Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands
Authorized Users Only
2012
Authors
Šumar-Ristović, Maja
Gruden-Pavlović, Maja

Zlatar, Matija

Blagojević, Vladimir A.

Anđelković, Katarina K.

Poleti, Dejan
Minić, Dragica M.

Article (Published version)

Metadata
Show full item recordAbstract
A Zn(II) complex with N-benzyloxycarbonylglycinato ligands was studied by non-isothermal methods, in particular Kissinger-Akahira-Sunose's method, and further analysis of these results was performed by Vyazovkin's algorithm and an artificial compensation effect. Density functional theory calculations of thermodynamic quantities were performed, and results obtained by both methods are consistent, thus clarifying the mechanism of this very interesting multi-step degradation.
Keywords:
Transition metals compounds / Thermochemistry / Density functional theory / Reaction mechanismsSource:
Monatshefte Fur Chemie, 2012, 143, 8, 1133-1139Publisher:
- Springer Wien, Wien
Funding / projects:
DOI: 10.1007/s00706-012-0793-6
ISSN: 0026-9247
WoS: 000306593800006
Scopus: 2-s2.0-84864557200
Collections
Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Šumar-Ristović, Maja AU - Gruden-Pavlović, Maja AU - Zlatar, Matija AU - Blagojević, Vladimir A. AU - Anđelković, Katarina K. AU - Poleti, Dejan AU - Minić, Dragica M. PY - 2012 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1321 AB - A Zn(II) complex with N-benzyloxycarbonylglycinato ligands was studied by non-isothermal methods, in particular Kissinger-Akahira-Sunose's method, and further analysis of these results was performed by Vyazovkin's algorithm and an artificial compensation effect. Density functional theory calculations of thermodynamic quantities were performed, and results obtained by both methods are consistent, thus clarifying the mechanism of this very interesting multi-step degradation. PB - Springer Wien, Wien T2 - Monatshefte Fur Chemie T1 - Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands VL - 143 IS - 8 SP - 1133 EP - 1139 DO - 10.1007/s00706-012-0793-6 ER -
@article{ author = "Šumar-Ristović, Maja and Gruden-Pavlović, Maja and Zlatar, Matija and Blagojević, Vladimir A. and Anđelković, Katarina K. and Poleti, Dejan and Minić, Dragica M.", year = "2012", abstract = "A Zn(II) complex with N-benzyloxycarbonylglycinato ligands was studied by non-isothermal methods, in particular Kissinger-Akahira-Sunose's method, and further analysis of these results was performed by Vyazovkin's algorithm and an artificial compensation effect. Density functional theory calculations of thermodynamic quantities were performed, and results obtained by both methods are consistent, thus clarifying the mechanism of this very interesting multi-step degradation.", publisher = "Springer Wien, Wien", journal = "Monatshefte Fur Chemie", title = "Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands", volume = "143", number = "8", pages = "1133-1139", doi = "10.1007/s00706-012-0793-6" }
Šumar-Ristović, M., Gruden-Pavlović, M., Zlatar, M., Blagojević, V. A., Anđelković, K. K., Poleti, D.,& Minić, D. M.. (2012). Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands. in Monatshefte Fur Chemie Springer Wien, Wien., 143(8), 1133-1139. https://doi.org/10.1007/s00706-012-0793-6
Šumar-Ristović M, Gruden-Pavlović M, Zlatar M, Blagojević VA, Anđelković KK, Poleti D, Minić DM. Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands. in Monatshefte Fur Chemie. 2012;143(8):1133-1139. doi:10.1007/s00706-012-0793-6 .
Šumar-Ristović, Maja, Gruden-Pavlović, Maja, Zlatar, Matija, Blagojević, Vladimir A., Anđelković, Katarina K., Poleti, Dejan, Minić, Dragica M., "Kinetics, mechanism, and DFT calculations of thermal degradation of a Zn(II) complex with N-benzyloxycarbonylglycinato ligands" in Monatshefte Fur Chemie, 143, no. 8 (2012):1133-1139, https://doi.org/10.1007/s00706-012-0793-6 . .