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Palladium(II) complexes with R(2)edda derived ligands. Part III. Diisobutyl (S,S)-2,2 '-(1,2-ethanediyldiimino)di(4-methylpentanoate) and its palladium(II) complex: synthesis and characterization
Kompleksi paladijuma(II) sa ligandima R2edda tipa, deo III - diizobutil-(s,s)-2,2'-(1,2,-etandiildiimino)-di(4-metilpentanoat)-dihidrohlorid i njegov kompleks sa paladijumom(II) - sinteza i karakterizacija
dc.creator | Zmejkovski, Bojana B. | |
dc.creator | Kaluđerović, Goran N. | |
dc.creator | Gomez-Ruiz, Santiago | |
dc.creator | Sabo, Tibor | |
dc.date.accessioned | 2018-11-22T00:15:30Z | |
dc.date.available | 2018-11-22T00:15:30Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/1035 | |
dc.description.abstract | A new R(2)edda-type ester, diisobutyl (SS)-2,2'-(1,2-ethane-diyldiimino)di(4-methylpentanoate) dihydrochloride, [(S,S)-H(2)iBu(2)eddl]Cl-2, 1, and its palladium(II) complex, dichloro(diisobutyl (SS)-2,2'-(1,2-ethanediyldiimino)di(4-methylpentanoate))palladium(II), [PdCl2{(S,S)-iBu(2)eddl}], 2, were synthesized and characterized by elemental analysis, as well as IR and NMR spectroscopy. It was found that complex 2 was obtained as mixture of two diastereoisomers, observed in NMR spectra. The crystal structure of compound I was determined by X-ray diffraction studies and is described. The isolated crystals consisted of one dicationic species [(SS)-H(2)iBu(2)eddl](2+) and two Cl-. The crystal system was tetragonal with the space group P4(2). Hydrogen bonds significant for the manner of packing are N-H1N center dot center dot center dot Cl, 3.049(3) angstrom, 159(3)degrees and N-H2N center dot center dot center dot Cl, 3.100(3) angstrom, 164(3)degrees. An infinite chain was formed building a one layer structure, usual for these types of compounds. The C-2 symmetry axis of the compound passes through the Cl-Cl-i bond vector and lies perpendicular to the plane N2Cl2. | en |
dc.description.abstract | Novi estar R2edda-tipa diizobutil-(S,S)-2,2'-(1,2-etandiildiimino)-di(4-metilpen-tanoat)-dihidrohlorid [(S,S)-H2iBu2eddl]Cl2,1, i njegov kompleks paladijuma(II), dihlorodiizobutil-(S,S)-2,2'-(1,2-etandiildiimino)-di(4-metilpentanoat)-paladijum(II) [PdCl2{(S,S)-iBu2eddl}], 2, sintetisani su i okarakterisani uz pomoć elementalne analize, IR i NMR spektroskopije. Nađeno je da je kompleks 2 dobijen kao smeša dva dijastereoizomera, što je primećeno u NMR spektrima. Kristalna struktura 1 je rešena i opisana. Izolovani kristali se sastoje iz jedne dikatjonske vrste [(S,S)-H2iBu2eddl]2+ i dva Cl-. Kristalni sistem je tetragonalan sa prostornim grupom P42. Značajne vodonične veze za način pakovanja su N-H1N•••Cl, 3,049(3) Å, 159(3)°i N-H2N...Cl, 3,100(3) Å, 164(3)°. Time se formira beskonačan lanac i jednoslojna struktura, koji su uobičajeni za ove tipove struktura. Osa simetrije C2 jedinjenja prolazi kroz C1-C1i vektor veze i leži normalno na N2Cl2 ravan. PR Projekat Ministarstva nauke Republike Srbije, br. 142010. | sr |
dc.publisher | Serbian Chemical Soc, Belgrade | |
dc.relation | info:eu-repo/grantAgreement/MESTD/MPN2006-2010/142010/RS// | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Journal of the Serbian Chemical Society | |
dc.subject | palladium complexes | en |
dc.subject | crystal structure | en |
dc.subject | crystal structure | en |
dc.subject | EDDP ligands | en |
dc.subject | EDDP ligands | en |
dc.subject | characterization | en |
dc.subject | characterization | en |
dc.title | Palladium(II) complexes with R(2)edda derived ligands. Part III. Diisobutyl (S,S)-2,2 '-(1,2-ethanediyldiimino)di(4-methylpentanoate) and its palladium(II) complex: synthesis and characterization | en |
dc.title | Kompleksi paladijuma(II) sa ligandima R2edda tipa, deo III - diizobutil-(s,s)-2,2'-(1,2,-etandiildiimino)-di(4-metilpentanoat)-dihidrohlorid i njegov kompleks sa paladijumom(II) - sinteza i karakterizacija | sr |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dcterms.abstract | Гомез-Руиз, Сантиаго; Калудеровиц, Горан Н.; Змејковски, Бојана Б.; Сабо, Тибор; Комплекси паладијума(ИИ) са лигандима Р2едда типа, део ИИИ - диизобутил-(с,с)-2,2'-(1,2,-етандиилдиимино)-ди(4-метилпентаноат)-дихидрохлорид и његов комплекс са паладијумом(ИИ) - синтеза и карактеризација; Комплекси паладијума(ИИ) са лигандима Р2едда типа, део ИИИ - диизобутил-(с,с)-2,2'-(1,2,-етандиилдиимино)-ди(4-метилпентаноат)-дихидрохлорид и његов комплекс са паладијумом(ИИ) - синтеза и карактеризација; | |
dc.citation.volume | 74 | |
dc.citation.issue | 11 | |
dc.citation.spage | 1249 | |
dc.citation.epage | 1258 | |
dc.identifier.wos | 000272469700007 | |
dc.identifier.doi | 10.2298/JSC0911249Z | |
dc.citation.other | 74(11): 1249-1258 | |
dc.citation.rank | M23 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-77349108581 | |
dc.identifier.fulltext | https://cherry.chem.bg.ac.rs/bitstream/id/8241/1033.pdf |