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Nova jedinjenja kobalta(II) i kadmijuma(II) sa adamantan-1-sulfonskom kiselinom

dc.creatorĐorđević, Milena
dc.creatorJeremić, Dejan
dc.creatorAnđelković, Katarina K.
dc.creatorGruden-Pavlović, Maja
dc.creatorDivjaković, Vladimir
dc.creatorŠumar-Ristović, Maja
dc.creatorBrčeski, Ilija
dc.date.accessioned2018-11-22T00:22:19Z
dc.date.available2018-11-22T00:22:19Z
dc.date.issued2012
dc.identifier.issn0352-5139
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/1553
dc.description.abstractIn this work, the syntheses and characterization of two novel compounds of adamantane-1-sulfonic acid (1-AdSO(3)H) with cobalt(II) and cadmium(II) are reported. The results of single crystal X-ray analysis of the compounds revealed that adamantane-1-sulfonate (1-AdSO(3)(-)) in the monoanionic form plays different roles in the investigated compounds. Namely, while in compound [Co(H2O)(6)](1-AdSO(3))(2), six water molecules are coordinated to the cobalt(II) ion and 1-AdSO(3)(-) serves as a counter ion, in compound [Cd(H2O)(4)(1-AdSO(3))(2)], two molecules of 1-AdSO(3)(-) are trans-coordinated to the cadmium(II) ion as a monodentate (O)-ligand and the other coordination sites are occupied by water molecules. The obtained compounds showed moderate activity against Artemia salina.en
dc.description.abstractU ovom radu prikazana je sinteza i karakterizacija dva nova jedinjenja adamantan-1-sulfonske kiseline (1-AdSO3H) sa kobaltom(II) i kadmijumom(II). Rezultati rend- genske strukturne analize datih jedinjenja ukazuju da monoanjon adamantan-1-sulfonata (1-AdSO3 pokazuje različit afinitet prema Co(II) i Cd(II) jonima). U kompleksu [Co(H2O)6](1-AdSO3)2, šest molekula vode se koordinuje za Co(II) jon, dok 1-AdSO3 ima ulogu kontrajona. U kompleksu [Cd(H2O)4(1-AdSO3)2] dva jona 1-AdSO3 su koordinovana za Cd(II) jon kao monodentati u trans položaju preko kiseonikovih atoma, dok su ostala koordinaciona mesta zauzeta molekulima vode. Dobijena jedinjenja su pokazala umerenu aktivnost na Artemia salina.sr
dc.publisherSerbian Chemical Soc, Belgrade
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172017/RS//
dc.rightsopenAccess
dc.sourceJournal of the Serbian Chemical Society
dc.subjectX-ray structure determinationen
dc.subjecttransition metal compoundsen
dc.subjecttransition metal compoundsen
dc.subjectmetal complexesen
dc.subjectmetal complexesen
dc.subjectadamantane-1-sulfonate derivativesen
dc.subjectadamantane-1-sulfonate derivativesen
dc.titleCobalt(II) and cadmium(II) compounds with adamantane-1-sulfonic aciden
dc.titleNova jedinjenja kobalta(II) i kadmijuma(II) sa adamantan-1-sulfonskom kiselinomsr
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractШумар-Ристовић, Маја; Aнђелковић, Катарина; Груден-Павловић, Маја; Јеремиц, Дејан; Брчески, Илија; Дордевиц, Милена; Дивјаковиц, Владимир; Нова једињења кобалта(ИИ) и кадмијума(ИИ) са адамантан-1-сулфонском киселином; Нова једињења кобалта(ИИ) и кадмијума(ИИ) са адамантан-1-сулфонском киселином;
dc.citation.volume77
dc.citation.issue10
dc.citation.spage1391
dc.citation.epage1399
dc.identifier.wos000311594100007
dc.identifier.doi10.2298/JSC120419051D
dc.citation.other77(10): 1391-1399
dc.citation.rankM23
dc.type.versionpublishedVersion
dc.identifier.scopus2-s2.0-84870201150
dc.identifier.fulltexthttp://cherry.chem.bg.ac.rs/bitstream/id/8657/1551.pdf
dc.identifier.rcubKon_2384


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