Emission of Polycyclic Aromatic Hydrocarbons from Beech Wood Combustion
Abstract
This study reports results on 16 EU priority polycyclic aromatic hydrocarbons in smoke produced by beech wood combustion from Zlatibor region, Serbia. Smoke samples were collected with two different types of tubes (PUF and XAD-2), at a height of 2 and 5 m away from the firebox; 16 EU priority polycyclic aromatic hydrocarbons [European Commission (2005), Commission Recommendation 2005/108/EC, Official Journal of European Union L34:4345; JECFA (2005), Summary and Conclusion. Paper No. JECFA/64/SC, Joint FAO/WHO Expert Committee on Food Additives, Sixty-Fourth Meeting, Rome, Italy, February 817] were identified and quantified by Fast-GC/HRMS. The analyzed PAHs were: benzo[c]fluorene (BcL), benzo[a]anthracene (BaA), cyclopenta[c,d]pyrene (CPP), chrysene (CHR), 5-methylchrysene (5MC), benzo[b]fluoranthene (BbF), benzo[j]fluoranthene (BjF), benzo[k]fluoranthene (BkF), benzo[a]pyrene (BaP), benzo[g,h,i]perylene (BgP), dibenzo[a,h]anthracene (DhA), indeno[1,2,3-cd]pyrene (IcP), dibenzo[a,e]pyr...ene (DeP), dibenzo[a,h]pyrene (DhP), dibenzo[a,i]pyrene (DiP) and dibenzo[a,l]pyrene (DlP). Results show that total emission of polycyclic aromatic hydrocarbons at a height of 2 m was 6.7 and 7.4 mg m3 , in PUF and XAD-2 tubes, respectively. At height of 5 m polycyclic aromatic hydrocarbons emission was 2.4 and 4.3 mg m3 , in PUF and XAD-2 tubes, respectively. BaP contribution to total sum of 16 EU priority polycyclic aromatic hydrocarbons was 4% (PUF tubes) and 7.2% (XAD-2 tubes) at a height of 2 m, and 5% (PUF tubes) and 8.3% (XAD-2 tubes) at a height of 5 m. Total benzo[a]pirene equivalent concentrations (BaPeq) in smoke samples were calculated.
Keywords:
emission / polycyclic aromatic hydrocarbons / smoke / toxic equivalency factors / wood combustionSource:
Energy Sources Part A-Recovery Utilization and Environmental Effects, 2013, 35, 4, 328-336Publisher:
- Taylor & Francis Inc, Philadelphia
Funding / projects:
- Improvement and development of hygienic and technological procedures in production of animal originating foodstuffs with the aim of producing high-quality and safe products competetive on the global market (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-46009)
DOI: 10.1080/15567036.2010.503234
ISSN: 1556-7036
WoS: 000315983300004
Scopus: 2-s2.0-84872458073
Collections
Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Đinović-Stojanović, Jasna AU - Popović, Aleksandar R. AU - Spiric, A. AU - Jira, W. PY - 2013 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1611 AB - This study reports results on 16 EU priority polycyclic aromatic hydrocarbons in smoke produced by beech wood combustion from Zlatibor region, Serbia. Smoke samples were collected with two different types of tubes (PUF and XAD-2), at a height of 2 and 5 m away from the firebox; 16 EU priority polycyclic aromatic hydrocarbons [European Commission (2005), Commission Recommendation 2005/108/EC, Official Journal of European Union L34:4345; JECFA (2005), Summary and Conclusion. Paper No. JECFA/64/SC, Joint FAO/WHO Expert Committee on Food Additives, Sixty-Fourth Meeting, Rome, Italy, February 817] were identified and quantified by Fast-GC/HRMS. The analyzed PAHs were: benzo[c]fluorene (BcL), benzo[a]anthracene (BaA), cyclopenta[c,d]pyrene (CPP), chrysene (CHR), 5-methylchrysene (5MC), benzo[b]fluoranthene (BbF), benzo[j]fluoranthene (BjF), benzo[k]fluoranthene (BkF), benzo[a]pyrene (BaP), benzo[g,h,i]perylene (BgP), dibenzo[a,h]anthracene (DhA), indeno[1,2,3-cd]pyrene (IcP), dibenzo[a,e]pyrene (DeP), dibenzo[a,h]pyrene (DhP), dibenzo[a,i]pyrene (DiP) and dibenzo[a,l]pyrene (DlP). Results show that total emission of polycyclic