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Palladium(II) complexes with R(2)edda derived ligands. Part VI. O,O '-Diisopropyl ester of N,N '-1,2-ethanediylbis-L-leucine, dihydrochloride dihydrate and its palladium(II) complex: synthesis and characterization

Kompleksi paladijuma(II) sa ligandima R2edda tipa. Deo VI. 0,0'-diizopropil estar N,N'-1,2-etandiilbis-L-leucina, dihidrohlorid dihidrat i njegov kompleks sa paladijumom(II) - sinteza i karakterizacija

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1422.pdf (235.6Kb)
Authors
Zmejkovski, Bojana B.
Sabo, Tibor
Kaluđerović, Goran N.
Article (Published version)
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Abstract
A new R(2)edda-type ester, O,O'-diisopropyl ester of N,N'-1,2-ethanediylbis-L-leucine, dihydrochloride dihydrate, [(S,S)-H(2)iPr(2)eddl]Cl-2 center dot 2H(2)O, 1, and its palladium(II) complex, dichlorido(O,O'-diisopropyl-N,N'-1,2-ethanediylbis-L-leucinate)palladium(II) hemihydrate, [PdCl2{(S,S)-iPr(2)eddl}]center dot 0.5H(2)O, 2, were synthesized and characterized by elemental analysis, and IR and NMR spectroscopy. As expected, the palladium(II) complex was found in two from three possible diastereoisomeric forms (R,R), (S,S) and (R,S) equivalent to (S,R).
Nov estar R2dda-tipa 0,0'-diizopropil estar N,N'-1,2-etandiilbis-L-leucina, dihidrohlorid dihidrat [(S,S)-H2iPr2eddl]Cl2-2H2O (1) i njegov kompleks paladijuma(II), dihlorido(0,0'-diizopropil-N,N'-1,2-etandiilbis-L-leucinat)paladijum(II)- -hemihidrat [PdCl2{(S,SHPr2eddl}]-0.5H2O (2) su sintetisani i okarakterisani uz pomoć elementalne analize, IR i NMR spektroskopije. Kalijum-tetrahloridopaladat(II), reagujući sa [(S,S)-H2iPr2eddl]Cl2-2H2O, očekivano daje paladijumov kompleks 2 u obliku dva od moguća tri dijastereoizomera, (R,R), (S,S) i (R,S) = (S,R), što je potvrđeno uz pomoć NMR spektroskopije, a u saglasnosti je sa ranije urađenim DFT proračunima. PR Projekat Ministarstva nauke Republike Srbije, br. 172035.
Keywords:
palladium complexes / R(2)edda-type ligands / R2edda-type ligands / diastereoisomers / diastereoisomers
Source:
Journal of the Serbian Chemical Society, 2013, 78, 8, 1171-1176
Publisher:
  • Serbian Chemical Soc, Belgrade
Funding / projects:
  • Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology (RS-172035)

