Приказ основних података о документу

dc.creatorDžambaski, Zdravko
dc.creatorStojanović, Milovan
dc.creatorBaranac-Stojanović, Marija
dc.creatorMinić, Dragica M.
dc.creatorMarković, Rade
dc.date.accessioned2018-11-22T00:19:26Z
dc.date.available2018-11-22T00:19:26Z
dc.date.issued2011
dc.identifier.issn0352-5139
dc.identifier.urihttps://cherry.chem.bg.ac.rs/handle/123456789/1331
dc.description.abstractConfigurational isomerization of stereo-defined 5-substituted and un-substituted 2-alkylidene-4-oxothiazolidines (1) in the solid state, giving the Z/E mixtures in various ratios, was investigated by H-1-NMR spectroscopy, X-ray powder crystallography and differential scanning calorimetry (DSC). The Z/E composition can be rationalized in terms of non-covalent interactions, involving intermolecular and intramolccular hydrogen bonding and directional non-bonded 1,5-type S center dot center dot center dot O interactions. X-Ray powder crystallography, using selected crystalline (Z)-4-oxothiazolidine substrate, revealed transformation to the amorphous state during the irreversible Z - gt E process. A correlation between previous results on the Z/E isomerization in solution and now in the solid state was established.en
dc.publisherSerbian Chemical Soc, Belgrade
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142007/RS//
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.sourceJournal of the Serbian Chemical Society
dc.subject4-thiazolidinonesen
dc.subjectsolid-state isomerisationen
dc.subjectnon-covalent interactionsen
dc.subjectdynamic H-1-NMR spectroscopyen
dc.titleThermal solid-state Z/E isomerization of 2-alkylidene-4-oxothiazolidines: effects of non-covalent interactionsen
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractМиниц, Драгица М.; Дзамбаски, Здравко; Марковиц, Раде; Баранац-Стојановић, Марија; Стојановиц, Милован;
dc.citation.volume76
dc.citation.issue3
dc.citation.spage317
dc.citation.epage328
dc.identifier.wos000289270000001
dc.identifier.doi10.2298/JSC100607038D
dc.citation.other76(3): 317-328
dc.citation.rankM23
dc.type.versionpublishedVersion
dc.identifier.scopus2-s2.0-79953153021
dc.identifier.fulltexthttps://cherry.chem.bg.ac.rs/bitstream/id/8488/1329.pdf


Документи

Thumbnail

Овај документ се појављује у следећим колекцијама

Приказ основних података о документу