 (2009):2397-2402, https://doi.org/10.1016/j.poly.2009.05.002 . .