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Unusual mode of reactivity of 2-alkylidene-4-oxothiazolidine S-oxides under the Pummerer reaction conditions

dc.creatorDžambaski, Zdravko
dc.creatorToljić, Đorđe
dc.creatorBondžić, Bojan
dc.creatorMarković, Rade
dc.creatorBaranac-Stojanović, Marija
dc.date.accessioned2018-11-22T00:24:30Z
dc.date.available2018-11-22T00:24:30Z
dc.date.issued2013
dc.identifier.issn0040-4020
dc.identifier.urihttps://cherry.chem.bg.ac.rs/handle/123456789/1434
dc.description.abstractThe reactivity of 2-alkylidene-4-oxothiazolidine S-oxides under the Pummerer reaction conditions, using Ac2O, TFAA, SOCl2 and SOBr2 as initiators, has been examined. Almost all reactions proceeded with absolute regioselectivity yielding alpha-substituted sulfides or vinyl-chloro derivatives. The mechanism for the formation of the latter products was postulated and proved experimentally.en
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172020/RS//
dc.rightsrestrictedAccess
dc.sourceTetrahedron
dc.subjectPummerer reactionen
dc.subject2-Alkylidene-4-oxothiazolidine S-oxideen
dc.subjectRegioselectivityen
dc.subjectDensity functional calculationsen
dc.titleUnusual mode of reactivity of 2-alkylidene-4-oxothiazolidine S-oxides under the Pummerer reaction conditionsen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractБаранац-Стојановић, Марија; Дзамбаски, Здравко; Бондзиц, Бојан; Тољиц, Дорде; Марковиц, Раде;
dc.citation.volume69
dc.citation.issue46
dc.citation.spage9819
dc.citation.epage9825
dc.identifier.wos000326768800035
dc.identifier.doi10.1016/j.tet.2013.09.004
dc.citation.other69(46): 9819-9825
dc.citation.rankM21
dc.description.otherSupplementary material: [http://cherry.chem.bg.ac.rs/handle/123456789/3558]
dc.type.versionpublishedVersionen
dc.identifier.scopus2-s2.0-84885181662


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