Size-segregated mass concentration and water soluble inorganic ions in an urban aerosol of the Central Balkans (Belgrade)
Само за регистроване кориснике
2012
Аутори
Đorđević, Dragana S.Mihajlidi-Zelić, Aleksandra
Relić, Dubravka
Ignjatovic, Lj
Huremovic, J.
Stortini, Angela Maria
Gambaro, Andrea
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The distribution of nano/micron inorganic main ions in the size-segregated urban aerosol of Belgrade center was studied during the summer-autumn of 2008. The particle size distribution in the size ranges D(p) lt = 0.49 mu m, 0.49 lt = D(p) lt = 0.95 mu m, 0.95 lt = D(p) lt = 1.5 mu m, 1.5 lt = D(p) lt = 3.0 mu m, 3.0 lt = D(p) lt = 7.2 mu m and D(p) gt = 7.2 mu m was measured. The aerosol samples were submitted to gravimetric and chemical analyses. The obtained mean mass concentration of the PM fractions was in accordance with an urban aerosol distribution. The aerosol mass concentrations were determined by gravimetric measurements (m(GM)) and, analyzed by ion chromatography for Na(+), NH(4)(+), K(+), Mg(2+), Ca(2+), Cl(-), NO(3)(-), PO(4)(3-) and SO(4)(2-). The mean random uncertainties associated with the determinations of Na(+), NH(4)(+), K(+), Mg(2+), Ca(2+), Cl(-), NO(3)(-) and SO(4)(2-) were assessed. The absolute highest concentration is found for SO(4)(2-) (1555.8 +/-... 973.6 ng m(-3)) in the range of D(p) lt = 0.49 mu m with an average participation of 8.19% to the total mass of the particles. The highest coefficients of correlation were found between NH(4)(+) and SO(4)(2-). Principal component analysis, PCA, was used for the identification and evaluation of the contributions of the main emission sources to the contents of water soluble ions in the urban aerosol. The formation of (NH(4))(2)SO(4) was found to be the dominant process. The influences of local urban (traffic) and regional industrial sources (nearby city Pancevo) were identified and a contribution of marine aerosol was observed. (C) 2011 Elsevier Ltd. All rights reserved.
Кључне речи:
Size distribution / Urban aerosols / Water soluble main ionsИзвор:
Atmospheric Environment, 2012, 46, 309-317Издавач:
- Pergamon-Elsevier Science Ltd, Oxford
Финансирање / пројекти:
- Проучавање физичкохемијских и биохемијских процеса у животној средини који утичу на загађење и истраживање могућности за минимизирање последица (RS-MESTD-Basic Research (BR or ON)-172001)
- Истраживање климатских промена и њиховог утицаја на животну средину - праћење утицаја, адаптација и ублажавање (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43007)
- SIMCA project (INTER-REG/CARDS-PHARE Adriatic New Neighborhood Program) [06SER02/01/04]
DOI: 10.1016/j.atmosenv.2011.09.057
ISSN: 1352-2310
WoS: 000298763200035
Scopus: 2-s2.0-82955163011
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Đorđević, Dragana S. AU - Mihajlidi-Zelić, Aleksandra AU - Relić, Dubravka AU - Ignjatovic, Lj AU - Huremovic, J. AU - Stortini, Angela Maria AU - Gambaro, Andrea PY - 2012 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1239 AB - The distribution of nano/micron inorganic main ions in the size-segregated urban aerosol of Belgrade center was studied during the summer-autumn of 2008. The particle size distribution in the size ranges D(p) lt = 0.49 mu m, 0.49 lt = D(p) lt = 0.95 mu m, 0.95 lt = D(p) lt = 1.5 mu m, 1.5 lt = D(p) lt = 3.0 mu m, 3.0 lt = D(p) lt = 7.2 mu m and D(p) gt = 7.2 mu m was measured. The aerosol samples were submitted to gravimetric and chemical analyses. The obtained mean mass concentration of the PM fractions was in accordance with an urban aerosol distribution. The aerosol mass concentrations were determined by gravimetric measurements (m(GM)) and, analyzed by ion chromatography for Na(+), NH(4)(+), K(+), Mg(2+), Ca(2+), Cl(-), NO(3)(-), PO(4)(3-) and SO(4)(2-). The mean random uncertainties associated with the determinations of Na(+), NH(4)(+), K(+), Mg(2+), Ca(2+), Cl(-), NO(3)(-) and SO(4)(2-) were assessed. The absolute highest concentration is found for SO(4)(2-) (1555.8 +/- 973.6 ng m(-3)) in the range of D(p) lt = 