Leaching of polycyclic aromatic hydrocarbons from power plant lignite ash-influence of parameters important for environmental pollution
Samo za registrovane korisnike
2014
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Nikola Tesla B power plant (TENT B), located at the Sava River, in Obrenovac, 50 km west from the Serbian's capital, Belgrade, is the second largest coal-fired power plant in the country, consisting of two blocks, each of 620 MW capacity. In order to investigate the threat polycyclic aromatic hydrocarbons (PAHs) from deposited coal ash, obtained by coal combustion in this power plant, can represent for the surrounding environment, samples of coal ash were submitted to extraction with river water used for transport of coal ash to the dump, as well as with water of different ionic strength and acidity. It was found that, out of 16 EPA priority PAHs, only naphthalene, acenaphthylene, fluorene, phenantrene, fluoranthene, and pyrene were found in measurable concentrations in the different extracts. Their combined concentration was around 0.1 mu g/L, so they do not, in terms of leached concentrations, represent serious danger for the surrounding environment. In all cases of established (and ...leached) PAH compounds, changes of ionic strength, acidity, or the presence of organic compounds in river water may to some extent influence the leached concentrations. However, under the examined conditions, similar to those present in the environment, leached concentrations were not more than 50 % greater than the concentrations leached by distilled water. Therefore, water desorption is likely the most important mechanism responsible for leaching of PAH compounds from filter coal ash.
Ključne reči:
Polycyclic aromatic hydrocarbons / Leaching / Power plant / Ash / pH / Ionic strength / River waterIzvor:
Environmental Science and Pollution Research, 2014, 21, 5, 3435-3442Izdavač:
- Springer Heidelberg, Heidelberg
Finansiranje / projekti:
- Proučavanje fizičkohemijskih i biohemijskih procesa u životnoj sredini koji utiču na zagađenje i istraživanje mogućnosti za minimiziranje posledica (RS-MESTD-Basic Research (BR or ON)-172001)
- Korelacija strukture i osobina prirodnih i sintetičkih molekula i njihovih kompleksa sa metalima (RS-MESTD-Basic Research (BR or ON)-172017)
DOI: 10.1007/s11356-013-2314-5
ISSN: 0944-1344
PubMed: 24243163
WoS: 000331823000021
Scopus: 2-s2.0-84893900636
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Pergal, Miodrag M. AU - Relić, Dubravka AU - Tešić, Živoslav Lj. AU - Popović, Aleksandar R. PY - 2014 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1507 AB - Nikola Tesla B power plant (TENT B), located at the Sava River, in Obrenovac, 50 km west from the Serbian's capital, Belgrade, is the second largest coal-fired power plant in the country, consisting of two blocks, each of 620 MW capacity. In order to investigate the threat polycyclic aromatic hydrocarbons (PAHs) from deposited coal ash, obtained by coal combustion in this power plant, can represent for the surrounding environment, samples of coal ash were submitted to extraction with river water used for transport of coal ash to the dump, as well as with water of different ionic strength and acidity. It was found that, out of 16 EPA priority PAHs, only naphthalene, acenaphthylene, fluorene, phenantrene, fluoranthene, and pyrene were found in measurable concentrations in the different extracts. Their combined concentration was around 0.1 mu g/L, so they do not, in terms of leached concentrations, represent serious danger for the surrounding environment. In all cases of established (and leached) PAH compounds, changes of ionic strength, acidity, or the presence of organic compounds in river water may to some extent influence the leached concentrations. However, under the examined conditions, similar to those present in the environment, leached concentrations were not more than 50 % greater than the concentrations leached by distilled water. Therefore, water desorption is likely the most important mechanism responsible for leaching of PAH compounds from filter coal ash. PB - Springer Heidelberg, Heidelberg T2 - Environmental Science and Pollution Research T1 - Leaching of polycyclic aromatic hydrocarbons from power plant lignite ash-influence of parameters important for environmental pollution VL - 21 IS - 5 SP - 3435 EP - 3442 DO - 10.1007/s11356-013-2314-5 ER -
@article{ author = "Pergal, Miodrag M. and Relić, Dubravka and Tešić, Živoslav Lj. and Popović, Aleksandar R.", year = "2014", abstract = "Nikola Tesla B power plant (TENT B), located at the Sava River, in Obrenovac, 50 km west from the Serbian's capital, Belgrade, is the second largest coal-fired power plant in the country, consisting of two blocks, each of 620 MW capacity. In order to investigate the threat polycyclic aromatic hydrocarbons (PAHs) from deposited coal ash, obtained by coal combustion in this power plant, can represent for the surrounding environment, samples of coal ash were submitted to extraction with river water used for transport of coal ash to the dump, as well as with water of different ionic strength and acidity. It was found that, out of 16 EPA priority PAHs, only naphthalene, acenaphthylene, fluorene, phenantrene, fluoranthene, and pyrene were found in measurable concentrations in the different extracts. Their combined concentration was around 0.1 mu g/L, so they do not, in terms of leached concentrations, represent serious danger for the surrounding environment. In all cases of established (and leached) PAH compounds, changes of ionic strength, acidity, or the presence of organic compounds in river water may to some extent influence the leached concentrations. However, under the examined conditions, similar to those present in the environment, leached concentrations were not more than 50 % greater than the concentrations leached by distilled water. Therefore, water desorption is likely the most important mechanism responsible for leaching of PAH compounds from filter coal ash.", publisher = "Springer Heidelberg, Heidelberg", journal = "Environmental Science and Pollution Research", title = "Leaching of polycyclic aromatic hydrocarbons from power plant lignite ash-influence of parameters important for environmental pollution", volume = "21", number = "5", pages = "3435-3442", doi = "10.1007/s11356-013-2314-5" }
Pergal, M. M., Relić, D., Tešić, Ž. Lj.,& Popović, A. R.. (2014). Leaching of polycyclic aromatic hydrocarbons from power plant lignite ash-influence of parameters important for environmental pollution. in Environmental Science and Pollution Research Springer Heidelberg, Heidelberg., 21(5), 3435-3442. https://doi.org/10.1007/s11356-013-2314-5
Pergal MM, Relić D, Tešić ŽL, Popović AR. Leaching of polycyclic aromatic hydrocarbons from power plant lignite ash-influence of parameters important for environmental pollution. in Environmental Science and Pollution Research. 2014;21(5):3435-3442. doi:10.1007/s11356-013-2314-5 .
Pergal, Miodrag M., Relić, Dubravka, Tešić, Živoslav Lj., Popović, Aleksandar R., "Leaching of polycyclic aromatic hydrocarbons from power plant lignite ash-influence of parameters important for environmental pollution" in Environmental Science and Pollution Research, 21, no. 5 (2014):3435-3442, https://doi.org/10.1007/s11356-013-2314-5 . .