Cobalt(II) and cadmium(II) compounds with adamantane-1-sulfonic acid
Nova jedinjenja kobalta(II) i kadmijuma(II) sa adamantan-1-sulfonskom kiselinom
2012
Аутори
Đorđević, Milena M.Jeremić, Dejan
Anđelković, Katarina K.
Gruden-Pavlović, Maja
Divjaković, Vladimir
Šumar-Ristović, Maja
Brčeski, Ilija
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
In this work, the syntheses and characterization of two novel compounds of adamantane-1-sulfonic acid (1-AdSO(3)H) with cobalt(II) and cadmium(II) are reported. The results of single crystal X-ray analysis of the compounds revealed that adamantane-1-sulfonate (1-AdSO(3)(-)) in the monoanionic form plays different roles in the investigated compounds. Namely, while in compound [Co(H2O)(6)](1-AdSO(3))(2), six water molecules are coordinated to the cobalt(II) ion and 1-AdSO(3)(-) serves as a counter ion, in compound [Cd(H2O)(4)(1-AdSO(3))(2)], two molecules of 1-AdSO(3)(-) are trans-coordinated to the cadmium(II) ion as a monodentate (O)-ligand and the other coordination sites are occupied by water molecules. The obtained compounds showed moderate activity against Artemia salina.
U ovom radu prikazana je sinteza i karakterizacija dva nova jedinjenja adamantan-1-sulfonske kiseline (1-AdSO3H) sa kobaltom(II) i kadmijumom(II). Rezultati rend- genske strukturne analize datih jedinjenja ukazuju da monoanjon adamantan-1-sulfonata (1-AdSO3 pokazuje različit afinitet prema Co(II) i Cd(II) jonima). U kompleksu [Co(H2O)6](1-AdSO3)2, šest molekula vode se koordinuje za Co(II) jon, dok 1-AdSO3 ima ulogu kontrajona. U kompleksu [Cd(H2O)4(1-AdSO3)2] dva jona 1-AdSO3 su koordinovana za Cd(II) jon kao monodentati u trans položaju preko kiseonikovih atoma, dok su ostala koordinaciona mesta zauzeta molekulima vode. Dobijena jedinjenja su pokazala umerenu aktivnost na Artemia salina.
Кључне речи:
X-ray structure determination / transition metal compounds / transition metal compounds / metal complexes / metal complexes / adamantane-1-sulfonate derivatives / adamantane-1-sulfonate derivativesИзвор:
Journal of the Serbian Chemical Society, 2012, 77, 10, 1391-1399Издавач:
- Serbian Chemical Soc, Belgrade
Финансирање / пројекти:
- Корелација структуре и особина природних и синтетичких молекула и њихових комплекса са металима (RS-MESTD-Basic Research (BR or ON)-172017)
DOI: 10.2298/JSC120419051D
ISSN: 0352-5139
WoS: 000311594100007
Scopus: 2-s2.0-84870201150
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Đorđević, Milena M. AU - Jeremić, Dejan AU - Anđelković, Katarina K. AU - Gruden-Pavlović, Maja AU - Divjaković, Vladimir AU - Šumar-Ristović, Maja AU - Brčeski, Ilija PY - 2012 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1553 AB - In this work, the syntheses and characterization of two novel compounds of adamantane-1-sulfonic acid (1-AdSO(3)H) with cobalt(II) and cadmium(II) are reported. The results of single crystal X-ray analysis of the compounds revealed that adamantane-1-sulfonate (1-AdSO(3)(-)) in the monoanionic form plays different roles in the investigated compounds. Namely, while in compound [Co(H2O)(6)](1-AdSO(3))(2), six water molecules are coordinated to the cobalt(II) ion and 1-AdSO(3)(-) serves as a counter ion, in compound [Cd(H2O)(4)(1-AdSO(3))(2)], two molecules of 1-AdSO(3)(-) are trans-coordinated to the cadmium(II) ion as a monodentate (O)-ligand and the other coordination sites are occupied by water molecules. The obtained compounds showed moderate activity against Artemia salina. AB - U ovom radu prikazana je sinteza i karakterizacija dva nova jedinjenja adamantan-1-sulfonske kiseline (1-AdSO3H) sa kobaltom(II) i kadmijumom(II). Rezultati rend- genske strukturne analize datih jedinjenja ukazuju da monoanjon