Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen
Само за регистроване кориснике
2015
Аутори
Marković, MarijanaJović, Milica
Stanković, Dalibor
Kovačević, Vesna V.
Roglić, Goran
Gojgić-Cvijović, Gordana D.
Manojlović, Dragan D.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Pharmaceutical compounds have been detected frequently in surface and ground water. Advanced Oxidation Processes (AOPs) were reported as very efficient for removal of various organic compounds. Nevertheless, due to incomplete degradation, toxic intermediates can induce more severe effects than the parent compound. Therefore, toxicity studies are necessary for the evaluation of possible uses of AOPs. In this study the effectiveness and capacity for environmental application of three different AOPs were estimated. They were applied and evaluated for removal of ibuprofen from water solutions. Therefore, two treatments were performed in a non-thermal plasma reactor with dielectric barrier discharge with and without a homogenous catalyst (Fe2+). The third treatment was the Fenton reaction. The degradation rate of ibuprofen was measured by HPLC-DAD and the main degradation products were identified using LC-MS TOF. Twelve degradation products were identified, and there were differences accord...ing to the various treatments applied. Toxicity effects were determined with two bioassays: Vibrio fischeri and Artemia salina. The efficiency of AOPs was demonstrated for all treatments, where after 15 min degradation percentage was over 80% accompanied by opening of the aromatic ring. In the treatment with homogenous catalyst degradation reached 99%. V. fischeri toxicity test has shown greater sensitivity to ibuprofen solution after the Fenton treatment in comparison to A. salina. (C) 2014 Elsevier B.V. All rights reserved.
Кључне речи:
AOPs / Non-thermal plasma / Ibuprofen removal / Toxicity / V. fischeri / A. salinaИзвор:
Science of the Total Environment, 2015, 505, 1148-1155Издавач:
- Elsevier Science Bv, Amsterdam
Финансирање / пројекти:
- Примена унапређених оксидационих процеса и наноструктурисаних оксидних материјала за уклањање загађивача из животне средине, развој и оптимизација инструменталних техника за праћење ефикасности (RS-MESTD-Basic Research (BR or ON)-172030)
- Дијагностика и оптимизација извора плазме значајних за примене (RS-MESTD-Basic Research (BR or ON)-171034)
- Интегрисани системи за уклањање штетних састојака дима и развој технологија за реализацију термоелектрана и енергана без аерозагађења (RS-MESTD-Technological Development (TD or TR)-33022)
- Симултана биоремедијација и соилификација деградираних простора, за очување природних ресурса биолошки активних супстанци и развој и производњу биоматеријала и дијететских производа (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43004)
DOI: 10.1016/j.scitotenv.2014.11.017
ISSN: 0048-9697
PubMed: 25466684
WoS: 000347654900113
Scopus: 2-s2.0-84915749003
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Marković, Marijana AU - Jović, Milica AU - Stanković, Dalibor AU - Kovačević, Vesna V. AU - Roglić, Goran AU - Gojgić-Cvijović, Gordana D. AU - Manojlović, Dragan D. PY - 2015 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1898 AB - Pharmaceutical compounds have been detected frequently in surface and ground water. Advanced Oxidation Processes (AOPs) were reported as very efficient for removal of various organic compounds. Nevertheless, due to incomplete degradation, toxic intermediates can induce more severe effects than the parent compound. Therefore, toxicity studies are necessary for the evaluation of possible uses of AOPs. In this study the effectiveness and capacity for environmental application of three different AOPs were estimated. They were applied and evaluated for removal of ibuprofen from water solutions. Therefore, two treatments were performed in a non-thermal plasma reactor with dielectric barrier discharge with and without a homogenous catalyst (Fe2+). The third treatment was the Fenton reaction. The degradation rate of ibuprofen was measured by HPLC-DAD and the main degradation products were identified using LC-MS TOF. Twelve degradation products were identified, and there were differences according to the various treatments applied. Toxicity effects were determined with two bioassays: Vibrio fischeri and Artemia salina. The efficiency of AOPs was demonstrated for all treatments, where after 15 min degradation percentage was over 80% accompanied by opening of the aromatic ring. In the treatment with homogenous catalyst degradation reached 99%. V. fischeri toxicity test has shown greater sensitivity to ibuprofen solution after the Fenton treatment in comparison to A. salina. (C) 2014 Elsevier B.V. All rights reserved. PB - Elsevier Science Bv, Amsterdam T2 - Science of the Total Environment T1 - Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen VL - 505 SP - 1148 EP - 1155 DO - 10.1016/j.scitotenv.2014.11.017 ER -
@article{ author = "Marković, Marijana and Jović, Milica and Stanković, Dalibor and Kovačević, Vesna V. and Roglić, Goran and Gojgić-Cvijović, Gordana D. and Manojlović, Dragan D.", year = "2015", abstract = "Pharmaceutical compounds have been detected frequently in surface and ground water. Advanced Oxidation Processes (AOPs) were reported as very efficient for removal of various organic compounds. Nevertheless, due to incomplete degradation, toxic intermediates can induce more severe effects than the parent compound. Therefore, toxicity studies are necessary for the evaluation of possible uses of AOPs. In this study the effectiveness and capacity for environmental application of three different AOPs were estimated. They were applied and evaluated for removal of ibuprofen from water solutions. Therefore, two treatments were performed in a non-thermal plasma reactor with dielectric barrier discharge with and without a homogenous catalyst (Fe2+). The third treatment was the Fenton reaction. The degradation rate of ibuprofen was measured by HPLC-DAD and the main degradation products were identified using LC-MS TOF. Twelve degradation products were identified, and there were differences according to the various treatments applied. Toxicity effects were determined with two bioassays: Vibrio fischeri and Artemia salina. The efficiency of AOPs was demonstrated for all treatments, where after 15 min degradation percentage was over 80% accompanied by opening of the aromatic ring. In the treatment with homogenous catalyst degradation reached 99%. V. fischeri toxicity test has shown greater sensitivity to ibuprofen solution after the Fenton treatment in comparison to A. salina. (C) 2014 Elsevier B.V. All rights reserved.", publisher = "Elsevier Science Bv, Amsterdam", journal = "Science of the Total Environment", title = "Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen", volume = "505", pages = "1148-1155", doi = "10.1016/j.scitotenv.2014.11.017" }
Marković, M., Jović, M., Stanković, D., Kovačević, V. V., Roglić, G., Gojgić-Cvijović, G. D.,& Manojlović, D. D.. (2015). Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen. in Science of the Total Environment Elsevier Science Bv, Amsterdam., 505, 1148-1155. https://doi.org/10.1016/j.scitotenv.2014.11.017
Marković M, Jović M, Stanković D, Kovačević VV, Roglić G, Gojgić-Cvijović GD, Manojlović DD. Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen. in Science of the Total Environment. 2015;505:1148-1155. doi:10.1016/j.scitotenv.2014.11.017 .
Marković, Marijana, Jović, Milica, Stanković, Dalibor, Kovačević, Vesna V., Roglić, Goran, Gojgić-Cvijović, Gordana D., Manojlović, Dragan D., "Application of non-thermal plasma reactor and Fenton reaction for degradation of ibuprofen" in Science of the Total Environment, 505 (2015):1148-1155, https://doi.org/10.1016/j.scitotenv.2014.11.017 . .