Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]
Само за регистроване кориснике
2013
Аутори
Filipović, Nenad R.Borna, Marija
Klisurić, Olivera
Pregelj, Matej
Jagodić, Marko
Anđelković, Katarina K.
Todorović, Tamara
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Copper(II) and zinc(II) complexes with the condensation derivative of 2-acetylpyridine and hydrolyzed ethyl hydrazinoacetate were synthesized in a one pot reaction. Crystal structure of the zinc(II) complex was determined by single-crystal X-ray diffraction. In this binuclear complex, the ligand is coordinated via pyridine and imine nitrogen, while carboxylate oxygen is a bridge between metal centers. The fifth coordination site is occupied by a chloride, giving a distorted square pyramidal geometry around each zinc(II). The molecular structure of the copper(II) complex was determined from elemental analysis, infrared and electron paramagnetic resonance spectroscopy, molar conductivity, mass spectrometry, and measurements of the magnetic moment. Thermal behavior of both complexes was studied by thermogravimetric analysis coupled with mass spectrometer.
Кључне речи:
Copper(II) / Zinc(II) / X-ray analysis / EPR spectroscopy / Thermogravimetric analysisИзвор:
Journal of Coordination Chemistry, 2013, 66, 9, 1549-1560Издавач:
- Taylor & Francis Ltd, Abingdon
Финансирање / пројекти:
- Интеракције природних производа, њихових деривата и комплексних једињења са протеинима и нуклеинским киселинама (RS-MESTD-Basic Research (BR or ON)-172055)
- Max Planck Society
Напомена:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3538
DOI: 10.1080/00958972.2013.786052
ISSN: 0095-8972
WoS: 000318280000008
Scopus: 2-s2.0-84877640099
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Filipović, Nenad R. AU - Borna, Marija AU - Klisurić, Olivera AU - Pregelj, Matej AU - Jagodić, Marko AU - Anđelković, Katarina K. AU - Todorović, Tamara PY - 2013 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1639 AB - Copper(II) and zinc(II) complexes with the condensation derivative of 2-acetylpyridine and hydrolyzed ethyl hydrazinoacetate were synthesized in a one pot reaction. Crystal structure of the zinc(II) complex was determined by single-crystal X-ray diffraction. In this binuclear complex, the ligand is coordinated via pyridine and imine nitrogen, while carboxylate oxygen is a bridge between metal centers. The fifth coordination site is occupied by a chloride, giving a distorted square pyramidal geometry around each zinc(II). The molecular structure of the copper(II) complex was determined from elemental analysis, infrared and electron paramagnetic resonance spectroscopy, molar conductivity, mass spectrometry, and measurements of the magnetic moment. Thermal behavior of both complexes was studied by thermogravimetric analysis coupled with mass spectrometer. PB - Taylor & Francis Ltd, Abingdon T2 - Journal of Coordination Chemistry T1 - Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2] VL - 66 IS - 9 SP - 1549 EP - 1560 DO - 10.1080/00958972.2013.786052 ER -
@article{ author = "Filipović, Nenad R. and Borna, Marija and Klisurić, Olivera and Pregelj, Matej and Jagodić, Marko and Anđelković, Katarina K. and Todorović, Tamara", year = "2013", abstract = "Copper(II) and zinc(II) complexes with the condensation derivative of 2-acetylpyridine and hydrolyzed ethyl hydrazinoacetate were synthesized in a one pot reaction. Crystal structure of the zinc(II) complex was determined by single-crystal X-ray diffraction. In this binuclear complex, the ligand is coordinated via pyridine and imine nitrogen, while carboxylate oxygen is a bridge between metal centers. The fifth coordination site is occupied by a chloride, giving a distorted square pyramidal geometry around each zinc(II). The molecular structure of the copper(II) complex was determined from elemental analysis, infrared and electron paramagnetic resonance spectroscopy, molar conductivity, mass spectrometry, and measurements of the magnetic moment. Thermal behavior of both complexes was studied by thermogravimetric analysis coupled with mass spectrometer.", publisher = "Taylor & Francis Ltd, Abingdon", journal = "Journal of Coordination Chemistry", title = "Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]", volume = "66", number = "9", pages = "1549-1560", doi = "10.1080/00958972.2013.786052" }
Filipović, N. R., Borna, M., Klisurić, O., Pregelj, M., Jagodić, M., Anđelković, K. K.,& Todorović, T.. (2013). Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]. in Journal of Coordination Chemistry Taylor & Francis Ltd, Abingdon., 66(9), 1549-1560. https://doi.org/10.1080/00958972.2013.786052
Filipović NR, Borna M, Klisurić O, Pregelj M, Jagodić M, Anđelković KK, Todorović T. Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]. in Journal of Coordination Chemistry. 2013;66(9):1549-1560. doi:10.1080/00958972.2013.786052 .
Filipović, Nenad R., Borna, Marija, Klisurić, Olivera, Pregelj, Matej, Jagodić, Marko, Anđelković, Katarina K., Todorović, Tamara, "Synthesis, characterization, and thermal behavior of Cu(II) and Zn(II) complexes with (E)-2-[N-(1-pyridin-2-yl-ethylidene)hydrazino]acetic acid (aphaOH). Crystal structure of [Zn-2(aphaO)(2)Cl-2]" in Journal of Coordination Chemistry, 66, no. 9 (2013):1549-1560, https://doi.org/10.1080/00958972.2013.786052 . .