Приказ основних података о документу

dc.creatorBaranac-Stojanović, Marija
dc.date.accessioned2018-11-22T00:29:35Z
dc.date.available2018-11-22T00:29:35Z
dc.date.issued2014
dc.identifier.issn2046-2069
dc.identifier.urihttps://cherry.chem.bg.ac.rs/handle/123456789/1878
dc.description.abstractThe origin of the gauche preference in 1,2-difluoroethane has been investigated by using an energy decomposition analysis (EDA). The EDA results show that favourable orbital interactions are not the sole source of stabilization in this conformer. Electrostatic interactions, too, are more attractive in the gauche than in the anti form. This finding opposes our traditional view of electrostatic interactions and their influence on conformational equilibria, but points out that they should be considered as an all-charge phenomenon, rather than partial interaction between pairs of bonds.en
dc.publisherRoyal Soc Chemistry, Cambridge
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172020/RS//
dc.rightsrestrictedAccess
dc.sourceRSC Advances
dc.titleGauche preference in 1,2-difluoroethane originates from both orbital and electrostatic stabilization interactionsen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractБаранац-Стојановић, Марија;
dc.citation.volume4
dc.citation.issue83
dc.citation.spage43834
dc.citation.epage43838
dc.identifier.wos000344527300004
dc.identifier.doi10.1039/c4ra07909d
dc.citation.other4(83): 43834-43838
dc.citation.rankM21
dc.type.versionpublishedVersion
dc.identifier.scopus2-s2.0-84907653016


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Приказ основних података о документу