DOI: 10.2298/JSC130113021Z

ISSN: 0352-5139

WoS: 000326199100007

Scopus: 2-s2.0-84884260366
[ Google Scholar ]
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URI
https://cherry.chem.bg.ac.rs/handle/123456789/1424
Collections
  • Publikacije
Institution/Community
Hemijski fakultet
TY  - JOUR
AU  - Zmejkovski, Bojana B.
AU  - Sabo, Tibor
AU  - Kaluđerović, Goran N.
PY  - 2013
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/1424
AB  - A new R(2)edda-type ester, O,O'-diisopropyl ester of N,N'-1,2-ethanediylbis-L-leucine, dihydrochloride dihydrate, [(S,S)-H(2)iPr(2)eddl]Cl-2 center dot 2H(2)O, 1, and its palladium(II) complex, dichlorido(O,O'-diisopropyl-N,N'-1,2-ethanediylbis-L-leucinate)palladium(II) hemihydrate, [PdCl2{(S,S)-iPr(2)eddl}]center dot 0.5H(2)O, 2, were synthesized and characterized by elemental analysis, and IR and NMR spectroscopy. As expected, the palladium(II) complex was found in two from three possible diastereoisomeric forms (R,R), (S,S) and (R,S) equivalent to (S,R).
AB  - Nov estar R2dda-tipa 0,0'-diizopropil estar N,N'-1,2-etandiilbis-L-leucina, dihidrohlorid dihidrat [(S,S)-H2iPr2eddl]Cl2-2H2O (1) i njegov kompleks paladijuma(II), dihlorido(0,0'-diizopropil-N,N'-1,2-etandiilbis-L-leucinat)paladijum(II)- -hemihidrat [PdCl2{(S,SHPr2eddl}]-0.5H2O (2) su sintetisani i okarakterisani uz pomoć elementalne analize, IR i NMR spektroskopije. Kalijum-tetrahloridopaladat(II), reagujući sa [(S,S)-H2iPr2eddl]Cl2-2H2O, očekivano daje paladijumov kompleks 2 u obliku dva od moguća tri dijastereoizomera, (R,R), (S,S) i (R,S) = (S,R), što je potvrđeno uz pomoć NMR spektroskopije, a u saglasnosti je sa ranije urađenim DFT proračunima. PR Projekat Ministarstva nauke Republike Srbije, br. 172035.
PB  - Serbian Chemical Soc, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - Palladium(II) complexes with R(2)edda derived ligands. Part VI. O,O '-Diisopropyl ester of N,N '-1,2-ethanediylbis-L-leucine, dihydrochloride dihydrate and its palladium(II) complex: synthesis and characterization
T1  - Kompleksi paladijuma(II) sa ligandima R2edda tipa. Deo VI. 0,0'-diizopropil estar N,N'-1,2-etandiilbis-L-leucina, dihidrohlorid dihidrat i njegov kompleks sa paladijumom(II) - sinteza i karakterizacija
VL  - 78
IS  - 8
SP  - 1171
EP  - 1176
DO  - 10.2298/JSC130113021Z
UR  - Kon_2544
ER  - 
@article{
author = "Zmejkovski, Bojana B. and Sabo, Tibor and Kaluđerović, Goran N.",
year = "2013",
abstract = "A new R(2)edda-type ester, O,O'-diisopropyl ester of N,N'-1,2-ethanediylbis-L-leucine, dihydrochloride dihydrate, [(S,S)-H(2)iPr(2)eddl]Cl-2 center dot 2H(2)O, 1, and its palladium(II) complex, dichlorido(O,O'-diisopropyl-N,N'-1,2-ethanediylbis-L-leucinate)palladium(II) hemihydrate, [PdCl2{(S,S)-iPr(2)eddl}]center dot 0.5H(2)O, 2, were synthesized and characterized by elemental analysis, and IR and NMR spectroscopy. As expected, the palladium(II) complex was found in two from three possible diastereoisomeric forms (R,R), (S,S) and (R,S) equivalent to (S,R)., Nov estar R2dda-tipa 0,0'-diizopropil estar N,N'-1,2-etandiilbis-L-leucina, dihidrohlorid dihidrat [(S,S)-H2iPr2eddl]Cl2-2H2O (1) i njegov kompleks paladijuma(II), dihlorido(0,0'-diizopropil-N,N'-1,2-etandiilbis-L-leucinat)paladijum(II)- -hemihidrat [PdCl2{(S,SHPr2eddl}]-0.5H2O (2) su sintetisani i okarakterisani uz pomoć elementalne analize, IR i NMR spektroskopije. Kalijum-tetrahloridopaladat(II), reagujući sa [(S,S)-H2iPr2eddl]Cl2-2H2O, očekivano daje paladijumov kompleks 2 u obliku dva od moguća tri dijastereoizomera, (R,R), (S,S) i (R,S) = (S,R), što je potvrđeno uz pomoć NMR spektroskopije, a u saglasnosti je sa ranije urađenim DFT proračunima. PR Projekat Ministarstva nauke Republike Srbije, br. 172035.",
publisher = "Serbian Chemical Soc, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Palladium(II) complexes with R(2)edda derived ligands. Part VI. O,O '-Diisopropyl ester of N,N '-1,2-ethanediylbis-L-leucine, dihydrochloride dihydrate and its palladium(II) complex: synthesis and characterization, Kompleksi paladijuma(II) sa ligandima R2edda tipa. Deo VI. 0,0'-diizopropil estar N,N'-1,2-etandiilbis-L-leucina, dihidrohlorid dihidrat i njegov kompleks sa paladijumom(II) - sinteza i karakterizacija",
volume = "78",
number = "8",
pages = "1171-1176",
doi = "10.2298/JSC130113021Z",
url = "Kon_2544"
}
Zmejkovski, B. B., Sabo, T.,& Kaluđerović, G. N.. (2013). Palladium(II) complexes with R(2)edda derived ligands. Part VI. O,O '-Diisopropyl ester of N,N '-1,2-ethanediylbis-L-leucine, dihydrochloride dihydrate and its palladium(II) complex: synthesis and characterization. in Journal of the Serbian Chemical Society
Serbian Chemical Soc, Belgrade., 78(8), 1171-1176.
https://doi.org/10.2298/JSC130113021Z
Kon_2544
Zmejkovski BB, Sabo T, Kaluđerović GN. Palladium(II) complexes with R(2)edda derived ligands. Part VI. O,O '-Diisopropyl ester of N,N '-1,2-ethanediylbis-L-leucine, dihydrochloride dihydrate and its palladium(II) complex: synthesis and characterization. in Journal of the Serbian Chemical Society. 2013;78(8):1171-1176.
doi:10.2298/JSC130113021Z
Kon_2544 .
Zmejkovski, Bojana B., Sabo, Tibor, Kaluđerović, Goran N., "Palladium(II) complexes with R(2)edda derived ligands. Part VI. O,O '-Diisopropyl ester of N,N '-1,2-ethanediylbis-L-leucine, dihydrochloride dihydrate and its palladium(II) complex: synthesis and characterization" in Journal of the Serbian Chemical Society, 78, no. 8 (2013):1171-1176,
https://doi.org/10.2298/JSC130113021Z .,
Kon_2544 .

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