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dc.creatorŠumar-Ristović, Maja
dc.creatorMinić, Dragica M.
dc.creatorBlagojević, Vladimir A.
dc.creatorAnđelković, Katarina K.
dc.date.accessioned2018-11-22T00:28:38Z
dc.date.available2018-11-22T00:28:38Z
dc.date.issued2014
dc.identifier.issn0350-820X
dc.identifier.urihttp://cherry.chem.bg.ac.rs/handle/123456789/1818
dc.description.abstractThermal decomposition of Co(II) complex with N-benzyloxycarbonylglycinato ligand, [Co(N-Boc-gly)(2)(H2O)(4)]center dot 2H(2)O, in non-isothermal conditions occurs in three complex steps. In order to investigate detail kinetics of first two steps, dehydration and ligand degradation, DTG curves were deconvoluted using product of Gaussian and Lorentzian function. It was shown that process of complex dehydration consists of three, while process of ligand fragmentation consist of five elementary steps. For elementary steps the kinetic triplet (E-a, Z and f(alpha)) was determinated. Kinetic parameters were obtained by application of IKP method. On the basis of Malek's criteria and Sestak-Berggren's method, Sestak-Berggren's model, f(alpha)=alpha(M)(1-alpha)(N) was suggested for all elementary steps, while Master plot method and Perez-Maqueda criteria confirmed suggested reaction models. The thermodynamic activation parameters were calculated for process of complex dehydration, and lifetime for first elementary step of the dehydration and ligand degradation processes was estimated.en
dc.publisherInt Inst Science Sintering (I I S S), Belgrade
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172055/RS//
dc.rightsopenAccess
dc.sourceScience of Sintering
dc.subjectKineticsen
dc.subjectCo-N-benzyloxycarbonylglycinato complexen
dc.subjectThermal degradationen
dc.subjectDTG curves deconvolutionen
dc.titleKinetics of Multi-Step Processes of Thermal Degradation of Co(II) Complex With N-Benzyloxycarbonylglycinato Ligand. Deconvolution of DTG Curvesen
dc.typearticle
dc.rights.licenseBY
dcterms.abstractМиниц, Д. М.; Шумар-Ристовић, Маја; Благојевиц, В.; Aнђелковић, Катарина;
dc.citation.volume46
dc.citation.issue1
dc.citation.spage37
dc.citation.epage53
dc.identifier.wos000339449400004
dc.identifier.doi10.2298/SOS1401037S
dc.citation.other46(1): 37-53
dc.citation.rankM23
dc.type.versionpublishedVersion
dc.identifier.scopus2-s2.0-84899688344
dc.identifier.fulltexthttp://cherry.chem.bg.ac.rs/bitstream/id/8875/1816.pdf
dc.identifier.rcubKon_2701


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