Engineering molecular chains in carbon nanotubes
Samo za registrovane korisnike
2012
Autori
Chamberlain, Thomas W.Pfeiffer, Rudolf
Howells, Jonathan
Peterlik, Herwig
Kuzmany, Hans
Kraeutler, Bernhard
Da Ros, Tatiana
Melle-Franco, Manuel
Zerbetto, Francesco
Milić, Dragana
Khlobystov, Andrei N.
Članak u časopisu (Objavljena verzija)
Metapodaci
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A range of mono- and bis-functionalised fullerenes have been synthesised and inserted into single-walled carbon nanotubes. The effect of the size and shape of the functional groups of the fullerenes on the resultant 1D arrays formed within the nanotubes was investigated by high resolution transmission electron microscopy and X-ray diffraction. The addition of non-planar, sterically bulky chains to the fullerene cage results in highly ordered 1D structures in which the fullerenes are evenly spaced along the internal nanotube cavity. Theoretical calculations reveal that the functional groups interact with neighbouring fullerene cages to space the fullerenes evenly within the confines of the nanotube. The addition of two functional groups to opposite sides of the fullerene cages results in a further increase in the separation of the fullerene cages within the nanotubes at the cost of lower nanotube filling rates.
Izvor:
Nanoscale, 2012, 4, 23, 7540-7548Izdavač:
- Royal Soc Chemistry, Cambridge
Finansiranje / projekti:
- Engineering and Physical Sciences Research Council [EP/C545273/1]
- FWF [I83-N20 (ESF IMPrESS)]
- Nottingham Nanoscience and Nanotechnology Centre (NNNC)
- project SeARCH (Services and Advanced Research Computing with HTC/HPC clusters)
- Fundacao para a Ciencia ea Tecnologia
- Royal Society
- European Research Council (ERC)
DOI: 10.1039/c2nr32571c
ISSN: 2040-3364
PubMed: 23104233
WoS: 000310978900037
Scopus: 2-s2.0-84870901795
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Chamberlain, Thomas W. AU - Pfeiffer, Rudolf AU - Howells, Jonathan AU - Peterlik, Herwig AU - Kuzmany, Hans AU - Kraeutler, Bernhard AU - Da Ros, Tatiana AU - Melle-Franco, Manuel AU - Zerbetto, Francesco AU - Milić, Dragana AU - Khlobystov, Andrei N. PY - 2012 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1550 AB - A range of mono- and bis-functionalised fullerenes have been synthesised and inserted into single-walled carbon nanotubes. The effect of the size and shape of the functional groups of the fullerenes on the resultant 1D arrays formed within the nanotubes was investigated by high resolution transmission electron microscopy and X-ray diffraction. The addition of non-planar, sterically bulky chains to the fullerene cage results in highly ordered 1D structures in which the fullerenes are evenly spaced along the internal nanotube cavity. Theoretical calculations reveal that the functional groups interact with neighbouring fullerene cages to space the fullerenes evenly within the confines of the nanotube. The addition of two functional groups to opposite sides of the fullerene cages results in a further increase in the separation of the fullerene cages within the nanotubes at the cost of lower nanotube filling rates. PB - Royal Soc Chemistry, Cambridge T2 - Nanoscale T1 - Engineering molecular chains in carbon nanotubes VL - 4 IS - 23 SP - 7540 EP - 7548 DO - 10.1039/c2nr32571c ER -
@article{ author = "Chamberlain, Thomas W. and Pfeiffer, Rudolf and Howells, Jonathan and Peterlik, Herwig and Kuzmany, Hans and Kraeutler, Bernhard and Da Ros, Tatiana and Melle-Franco, Manuel and Zerbetto, Francesco and Milić, Dragana and Khlobystov, Andrei N.", year = "2012", abstract = "A range of mono- and bis-functionalised fullerenes have been synthesised and inserted into single-walled carbon nanotubes. The effect of the size and shape of the functional groups of the fullerenes on the resultant 1D arrays formed within the nanotubes was investigated by high resolution transmission electron microscopy and X-ray diffraction. The addition of non-planar, sterically bulky chains to the fullerene cage results in highly ordered 1D structures in which the fullerenes are evenly spaced along the internal nanotube cavity. Theoretical calculations reveal that the functional groups interact with neighbouring fullerene cages to space the fullerenes evenly within the confines of the nanotube. The addition of two functional groups to opposite sides of the fullerene cages results in a further increase in the separation of the fullerene cages within the nanotubes at the cost of lower nanotube filling rates.", publisher = "Royal Soc Chemistry, Cambridge", journal = "Nanoscale", title = "Engineering molecular chains in carbon nanotubes", volume = "4", number = "23", pages = "7540-7548", doi = "10.1039/c2nr32571c" }
Chamberlain, T. W., Pfeiffer, R., Howells, J., Peterlik, H., Kuzmany, H., Kraeutler, B., Da Ros, T., Melle-Franco, M., Zerbetto, F., Milić, D.,& Khlobystov, A. N.. (2012). Engineering molecular chains in carbon nanotubes. in Nanoscale Royal Soc Chemistry, Cambridge., 4(23), 7540-7548. https://doi.org/10.1039/c2nr32571c
Chamberlain TW, Pfeiffer R, Howells J, Peterlik H, Kuzmany H, Kraeutler B, Da Ros T, Melle-Franco M, Zerbetto F, Milić D, Khlobystov AN. Engineering molecular chains in carbon nanotubes. in Nanoscale. 2012;4(23):7540-7548. doi:10.1039/c2nr32571c .
Chamberlain, Thomas W., Pfeiffer, Rudolf, Howells, Jonathan, Peterlik, Herwig, Kuzmany, Hans, Kraeutler, Bernhard, Da Ros, Tatiana, Melle-Franco, Manuel, Zerbetto, Francesco, Milić, Dragana, Khlobystov, Andrei N., "Engineering molecular chains in carbon nanotubes" in Nanoscale, 4, no. 23 (2012):7540-7548, https://doi.org/10.1039/c2nr32571c . .