Substrate Stereocontrol in the Intramolecular Organocatalyzed Tsuji-Trost Reaction: Enantioselective Synthesis of Allokainates
Abstract
Organocatalyzed Tsuji-Trost cyclization of 3b proceeds with asymmetric induction and allows for stereoselective synthesis of (+)-allokainic acid. The stereochemical outcome of the cyclization was predicted by calculations.
Source:
Organic Letters, 2014, 16, 1, 34-37Publisher:
- Amer Chemical Soc, Washington
Projects:
- The development of new synthetic methods and their application in the synthesis of natural products and biologically active molecules (RS-172027)
- Municipality of Stari Grad
DOI: 10.1021/ol4028557
ISSN: 1523-7060
PubMed: 24328350
WoS: 000329472800010
Scopus: 2-s2.0-84891774803
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