Determination of Copper in Water by Anodic Stripping Voltammetry Using Cu-DPABA-NA/GCE Modified Electrode
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Stanković, DaliborRoglić, Goran
Mutić, Jelena
Anđelković, Ivan
Marković, Marijana
Manojlović, Dragan D.
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The determination of Cu by anodic stripping voltammetry using a Nafion-modified glassy carbon electrode incorporated with Cu-DPABA complex (Cu-DPABA-NA/GCE) was described. Cu was accumulated in acetic buffer pH 4 at potential of -1.4 V (vs. Ag/AgCl ref. electrode) and then determined with DPASV. Under the optimum conditions the calibration curve was linear in the range 7.0 x 10(-9) -5.0 x 10(-5) mol/L. The detection limit was 3.0 x 10(-9) mol/L. Different parameters and conditions, such as membrane ingredients, accumulation time and pH value was optimized. A study of the interfering substances was also performed. A significant increase in current was achieved at the modified electrode compared to a bare glassy carbon electrode. For explanation of voltammetric behavior of modified electrode in copper solution, cyclic voltammograms were recorded. The electrode was applied in the direct determination of Cu in water.
Keywords:
Modified electrode / anodic stripping voltammetry / copper determination / NafionSource:
International Journal of Electrochemical Science, 2011, 6, 11, 5617-5625Publisher:
- Electrochemical Science Group, Belgrade
Funding / projects:
- Application of advanced oxidation processes and nanostructured oxide materials for the removal of pollutants from the environment, development and optimisation of instrumental techniques for efficiency monitoring (RS-MESTD-Basic Research (BR or ON)-172030)
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Stanković, Dalibor AU - Roglić, Goran AU - Mutić, Jelena AU - Anđelković, Ivan AU - Marković, Marijana AU - Manojlović, Dragan D. PY - 2011 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1225 AB - The determination of Cu by anodic stripping voltammetry using a Nafion-modified glassy carbon electrode incorporated with Cu-DPABA complex (Cu-DPABA-NA/GCE) was described. Cu was accumulated in acetic buffer pH 4 at potential of -1.4 V (vs. Ag/AgCl ref. electrode) and then determined with DPASV. Under the optimum conditions the calibration curve was linear in the range 7.0 x 10(-9) -5.0 x 10(-5) mol/L. The detection limit was 3.0 x 10(-9) mol/L. Different parameters and conditions, such as membrane ingredients, accumulation time and pH value was optimized. A study of the interfering substances was also performed. A significant increase in current was achieved at the modified electrode compared to a bare glassy carbon electrode. For explanation of voltammetric behavior of modified electrode in copper solution, cyclic voltammograms were recorded. The electrode was applied in the direct determination of Cu in water. PB - Electrochemical Science Group, Belgrade T2 - International Journal of Electrochemical Science T1 - Determination of Copper in Water by Anodic Stripping Voltammetry Using Cu-DPABA-NA/GCE Modified Electrode VL - 6 IS - 11 SP - 5617 EP - 5625 UR - https://hdl.handle.net/21.15107/rcub_cherry_1225 ER -
@article{ author = "Stanković, Dalibor and Roglić, Goran and Mutić, Jelena and Anđelković, Ivan and Marković, Marijana and Manojlović, Dragan D.", year = "2011", abstract = "The determination of Cu by anodic stripping voltammetry using a Nafion-modified glassy carbon electrode incorporated with Cu-DPABA complex (Cu-DPABA-NA/GCE) was described. Cu was accumulated in acetic buffer pH 4 at potential of -1.4 V (vs. Ag/AgCl ref. electrode) and then determined with DPASV. Under the optimum conditions the calibration curve was linear in the range 7.0 x 10(-9) -5.0 x 10(-5) mol/L. The detection limit was 3.0 x 10(-9) mol/L. Different parameters and conditions, such as membrane ingredients, accumulation time and pH value was optimized. A study of the interfering substances was also performed. A significant increase in current was achieved at the modified electrode compared to a bare glassy carbon electrode. For explanation of voltammetric behavior of modified electrode in copper solution, cyclic voltammograms were recorded. The electrode was applied in the direct determination of Cu in water.", publisher = "Electrochemical Science Group, Belgrade", journal = "International Journal of Electrochemical Science", title = "Determination of Copper in Water by Anodic Stripping Voltammetry Using Cu-DPABA-NA/GCE Modified Electrode", volume = "6", number = "11", pages = "5617-5625", url = "https://hdl.handle.net/21.15107/rcub_cherry_1225" }
Stanković, D., Roglić, G., Mutić, J., Anđelković, I., Marković, M.,& Manojlović, D. D.. (2011). Determination of Copper in Water by Anodic Stripping Voltammetry Using Cu-DPABA-NA/GCE Modified Electrode. in International Journal of Electrochemical Science Electrochemical Science Group, Belgrade., 6(11), 5617-5625. https://hdl.handle.net/21.15107/rcub_cherry_1225
Stanković D, Roglić G, Mutić J, Anđelković I, Marković M, Manojlović DD. Determination of Copper in Water by Anodic Stripping Voltammetry Using Cu-DPABA-NA/GCE Modified Electrode. in International Journal of Electrochemical Science. 2011;6(11):5617-5625. https://hdl.handle.net/21.15107/rcub_cherry_1225 .
Stanković, Dalibor, Roglić, Goran, Mutić, Jelena, Anđelković, Ivan, Marković, Marijana, Manojlović, Dragan D., "Determination of Copper in Water by Anodic Stripping Voltammetry Using Cu-DPABA-NA/GCE Modified Electrode" in International Journal of Electrochemical Science, 6, no. 11 (2011):5617-5625, https://hdl.handle.net/21.15107/rcub_cherry_1225 .