adamantan-1-sulfonata (1-AdSO3 pokazuje različit afinitet prema Co(II) i Cd(II) jonima). U kompleksu [Co(H2O)6](1-AdSO3)2, šest molekula vode se koordinuje za Co(II) jon, dok 1-AdSO3 ima ulogu kontrajona. U kompleksu [Cd(H2O)4(1-AdSO3)2] dva jona 1-AdSO3 su koordinovana za Cd(II) jon kao monodentati u trans položaju preko kiseonikovih atoma, dok su ostala koordinaciona mesta zauzeta molekulima vode. Dobijena jedinjenja su pokazala umerenu aktivnost na Artemia salina. PB - Serbian Chemical Soc, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Cobalt(II) and cadmium(II) compounds with adamantane-1-sulfonic acid T1 - Nova jedinjenja kobalta(II) i kadmijuma(II) sa adamantan-1-sulfonskom kiselinom VL - 77 IS - 10 SP - 1391 EP - 1399 DO - 10.2298/JSC120419051D ER -
@article{ author = "Đorđević, Milena M. and Jeremić, Dejan and Anđelković, Katarina K. and Gruden-Pavlović, Maja and Divjaković, Vladimir and Šumar-Ristović, Maja and Brčeski, Ilija", year = "2012", abstract = "In this work, the syntheses and characterization of two novel compounds of adamantane-1-sulfonic acid (1-AdSO(3)H) with cobalt(II) and cadmium(II) are reported. The results of single crystal X-ray analysis of the compounds revealed that adamantane-1-sulfonate (1-AdSO(3)(-)) in the monoanionic form plays different roles in the investigated compounds. Namely, while in compound [Co(H2O)(6)](1-AdSO(3))(2), six water molecules are coordinated to the cobalt(II) ion and 1-AdSO(3)(-) serves as a counter ion, in compound [Cd(H2O)(4)(1-AdSO(3))(2)], two molecules of 1-AdSO(3)(-) are trans-coordinated to the cadmium(II) ion as a monodentate (O)-ligand and the other coordination sites are occupied by water molecules. The obtained compounds showed moderate activity against Artemia salina., U ovom radu prikazana je sinteza i karakterizacija dva nova jedinjenja adamantan-1-sulfonske kiseline (1-AdSO3H) sa kobaltom(II) i kadmijumom(II). Rezultati rend- genske strukturne analize datih jedinjenja ukazuju da monoanjon adamantan-1-sulfonata (1-AdSO3 pokazuje različit afinitet prema Co(II) i Cd(II) jonima). U kompleksu [Co(H2O)6](1-AdSO3)2, šest molekula vode se koordinuje za Co(II) jon, dok 1-AdSO3 ima ulogu kontrajona. U kompleksu [Cd(H2O)4(1-AdSO3)2] dva jona 1-AdSO3 su koordinovana za Cd(II) jon kao monodentati u trans položaju preko kiseonikovih atoma, dok su ostala koordinaciona mesta zauzeta molekulima vode. Dobijena jedinjenja su pokazala umerenu aktivnost na Artemia salina.", publisher = "Serbian Chemical Soc, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Cobalt(II) and cadmium(II) compounds with adamantane-1-sulfonic acid, Nova jedinjenja kobalta(II) i kadmijuma(II) sa adamantan-1-sulfonskom kiselinom", volume = "77", number = "10", pages = "1391-1399", doi = "10.2298/JSC120419051D" }
Đorđević, M. M., Jeremić, D., Anđelković, K. K., Gruden-Pavlović, M., Divjaković, V., Šumar-Ristović, M.,& Brčeski, I.. (2012). Cobalt(II) and cadmium(II) compounds with adamantane-1-sulfonic acid. in Journal of the Serbian Chemical Society Serbian Chemical Soc, Belgrade., 77(10), 1391-1399. https://doi.org/10.2298/JSC120419051D
Đorđević MM, Jeremić D, Anđelković KK, Gruden-Pavlović M, Divjaković V, Šumar-Ristović M, Brčeski I. Cobalt(II) and cadmium(II) compounds with adamantane-1-sulfonic acid. in Journal of the Serbian Chemical Society. 2012;77(10):1391-1399. doi:10.2298/JSC120419051D .
Đorđević, Milena M., Jeremić, Dejan, Anđelković, Katarina K., Gruden-Pavlović, Maja, Divjaković, Vladimir, Šumar-Ristović, Maja, Brčeski, Ilija, "Cobalt(II) and cadmium(II) compounds with adamantane-1-sulfonic acid" in Journal of the Serbian Chemical Society, 77, no. 10 (2012):1391-1399, https://doi.org/10.2298/JSC120419051D . .