0.49 mu m with an average participation of 8.19% to the total mass of the particles. The highest coefficients of correlation were found between NH(4)(+) and SO(4)(2-). Principal component analysis, PCA, was used for the identification and evaluation of the contributions of the main emission sources to the contents of water soluble ions in the urban aerosol. The formation of (NH(4))(2)SO(4) was found to be the dominant process. The influences of local urban (traffic) and regional industrial sources (nearby city Pancevo) were identified and a contribution of marine aerosol was observed. (C) 2011 Elsevier Ltd. All rights reserved. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Atmospheric Environment T1 - Size-segregated mass concentration and water soluble inorganic ions in an urban aerosol of the Central Balkans (Belgrade) VL - 46 SP - 309 EP - 317 DO - 10.1016/j.atmosenv.2011.09.057 ER -
@article{ author = "Đorđević, Dragana S. and Mihajlidi-Zelić, Aleksandra and Relić, Dubravka and Ignjatovic, Lj and Huremovic, J. and Stortini, Angela Maria and Gambaro, Andrea", year = "2012", abstract = "The distribution of nano/micron inorganic main ions in the size-segregated urban aerosol of Belgrade center was studied during the summer-autumn of 2008. The particle size distribution in the size ranges D(p) lt = 0.49 mu m, 0.49 lt = D(p) lt = 0.95 mu m, 0.95 lt = D(p) lt = 1.5 mu m, 1.5 lt = D(p) lt = 3.0 mu m, 3.0 lt = D(p) lt = 7.2 mu m and D(p) gt = 7.2 mu m was measured. The aerosol samples were submitted to gravimetric and chemical analyses. The obtained mean mass concentration of the PM fractions was in accordance with an urban aerosol distribution. The aerosol mass concentrations were determined by gravimetric measurements (m(GM)) and, analyzed by ion chromatography for Na(+), NH(4)(+), K(+), Mg(2+), Ca(2+), Cl(-), NO(3)(-), PO(4)(3-) and SO(4)(2-). The mean random uncertainties associated with the determinations of Na(+), NH(4)(+), K(+), Mg(2+), Ca(2+), Cl(-), NO(3)(-) and SO(4)(2-) were assessed. The absolute highest concentration is found for SO(4)(2-) (1555.8 +/- 973.6 ng m(-3)) in the range of D(p) lt = 0.49 mu m with an average participation of 8.19% to the total mass of the particles. The highest coefficients of correlation were found between NH(4)(+) and SO(4)(2-). Principal component analysis, PCA, was used for the identification and evaluation of the contributions of the main emission sources to the contents of water soluble ions in the urban aerosol. The formation of (NH(4))(2)SO(4) was found to be the dominant process. The influences of local urban (traffic) and regional industrial sources (nearby city Pancevo) were identified and a contribution of marine aerosol was observed. (C) 2011 Elsevier Ltd. All rights reserved.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Atmospheric Environment", title = "Size-segregated mass concentration and water soluble inorganic ions in an urban aerosol of the Central Balkans (Belgrade)", volume = "46", pages = "309-317", doi = "10.1016/j.atmosenv.2011.09.057" }
Đorđević, D. S., Mihajlidi-Zelić, A., Relić, D., Ignjatovic, L., Huremovic, J., Stortini, A. M.,& Gambaro, A.. (2012). Size-segregated mass concentration and water soluble inorganic ions in an urban aerosol of the Central Balkans (Belgrade). in Atmospheric Environment Pergamon-Elsevier Science Ltd, Oxford., 46, 309-317. https://doi.org/10.1016/j.atmosenv.2011.09.057
Đorđević DS, Mihajlidi-Zelić A, Relić D, Ignjatovic L, Huremovic J, Stortini AM, Gambaro A. Size-segregated mass concentration and water soluble inorganic ions in an urban aerosol of the Central Balkans (Belgrade). in Atmospheric Environment. 2012;46:309-317. doi:10.1016/j.atmosenv.2011.09.057 .
Đorđević, Dragana S., Mihajlidi-Zelić, Aleksandra, Relić, Dubravka, Ignjatovic, Lj, Huremovic, J., Stortini, Angela Maria, Gambaro, Andrea, "Size-segregated mass concentration and water soluble inorganic ions in an urban aerosol of the Central Balkans (Belgrade)" in Atmospheric Environment, 46 (2012):309-317, https://doi.org/10.1016/j.atmosenv.2011.09.057 . .