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dc.creatorSavić, Aleksandar
dc.creatorBaroud, Afya A.
dc.creatorGrgurić-Šipka, Sanja
dc.date.accessioned2018-11-22T00:27:58Z
dc.date.available2018-11-22T00:27:58Z
dc.date.issued2014
dc.identifier.issn1857-5552
dc.identifier.urihttps://cherry.chem.bg.ac.rs/handle/123456789/1778
dc.description.abstractThe new bipyridyl complex of ruthenium(II) with O, O'-diethyl-(S, S)-ethylenediamine- N, N'-di- 2(3-cyclohexyl) propanoate was synthesized. The reaction of cis-[RuCl2(bpy)(2)] and its ligand was performed in water/ethanol solution, in the presence of lithium hydroxide, under reflux. After the addition of ammonium hexafluorophosphate, the complex was precipitated. The complex, cis-[Ru(bpy)(2)L](PF6)(2), was characterized by H-1 and C-13 NMR, UV-Vis, IR spectroscopy, ESI-MS spectrometry and elemental analysis. Results indicate an octahedral geometry of the complex, with N, N'-coordinated O, O'- diethyl-(S, S)ethylenediamine-N, N'-di- 2-(3-cyclohexyl) propanoate. Complexes of this type are particularly important in terms of potential cytotoxicity and application in photodynamic therapy. Using this therapy, many side effects can be reduced, which may allow the administration of higher drug dosages.en
dc.publisherSoc Chemists Technologists Madeconia, Skopje
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172035/RS//
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc/4.0/
dc.sourceMacedonian Journal of Chemistry and Chemical Engineering
dc.subjectruthenium(II) complexesen
dc.subjectedda-type liganden
dc.subjectphotodynamic therapyen
dc.titleThe New Ruthenium(Ii)-Bipyridyl Complex with O,O '-Diethyl-(S,S)Ethylenediamine-N,N '-Di-2-(3-Cyclohexyl)Propanoate: Synthesis and Characterizationen
dc.typearticle
dc.rights.licenseBY-NC
dcterms.abstractСавић, Aлександар; Бароуд, Aфyа A.; Гргурић-Шипка, Сања;
dc.citation.volume33
dc.citation.issue1
dc.citation.spage59
dc.citation.epage64
dc.identifier.wos000336241300006
dc.identifier.doi10.20450/mjcce.2014.424
dc.citation.other33(1): 59-64
dc.citation.rankM23
dc.type.versionpublishedVersion
dc.identifier.scopus2-s2.0-84902580817
dc.identifier.fulltexthttps://cherry.chem.bg.ac.rs/bitstream/id/8838/1776.pdf
dc.identifier.rcubKon_2661


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