aromatic hydrocarbons at a height of 2 m was 6.7 and 7.4 mg m3 , in PUF and XAD-2 tubes, respectively. At height of 5 m polycyclic aromatic hydrocarbons emission was 2.4 and 4.3 mg m3 , in PUF and XAD-2 tubes, respectively. BaP contribution to total sum of 16 EU priority polycyclic aromatic hydrocarbons was 4% (PUF tubes) and 7.2% (XAD-2 tubes) at a height of 2 m, and 5% (PUF tubes) and 8.3% (XAD-2 tubes) at a height of 5 m. Total benzo[a]pirene equivalent concentrations (BaPeq) in smoke samples were calculated. PB - Taylor & Francis Inc, Philadelphia T2 - Energy Sources Part A-Recovery Utilization and Environmental Effects T1 - Emission of Polycyclic Aromatic Hydrocarbons from Beech Wood Combustion VL - 35 IS - 4 SP - 328 EP - 336 DO - 10.1080/15567036.2010.503234 ER -
@article{ author = "Đinović-Stojanović, Jasna and Popović, Aleksandar R. and Spiric, A. and Jira, W.", year = "2013", abstract = "This study reports results on 16 EU priority polycyclic aromatic hydrocarbons in smoke produced by beech wood combustion from Zlatibor region, Serbia. Smoke samples were collected with two different types of tubes (PUF and XAD-2), at a height of 2 and 5 m away from the firebox; 16 EU priority polycyclic aromatic hydrocarbons [European Commission (2005), Commission Recommendation 2005/108/EC, Official Journal of European Union L34:4345; JECFA (2005), Summary and Conclusion. Paper No. JECFA/64/SC, Joint FAO/WHO Expert Committee on Food Additives, Sixty-Fourth Meeting, Rome, Italy, February 817] were identified and quantified by Fast-GC/HRMS. The analyzed PAHs were: benzo[c]fluorene (BcL), benzo[a]anthracene (BaA), cyclopenta[c,d]pyrene (CPP), chrysene (CHR), 5-methylchrysene (5MC), benzo[b]fluoranthene (BbF), benzo[j]fluoranthene (BjF), benzo[k]fluoranthene (BkF), benzo[a]pyrene (BaP), benzo[g,h,i]perylene (BgP), dibenzo[a,h]anthracene (DhA), indeno[1,2,3-cd]pyrene (IcP), dibenzo[a,e]pyrene (DeP), dibenzo[a,h]pyrene (DhP), dibenzo[a,i]pyrene (DiP) and dibenzo[a,l]pyrene (DlP). Results show that total emission of polycyclic aromatic hydrocarbons at a height of 2 m was 6.7 and 7.4 mg m3 , in PUF and XAD-2 tubes, respectively. At height of 5 m polycyclic aromatic hydrocarbons emission was 2.4 and 4.3 mg m3 , in PUF and XAD-2 tubes, respectively. BaP contribution to total sum of 16 EU priority polycyclic aromatic hydrocarbons was 4% (PUF tubes) and 7.2% (XAD-2 tubes) at a height of 2 m, and 5% (PUF tubes) and 8.3% (XAD-2 tubes) at a height of 5 m. Total benzo[a]pirene equivalent concentrations (BaPeq) in smoke samples were calculated.", publisher = "Taylor & Francis Inc, Philadelphia", journal = "Energy Sources Part A-Recovery Utilization and Environmental Effects", title = "Emission of Polycyclic Aromatic Hydrocarbons from Beech Wood Combustion", volume = "35", number = "4", pages = "328-336", doi = "10.1080/15567036.2010.503234" }
Đinović-Stojanović, J., Popović, A. R., Spiric, A.,& Jira, W.. (2013). Emission of Polycyclic Aromatic Hydrocarbons from Beech Wood Combustion. in Energy Sources Part A-Recovery Utilization and Environmental Effects Taylor & Francis Inc, Philadelphia., 35(4), 328-336. https://doi.org/10.1080/15567036.2010.503234
Đinović-Stojanović J, Popović AR, Spiric A, Jira W. Emission of Polycyclic Aromatic Hydrocarbons from Beech Wood Combustion. in Energy Sources Part A-Recovery Utilization and Environmental Effects. 2013;35(4):328-336. doi:10.1080/15567036.2010.503234 .
Đinović-Stojanović, Jasna, Popović, Aleksandar R., Spiric, A., Jira, W., "Emission of Polycyclic Aromatic Hydrocarbons from Beech Wood Combustion" in Energy Sources Part A-Recovery Utilization and Environmental Effects, 35, no. 4 (2013):328-336, https://doi.org/10.1080/15567036.2010.503234 . .