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dc.creatorBaranac-Stojanović, Marija
dc.date.accessioned2018-11-22T00:26:44Z
dc.date.available2018-11-22T00:26:44Z
dc.date.issued2014
dc.identifier.issn2046-2069
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/1445
dc.description.abstractNuclear magnetic resonance (NMR) spectroscopy is an important technique for structure determination. Within it, anisotropic effects of different functional groups and ring systems, depicted as familiar "anisotropy cones", are broadly used to deduce the stereochemistry, for chemical shift assignments and to explain shielding or deshielding of nuclei spatially close, or directly attached to the corresponding functional group, or ring. Progress in computational methods has enabled the quantification of anisotropic effects, an insight into their origin and to the source of (de) shielding of proximal nucleus. Some widely accepted traditional explanations, presented in NMR spectroscopy textbooks, have been questioned. The purpose of this review is to collect and discuss the research, mainly based on theoretical calculations, that provided new insight into the anisotropic effects, their origin and factors responsible for (de) shielding of proximal protons.en
dc.publisherRoyal Soc Chemistry, Cambridge
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172020/RS//
dc.rightsrestrictedAccess
dc.sourceRSC Advances
dc.titleNew insight into the anisotropic effects in solution-state NMR spectroscopyen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractБаранац-Стојановић, Марија;
dc.citation.volume4
dc.citation.issue1
dc.citation.spage308
dc.citation.epage321
dc.identifier.wos000327547000042
dc.identifier.doi10.1039/c3ra45512b
dc.citation.other4(1): 308-321
dc.citation.rankM21
dc.type.versionpublishedVersion
dc.identifier.scopus2-s2.0-84888599731
dc.identifier.rcubKon_2565


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