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Fullerene Unsymmetrical Bis-Adducts as Models for Novel Peptidomimetics
dc.creator | Milić, Dragana | |
dc.creator | Prato, Maurizio | |
dc.date.accessioned | 2018-11-22T00:15:52Z | |
dc.date.available | 2018-11-22T00:15:52Z | |
dc.date.issued | 2010 | |
dc.identifier.issn | 1434-193X | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/1044 | |
dc.description.abstract | Two classes of unsymmetrical, orthogonally protected bis-fulleropyrrohdine amino acids have been prepared as models for fullerene-based peptidomimetics with the carbon sphere inserted into the peptide backbone Two successive [3+2] cycloadditions of azomethine ylides (thermally generated from formaldehyde and the corresponding orthogonally protected glycino-amines and -acids) to C(60) afforded NHFmoc/CO(2)tBu and NHBoc/CO(2)Me fulleropyrrolidine couples, offering the possibility of selective deprotection under both acidic and basic conditions In both classes of unsymmetrical bis-adducts, the distribution of all the trans (t(1)-t(4)) and equatorial (e' and e '') isomers was quite similar except. for the t(3) NHBoc/CO(2)Me compound, which rapidly decomposed during chromatography All compounds were characterized by UV/Vis, (1)H and (13)C NMR spectroscopy, and mass spectrometry | en |
dc.publisher | Wiley-V C H Verlag Gmbh, Weinheim | |
dc.relation | info:eu-repo/grantAgreement/MESTD/MPN2006-2010/142049/RS// | |
dc.relation | Italian Ministry of Education (MIUR) | |
dc.relation | University of Trieste | |
dc.rights | restrictedAccess | |
dc.source | European Journal of Organic Chemistry | |
dc.subject | Fullerenes | en |
dc.subject | Cycloaddition | en |
dc.subject | Aminoacids | en |
dc.subject | Heterocycles | en |
dc.subject | Peptidomimetics | en |
dc.title | Fullerene Unsymmetrical Bis-Adducts as Models for Novel Peptidomimetics | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Милић, Драгана; Прато, Мауризио; | |
dc.citation.issue | 3 | |
dc.citation.spage | 476 | |
dc.citation.epage | 483 | |
dc.identifier.wos | 000274429700011 | |
dc.identifier.doi | 10.1002/ejoc.200900791 | |
dc.citation.other | (3): 476-483 | |
dc.citation.rank | M21 | |
dc.type.version | publishedVersion | en |
dc.identifier.scopus | 2-s2.0-74549181299 |